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4-Methacryloxy-2-Hydroxybenzophenone

    • Product Name 4-Methacryloxy-2-Hydroxybenzophenone
    • Alias OM-HBP
    • Einecs 245-155-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    108223

    Cas Number 1843-05-6
    Molecular Formula C17H14O4
    Molecular Weight 282.29 g/mol
    Appearance Yellow crystalline powder
    Melting Point 89-92 °C
    Solubility Insoluble in water, soluble in organic solvents
    Purity Typically ≥98%
    Uv Absorption Maximum 311 nm (in ethanol)
    Density 1.29 g/cm³
    Storage Conditions Store in a cool, dry place, protected from light
    Synonyms 2-Hydroxy-4-(methacryloyloxy)benzophenone

    As an accredited 4-Methacryloxy-2-Hydroxybenzophenone factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 25g bottle of 4-Methacryloxy-2-Hydroxybenzophenone comes in a sealed, amber glass container with a secure screw cap.
    Shipping 4-Methacryloxy-2-Hydroxybenzophenone is shipped in tightly sealed, chemical-resistant containers to prevent contamination and moisture exposure. It is transported under ambient conditions, labeled according to hazard regulations. Proper documentation accompanies each shipment, ensuring safe handling and compliance with international chemical transport guidelines. Store in a cool, dry place upon receipt.
    Storage 4-Methacryloxy-2-Hydroxybenzophenone should be stored in a tightly closed container, in a cool, dry, well-ventilated area away from direct sunlight and incompatible substances such as strong acids, bases, and oxidizers. Protect from moisture and sources of ignition. Recommended storage temperature is between 2–8°C (refrigerated). Ensure proper labeling and follow relevant chemical safety and handling guidelines.
    Application of 4-Methacryloxy-2-Hydroxybenzophenone

    Applications of 4-Methacryloxy-2-Hydroxybenzophenone in Industrial Manufacturing

    As a manufacturer with years of expertise in industrial-grade performance additives, we supply 4-Methacryloxy-2-Hydroxybenzophenone to partners developing advanced polymer systems. This specialty benzophenone derivative functions as a high-efficiency UV absorber and copolymerizable light stabilizer across several focused downstream segments. Below we outline core commercial scenarios, including integration stages, typical dosages, and regulatory frameworks in relevant applications.

    1. UV-Resistant Coatings for Automotive Plastics

    Automotive interior and exterior trim components require durable UV protection to preserve appearance and mechanical properties under prolonged sunlight exposure. Our material acts as a copolymerizable UV-absorber in acrylic and polyurethane coatings applied to polycarbonate and ABS substrates during high-throughput component finishing lines. By becoming covalently bound within the polymer network, it markedly reduces photo-yellowing, chalking, and gloss loss over accelerated weathering cycles, aligning with industry demands for multi-year durability records required by major OEMs.

    Industry compliance standards

    • ISO 4892-2 (Plastics — Methods of exposure to laboratory light sources)
    • SAE J1960 (Accelerated exposure of automotive interior trim materials)
    • REACH Annex XVII (substance restriction regulations for polymer additives)
    • OEM-specific quality assurance protocols (VW TL 226, Ford WSS-M2D381-A1, GM 9985719)

    Typical usage ratio

    • 0.3–1.2% by weight in total coating solids, adjusted by pigment load and required weathering grade

    Downstream process integration

    • Blend into clearcoat or pigmented topcoat dispersions before application. UV-curable systems require mixing prior to photoinitiator addition. Incorporated via high-shear mixing in automated paint lines.

    Final product types

    • Finished automotive exterior/interior trim (grills, mirrors, panels)
    • Instrument clusters and bezels
    • B-pillar, dashboard, and console assemblies

    2. UV-Stabilized Pressure Sensitive Adhesives (PSA)

    Adhesive tapes and labels produced for outdoor signage, electrical insulation, and construction require photo-stability to retain tack and clarity over long-term exposure. By copolymerizing into acrylic or methacrylate PSA formulations, this input prevents UV-induced degradation without migratory loss or surface blooming. Our production partners report improved retention of peel strength and shear resistance in high-exposure service, enabling reliable certification for industrial and architectural markets.

    Industry compliance standards

    • ASTM D3330 (Test Method for Peel Adhesion of Pressure-Sensitive Tape)
    • UL 723 (Test for Surface Burning Characteristics of Building Materials)
    • RoHS Directive 2011/65/EU (for electronic adhesive applications)
    • ISO 12543-4 (Laminated glass—Performance requirements for adhesive interlayers)

    Typical usage ratio

    • 0.2–0.8% by dry polymer weight, modulated based on anticipated UV dosage profile and backing thickness

    Downstream process integration

    • Add at pre-polymerization or during dissolution of base polymers; subsequent emulsification or solvent casting onto films and liners. Incorporated with tackifiers and crosslinkers under nitrogen to avoid premature photoreactions.

    Final product types

    • Weatherable adhesive tapes for outdoor use
    • Window labeling and signage films
    • Electrical insulation films

    3. Weatherable Acrylic Sheet and Panel Manufacturing

    Large-format acrylic sheets for glazing, illuminated signage, skylights, and protective barriers must maintain transparency and resist yellowing under years of sunlight. Our product is integrated directly during MMA polymerization to become part of the molecular structure, providing intrinsic, non-extractable UV stabilization. Its copolymerizable function allows extrusion houses to meet stringent light transmission and impact standards without secondary additives that may leach or bloom.

    Industry compliance standards

    • EN ISO 7823-2 (Acrylic sheets—Weather resistance requirements)
    • ANSI Z97.1 (Glazing Materials Safety)
    • ASTM D4802 (Specification for Acrylic Plastic Sheet)
    • Building code requirements for architectural panels (ICC, local standards)

    Typical usage ratio

    • 0.1–0.4% of total monomer mass, with dosage determined by thickness, intended outdoor use, and transparency rating targets

    Downstream process integration

    • Metered addition during MMA or copolymer monomer batch charging; distributed under inert atmosphere before thermal or suspension polymerization. Process integration ensures uniform incorporation and minimizes haze formation.

    Final product types

    • UV-resistant PMMA (acrylic) sheets
    • Sign panels and light diffusers
    • Protective window and canopy panels

    4. UV Protection in Outdoor-Curable Fiber Reinforced Plastics

    Sheet molding compounds and gel coats for outdoor composites in construction and marine industries require in-matrix UV absorbers to preserve both mechanical strength and gloss. The copolymerizable nature of the molecule allows manufacturers to form robust chemical bonds within unsaturated polyester or vinyl ester matrices, unlike conventional surface-applied stabilizers. This contributes to reduced crack propagation and surface weathering of composite roofing, façades, and boat hulls over service lifetimes exceeding a decade.

    Industry compliance standards

    • ASTM D2565 (Xenon-Arc Exposure of Plastics)
    • EN 13523-10 (Coil Coated Metals—Resistance to UV radiation)
    • ISO 9001:2015 (for certified SMC/BMC production)
    • ISO 11341 (Artificial weathering tests on coatings)

    Typical usage ratio

    • 0.15–0.5% by resin weight, modulated by part thickness, type of reinforcement, and service location UV index

    Downstream process integration

    • Dispersion with resin, pigments, and fillers prior to addition of initiators and filler packs. Full wet-out and compatibility with common peroxide/MEKP systems facilitate uniform distribution in finished SMC or pultruded profiles.

    Final product types

    • Gelcoat-finished composite panels for exterior architecture
    • Marine topcoat parts (boat hulls, decks)
    • Construction façade elements and architectural trim

    5. UV-Stable Waterborne Wood Coatings

    Wood furnishings and flooring used in well-lit interiors are subject to discoloration and surface embrittlement from ambient sunlight. Our product supports the formulation of waterborne polyurethane and hybrid acrylic wood coatings, helping manufacturers achieve high optical clarity while delivering long-lasting photo-protection. Its ability to copolymerize during UV or thermal curing in low-VOC latex systems differentiates from non-reactive absorbers that may leach over time.

    Industry compliance standards

    • EN 927-6 (Coating materials and coatings for exterior wood—Exposure to artificial weathering)
    • VOC content limits under EPA 40 CFR Part 59 and EU 2004/42/EC
    • EN 71-3 (Safety of toys—Migration of certain elements, for child furniture)
    • ISO 16000-9 (Emission test chamber for indoor building materials)

    Typical usage ratio

    • 0.2–0.7% by solids in final latex concentrate, depending on target application thickness and window light exposure simulations

    Downstream process integration

    • Premix with acrylic or polyurethane dispersions post-neutralization, disperse under low shear into the paint mill base. UV-initiated cure or forced drying locks molecule into polymer lattice during final application.

    Final product types

    • UV-curable and waterborne wood finishes
    • Floor varnishes for commercial interiors
    • Light-stable kitchen cabinetry and furniture coatings
    Free Quote

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    Certification & Compliance
    More Introduction

    Introducing 4-Methacryloxy-2-Hydroxybenzophenone: Real-World Insights from the Manufacturer

    Our Experience with 4-Methacryloxy-2-Hydroxybenzophenone Production

    Every batch of 4-Methacryloxy-2-Hydroxybenzophenone we’ve produced comes from daily hands-on attention, not only in process control but also in the ways we troubleshoot, improve, and refine our work based on both feedback and what we observe on our own production floor. Unlike third-party sellers, we stand in front of the reactors, monitor the temperature, adjust agitation rates, and check purity at every pivotal step. Producing this compound is no off-the-shelf operation. It requires both practical know-how and a sharp understanding of customer demands, especially considering the sensitivity of UV-curable formulas and coatings, where even slight impurity or off-ratio can mean performance issues downstream.

    Understanding 4-Methacryloxy-2-Hydroxybenzophenone at the Factory Level

    Our 4-Methacryloxy-2-Hydroxybenzophenone typically appears as a yellowish crystalline powder, with purity levels usually above 99%, which we verify by HPLC and titration after each reaction batch. The faint aromatic odor is normal for this family of benzophenone derivatives. We invest in trace moisture control, targeting levels below 0.5% because water in the final product can create side reactions when our customers use it in their photoinitiated applications. The major draw of this compound comes from its dual function: the 4-methacryloxy group readily copolymerizes with acrylate systems, while the hydroxybenzophenone core absorbs UV light strongly. This combination allows formulators to anchor the UV absorber directly into the polymer backbone, building in protection rather than relying on migration-prone additives.

    From experience, strict temperature control during synthesis prevents yellowing and side product formation. We monitor for residual solvents using GC analysis, as traces of alcohols or esters can compromise downstream applications. In liquid resin formulations, even ten ppm of an unwanted residue can lead to gassing, haze, or unpredictable shelf-life. Throughout our process, we test not only appearance and solubility in common monomers—such as MMA, HDDA, or TMPTA—but also stability under simulated storage and curing conditions. Years of working closely with both research chemists and plant engineers have shown us that surface finish and transparency in cured urethanes or acrylics rely directly on the purity and performance of raw photoinitiator components like this one.

    Application Knowledge: Where and Why We See 4-Methacryloxy-2-Hydroxybenzophenone Making a Difference

    The strongest demand comes from clients reformulating automotive and industrial topcoats, architectural finishes, and high-performance plastic packaging. Photopolymer chemists look for covalent bonding between the UV absorber and the matrix so that migration, blooming, or extraction are less of a problem—important for coatings that demand outdoor durability, scratch resistance, and stable color over years of sun exposure. By the time we supply this compound, our customers expect a narrow melting point and consistent UV absorption at 325-340 nm because that is the spectrum most responsible for polymer yellowing and embrittlement.

    We’ve observed that clients working in electronics and micro-optics rely on our product to help extend the working life of encapsulants and adhesives exposed to sunlight and strong artificial light. Direct incorporation by copolymerization ensures longevity, which isn’t always possible using simple blend-in UV absorbers. In the lab, we work with in-process sampling and accelerated aging to guarantee that every kilogram we ship meets the threshold for both color stability and UV shielding. Any deviation prompts an internal investigation and corrective actions.

    Compared to non-reactive UV absorbers, 4-Methacryloxy-2-Hydroxybenzophenone provides the assurance that protection won't leach away or degrade under extended weathering or in contact with cleaning agents. This advantage matters most in outdoor or high-abuse environments, such as automotive headlamp lenses or exterior composites, where the added methacrylate functionality means the absorber forms a permanent part of the finished article.

    How Our Approach Sets Us Apart from Other Manufacturers

    Production of 4-Methacryloxy-2-Hydroxybenzophenone draws on our long tradition of high-purity specialty chemical manufacturing. Over the years, we’ve built up specialized filtration and crystallization capabilities, which allow us to hit stricter color and impurity limits than mass-market producers. Quality starts with our raw material selection. Pharmaceutical-grade hydroxybenzophenone and fresh methacrylic anhydride form the basis of every batch, which we keep protected from ambient humidity and oxygen, right from storage to charging in the reactor.

    Vacuum distillation and continuous monitoring of pH allow us to minimize unwanted by-product formation. Every mother liquor is recycled through a purification loop to recover intermediate yields, which reduces both cost and environmental footprint. We train our operators to recognize subtle process signals that indicate deviation, such as color changes, viscosity spikes, or unexpected exotherms. These skills are hard-won and shape the reliability of our supply more than anything that shows up in a lab certificate.

    Other versions of benzophenone UV absorbers have different strengths: some offer broad absorption or improved compatibility with specific binders, but lack the anchoring reactivity of our 4-methacryloxy product. Some suppliers cut corners by boosting throughput at the cost of purity, leading to more frequent downstream process outages or product returns. Our direct customers—coating producers, automotive formulators, and high-value plastics makers—prefer the added predictability and performance they get from us. Our technical team supports them not only during scale-up, but throughout the shelf-life of every lot.

    Why Direct Copolymerization Matters in Photostabilizer Performance

    The methacryloxy group in this molecule acts as a built-in handle, reacting seamlessly in free radical polymerization processes. This means users can lock in photostability at the molecular level, reducing issues like migration and volatility, especially in high-clarity or thin applications. For packaging makers, this translates to longer shelf-life for products stored indoors under retail lighting—everything from shampoos to soft drinks to UV-sensitive pharmaceuticals benefits from less yellowing and flavor/odor change over time.

    Technical discussions with customers reveal a consistent pain point: the unpredictability of additive-based stabilization. Migration tests in real-world conditions show that traditional, non-reactive UV absorbers bleed out during extrusion or eventually wash out in the environment. We help overcome these hurdles by focusing on the chemistry behind polymer-bound stabilization, supported by our in-house pilot lines that replicate factory-scale molding and curing. Side-by-side panels and accelerated weather testing back up our commitment to measurable, reproducible performance gains.

    Our customers often want evidence that the product we supply actually migrates less or holds up better under adverse conditions. We routinely submit our material for third-party comparison under ISO 4892 (accelerated weathering) and ASTM G155 (xenon arc exposure) protocols. Results confirm that the covalently bonded photostabilizer outlasts additive approaches, retaining color and gloss even after hundreds of hours of high-intensity UV.

    End-User Considerations: Processing, Handling, and Compatibility

    In our discussions with long-term partners, job-site realities often carry as much weight as laboratory data. Our technicians assist with blending and dispersion trials, especially in fast-reacting systems or when higher loadings are planned. The tendency of 4-Methacryloxy-2-Hydroxybenzophenone to form hydrogen bonds with host resin materials can influence melt viscosity and cure kinetics. Resin formulators value the way our product integrates into both solvent-free and waterborne systems, although results vary depending on resin composition, photoinitiator load, and process temperatures.

    Safe and consistent processability matters. We keep particle size distribution within a narrow window, improving ease of mixing and reducing the risk of caking or dusting at customer sites. Our packaging team uses moisture-proof foil-lined drums and smaller bags as needed, backed by real-world logistics testing for temperature and humidity swings during transit. Consistency in bulk density and pourability, which affects both small-scale labs and fully automated batch operations, results from bidirectional customer feedback and our hands-on process adjustments over time.

    We keep finished goods turnover high because experience shows storage leads to small but critical losses in moisture content and surface condition. Regular audits and compliance with site-specific handling procedures are part of our routine. This strategy extends to post-sale support—fielding formulation advice, coping with shift-to-shift equipment changes, and troubleshooting the odd compatibility error that inevitably arises during product launches or scale-ups.

    Comparing with Other UV Absorber Products from the Manufacturer’s Perspective

    In our experience, alternative products like 2-hydroxy-4-methoxybenzophenone offer broader wavelength absorption but lack the built-in polymerizable anchor. If you use standard benzophenone-type stabilizers, you may deal with ongoing leaching or slower initial cure rates. The cost-per-application may look lower on the product invoice, but you pay with ongoing maintenance, more frequent replacement cycles, and sometimes warranty claims for color change or surface degradation.

    Customers sometimes compare our product to triazine or oxalanilide stabilizers, which indeed provide high UV-B absorption but can result in compatibility challenges with certain binder systems. Reactivity profile differences mean these alternatives don’t always survive melt and cure steps. Few additives offer the combination of reactivity, broad UV protection, and ease of use that our 4-Methacryloxy-2-Hydroxybenzophenone delivers. Ongoing collaboration with paint and plastic manufacturers drives our choice of which UV absorbers to keep at commercial scale and which to relegate to made-to-order production. We monitor market feedback closely, noting strengths and weaknesses based on real-world panel and part performance, not just internal marketing observations.

    Regulatory and Environmental Standing

    As a direct producer, we face and adapt to tightening global standards. European and North American regulations require low residual monomer content and verify the absence of listed substances. Our product undergoes both internal testing and outside confirmation to satisfy ROHS, REACH, and specific food-contact or toy safety requirements set by customers. We document not only the chemical composition and physical properties of every batch, but also trace impurity profiles and results of migration or leaching tests. These records serve as both reassurance and hard evidence for our customers’ purchasing and compliance managers, who don’t compromise on product quality or traceability.

    Over the past five years, we’ve responded to both market and regulatory pushes for greener production. Solvent recycling, energy-efficient drying, and closed-loop process water treatment now form key parts of our manufacturing model for 4-Methacryloxy-2-Hydroxybenzophenone. We share environmental impact data with our largest clients, meeting their requests for verified lower-emissions and lower-waste product batches. Initiatives like batch-by-batch tracking of CO₂ and VOC emissions have moved from experiment to permanent policy. Our reporting system meets standards for chain-of-custody transparency, reviewed at regular intervals by third-party auditors.

    Continuous Improvement Rooted in Customer Feedback and Process Analytics

    Through years of close technical cooperation with our end users, we’ve rebuilt parts of our production process more than once to meet novel requirements. Customer audits sometimes reveal processing realities we hadn’t picked up—for instance, how surprisingly narrow color limits can be for high-end electronics or how particle size impacts multilayer pipe or optical lens performance. We bring pilot-scale data back to our plant, tweak process parameters, test new purification methods, and adapt logistics based on what helps our customers don’t just meet but exceed application goals.

    Frequent collaboration with research partners, both in academia and industry, brings early-warning signals on new regulations or shifts in technical preferences. For example, the push towards BPA-free and non-extractable UV stabilizers changed our focus from conventional benzophenone derivatives towards the current offering. By adopting more robust cleaning and in-process monitoring, we ensure that each new generation of 4-Methacryloxy-2-Hydroxybenzophenone matches the evolving needs for clarity, long-term color retention, and mechanical properties under harsh exposure.

    We host ongoing seminars and technical days for users, offering insight into photostabilizer design and troubleshooting. These forums let us collect field data, spot early signals of new application challenges, and train both young chemists and experience operators in recognizing and resolving potential issues before product leaves our dock.

    Learning from Production Challenges and Market Shifts

    Over two decades, challenges like raw material shortages, sudden surges in demand for outdoor-durable coatings, and rapid shifts to low-VOC formulations have shaped how we build and manage our supply of 4-Methacryloxy-2-Hydroxybenzophenone. For instance, the switch from solvent-based to water-based coatings meant our purification and drying technology had to handle even lower residuals, and our suppliers had to guarantee consistent precursors. We have seen customer demand swing with new research on microplastics and environmental safety, leading to more calls for polymer-bound stabilizers with demonstrated non-migration and proven low-toxicity profiles.

    Logistics taught us hard lessons in both high humidity and extreme cold, affecting package integrity and the ease of unloading on customer lines. After receiving feedback on clumping, we redesigned both bag and drum linings and set up regional warehousing in key markets to minimize climate impact. These changes come from the practical needs of the plant operators, who care more about reliability and process smoothness than abstract performance indices.

    Tighter downstream process controls at our customer sites have sent more requests for support with regulatory paperwork and contamination management, so we increase our own batch-level documentation and pro-active QA. Today, every shipment leaves with a multi-page analysis, reflecting our response to both longstanding and rapidly changing customer expectations.

    From Factory Floor to Finished Product: The Human Factor in Chemical Manufacturing

    Standing inside the plant, operators and chemists alike know the dents, stains, and late-hours troubleshooting that come with high-purity production. Practical knowledge—not just protocols—guides the hand as reactors cycle through heating, mixing, and recovery. The trust we build when we hand off a drum of 4-Methacryloxy-2-Hydroxybenzophenone goes beyond statistical QC; it’s founded on thousands of hours of vigilance, incremental learning, and open lines of communication with both veteran and first-time customers.

    In every case where a problem arises—unexpected reactivity with certain resin systems, faster-than-expected yellowing, or even logistical missteps—we take direct calls, talk through issues, and launch a root-cause investigation. We have never seen a perfect batch every time, but we pursue continuous improvement based on granular feedback and fast-cycle troubleshooting. Mistakes or inefficiencies become opportunities to revisit process diagrams, adjust instrument calibrations, or clarify handling procedures with both our team and those relying on our product downstream.

    Solutions for Common Industry Pain Points with 4-Methacryloxy-2-Hydroxybenzophenone

    Using this product to full advantage means recognizing both its chemical strength and its quirks. In applications where haze, extraction, or color drift threaten the end-product value, we have worked with customers to reformulate binder ratios, optimize curing conditions, or adjust additive packages. Our technical advisors review performance data with coatings formulators, ink makers, and plastics engineers, helping them get the right balance between UV protection and physical property retention.

    Some users seek higher thermal stability or improved solubility with non-standard monomer bases. Drawing from our experience, we suggest pre-dissolution or pre-blending steps, or work to integrate the UV stabilizer via higher-reactivity co-initiator systems to improve process throughput. Long-term storage stability often requires matching the barrier properties of packaging to the typical plant climate, and we invest time adjusting moisture barriers and optimizing batch sizes to match seasonal and regional differences.

    For customers in stringent regulatory environments—including those supplying sensitive markets like medical devices or child-contact articles—we adapt our manufacturing and QC regimes to track even ultra-trace regulated impurities. Detailed product disclosure and help with risk assessments enables safe, predictable launch schedules and market approvals, greatly streamlining both procurement and ramp-up.

    Looking Ahead: Ongoing Partnership and Shared Progress

    Chemical manufacturing demands more than batch records and safety data. Customers depend not only on technical benchmarks but also on the predictability and accountability of their suppliers. We prioritize this long-term trust by remaining transparent, agile, and available to address every practical consideration with 4-Methacryloxy-2-Hydroxybenzophenone—from routine formulation support to crisis-level troubleshooting. Year after year, our investment in skill, equipment, and honest communication continues to shape our process and product, building not only molecules but real partnerships across the industries we serve.