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4-(Tert-Butyl)-1,2-Diaminobenzene

    • Product Name 4-(Tert-Butyl)-1,2-Diaminobenzene
    • Alias 4-TBDA
    • Einecs 211-777-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    513491

    Chemical Name 4-(Tert-Butyl)-1,2-diaminobenzene
    Cas Number 21406-56-0
    Molecular Formula C10H16N2
    Molecular Weight 164.25
    Appearance Off-white to light yellow solid
    Melting Point 110-115°C
    Solubility Slightly soluble in water; soluble in common organic solvents
    Storage Conditions Store at room temperature, tightly closed, in a dry place
    Synonyms 2,3-Diamino-4-tert-butylbenzene
    Pubchem Cid 14447580
    Inchi Key BNRUOVFMINUCIK-UHFFFAOYSA-N

    As an accredited 4-(Tert-Butyl)-1,2-Diaminobenzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, tightly sealed, labeled with chemical name, hazard symbols, and batch details; contains 25 grams of 4-(Tert-Butyl)-1,2-Diaminobenzene.
    Shipping 4-(Tert-Butyl)-1,2-Diaminobenzene is shipped in tightly sealed containers to prevent moisture and air exposure. It is packaged in accordance with chemical safety regulations, labeled appropriately, and handled by trained personnel. Shipping typically follows ground or air transport guidelines for non-hazardous chemicals, ensuring product integrity during transit.
    Storage Store 4-(tert-Butyl)-1,2-diaminobenzene in a tightly sealed container, under cool, dry conditions and away from light. Keep it in a well-ventilated area, separated from incompatible substances such as strong oxidizers and acids. Protect from moisture and ignition sources. Clearly label the storage container, and ensure access is restricted to trained personnel using proper personal protective equipment.
    Application of 4-(Tert-Butyl)-1,2-Diaminobenzene

    Applications of 4-(Tert-Butyl)-1,2-Diaminobenzene in Industrial Manufacturing

    We supply 4-(Tert-Butyl)-1,2-Diaminobenzene directly from our production facility to leading global manufacturers who rely on its high purity and performance consistency across a range of downstream industries. Below we outline established, real-world application segments where downstream producers utilize this intermediate, based on validated chemical processes and end-market product requirements.

    1. High-Performance Epoxy Curing Agents for Coatings

    Formulators in the industrial coatings sector incorporate this aromatic diamine as a key component in two-component epoxy hardeners requiring accelerated room-temperature cure and enhanced resistance to yellowing. Performance coatings for infrastructure and heavy-duty industrial floors depend on blends where thermal and chemical durability are prioritized for long-lasting protection.

    Industry compliance standards

    • ISO 12944 for corrosion protection of steel structures
    • CE Marking for construction products (Regulation EU No 305/2011)
    • REACH Annex XVII (chemicals restrictions and SVHC screening)
    • ASTM D4226 and D1308 for chemical resistance and compatibility testing

    Typical usage ratio

    • 5–18% of total epoxy hardener component, depending on required cure speed and final film properties; adjusted according to resin epoxide equivalent weight and working temperature.

    Downstream process integration

    • Blended with polyamide or cycloaliphatic amine adducts during the formulation of two-component epoxy systems; incorporated at the pre-mixing stage before end-user application to facilitate controlled curing kinetics.

    Final product types

    • High-build industrial floor coatings
    • Chemical-resistant tank linings
    • Protective anti-corrosion primers for steel structures
    • Heavy-duty machine coatings and adhesives

    2. Organic Intermediate for Specialty Dye and Pigment Synthesis

    Dye manufacturers use this diamine as a critical building block in synthesizing anthraquinone, azo, and specialty metal complex dyes. Its sterically hindered nature enables the creation of chromophores with vivid color intensity and enhances lightfastness properties for demanding textile and plastic coloration applications.

    Industry compliance standards

    • OEKO-TEX Standard 100 (textile chemical safety)
    • ZDHC Manufacturing Restricted Substances List (MRSL)
    • EU Regulation (EC) No 1907/2006 (REACH registration for dye intermediates)
    • EN 71-3 (Migration of certain elements in toys and children’s products)

    Typical usage ratio

    • Varies from 1.5–6% of dye batch mass depending on target pigment shade and reactivity; formulation ratios refined after laboratory color matching and alkali/acid resistance tests.

    Downstream process integration

    • Employed in diazotization and coupling steps during multi-step synthesis of advanced dyes and pigments; introduced as the first amination substrate or as a finishing component for specific tone adjustment after initial condensation reactions.

    Final product types

    • Disperse dyes for polyester fibers
    • Solvent-soluble metal complex dyes for inks
    • Organic pigments for engineering plastics coloration
    • High-performance colorants for synthetic leather and packaging films

    3. Antioxidant Additive Manufacturing for Lubricant Formulations

    Lubricant compounders select this material for use as a precursor in the synthesis of aminic antioxidants, which inhibit thermal degradation under severe engine or industrial conditions. The bulky tert-butyl group confers superior oxidation stability, especially in high-temperature lubricant systems for automotive and power generation applications.

    Industry compliance standards

    • API SN/CF (lubricant performance classification)
    • ACEA 2016 Oil Sequences
    • ILSAC GF-6 for automotive engine oils
    • ISO 6743-4 (classification of lubricants, industrial oils, and related products)

    Typical usage ratio

    • 0.1–0.7% antioxidant content relative to base oil weight; exact proportion tailored to sulfur, phosphorus, and ash content limits as well as target oxidation test thresholds.

    Downstream process integration

    • Converted in situ or externally into aminic antioxidants, then introduced to base stock during the final blending or post-filtration stage of finished lubricant oil compounding.

    Final product types

    • Fully-formulated engine oils (synthetic, semi-synthetic, mineral oil-based)
    • Hydraulic fluids for industrial machinery
    • Automatic transmission fluids (ATF)
    • Heavy-duty gear oils

    4. Photoinitiator Intermediate for UV-Curable Monomer Resins

    Specialty chemical manufacturers rely on this diamine in the synthesis of certain photoinitiator compounds, where its electron-donating structure tunes reactivity for fast-curing UV monomer and oligomer resin systems. The material supports manufacturing of coatings, adhesives, and 3D printing resins with rapid polymerization and low yellowing under LED or mercury UV exposure.

    Industry compliance standards

    • ISO 9001 (Quality Management System for chemical production)
    • RoHS 2 Directive 2011/65/EU (restriction of hazardous substances in electrical and electronic equipment)
    • IEC 61215/61730 for materials used in photovoltaic module encapsulants
    • FDA 21 CFR 175.300 (resinous and polymeric coatings for indirect food contact, for relevant end-uses)

    Typical usage ratio

    • Integrated into photoinitiator synthesis at 10–20 mole% stoichiometry relative to other amine donors; resulting photoinitiator concentration in the final UV-curable resin is usually 0.2–2% by weight, adjusted for application thickness and lamp intensity.

    Downstream process integration

    • Synthesized into multi-component photoinitiator blends prior to resin compounding; photoinitiator masterbatch added during stage-wise formulation of UV-curable monomer and oligomer blends for industrial scale-up.

    Final product types

    • UV-curable coatings for electronic device housings
    • Photopolymer resins for SLA/DLP 3D printing
    • Clear adhesives and varnishes for electronics or automotive assembly
    • Encapsulant resins for photovoltaic modules and optoelectronics

    5. Intermediate for Specialty Polybenzoxazole and Polybenzimidazole Polymer Synthesis

    High-performance polymer manufacturers employ this aromatic diamine in the production of specialty engineering resins such as polybenzoxazoles (PBO) and polybenzimidazoles (PBI). Its molecular structure lends thermal stability and resistance to oxidation, supporting the creation of polymers for applications exposed to extreme chemical and heat stress in aerospace and industrial processing.

    Industry compliance standards

    • NADCAP (National Aerospace and Defense Contractors Accreditation Program) for polymer processing
    • EN ISO 1043 (classification of plastics by chemical structure)
    • ASTM D5207 (testing of PBI polymers)
    • UL 94 (flammability of polymeric materials)

    Typical usage ratio

    • Maintained at 0.85–1.10 molar equivalents relative to diacid chloride comonomers; fine-tuned to achieve desired molecular weight and mechanical performance in PBO and PBI synthesis runs.

    Downstream process integration

    • Charged during the polycondensation stage under inert atmosphere; reacts with dicarboxylic acid chlorides or derivatives in high-boiling polar solvents before post-polymerization purification and engineering granule formation.

    Final product types

    • High-strength PBO fibers for cut-resistant protective gear
    • PBI molded parts and films for aerospace applications
    • High-temperature filter bag media for chemical processing
    • Reinforced polymer composites for semiconductor wafer carriers
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    Certification & Compliance
    More Introduction

    4-(Tert-Butyl)-1,2-Diaminobenzene: Consistency, Craftsmanship, and Experience

    What Our Decades of Manufacturing Have Shown Us About 4-(Tert-Butyl)-1,2-Diaminobenzene

    As a manufacturer with many years working hands-on with aromatic diamines, we have watched 4-(Tert-Butyl)-1,2-Diaminobenzene transform from a specialty chemical in niche research to a standard compound supporting countless syntheses and technological advances. Our team handles the actual process from raw material intake to finished product delivery, so every batch passing through our plant reflects a keen understanding of the subtleties that make the difference between average and reliable.

    Product Overview: Model and Specifications Developed for Practical Lab and Plant Use

    Over the years, we have settled on production standards that consistently deliver technical and high-purity grades of 4-(Tert-Butyl)-1,2-Diaminobenzene. The model ABTBD-100, as manufactured here, demonstrates how tight process control results in a fine crystalline powder with a distinctive pale yellow hue. Typical purity ranges exceed 98.5%, with trace impurities kept at low levels by strict raw material selection, solvent management, and analytical checkpoints. This purity is vital for chemists looking to achieve controlled syntheses, especially in pharmaceutical and advanced materials research.

    Specification testing relies not just on instrumentation but experience—our operators have recognized subtle changes in melting range or crystallization state that signal a problem before the data shows deviation. Each lot undergoes melting point analysis, HPLC and GC checks, and advanced spectroscopic examination. Customers working at small scale in academia or scaling up for pilot plant production have indicated how consistent test results save significant troubleshooting time on their end.

    Usage Insights from the Manufacturer’s Floor

    In actual use, 4-(Tert-Butyl)-1,2-Diaminobenzene goes far beyond the catalog entry. Its structure, with both amino groups placed ortho and meta to the tert-butyl substituent, opens up flexibility in coupling reactions. Process chemists prefer it for selective N-alkylation, C–N cross-coupling, and as a precursor in manufacturing high-performance materials such as certain polyimides. Synthetic organic labs tell us the tert-butyl group enhances both solubility and resistance to over-oxidation. We have received feedback from medicinal chemistry teams confirming that the increased steric bulk at the para position makes it a preferred scaffold for selective ligand or polymer synthesis, staving off unwanted side reactions.

    Beyond laboratory syntheses, companies focused on dyes and pigments use our product as an intermediate for new chromophores. These applications test batch-to-batch consistency to its limits because subtle structural inconsistencies or residual contaminants can introduce unpredictable color impurities or affect polymerization. As the manufacturer, we integrate additional washing steps and closed-system crystallization to meet these advanced requirements. Our technical support team maintains contacts with production chemists at customer facilities to directly gather use-case issues and propose fine-tuning of our own steps in response.

    Differences That Matter: 4-(Tert-Butyl)-1,2-Diaminobenzene and Related Diamines

    Comparing 4-(Tert-Butyl)-1,2-Diaminobenzene to other aromatic diamines like o-phenylenediamine or m-phenylenediamine helps clarify its niche—and reveals where our product stands out. Engineers at our site have noticed that the tert-butyl substituent confers greater solubility in organic solvents such as toluene and dichloromethane, resulting in more straightforward reaction clean-up. This property also reduces the frequency of tar formation during high-temperature reactions, which we have confirmed via internal plant trials. In contrast, basic phenylenediamines tend to deposit more residue, increasing vessel cleaning time and maintenance costs.

    Our research teams observed that the “4-(tert-butyl)” architecture enhances selectivity in catalytic asymmetric transformations. In complex-molecule construction, such precision translates to a higher yield of the desired regioisomer or stereoisomer. Researchers working on high-purity pharmaceuticals use this property to cut down the number of purification steps.

    Some customers ask why one should not simply use a more readily available diamine. Our answer, drawn from direct involvement in both our process and our customers’ reactions, is that substituent pattern controls more than just reactivity—it drives operational efficiency and impacts the quality of downstream products. We invite technical users to compare typical product losses across steps, as many of the process headaches come from overlooked interactions between functional groups and the presence of persistent impurities or residual water. The way we manage these with targeted drying, direct nitrogen-purging, and specific anti-oxidant additions has evolved from daily feedback, hands-on troubleshooting, and joint development with our most demanding customers.

    Direct Dialogue with the End User: Plant-Level Manufacturing Insight

    Batches of 4-(Tert-Butyl)-1,2-Diaminobenzene leaving our plant represent not just a set of numbers on a specification sheet, but a history of challenge and solution. Equipment operators here are the first to know if a feedstock lot smells off, if a filter cake looks lumpy, or if a crystallization vessel’s temperature profile needs tweaking. This next-level attention prevents costly recalls and quality complaints long before a bottle ever reaches a customer’s bench.

    We keep daily logs on all pertinent details, from the appearance and scent of intermediates, to subtle shifts in melting point. Such diligence has made a measurable impact: some customers have reported a drop in their out-of-spec product issues by more than half upon switching to our regularly tested and tracked lots. Repeat orders have grown out of this reliability, especially from labs where every gram must perform precisely as expected. Our approach, based on thorough, regular feedback from chemistry and engineering teams, outpaces competitors who lack direct, ongoing involvement in both manufacturing and end-use troubleshooting.

    Experience Handles the Nuances: Environmental and Safety Considerations

    Anyone manufacturing aromatic diamines recognizes the significance of precise handling protocols. 4-(Tert-Butyl)-1,2-Diaminobenzene, with its amine functionalities, requires careful environmental controls and process safety diligence. Plant ventilation gets regular upgrades and staff training includes repeated review of spill and exposure procedures. Every production zone features specifically designed barriers and redundant containment for volatiles. We process waste streams with in-house advanced oxidation and biological treatment units, given the product’s resistance to standard bacterial breakdown. On the logistics side, only trusted carriers receive finished goods, and our barrels come with tamper-evident features and tailored labeling.

    Customers experimenting with scaling from grams to kilograms have found direct value in our technical guidance—our plant’s deep library of incident records informs recommendations on safe storage, controlled addition, and real-time monitoring practices during use. This includes simple, actionable advice, such as preferred packaging types for different climate zones and how to set up a receiving station that limits personnel exposure without reducing throughput.

    Supporting Innovation Through Real-World Collaboration

    No textbook or datasheet can substitute for lived experience. Over the years, our partnerships with universities, process developers, and application engineers have allowed us to anticipate evolving needs in catalysis, polymer chemistry, and dye manufacture. Product development meetings often start by dissecting practical problems: stalled reactions, repeat filtration troubles, color instability. Adjustments are mapped out together, and our pilot plant integrates new findings to fine-tune each production run.

    Long-term clients often bring prototype ideas for custom blends or ask us to push purity levels beyond standard offerings. We offer controlled pilot batches with additional analytical support, accommodating custom requests for trace impurity profiles, packaging weights, or stability studies. Such requests fuel our own internal R&D, as we scale up promising results for wider release. Solutions are not handed down from a salesman’s desk, but evolve from face-to-face meetings with users who understand the impact of every percent gained in consistency, reaction rate, or shelf-life extension.

    More recently, customers developing next-generation OLED materials and specialty polyimides have pointed out that 4-(Tert-Butyl)-1,2-Diaminobenzene’s unique reactivity profile helps address roadblocks in forming extended conjugated structures or achieving new color shades. Our process chemists have adjusted solvent ratios, temperature ramps, and batch dwell times in response to these challenges, delivering a reliable starting material that minimizes side-product formation and off-hue issues. As a result, some of the latest functional material launches rely on our product’s predictable performance.

    True Manufacturing: From Raw Material to Final Application

    Raw material selection remains one of the most critical contributions we make to the product’s final character. We never substitute lower-grade starting materials, even if prices rise in the global market. Each consignment entering our facility is checked for both chemical makeup and physical appearance; unacceptable lots are returned before even entering the process stage. This commitment shapes every subsequent step—from solvent system maintenance (no recycled solvents here) to batch-by-batch monitoring for trace metals, chlorides, and potential airborne contaminants.

    Our synthesis runs in fully enclosed, atmospheric-pressure reactors. Each charge follows a validated protocol, but shop-floor operators still watch for unexpected changes—foaming, unexpected gas evolution, or minor heat output increases. The crystalline end-product is subjected to stepwise purification and vacuum drying to drive off moisture, ensuring low water content in the final powder. Each lot is packaged with inert gas blanketing until opened by the end user. The hands-on manufacturing experience means we have direct knowledge of actual product behavior—not just what’s written on a specification file.

    Detailed Application Support: Working with Chemists at Every Scale

    We routinely work with researchers who attempt to scale up successful experiments only to encounter new obstacles with material consistency, contamination, or unexpected sensitivity to temperature or moisture. Technicians on our end take customer calls directly, often reviewing chromatograms or NMR data alongside lab staff at the customer site, pinpointing whether deviations come from ambient conditions, cross-contamination from previous syntheses, or subtle shifts in handling during transfer. Through such collaborations, tweaks to drying regimens, customized packaging size, or alternate anti-oxidant additions are implemented.

    Each application—small-molecule drug synthesis, engineering thermosets, high-efficiency dyes, or catalytic intermediates—demands unique modifications. Rather than dictating solutions, we draw from years of batch data and operational memories to suggest what has worked under similar conditions. Our involvement in several published syntheses and scale-up trials has established benchmarks not easily matched by less experienced suppliers or resellers who rely on only generic product sheets.

    Continuous Improvement and Customer-Centered Manufacturing

    Long-standing relationships with demanding industrial users have strengthened both our process and our commitment to improvement. We solicit feedback beyond surface-level satisfaction—our provable metrics include time to resolution for reported issues and number of successful repeat orders from audited customers. This willingness to listen and act on direct, practical experience means our 4-(Tert-Butyl)-1,2-Diaminobenzene adapts in response to changes in the marketplace, new research directions, or evolving regulatory standards. Improvements to solvent management have reduced trace residuals, while new anti-static packaging options address powder handling concerns at customer sites. We have also invested in expanded analytical facilities onsite to catch micro-level contamination before it can impact downstream uses.

    Adapting our process further, we instituted a customer-driven annual review session, inviting major buyers to inspect our site, review process logs, and offer suggestions unfiltered by marketing staff. Many of the best process tweaks—such as introducing isolated drying compartments for enhanced product flowability—originated directly from these meetings. This tradition not only supports the customer’s success but drives our continual evolution as both a partner and a producer.

    The Trust Built Through Direct Manufacturing: Why It Matters

    At the end of the day, anyone working with fine chemicals learns to distinguish between glossy claims and lived reliability. Our position as direct manufacturer of 4-(Tert-Butyl)-1,2-Diaminobenzene means we stand behind technical data with firsthand experience. We do not rely on a chain of brokers, resellers, or remote warehouses; everything offered comes through our own process, measured and checked by people with names and faces. Our approach supports both routine and breakthrough applications because we have shaped the product to respond to real-world constraints and opportunities.

    Issues with resin color instability, difficult reaction clean-ups, or inconsistent product grades are well-known to anyone making or consuming aromatic diamines. Experience shows that sourcing directly from a manufacturer who controls every step reduces the surprises, cuts downtime, and supports both innovation and operational stability. Our engagement continues, shaped by decades of production floor learning, technical adaptability, and trusted user feedback.