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4-Methyl-N-Hexylpyridinium Hexafluorophosphate

    • Product Name 4-Methyl-N-Hexylpyridinium Hexafluorophosphate
    • Alias [4-Methyl-1-hexylpyridinium][PF6]
    • Einecs 629-761-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    969896

    Cas Number 75886-66-7
    Molecular Formula C12H20NPF6
    Molecular Weight 325.26 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point Decomposes before boiling
    Density 1.16 g/cm³ (approximate)
    Solubility In Water Slightly soluble
    Purity Typically ≥99%
    Ionic Liquid Yes
    Cation 4-Methyl-N-hexylpyridinium
    Anion Hexafluorophosphate
    Refractive Index 1.410 (approximate)
    Storage Temperature Room temperature, tightly closed
    Hazard Statement May cause skin and eye irritation

    As an accredited 4-Methyl-N-Hexylpyridinium Hexafluorophosphate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 100g of 4-Methyl-N-Hexylpyridinium Hexafluorophosphate is supplied in a sealed amber glass bottle with tamper-evident cap and labeling.
    Shipping 4-Methyl-N-Hexylpyridinium Hexafluorophosphate is shipped in tightly sealed containers, protected from moisture and light. It is classified as a hazardous material; thus, delivery complies with relevant chemical transport regulations. Proper labeling and documentation, including Material Safety Data Sheets (MSDS), are provided to ensure safe handling during transit and upon receipt.
    Storage 4-Methyl-N-Hexylpyridinium Hexafluorophosphate should be stored in a cool, dry, and well-ventilated area, away from heat, moisture, and incompatible substances such as strong oxidizers. Keep the container tightly closed and protect it from direct sunlight. Store under inert atmosphere if possible to prevent hydrolysis. Always use proper personal protective equipment during handling and consult the Safety Data Sheet for detailed instructions.
    Application of 4-Methyl-N-Hexylpyridinium Hexafluorophosphate

    Applications of 4-Methyl-N-Hexylpyridinium Hexafluorophosphate in Industrial Manufacturing

    4-Methyl-N-Hexylpyridinium Hexafluorophosphate supports several advanced industrial processes as a functional ionic liquid, due to its specific physicochemical properties, electrochemical stability, and immiscibility with water. Below, we outline its real-world applications within key chemical manufacturing sectors, detailing integration, regulatory compliance, and formulation guidance for downstream production operations.

    1. Electrolyte Additive in High-Energy Lithium-Ion Batteries

    Manufacturers integrate this compound as an additive or co-electrolyte salt in advanced lithium-ion cell formulations, particularly for high-voltage chemistries. Its non-flammable character and thermal stability extend battery lifetime and enable wider operational temperature ranges. Formulators adjust concentration based on cycling stability, conductivity optimization, and compatibility with electrode and separator materials.

    Industry compliance standards

    • IEC 62660-2:2018 (Secondary lithium-ion cells for automotive applications – Safety requirements)
    • UN 38.3 (Transport of Dangerous Goods – Lithium Metal and Lithium Ion Batteries)
    • GB/T 31486-2015 (Safety requirements for power battery systems in electric vehicles, China)
    • ISO 9001:2015 (Quality Management Systems in battery production)

    Typical usage ratio

    • 0.5–5 wt% based on total electrolyte mass. Adjust formulation for cathode chemistry (NMC, LFP, LCO) and targeted cell performance.

    Downstream process integration

    • Add during electrolyte mixing before cell filling. Monitor mixing temperature to prevent degradation. Integrate with other functional additives such as SEI stabilizers or flame retardants.

    Final product types

    • EV power batteries, grid storage modules, consumer electronics batteries, high-rate pouch cells

    2. Supporting Electrolyte in Electrochemical Organic Synthesis

    Chemical process engineers use this material as a supporting electrolyte for electro-organic synthesis, thanks to its excellent ionic conductivity and broad electrochemical window. It facilitates selective anodic and cathodic transformations, especially in flow electrolysis setups and for water-free synthesis of fine chemicals and active pharmaceutical intermediates.

    Industry compliance standards

    • REACH Registration (EC 1907/2006) for use in closed chemical processes
    • GMP Part II (ICH Q7) for pharmaceutical intermediates
    • ISO 14001:2015 (Environmental management)
    • Responsible Care Global Charter (Process safety in fine chemicals manufacturing)

    Typical usage ratio

    • 0.05–0.2 M as a supporting electrolyte in organic solvents, depending on cell size, electrode material, and target current density.

    Downstream process integration

    • Dissolve in reaction solvent before charge application. Ensure removal via extraction or precipitation prior to product isolation. Optimize dosage for selective conversion and minimal waste.

    Final product types

    • Pharmaceutical intermediates, specialty fine chemicals, advanced functionalized aromatics, organometallic precursors

    3. Ionic Liquid Phase for Metal Extraction and Separation

    Metallurgical processors use this ionic liquid as a solvent phase in selective extraction of rare earth elements and transition metals from mixed ores or industrial waste. Its unique hydrophobicity and ion-exchange ability enable efficient separation in both batch and continuous extraction circuits, reducing use of volatile organic solvents.

    Industry compliance standards

    • ISO 9001:2015 (Quality management in hydrometallurgy)
    • RoHS 2011/65/EU (For materials used in electronic component feedstocks)
    • International Cyanide Management Code (ICMC) guidelines (when extracting gold-co-mined ores; for alternatives)

    Typical usage ratio

    • 10–50 vol% as the ionic liquid phase in solvent extraction systems. Dosage depends on target element, feedstock composition, and process design.

    Downstream process integration

    • Add during the extraction stage, often combined with specific chelating agents. Regenerate ionic liquid for reuse via back-extraction or stripping cycles.

    Final product types

    • High-purity lanthanide oxides, cobalt/nickel concentrates, battery-grade lithium, metallurgical grade rare earths

    4. Analytical Reagent for Ion Chromatography and Mass Spectrometry

    Analytical laboratories utilize this reagent as a mobile phase modifier or ion-pairing agent in advanced ion chromatography and LC-MS methods. It offers improved separation efficiency and retention control of hydrophobic organic ions, supporting sensitive quantification in environmental, pharmaceutical, and industrial QC labs.

    Industry compliance standards

    • USP <1225> (Validation of Compendial Procedures)
    • ISO/IEC 17025:2017 (Testing and calibration laboratories competence)
    • ICH Q2(R1) (Validation of analytical procedures for pharma QC)

    Typical usage ratio

    • 10–100 μM in aqueous/organic mobile phases. Optimize for analyte class and instrument sensitivity requirements.

    Downstream process integration

    • Prepare fresh in mobile phase solution prior to sample injection. Monitor background ionization and matrix effects in MS analyses; filter to remove particulates.

    Final product types

    • Analytical reference materials, certified QC results for environment and pharma, laboratory-developed test reports

    5. Non-Aqueous Electroplating Bath Component

    This compound finds use in non-aqueous plating systems for the deposition of advanced alloys and functional coatings—particularly where water-driven corrosion or hydrogen embrittlement must be avoided. Electroplating engineers exploit its ionic conductivity and stability for producing uniform, adherent films on specialty substrates.

    Industry compliance standards

    • ISO 4527:2003 (Electroplated coatings for technical applications)
    • ASTM B567-98 (Measurement of coating thickness by X-ray spectrometry)
    • EU ELV Directive 2000/53/EC (Restrictions for platings in automotive applications)

    Typical usage ratio

    • 5–30 vol% in plating bath formulation, tuned based on metal/ligand ratio and target coating thickness.

    Downstream process integration

    • Combine with metal salts and complexing agents during bath preparation. Control bath temperature and electrode polarization to maintain film integrity.

    Final product types

    • Corrosion-resistant alloy coatings, electronic connector plating, microplated substrates for MEMS, decorative metal finishes

    6. Solvent Media for Homogeneous Catalysis

    Chemical synthesis plants select this ionic liquid as a solvent medium for homogeneous transition metal catalysis, especially when targeting challenging C–C or C–N bond formations. Its low nucleophilicity and excellent thermal stability allow operation at elevated temperatures, facilitating catalyst recovery and recycling in batch or continuous stirred tank reactors.

    Industry compliance standards

    • EU Regulation (EC) No 1907/2006 (REACH – for solvent use in synthesis)
    • GMP Guidelines for APIs (for pharma precursor synthesis)
    • ISO 9001:2015 (Quality management in chemical synthesis)

    Typical usage ratio

    • 60–100 vol% as primary solvent. Adjust with co-solvents or diluents depending on target catalyst system and product isolation strategy.

    Downstream process integration

    • Charge to reactor with catalyst and substrate. Post-reaction, recover product by extraction or distillation. Regenerate solvent to reduce operational costs and minimize environmental impact.

    Final product types

    • Agrochemical intermediates, advanced monomers, fine chemical building blocks, pharma intermediates
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    Certification & Compliance
    More Introduction

    4-Methyl-N-Hexylpyridinium Hexafluorophosphate: A Real-World Look from the Manufacturer’s Floor

    Meeting Evolving Industry Demands with Precision Chemistry

    From the concrete floors of our production facility, we see chemical innovation shaped by end-user problems, not just theory. 4-Methyl-N-Hexylpyridinium Hexafluorophosphate is no off-the-shelf commodity. Our crew knows its story well—this ionic liquid grew from lab curiosity toward a steady production mainstay, spurred by direct conversations with battery engineers, academic groups, and process development managers. With years behind us scaling reactions and iron-clad focus on reproducibility, we have watched this compound carve out a space in electrochemical and synthetic chemistry, where cleanliness, purity, and careful cation-anion pairing leave lasting results on the bottom line.

    Model, Consistency, and a Manufacturer’s Hands-On Approach

    Decades in the specialty chemical business have taught us the cost of inconsistency. Customers arrive at our doors after months wasted troubleshooting ionic liquid failures, batch-to-batch variation, or impurities they never saw disclosed. Our model for 4-Methyl-N-Hexylpyridinium Hexafluorophosphate reflects practical realities: tailored volumes, secure packaging, and documented purity assessments based on NMR, ion chromatography, and water content from Karl Fischer titrations. We rely on glovebox filling lines and pass our own internal audits, knowing every over-promised purity statistic eventually meets a scientist’s data report.

    On the manufacturing side, we do not cut corners on traceability. Raw materials—hexyl halide, 4-methylpyridine, phosphorus pentafluoride—each arrive with lot numbers and supplier analysis, but the real proof comes from our in-process controls. Traditionally, ionic liquid batches are prone to residual unreacted halides or hydrolysis byproducts; we monitor intermediary steps for these contaminants, using both spot checks and full-panel analytics. Ion-exchange cleanups and phase separations might add time to the process, but the result is a salt that protects sensitive lab and industrial applications from surprise liabilities.

    Specification Details Shaped by Daily Demands

    Our engineers and QC team define the specifications: water content typically stays below 100 ppm, confirmed by routine Karl Fischer checks. Organic and inorganic impurities fall within strict, published limits—not hidden in generic “by difference” metrics, but itemized down to sub-percent levels. We maintain lot-specific NMR traces to verify cation integrity, and routinely perform anion F-19 NMR and ion chromatography to confirm full exchange completion. Customers seeking ultra-high purity receive custom-run campaigns in segregated lines, and we stand ready to adjust surface area exposure, filtration cut-offs, or post-synthesis drying cycles based on feedback from pilot and scale-up partners.

    Shelf life does not come empty-handed: exposure to air and light are minimized. Our team developed vacuum-sealed, amber-glass units for sensitive shipments, storing finished product above desiccant beds until final packing. A logistics department familiar with hazardous goods ensures each shipment reaches customers in Europe, North America, or Asia with strict roll-call for each reagent touchpoint.

    Application Knowledge Earned Over Years in the Field

    The real story comes from usage reports: customers have integrated 4-Methyl-N-Hexylpyridinium Hexafluorophosphate as a supporting electrolyte in non-aqueous electrochemistry installations where conventional salts like TEAPF6 or LiPF6 break down or corrode. The combination of a methyl group at the 4-position and a medium-length hexyl substituent tempers viscosity and alter solubility properties—making it a secret ingredient in solvent mixtures where sluggish mass transport grinds experiments to a halt.

    Researchers synthesizing fine chemicals and pharmaceuticals report measurable improvement in yields and selectivity, compared to cruder or less specialized salts. In our own pilot studies with partners, we have documented a meaningful reduction in byproduct formation when using our product over less-pure commercial pyridinium salts. Process chemists relate reduced current leakage and cleaner cathode surfaces in applications ranging from low-temperature synthesis to impedance-modulated electro-analysis. The presence of the PF6- anion sets this salt apart from tetrafluoroborate or triflate-based analogs, especially in cases where moisture resistance stands as a non-negotiable requirement.

    We’ve learned side-by-side with our customers: one client, scaling a new fluorination protocol, found that off-the-shelf equivalents fouled their glassware with mysterious precipitates. Our production team verified, batch after batch, a clarity and color free of suspended contaminants. Ultra-low halide runs, achieved by tuning synthesis parameters, won recommendations from labs who struggled with previous black box salts. These stories reinforce our focus on minor details, not just broad purity stats.

    Differentiation Rooted in Manufacturing Reality

    Plenty of competing products claim to tick the same boxes—though often, a distributor’s rep can’t reach their own chemist when process anomalies appear. Our team works start-to-finish, troubleshooting and rethinking parameters as new practical hurdles arise. Experience tells us where cut points between product and impurity lie: we answer questions about cation-to-anion ratios, shelf life forecasts, and processing temperatures because we have first-hand exposure to every variable, from glassware cleaning protocols to impeller shear rates.

    Our chemists notice small changes in humidity, solvent residues, and glassware integrity—so our clients do not face sudden, unaccounted-for spikes in conductance or discoloration. The drive for transparency means full traceability: the barrel leaving our loading dock carries not just a lot number, but a backstory of the actual days in production, purification approaches, and storage logs. We know our reputation rests on reliability. If a technical team at a battery project needs a new lot tested, we ship representative samples at no charge on a known timeline, with application advice rooted in previous troubleshooting work.

    In a world of online specifications that grow more generic each year, our business retains direct ownership: no relabeling, no shrugged shoulders when questions arise. End users come to us for a salt produced at scale, but with the attention to detail of a craftsman in a small lab, and the openness to document and share each step. That hard-won experience at the intersection of chemistry and daily practical use defines why customers continue to trust our 4-Methyl-N-Hexylpyridinium Hexafluorophosphate for demanding applications.

    Challenges and the Path to Smarter Chemistry

    Sometimes, manufacturers like us shoulder skepticism when a novel salt or ionic liquid enters the market. Early arguments fixate on cost, but experienced researchers soon realize the cost of irreproducible data runs far greater. Complex projects—catalyst testing, battery R&D, sensor development—suffer more from a bad batch or hidden contaminant than an invoice. That’s the reality we work to improve.

    We collaborate with research partners to document evaporation rates, test new solvent compatibility, and share real-world aging data. In one collaborative case, a high-throughput electrolysis group documented dramatically longer functional lifetimes for their electrodes—backed by cycles of repeated salt refresh, with shipping and handling tracked down to the hour. In another, a startup testing organofluorine reactions highlighted how our careful drying and non-metal packaging eliminated reaction interference seen with “comparable” materials from catalog sources. These examples drive our process optimizations, not just internal standard upgrades.

    Supply chains do not always run smoothly in this sector. Sourcing raw ingredients sometimes means negotiating with upstream petrochemical and specialty gases producers, and our procurement team anticipates periodic volatility in availability or price. We shield our downstream customers as much as possible—buffering raw stock, maintaining redundant suppliers, and keeping end-users fully informed of any schedule impacts. Experience teaches that silence during delays only erodes trust. By maintaining open channels, we enable technical teams to plan or pivot, instead of scrambling post-facto.

    Safety and regulatory requirements are no afterthought. Our compliance lead works hand-in-hand with regulatory liaisons in each export region, tracking updates not just on R&D reagents but also as new product classes graduate into commercial-scale applications. SDS and transport compliance documentation undergo quarterly updates in response to both internal process adjustment and external feedback from end-users who notice subtle changes in sensory or shelf-life data. We build and verify thermal decomposition and hazard data ourselves before posting—each test tied directly to the actual product, not a generic standard.

    Reduction of Waste and the Push for Greener Chemistry

    Environmental stewardship means more than fashionable claims. Our continuous process improvements aim not only at cost, but also at process yields and waste minimization. We recover solvent streams, monitor effluents, and reclaim by-products when feasible. Internal teams conduct life-cycle assessments covering from raw input to packaging and distribution. Customers appreciate transparency—so completed reports are available by request for those needing downstream environmental certifications.

    Switching to 4-Methyl-N-Hexylpyridinium Hexafluorophosphate often reduces the use of volatile organic compounds in reaction mixtures, thanks to its favorable ionic conductivity and intrinsic stability. Some industrial clients reported, through measured data, fewer environmental incidents and easier solvent recovery steps post-reaction. As stewardship becomes a competitive differentiator, laboratories and production sites find value not simply in the salt’s function but also in predictable handling and responsible waste management.

    Hand-in-Hand Progress with Researchers and Industry

    Our facility is open to tours and third-party audits. We invite researchers, procurement leads, and scale-up engineers to review facilities, see production lines, and review analytics protocols in person. Transparency builds relationships beyond a single purchase order. We listen closely to user questions: coping with new regulatory hurdles, changing synthetic routes, and planning scale-ups demand not just a good product but a collaborative partner.

    From the chemists cleaning glass reactors to the logistics crew packing each drum, our team finds meaning in direct feedback from those who test theoretical chemistry under real-world production pressure. These daily conversations drive further improvement—smoother surface finishes, higher-purity solvent washes, and better user documentation for integration into automated systems.

    What Sets Our 4-Methyl-N-Hexylpyridinium Hexafluorophosphate Apart? We Keep Listening and Improving

    Not every product gains market trust. Some fade as trends change. The persistent high demand for our 4-Methyl-N-Hexylpyridinium Hexafluorophosphate comes from users’ feedback: robust electrochemical stability, low moisture uptake, and actual improvements in data reproducibility and process lifetime. Batch notes from production reveal the unseen value in timely adjustments—a fraction lower extrusion speed during crystallization, an extra filtration stage, adjusted drying protocols—all implemented in response to real issues, not mere speculation.

    Differences from the segment’s “me-too” offerings show up not just in numbers but in repeat outcomes for the labs and factories who return year after year. By keeping technical support and production under one roof, questions about compatibility, upscaling, or abnormal behavior are answered with candor, not excuses. The product’s chemistry may begin on a bench, but its true test lies in consistent yield, manageable process hazards, and the confidence of users whose timelines run on days, not months.

    Looking Ahead: Innovation Beyond a Single Product

    Chemistry changes quickly, and so do researchers’ needs. Continual investment in analytical technology and new production techniques means every raw material, lot, and output batch reflects what modern science and industry expect. We see new generations of 4-substituted pyridinium salts on the horizon, but hands-on improvements in drying, purity, and contaminant control for the current staple keep our customers productive and risk lower, today.

    We see the impact of each improvement not as a marketing pitch, but in the requests for consultation, repeat orders, and especially problem-solving sessions when scaling or regulatory issues pop up. The working relationships built over years of shared troubleshooting let us act nimbly and with reliable background knowledge.

    A chemical’s quality stands not just on the purity sheet, but on a network of choices and commitments behind each batch. At every stage—planning, production, quality control, shipping, and follow-up—we remain true to the principle that customers deserve direct answers, honest data, and ongoing practical support. For 4-Methyl-N-Hexylpyridinium Hexafluorophosphate and any new product that follows, this approach delivers value in the real world, where experimental hours cost more than retail prices and success depends on getting the details right, every time.