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4-Chlorobenzenesulfonic Acid Potassium Salt

    • Product Name 4-Chlorobenzenesulfonic Acid Potassium Salt
    • Alias Potassium 4-chlorobenzenesulfonate
    • Einecs 241-348-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    691274

    Chemical Name 4-Chlorobenzenesulfonic Acid Potassium Salt
    Cas Number 139-52-8
    Molecular Formula C6H4ClKO3S
    Molecular Weight 230.71 g/mol
    Appearance White to off-white crystalline powder
    Melting Point Above 300°C (decomposes)
    Solubility In Water Soluble
    Storage Conditions Store at room temperature, keep container tightly closed
    Synonyms Potassium 4-chlorobenzenesulfonate
    Inchi InChI=1S/C6H5ClO3S.K/c7-5-1-3-6(4-2-5)11(8,9)10;/h1-4H,(H,8,9,10);/q;+1/p-1
    Ec Number 205-358-6
    Pubchem Cid 23677955

    As an accredited 4-Chlorobenzenesulfonic Acid Potassium Salt factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 500g package contains 4-Chlorobenzenesulfonic Acid Potassium Salt in a sealed, white HDPE bottle with a tamper-evident cap.
    Shipping 4-Chlorobenzenesulfonic Acid Potassium Salt is shipped in tightly sealed, chemical-resistant containers to prevent moisture absorption and contamination. Packages are clearly labeled, comply with local and international regulations, and are handled as non-hazardous cargo under normal conditions. Shipping includes appropriate documentation and safety data sheets for safe transport and handling.
    Storage 4-Chlorobenzenesulfonic Acid Potassium Salt should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from incompatible substances such as strong oxidizers and acids. Protect it from moisture and direct sunlight. Proper labeling is essential, and storage at room temperature is recommended. Use suitable personal protective equipment (PPE) when handling to prevent skin and eye contact.
    Application of 4-Chlorobenzenesulfonic Acid Potassium Salt

    Applications of 4-Chlorobenzenesulfonic Acid Potassium Salt in Industrial Manufacturing

    4-Chlorobenzenesulfonic Acid Potassium Salt is a well-established intermediate in chemical manufacturing, supporting process innovation and product consistency across several specialized downstream sectors. As an original producer, we tailor specifications and supply stability to long-term partnerships in performance polymers, dyestuff synthesis, agrochemical manufacture, pharmaceutical intermediates, and electroplating additives.

    1. Reactive Dyestuff Synthesis for Cellulosic Fibers

    Major textile chemical plants use this sulfonic acid potassium salt in condensation and diazotization reactions for manufacturing monochloro-triazine, vinylsulfone, and azo-based reactive dyes. Its halogenated and sulfonate functionality is key in building highly water-soluble chromophores. Consistency in purity, controlled salt content, and batch reproducibility are critical for obtaining high tinctorial strength and stable dye performance for export-oriented dyehouses.

    Industry compliance standards

    • REACH Annex XVII and SVHC rules for azo intermediates
    • OEKO-TEX® Standard 100 (Annex 4) requirements for dye precursors
    • ZDHC MRSL (Version 3.1) manufacturer input chemical restrictions
    • ISO 9001:2015 and ISO 14001:2015 for certified chemical production

    Typical usage ratio

    • Ranges from 4%–8% by mass in diazotization or coupling step, based on molecular target and process water load
    • Process control labs adjust dosage for shade development and salt compensation

    Downstream process integration

    • Feeds directly into cooled reaction vessels with base and chilled acid for diazotization
    • Introduced prior to coupling component for color formation
    • Precipitation and filtration handled under inert atmosphere to preserve product

    Final product types

    • Powder and liquid reactive textile dyes (ME, HE, MCT, VS types)
    • High fastness print pastes for cellulosic fabrics
    • Specialty colorants for wool and nylon blends
    • Exported dye formulations for rotary and digital textile printing

    2. Electroplating Brightener and Additive Production

    Manufacturers of specialty chemicals for metal finishing incorporate this potassium salt as a sulfonating agent and functional group carrier in the synthesis of organic brighteners and leveling agents. By modifying aromatic substrates, this salt enables tailored molecular structures compatible with neutral and acidic plating baths, supporting advanced decor chrome and nickel plating systems in automotive and appliance assembly.

    Industry compliance standards

    • EU RoHS Directive 2011/65/EU (Annex II) for chemical restriction
    • EN ISO 9227 for corrosion testing of treated metals
    • IECQ QC 080000 for hazardous substance process management
    • ASTM B456 and B849 for deposit quality standards

    Typical usage ratio

    • Applied at 1%–3% loading in organic intermediary synthesis for plating formulations
    • Fine-tuned depending on surfactant or leveling agent yield requirements

    Downstream process integration

    • Charged during batch or semi-batch synthesis of organic sulfonate brighteners
    • Product purified by vacuum distillation and direct blending into concentrate bases
    • Tested for residual salt to reduce contamination risk in plating baths

    Final product types

    • Nickel and chromium plating additives
    • Electroplating brightener formulations and maintenance concentrates
    • Levelling agents for decorative and functional coatings
    • Pre-mixed electroplating bath chemicals for OEM surface finishing

    3. Agrochemical Sulfonylurea Herbicide Intermediate

    Agrochemical formulators select this chlorinated aromatic sulfonate as a key tosylation reagent in the preparation of highly effective sulfonylurea herbicide precursors. Its use supports molecular modifications to achieve both crop selectivity and good aqueous dispersibility in finished suspension concentrates, meeting industry expectations on weed spectrum control and environmental profile for commercial agriculture applications.

    Industry compliance standards

    • FAO Specifications for Plant Protection Products
    • EU Regulation (EC) No 1107/2009 on pesticide actives
    • ISO 9001:2015 quality management in active ingredient production
    • Chinese GB/T 1604-2008 and GB/T 1605-2008 for agrochemical intermediates

    Typical usage ratio

    • Used at 5%–9% by mass in tosylation step, depending on sulfonylurea target and batch scale
    • Adjusted for molecular yield and desired hydrophilic–hydrophobic balance in final tech

    Downstream process integration

    • Introduced to reaction sequence after base aromatic feedstock activation
    • Handles at mid- to late-stage condensation to ensure regioselective substitution
    • Wastewater processed through advanced sulfonate neutralization before discharge

    Final product types

    • Ready-to-use sulfonylurea herbicides such as metsulfuron and chlorimuron
    • Wettable granules and water-dispersible concentrate herbicides
    • Bulk technical grade actives shipped to formulation plants
    • Patented combination weed control products

    4. Pharmaceutical Bulk Intermediate for Active Synthesis

    Pharmaceutical manufacturers employ this potassium salt for regioselective aromatic sulfonation in the multi-step synthesis of APIs, especially in anti-infectives and cardiovascular agent families. The material’s controlled reactivity allows precise introduction of sulfonate and chloro aromatic functionalities, facilitating clean conversion and downstream purification in cGMP settings. Careful documentation and traceability support regulatory audit processes and DMF submissions for finished active approvals globally.

    Industry compliance standards

    • US FDA 21 CFR Part 210/211 for pharmaceutical manufacturing controls
    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • EP, USP, and JP pharmacopoeial monographs on intermediate purity
    • EU EudraLex Volume 4 Annex 15 for qualification and validation

    Typical usage ratio

    • Varies from 3%–7% by mass depending on sulfonation degree and target intermediate structure
    • Production engineers scale addition with reference to process analytical technology (PAT) data

    Downstream process integration

    • Added at temperature-controlled charging stages in glass-lined reactors
    • Facilitates direct aromatic conversion prior to API ring-closure or substitution
    • Intermediate tracked through material batch records and stability studies

    Final product types

    • Bulk API intermediates for anti-bacterial, anti-hypertensive, and anti-diabetic actives
    • Pharmaceutical compounds submitted for DMF/CEP registration
    • Small molecule intermediates for contract manufacturing organizations (CMOs)
    • Investigational new drug (IND) supply lots for global clinical trials

    5. Engineering Polymer Additive Preparation

    Producers of specialty engineering plastics apply this product as both a chain terminator and performance modifier in polymerizations requiring selective sulfonate-capping. Its high chemical stability and functional group control provide superior polymer dispersibility and antistatic behavior, allowing compounders to improve flow, strength, and surface charge in customized polymer blends for high-tech components in electronics and automotive supply lines.

    Industry compliance standards

    • EN ISO 9001:2015 for quality-controlled additive production
    • ISO 11469 and ISO 1043-4 for polymer marking and additive declaration
    • RoHS (2011/65/EU and amendments) for plastics in electrical/electronic goods
    • UL 94 and IEC 60695-2-11 fire retardancy testing on finished resins

    Typical usage ratio

    • Used at 0.5%–2% masterbatch concentration, depending on polymer matrix compatibility and desired property boost
    • Direct additive dosing monitored via in-process melt flow and dispersion analytics

    Downstream process integration

    • Feeds via volumetric dosing to single- or twin-screw extruders during melt blending
    • Multiple passes or higher shear used to ensure uniform distribution in engineering resins
    • QC sampling for antistatic and color performance in pellet form

    Final product types

    • Antistatic and flame-retardant engineering plastics
    • High-performance blends for automotive under-the-hood parts
    • Polymer films and sheets for display electronics and packaging
    • Masterbatches for wire and cable insulation compounds
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    Certification & Compliance
    More Introduction

    4-Chlorobenzenesulfonic Acid Potassium Salt: A Chemical Manufacturer’s Insight

    Understanding 4-Chlorobenzenesulfonic Acid Potassium Salt

    Making 4-Chlorobenzenesulfonic Acid Potassium Salt for years, we stand behind a product built on practical chemistry and close attention to what works on the ground for industrial processes. In our manufacturing plants, we carry through the precise sulfonation of chlorobenzene, followed by neutralization with potassium hydroxide under strictly controlled moisture and temperature conditions. This straightforward path keeps both purity and yield up to the standards our end-users demand. Our product, which many in the market recognize by its code 4-CBSA-K or simply PBSCA-K, plays a unique role in synthesis and processing, setting itself apart from similar benzenesulfonates.

    Production Methods Rooted in Experience

    We have learned firsthand that running a batch for 4-Chlorobenzenesulfonic Acid Potassium Salt is not about speed—it’s about understanding the exothermic reactions and thoroughly controlling final pH and clarity of the solution. Operating reactors ranging from 500 liters to several tons, our teams avoid shortcuts that compromise consistency. We always use high-purity chlorobenzene as the starting point. Water content and particle size distribution remain tightly monitored, because downstream users in dye intermediates and pharmaceuticals require reliable physical profiles. Slowing down the final crystallization phase keeps insoluble impurities out, allowing our clients to use the product repeatedly without major filtration or reprocessing.

    Unlike commodity potassium salts churned out with minimal oversight, we focus on keeping batch-to-batch variation negligible. Our lab teams check every drum for sulfonic content, chloride, and potassium specs, using methods honed over years of side-by-side comparison with international and regional standards. Staying honest about our results and learning where improvements are needed has won the trust of returning partners, especially those in export markets.

    Physical Features and Consistency Matter

    The potassium salt form of 4-Chlorobenzenesulfonic Acid typically arrives as a pale to off-white crystalline powder, sometimes with a slight pink tinge due to trace byproducts. Particle size distribution affects blendability in various formulas, especially in pigment production and certain applications in photographic chemicals. We noticed early on that customers running high-shear mixers or seeking fine suspensions prefer our standard mesh size, which remains consistent from lot to lot. Moisture content gets a lot of attention too, because excess water can throw off reactions and lead to caking—a real headache for automated feed systems. Our vacuum drying process reduces residual water far below what older open-pan methods yield, cutting rework and product loss downstream.

    Quality control doesn’t stop at the production line. For every order, we include supporting analysis of heavy metals and organic residues, both crucial for users needing clean reaction profiles in pharma synthesis or electronics. Fugitive sodium content—which sneaks in with potassium hydroxide of lower grades—remains minimal in our lots, so formulations do not drift over time. Unlike less disciplined manufacturers, we reject any lot falling outside these ranges and recycle it internally, cutting waste and cost for all involved.

    Applications in Industry

    From our vantage point, 4-Chlorobenzenesulfonic Acid Potassium Salt proves its worth through versatility. It has a steady presence in dye intermediates manufacturing, where the chlorinated aromatic ring and sulfonic group serve as a robust foundation for coupling reactions. Many leading dyestuff makers credit their consistent product hues and high yields to the predictable behavior of our potassium salt in the reaction vat. We also supply this chemical to facilities producing specialty surfactants, where the hydrophilic sulfonate group helps tune surface tension in tough conditions. The potassium counterion is especially sought after for its solubility in certain organic-media blends—unlike calcium or sodium analogs, it doesn’t build up troublesome precipitates when working with alkaline process waters.

    Another major outlet is the pharmaceutical industry, where this compound’s clean electrophilic aromatic framework makes it a building block for API intermediates. We see steady demand in southeast Asia for vitamin and antibiotic precursor synthesis, much of it driven by purity thresholds set by regulatory agencies. Having run side-by-side trials with multiple process routes, our tech teams found that the low residual chloride levels in our product cut purification times and waste, which matters for cost and compliance tracking. In comparison, generic grades often result in cloudy, off-spec reaction broths that slow everything down.

    In a more technical usage, 4-Chlorobenzenesulfonic Acid Potassium Salt enables sulfonation and chlorination reactions for our partners developing advanced polymer intermediates—including certain ion-exchange resins for water treatment. Potassium ion exchange with substrate matrices sometimes achieves better anchoring, so research labs ask us for custom particle size and surface area profiles. Having in-house customization flexibility lets us fill these needs on a short timeline.

    Why Potassium Salt Stands Apart from Sodium Sulfonates

    As the manufacturer, we often get asked why select the potassium salt above more common sodium analogs. The answer comes straight from our testing and our customers’ feedback. Potassium’s larger ionic radius and lower lattice energy foster better dissolution in specific solvents, reducing sediment formation in many aqueous-organic blends. For customers running multi-step synthesis, the lower tendency to form hard, insoluble cakes means easier cleanup and less downtime. Our team tested competing sodium versions using the same process conditions, and even with equal purity grades, potassium emerged with finer, more stable dispersions and no scaling on reactors.

    Another key difference shows up in metal-sensitive downstream processing. Sodium ions, even in trace amounts, interfere with catalysts and deactivate sensitive reagents—especially in pharmaceutics and battery material prep. Potassium displays a gentler profile in these scenarios, so our partners report fewer rework cycles and longer catalyst life. Every year, our R&D partners in paints and coatings send feedback suggesting potassium’s role in achieving consistent film formation and pigment wetting. Over time, this has driven us to direct more capacity to this salt, instead of trying to retrofit sodium products where they simply don’t fit.

    In waste management terms, potassium generates friendlier effluent profiles than sodium. Water treatment operators find it easier to adjust potassium-laden discharge with less risk of violating salinity thresholds. Several legislative frameworks now encourage switching away from sodium-heavy chemicals to reduce environmental footprint, so offering a robust potassium product positions our partners to future-proof their own production lines.

    Specifications That Actually Matter for End Users

    We learned not to flood data sheets with scores of unreadable specs. Instead, users want assurance on just a few factors: purity, solubility, and predictability of composition. In our operation, regularly tested quantities include active sulfonate content—averaging above 94% by titrimetric measurement—along with free chloride content, which we keep below 0.5% through consistent raw material screening. Potassium content checks out through flame photometry, cross-linked with titration results for confidence. Higher color numbers or odd-smelling batches never leave our warehouse, because we see first-hand how these cause issues for downstream blending, even if nominally “within spec.”

    Customers often ask about heavy metals or organic impurities; we comply with all relevant local and REACH/ECHA guidelines, regularly benchmarking against the strictest export standards. Experience tells us this up-front approach reduces quality disputes later and builds practical, rather than formal, trust. Each year, we invest in newer detection equipment because advancements in process traceability directly pay off in customer retention. We take pride in open dialog around test results—good or bad—and have learned that informed clients, not just “compliant” clients, become long-term partners.

    Supply Security and Traceability for Partners

    The global supply chain for raw chemicals faces regular disruptions. Our site operates with both local and resilient international material suppliers, and we maintain reserve stocks of main inputs. This backbone matters during volatile periods; we’ve weathered transport strikes, regulatory delays, even raw material export bans. Instead of promising the lowest upfront price, we offer delivery backed by stock and standing procurement contracts. End users appreciate knowing that one missing drum won’t halt a line.

    Every bag we ship carries batch-level traceability anchored to internal process records kept for at least five years. In the unlikely event of a recall or client-side issue, our QA staff don’t fumble for answers. We can trace the timeline of every kilogram from raw input through to drum sealing, cross-linked with quality control measurements. This open-book approach differs from the patchier records common among short-term brokers or traders, who often cannot say what happened further up the chain.

    Supporting Sustainable and Responsible Chemical Use

    Over the past years, customers have increasingly asked about upstream environmental and social impacts tied to specialty chemicals. We recognize that industry is never separate from community. Our plant runs closed-loop water usage and heat recovery systems, not simply to save money, but because reduced waste and energy cost benefit local stakeholders. We recover chlorinated organics for internal reuse and have installed effluent polishing units that keep discharge below government thresholds. Every improvement arose from practical troubleshooting, not distant policy directives.

    We source key raw materials from audited suppliers with established compliance to local labor and environmental laws. While no global system eliminates risk, our operational audits and in-person visits discourage corner-cutting. If a supplier strays from shared expectations, we shift volumes elsewhere—a lesson learned the hard way during several regional regulatory crackdowns. The upshot for our downstream buyers is that they don’t risk surprise regulatory or environmental penalties by using our material.

    Collaborating with Customers for Technical Improvements

    Some clients come with exact specs in hand; others arrive with process headaches and look for a problem-solver. On our end, shipping a product isn’t the end of the story. We keep a technical and applications-support team available, familiar with process chemistry and product performance. Small tweaks—like providing a special median particle size or enhanced blending properties—can mean the difference between a process that hums and one that grinds to a halt. Several times, we have custom-made grades for partners tackling new synthetic routes in agrochemicals or developing innovative colorants.

    Our feedback process draws directly from field reports. If a batch underperforms, we actively engage, sending out technical staff and bench-testing user samples side by side. Many process innovations used at customer sites started with our plant chemists troubleshooting a practical bottleneck with real samples. Over the years, this two-way feedback loop has shaped incremental improvements, from better dust suppression to improved packaging.

    For customers with strict documentation needs, we generate compliance reports, supply chain disclosures, and R&D support packages needed for regulatory filings or ISO process certifications. Unlike firms who keep clients at arm’s length behind web forms, we deal person-to-person with our clients’ process engineers, buyers, and plant managers.

    Responsiveness in a Changing Chemical Landscape

    Market pressures change faster than specification sheets. New applications for 4-Chlorobenzenesulfonic Acid Potassium Salt emerge as fields like electronics, water treatment, and renewable chemicals evolve. Recently, battery technology researchers and resin developers reached out asking for tighter controls on trace organics and a particular moisture range to support next-generation materials. By being embedded in manufacturing instead of just trading, we retain the agility needed to adapt formulations, shipping formats, or batch sizes. Our experience proved that being able to scale production up or down quickly, without compromising process fundamentals, gives our clients a buffer against demand swings and project delays.

    We stay engaged with chemical news, regulatory shifts, and sustainability movements—from local laws so strict that certain discharge values must be monitored hourly, to overseas clients suddenly incorporating full lifecycle assessments in their procurement decisions. Internally, we allocate regular review time for key staff to keep up with scientific and technical progress, because it often translates directly into a new product opportunity or a customer rescue when regulations turn.

    Conclusion: Why Our Perspective Matters

    Many specialty chemicals seem generic until hands-on work reveals their subtle, real-world differences. For us, 4-Chlorobenzenesulfonic Acid Potassium Salt isn’t just another box to tick in a catalog. It is a compound shaped by hard-earned experience, continual process refinement, and honest, technical dialog with the users who rely on it for their own products to succeed. Our approach—one based on know-how and responsiveness—keeps our material relevant and valued as new industries and higher standards emerge. The feedback and cooperation we get from real manufacturers sharpen each process step we take today, and prepare us for the next change down the road.