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4-Methylphthalic Acid

    • Product Name 4-Methylphthalic Acid
    • Alias 4-Methylbenzene-1,2-dicarboxylic acid
    • Einecs 214-488-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    121287

    Productname 4-Methylphthalic Acid
    Casnumber 4955-35-7
    Molecularformula C9H8O4
    Molecularweight 180.16 g/mol
    Appearance White to off-white solid
    Meltingpoint 218-222 °C
    Solubility Slightly soluble in water, soluble in organic solvents
    Iupacname 4-methylphthalic acid
    Smiles CC1=CC=C(C=C1)C(C(=O)O)=O
    Inchi InChI=1S/C9H8O4/c1-6-2-4-7(5-3-6)8(10)9(11)12/h2-5H,1H3,(H,11,12)
    Pubchemcid 108669
    Synonyms 4-Methyl-1,2-benzenedicarboxylic acid

    As an accredited 4-Methylphthalic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g of 4-Methylphthalic Acid is packaged in a sealed, amber glass bottle with tamper-evident cap and clear labeling.
    Shipping 4-Methylphthalic Acid is typically shipped in tightly sealed containers, protected from moisture and direct sunlight. It should be labeled with appropriate hazard information and handled according to safety regulations for chemicals. During shipping, it is kept at room temperature and secured against physical damage or spills to ensure safe transport.
    Storage 4-Methylphthalic acid should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from incompatible substances such as strong oxidizers. Protect from moisture and direct sunlight. Ensure containers are clearly labeled, and handle with appropriate personal protective equipment. Avoid inhalation, ingestion, and contact with skin or eyes. Store at room temperature, away from sources of ignition.
    Application of 4-Methylphthalic Acid

    Applications of 4-Methylphthalic Acid in Industrial Manufacturing

    4-Methylphthalic acid serves as a specialty intermediate in multiple industrial sectors, playing a critical role in advanced chemical formulations and precise synthesis processes. As a vertically integrated manufacturer, we supply high-purity grades designed for the requirements of each downstream segment described below, with attention to regulatory obligations, compositional needs, and production flows.

    1. Engineering Plastics Monomer Modification

    In the development of engineering plastics, formulators use 4-methylphthalic acid to introduce steric modifications during polycondensation reactions, improving thermal resistance and dimensional stability. It is typically utilized as a co-monomer in the synthesis of specialty polyesters and polyimides for electronic components, electrical housings, and automotive structural parts. Specific emphasis is placed on controlling side-reactions and ensuring traceability through each batch after full compliance audits of polymer-grade input streams. Downstream compounders adjust its incorporation based on the molecular weight targets and mechanical performance criteria of the formulated resin.

    Industry compliance standards

    • ISO 9001:2015 (Quality management for polymer intermediates)
    • IEC 61249-2-21 (Electronic substrate halogen content restrictions)
    • REACH Annex XVII (Restrictions on aromatic ester monomers)
    • RoHS 2011/65/EU (Directive on hazardous substances for electronics)

    Typical usage ratio

    • Polyester and polyimide manufacturing: 1.5%–6.0% by monomer molar ratio, adjusted to achieve glass transition targets and copolymer branching density.

    Downstream process integration

    • Added directly during monomer charge to the reactor alongside primary phthalic acid derivatives and glycol or diamine components; real-time monitoring required during esterification or imidization stages.

    Final product types

    • High-performance polyesters (e.g., PET, PBT for electrical and automotive use)
    • Polyimide films for flexible circuits
    • Composite housings for precision electronics
    • Thermally resistant automotive connectors

    2. Specialty Plasticizer Precursor

    Formulators utilize 4-methylphthalic acid as a modifier in the synthesis of specialty plasticizers, particularly for applications that require enhanced migration resistance and heat aging performance. By integrating the methyl-substituted phthalic unit into the plasticizer backbone, manufacturers achieve fine-tuned flexibility characteristics in high-end PVC and polyurethane elastomers. This route enables targeted reduction of volatile content—critical for sensitive construction and automotive interior applications—while maintaining compliance with evolving chemical inventory and toxicological limits.

    Industry compliance standards

    • EN 71-3 (Safety of toys, migration of certain elements)
    • CEN/TS 15901-8 (Plastics—Plasticizers specification)
    • US EPA TSCA Inventory Review
    • GB/T 21930-2011 (Evaluation of environmental labeling for building materials)

    Typical usage ratio

    • Plasticizer molecule building: 2.0%–5.5% by weight in esterification step, depending on target molecular size and application volatility requirements.

    Downstream process integration

    • Esterified with selected alcohols in continuous reactors to control byproduct profiles; intermediates purified before blending into polymer melts or compounding formulations.

    Final product types

    • Low-migration PVC plasticizers
    • Elasticized polyurethane foams
    • Interior automotive coatings
    • Architectural flooring compounds

    3. Liquid Crystal Polymer (LCP) Intermediate

    Producers of liquid crystal polymers incorporate 4-methylphthalic acid to alter mesogenic alignment and optimize melt-flow behavior in high-frequency electronics and micro-injection molding. Its controlled introduction influences stacking angles within the aromatic backbone, which in turn fine-tunes dielectric properties and surface smoothness for connectors and LCP films. Quality critical points include impurity management and chain propagation fidelity, with input ratios validated through small-lot pilot testing for each grade of downstream copolymer.

    Industry compliance standards

    • UL 94 (Flame retardancy rating for polymer products)
    • ISO 14001 (Environmental management for high performance polymers)
    • IPC-4101 (Base materials for printed wiring boards)
    • VDE Plastic Components Safety Approvals

    Typical usage ratio

    • LCP copolymer feed: 0.8%–2.8% by total aromatic acid input, regulated according to flow index and desired dielectric constant.

    Downstream process integration

    • Blended with other terephthalic and isophthalic acids during the oligomerization stage; methyl substituent content often optimized for injection-molding grades.

    Final product types

    • Precision electrical connectors
    • Smartphone micro-component housings
    • LCP-based high-frequency antennas
    • Flexible microelectronic circuit substrates

    4. Coatings and Resin Crosslinker Agent

    Manufacturers of industrial coatings and specialty resins deploy 4-methylphthalic acid as a chain-modifying crosslinker. Its incorporation adjusts glass transition temperature, hardness, and solvent resistance in baked enamels and 2K systems, particularly for protective metal, coil, and automotive bodywork coatings. Tight QC on input purity remains crucial, as even trace non-phthalic impurities disrupt downstream curing profiles and film uniformity. Usage must comply with sector-specific restrictions on aromatic anhydrides and related acid species.

    Industry compliance standards

    • ASTM D3029 (Polyester and alkyd resin specification)
    • GB/T 22233 (General technical conditions for automotive coatings)
    • ISO 12944 (Corrosion protection of steel structures by protective coatings)
    • ECHA SVHC Candidate List monitoring (for aromatic additives)

    Typical usage ratio

    • Crosslinking additive in polyester/alkyd resin manufacture: 0.5%–2.0% by total acid input, set based on desired film hardness and elasticity properties.

    Downstream process integration

    • Introduced to polycondensation reactor during acid charge phase; blends customized at pilot scale to balance reactivity with other anhydrides and modulate cure kinetics.

    Final product types

    • Baked coil coatings for steel and aluminum strip
    • Automotive OEM and refinish coatings
    • Industrial pipe and container linings
    • Protective marine paints with high resistance profile

    5. Reactive Dye Intermediate

    In the dye manufacturing sector, 4-methylphthalic acid acts as a precursor for select reactive dyes and pigment dispersants with enhanced binding capabilities to cellulose and synthetic fibers. Its structural modification enables synthesis of colorants with improved light and wash fastness, suitable for high-performance technical textiles. Downstream utilization necessitates stringent monitoring of aromatic amine by-products and full certification for textile safety, ensuring compliance with global eco-label and restricted substance programs.

    Industry compliance standards

    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals Manufacturing Restricted Substances List)
    • OEKO-TEX® Standard 100 (Textile chemical safety)
    • GB/T 7573 (Color fastness of textiles to perspiration)
    • REACH Annex XVII, dyes section

    Typical usage ratio

    • Reactive dye synthesis: 3.0%–7.0% by weight of intermediate dye batch, balanced against color strength and binding group activation.

    Downstream process integration

    • Introduced at diazotization or coupling stage with controlled pH; methyl substituent provides steric control for subsequent sulfonation or halogenation steps.

    Final product types

    • Reactive dyes for cotton and viscose fabrics
    • Disperse dyes for polyester blends
    • Color-stable pigment dispersants for industrial printing
    • High-stain-resistance automotive interior textiles

    6. Advanced Adhesive Hardener

    High-performance adhesives producers integrate 4-methylphthalic acid as a hardening agent in thermosetting epoxy and polyurethane systems for structural bonding. Its use offers enhancement in hydrolysis resistance and crosslink density, improving the mechanical properties critical for aerospace composite parts and high-load civil engineering fixtures. Close control over input acid equivalents and residual reactivity optimizes the mechanical curing cycle, with batch traceability maintained through throughout the QC chain. Specifications are aligned with rigorous downstream customer acceptance tests targeting adhesive durability and migration resistance.

    Industry compliance standards

    • EN 301-1 (Structural adhesives for load-bearing timber structures)
    • SAE AMS 3265 (Aerospace adhesives specification)
    • ISO 4587 (Metal-to-metal single lap joint shear strength)
    • GB/T 7124 (Adhesive bonded joint test methods)

    Typical usage ratio

    • Epoxy or polyurethane adhesives: 0.6%–1.9% by resin solids, fine-tuned based on required glass transition temperature and water-resistance profile.

    Downstream process integration

    • Added to resin matrix before curing agent introduction; real-time monitoring of viscosity and acid avidity during blending to ensure uniform crosslink distribution.

    Final product types

    • Aerospace composite adhesives
    • High-strength construction bonding systems
    • Vibration-resistant electronic potting compounds
    • Marine structural sealants
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    Certification & Compliance
    More Introduction

    4-Methylphthalic Acid: Direct from the Manufacturer’s Floor

    Understanding the Value of 4-Methylphthalic Acid

    Every batch of 4-Methylphthalic Acid that leaves our reactors tells its own story. We’ve spent years optimizing the synthesis route, so we can stand behind the purity and consistency of our product. You can spot a good 4-Methylphthalic Acid by how reliably it behaves under pressure, heat, and exposure to various solvents. Our process controls keep batch-to-batch variation tight, something we recognize matters most to downstream chemical engineers and R&D teams who don’t have time for surprises.

    Why all the interest in 4-Methylphthalic Acid? Its aromatic backbone with a methyl group at the fourth position gives it a kind of versatility that pure phthalic acid can’t match. Chemists and formulators prefer it for introducing subtle tweaks in molecular architectures, especially when a slightly bulkier substituent can unlock new reaction pathways or improve product stability. Not every project calls for derivatives, but customers come to our door when standard phthalic acid falls short.

    Our Real-World Experience: From Kilos to Tons

    Plenty of companies will talk about their clean facilities or sophisticated reactors, but the real test happens downstream. We run 4-Methylphthalic Acid at commercial scale, not just in the lab. In our experience, scale-up isn’t a matter of simply enlarging beakers—it means dealing with heat transfer quirks, gas evolution, and crystallization rates that won’t behave like models predict. Our technicians know the “feel” of a good crystal batch: how the powder looks on the filter, how it drains, how it packs. This hands-on attention gets translated into shipping drums where you’ll find consistent granule size and minimal fines.

    Stability is another piece we don’t take for granted. Some users want a compound that stands up to weeks in warehouse storage, in all weather, before it reaches the next processing step. We design our drying and packaging process around these needs—whether it’s double-lined fiber drums or lined sacks for export. Moisture content stays low, and adulteration risk drops because we source and handle our precursors ourselves.

    Specifications That Matter to Real Chemists

    Throughout the years, we’ve learned that most problems start with raw materials that don’t do what buyers expect. Our 4-Methylphthalic Acid shows purity above 99%, measured by HPLC, and trace metals aren’t just an afterthought—we screen every lot with ICP-OES to get a read on iron, nickel, and zinc levels, since catalysts and high-performance polymers don’t always tolerate these contaminants. Melting point remains sharp— a clear sign of minimal structural or chemical impurities.

    Particle size may sound like a small concern, but uneven feeding in automated plants can spell disaster for batch yields or downstream filters. We offer narrow particle size distributions suited for both batch and continuous plants. Customers using isostatic press or melt processes have told us our material flows better and blends more predictably, thanks to our screening and agglomeration steps.

    Applications Rooted in Practical Experience

    Most of our 4-Methylphthalic Acid finds its way into specialty plasticizers and certain high-performance thermosets, where that extra methyl group tweaks polymer flexibility or UV stability. R&D teams from epoxy manufacturers and specialty resins report that conventional phthalic acid sometimes falls flat when they aim for new property targets. Our product ended up in modified polyester resins designed for coatings exposed to harsh sunlight, where the slight steric hindrance from the methyl group kept yellowing and brittle fractures at bay longer than legacy formulations.

    We’ve also seen increasing inquiries from pharmaceutical intermediates researchers, particularly those exploring aromatic dicarboxylic acids that improve yield or simplify synthesis of active molecules. The presence of the methyl group often steers selectivity during the cyclization or amidation steps, resulting in cleaner reactions with less need for post-processing.

    Standing Out from Standard Phthalic Acid and its Cousins

    Having spent decades running phthalic acid, isophthalic acid, and their substituted relatives, we’ve seen firsthand how minor changes on the aromatic ring have outsize impact. The methyl group on the fourth position of 4-Methylphthalic Acid gives it a lower melting point and shifts solubility trends compared to plain phthalic acid. For users, this difference can shave hours off reaction times or give new options for solvent choice. When projects scaled up from liters to cubic meters, subtle physical differences, like how well the powder disperses or resists caking, start to matter in day-to-day operations.

    We often get questions about whether 4-Methylphthalic Acid can simply substitute for other phthalic derivatives. Sometimes the fit is perfect—especially in formulations that need more flexibility or a unique reactivity profile. Other times, our technical team works alongside clients to fine-tune dosages or blend ratios, since the methyl group adds mass and impacts certain reaction equilibria.

    Real-World Challenges: Supply, Quality Assurance, and Customization

    Not every 4-Methylphthalic Acid shipment comes from a single lot—commercial users want volumes that only integrated sourcing can provide. We keep strict chain-of-custody records, link each drum to precise process data, and sample constantly through bagging. When process interruptions happen, we don’t hide them. Our quality assurance team investigates root causes, looks at batch records, and rolls findings straight into future runs.

    Custom runs sometimes call for higher purity or alternative packaging. We’ve invested in flexible intermediate bulk containers, semi-bulk iso drums, and smaller kegs for trial runs. Our staff adjust filtration steps or strip volatile organics as needed, so pilot plant or high-throughput researchers receive exactly what matches their scale and protocol.

    Sustainability by Design—not Just a Buzzword

    Years ago, phthalic acid production focused on efficiency at the expense of waste. We redesigned our downstream recovery and solvent recycling lines to capture and reprocess the majority of organics used in methylation and oxidation. Scrubbers remove off-gases; spent catalysts get sent for repurposing, not landfilling. These measures translate to cleaner product and lower trace impurity risk for each batch, but they also respond to stricter environmental regulations across North America and the EU.

    Customers with ISO 14001 or Green Chemistry targets push for more information—and rightly so. Our operations team holds quarterly reviews to track emissions, water usage, and solvent waste generation against reduction targets. Not every new control gets cost approval unless it genuinely contributes to measurable improvements, but our track record shows that building in process safety and loss prevention pays back over the long run in consistent product quality.

    Evolution of Product Specifications: What We’ve Learned from Customers

    Working side-by-side with polymers specialists, battery researchers, and advanced materials teams brings new requests each year. In advance of large synthesis campaigns, some clients want lots produced under nitrogen instead of air to eliminate possible oxidation—sluggish rates or color formation can wreck yields. Others care more about sodium ion traces, especially those working on high-voltage applications. We respond by running custom analytical profiles, adding extra purification, or even recharging column beds to catch trace ions.

    We document these performance metrics, so the next customer benefits from cumulative know-how. Collaborative troubleshooting means quick turnaround on product modifications and cleaner project launches, with fewer mid-process delays. In this way, specification sheets grow not just from textbook standards, but from the lived requirements of world-class labs and manufacturing floors.

    The Human Element: Training, Safety, and Accountability

    Behind every drum of 4-Methylphthalic Acid sits a team that’s constantly learning. Operator training covers more than equipment use—crews understand how foaming looks during a reaction, recognize undesirable color changes in mother liquors, and know how to halt a crystallization without compromising the batch. Senior staff run monthly reviews, updating process maps, sharing near-misses, and proposing improvements.

    Wherever possible, new controls get folded into daily routines. Color tests at the dryer, particle screening protocols near the bagger, headspace tests for residual solvents—these routines matter when customers depend on perfect performance for months or years ahead. Emergency response and preventive maintenance both receive regular review, since an unplanned downtime could compromise product or delay a critical delivery.

    Long-Term Partnerships and the Future of 4-Methylphthalic Acid

    Most of our customers don’t just buy once. Development chemists, production supervisors, and procurement teams keep dialogues open about future requirements and regulatory changes. Products like 4-Methylphthalic Acid remain under the microscope as markets shift and end uses diversify. We’ve seen it move from classic resin modification into frontier materials, where unique substitution patterns can open up whole new application classes.

    Stability and supply security matter more each year. To address these needs, we expand tank farm capacity, plan multi-week campaign runs, and vet secondary supply routes. In volatile markets, early notification and flexible shipment volumes give our partners confidence their processes won’t grind to a halt.

    Comparing 4-Methylphthalic Acid to Other Dicarboxylic Acids

    Over time, technical teams ask how 4-Methylphthalic Acid stacks up against classic phthalic acid, isophthalic acid, or even more exotic derivatives. Each option brings its own set of properties—reaction rate differences, thermal behavior, color stability in final goods, and compatibility with high-value additives. The methyl group on 4-Methylphthalic Acid offers a balance: enough steric twist to increase durability or chemical selectivity, not so much that downstream processing stalls.

    From a compatibility standpoint, customers find that this molecule integrates well into multi-component resin systems, accepts a variety of curing agents, and rarely complicates pigment dispersion. These hands-on lessons only come after thousands of kilo-scale runs and feedback loops with industry partners, not just from literature assumptions.

    Continuous Improvement: Listening, Adapting, and Delivering More than Just Product

    We know buyers want more than a certificate of analysis—they want suppliers to own mistakes, communicate clearly, and invest in real improvements. Whenever a new report or customer call highlights a trace impurity or packaging shift, our team logs the case, diagnoses the issue, and changes the process so the fix sticks. This approach let us boost average purity by a full percentage point over the last decade and decrease out-of-spec complaints by more than half.

    Transparency isn’t optional. Regular plant audits, open access to process analytics, and a willingness to share batch histories—these keep technical trust levels high. Supply chain teams appreciate predictable lead times, while researchers value the consistent performance because it means their innovation efforts don’t get derailed over “mystery” plant variables.

    Seeing the Road Ahead: Challenges and New Opportunities

    Innovations in chemical manufacturing never stand still. Regulatory updates, market movement, and customer R&D stretch what’s possible. Our team stays alert to changes in REACH, TSCA, and similar frameworks, proactively updating compliance, conducting risk assessments, and running additional leachate and emissions tests to ensure downstream safety. Recent partnerships brought demands for materials meeting new food contact or high-purity electronic standards. These challenges push our engineering and QA teams to invest in equipment upgrades, improved documentation, and more training, so we keep pace.

    4-Methylphthalic Acid already supports projects from concept to commercial launch in coatings, plastics, adhesives, and specialty chemicals. We expect future customers will press for even narrower purity specs, custom particle forms, or packaging aligned with advanced logistics. We’ve planned investments in analytics—like LC-MS, GC-MS, and micro-contaminant screening—to spot material drift sooner and maintain the supply stability researchers and process managers demand.

    Conclusion: Real Experience, Real Results

    After decades in chemical manufacturing, we know reliability, accountability, and technical support are as important as high-performance materials. 4-Methylphthalic Acid stands apart from comparable acids by its ability to deliver not just consistent physical and chemical properties, but real-world usability on plant floors around the world. No batch leaves our facility without careful review, and no shipment crosses ocean or continent without our team watching quality markers and tracking regulatory shifts. Customers count on 4-Methylphthalic Acid to offer repeatable performance, whether their focus is plastics, coatings, or advanced synthesis. Our commitment is to keep listening and adapting, so your innovations don’t pause for basic raw material issues. That’s how we see the role of a chemical manufacturer: more than making molecules—we partner to build the future, one batch at a time.