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4-Bromotriphenylamine

    • Product Name 4-Bromotriphenylamine
    • Alias NSC34525
    • Einecs 221-773-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    347471

    Chemical Name 4-Bromotriphenylamine
    Molecular Formula C18H14BrN
    Molecular Weight 324.22 g/mol
    Cas Number 3017-70-1
    Appearance White to off-white solid
    Melting Point 166-168 °C
    Solubility Slightly soluble in organic solvents
    Purity Typically >98%
    Smiles c1ccc(cc1)N(c2ccccc2)c3ccc(Br)cc3
    Inchi InChI=1S/C18H14BrN/c19-16-11-9-15(10-12-16)20(17-13-5-1-2-6-13)18-14-7-3-4-8-14/h1-12H
    Storage Temperature Room temperature
    Synonyms N-(4-Bromophenyl)diphenylamine

    As an accredited 4-Bromotriphenylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 4-Bromotriphenylamine, 25 grams, is packaged in a sealed amber glass bottle with a tamper-evident cap and product labeling.
    Shipping **Shipping Description for 4-Bromotriphenylamine:** 4-Bromotriphenylamine is safely packed in tightly sealed containers, protected from moisture and light. It is shipped as a non-hazardous chemical under normal transport regulations. Standard safety precautions apply. Ensure proper labeling and documentation. Handle with care to avoid breakage and exposure during transit. For laboratory use only.
    Storage 4-Bromotriphenylamine should be stored in a tightly closed container in a cool, dry, and well-ventilated area, away from incompatible substances such as oxidizing agents. Protect the chemical from light, moisture, and sources of ignition. Ensure proper labeling and keep it away from food and drink. Use appropriate precautions and safety measures when handling or storing this chemical.
    Application of 4-Bromotriphenylamine

    Applications of 4-Bromotriphenylamine in Industrial Manufacturing

    4-Bromotriphenylamine serves as a specialized intermediate across high-value industrial sectors. Our manufacturing expertise allows tight process control for consistent quality, enabling downstream partners to meet demanding technical requirements. See below for selected application fields, with actionable details grounded in industry practice.

    1. Organic Light-Emitting Diode (OLED) Materials

    4-Bromotriphenylamine is widely adopted in the synthesis of advanced OLED hole transport materials. The arylamine structure supports efficient carrier mobility, while the bromine enables further cross-coupling reactions for custom molecular design. Users employ this material in Buchwald–Hartwig or Suzuki–Miyaura couplings to construct high-performance polymers and small molecule transport layers. Purity and trace metal content must align tightly with electronics-grade quality benchmarks to avoid device contamination. Downstream processing integrates this intermediate at the controlled polymerization or small-molecule assembly stage, directly impacting film uniformity and electronic characteristics under mass production.

    Industry compliance standards

    • RoHS Directive (EU 2015/863) for restricted substances in electronics
    • IEC 61249-2-21 low-halogen laminate standards
    • REACH (EC 1907/2006) registration requirements
    • QC: ICP-MS trace metal analysis for optoelectronic materials

    Typical usage ratio

    • 5–20 mol% in initial coupling reactions, adjusted for substrate molecular design
    • In polymer synthesis, 4–12 wt% as part of a multi-component mixture
    • Ratio determination based on target electrical mobility and film uniformity

    Downstream process integration

    • Initial coupling step in multi-step OLED hole transport layer synthesis
    • Introduced prior to polymerization for pre-functionalization
    • Quality-controlled via HPLC and GPC before film coating or vapor deposition

    Final product types

    • OLED display panels (mobile devices, televisions)
    • OLED lighting substrates
    • Flexible display modules
    • Wearable microdisplay electronics

    2. Photocatalyst Ligand Synthesis for Solar Energy

    The advanced triphenylamine scaffold of 4-bromo-derivatives enables downstream manufacturers to produce complex ligands for metal-organic photocatalyst systems. In dye-sensitized and organic solar cells, tailored ligands enhance light absorption and charge separation. Industrial users rely on batch or continuous synthesis where this intermediate offers high functional group tolerance and selective reactivity. The raw material feeds into palladium-catalyzed cross-couplings under nitrogen atmosphere, yielding custom ligands necessary for modern energy harvesting solutions. Lot-to-lot consistency and trace residual halides remain crucial for field performance and long-term stability.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems for electronic component manufacturing
    • IEC 61730 photovoltaic module safety qualification
    • Restriction of Specific Hazardous Substances: RoHS and REACH compliance
    • Internal ICP-OES analysis for trace metal control in solar applications

    Typical usage ratio

    • 0.2–1.5 eq relative to the metal precursor during ligand assembly
    • For multidentate ligand synthesis, 10–25 mol% depending on desired chelating structure
    • Adjustment based on desired photoactivity and absorption spectrum range

    Downstream process integration

    • Feedstock for ligand coupling stage in photocatalyst assembly
    • Post-synthesis purification via chromatography before entering solar cell ink formulation
    • QC implemented prior to module encapsulation

    Final product types

    • Dye-sensitized solar panels
    • Organic thin-film photovoltaic modules
    • Photoelectrochemical water-splitting devices
    • Hybrid photocatalytic coatings for energy applications

    3. High-Performance Polymer Synthesis

    4-Bromotriphenylamine becomes a key monomer in engineering specialty polymers for electrical insulation and flame retardant applications. Manufacturers utilize it in polycondensation and cross-coupling reactions to introduce stable, high-glass-transition point structures. Its brominated site offers controlled reactivity, supporting step-growth or chain polymerization alongside other functional monomers. Downstream producers demand uniformity in particle size and minimal residual starting materials, tested via NMR and DSC methods, to ensure long-term performance in harsh industrial settings.

    Industry compliance standards

    • UL 94 V-0 flame retardancy for polymer materials
    • IEC 60695-11-10 glow-wire test for electrical enclosures
    • ISO 178 Plastics—Determination of flexural properties
    • REACH registration for specialty monomers

    Typical usage ratio

    • 15–40 wt% as a comonomer in polyarylamine blends
    • 5–18 mol% in mixed-monomer matrices for electrical polymers
    • Exact loading driven by flame retardancy target and polymer rigidity

    Downstream process integration

    • Fed into polymerization reactor at initial monomer charge
    • Characterized for conversion by gel permeation chromatography
    • Formulated into pellets or films for extrusion and injection molding

    Final product types

    • High-voltage electrical insulators
    • Industrial circuit board laminates
    • Flame-retardant appliance enclosures
    • Flexible printed circuit boards

    4. Molecular Building Block in Organic Electronic Sensors

    Downstream sensor manufacturers leverage the electron-donating triphenylamine core to synthesize customized sensing layers for organic field-effect transistors (OFETs) and chemiresistive sensors. This intermediate enables modular surface functionalization and precise electronic tuning via cross-coupling, affecting sensitivity and selectivity to target analytes. Material enters the platform at the secondary monomer assembly stage, and analytical producers require high-purity grades with documented synthetic traceability, in line with device reliability and industrial analytical validation protocols.

    Industry compliance standards

    • IEC 60747 standard for semiconductor devices and sensors
    • IPC-2221 generic standard on printed board design for sensor substrates
    • REACH compliance for traceability of organic intermediates
    • ASTM D1003 haze and transparency test for sensor films

    Typical usage ratio

    • 3–12 mol% during functional monomer assembly
    • Layer thickness from 10 nm to 100 nm based on sensitivity design
    • Ratio adjusted for device electronic characteristics such as carrier mobility

    Downstream process integration

    • Introduced during pre-polymer formation for tailored sensor architectures
    • Spin- or slot-die coated in integrated sensor fabrication lines
    • Final device calibration incorporates QC feedback on input intermediate

    Final product types

    • OFET gas sensors
    • Flexible chemical analysis strips
    • Industrial environmental monitoring chips
    • Sensing modules for portable diagnostics
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    Certification & Compliance
    More Introduction

    4-Bromotriphenylamine: A Closer Look from the Factory Floor

    Introduction to 4-Bromotriphenylamine

    For years, my team and I have poured our craft into the precise production of 4-Bromotriphenylamine. In the chemical industry, the margin for error narrows sharply, especially with fine organics whose value reaches beyond the bottom line and stretches into pioneering technology. Among the specialty amine derivatives, this compound carries relevance that comes from its particular substitution of a bromine atom on the para position of triphenylamine’s backbone. We see first-hand how this simple change in molecular structure delivers properties that downstream users count on for reliability and high results in their advanced formulations.

    Manufacturing with Precision: What Sets Ours Apart

    The facility never sleeps. Our chemists work a process that requires both skill and responsiveness. The synthesis of 4-Bromotriphenylamine isn’t just a question of tossing reactants together—achieving high purity mandates stringent controls. Bromination demands attention to every parameter: temperature, stoichiometry, and a close eye for completion. Experienced plant hands, not just automated systems, keep watch for side product signals in real time. Yields reflect the effort; consistent batches assure downstream users they can rely on a stable supply chain.

    Over time, improvements crop up through trial and feedback. We don’t just ship it and move on; we check solubility, monitor for trace metal levels, and test batch-to-batch homogeneity. Never do we assume purity from paperwork alone. Each shipment must match the last in melting range, particle size, and color due to the sensitive nature of end uses. Laboratories flag the faintest impurity, so the work rarely stops at the reactors. Our operators respect the fine line between a product that meets a spec sheet, and one welcomed eagerly by development teams looking to build the next better electronic device.

    Understanding the Technical Edge

    Years of visiting customer plants and troubleshooting lab syntheses taught us that differences in trace byproducts or minor deviation in melting point can change how 4-Bromotriphenylamine behaves in OLED precursors, specialty polymers, or custom dyes. Even experienced chemists find the lot-to-lot consistency makes or breaks their yields, especially when moving from small-batch to pilot plant scale. We saw colleagues forced to repeat steps or clean up failed runs. For us as a manufacturer, these real-world mishaps push us hard to meet narrow specs, cut out contaminants early, and regularly invest in better purification. A few tenths of a percent can cost untold hours in development downtime; being stubborn about routine QC keeps trust strong with demanding clients.

    The technical team focuses on the needs voiced by actual users. In applications such as organic light-emitting diodes or semiconducting polymers, minute levels of residual bromide or color body can spoil optical clarity. Running a melting point higher than 120°C for this compound acts as one indicator for stability and processibility, but broader analytical panels regularly run alongside—UV-vis for color, GC and HPLC for composition checks, and even trace analyses for elemental impurities. Competing producers may offer the same nominal purity. Still, the details differentiate our 4-Bromotriphenylamine—clarity, particle morphology, reliable flow. Instead of chasing catalog numbers, our regular clients share their needs for continuous improvement and process problem-solving.

    Field Applications: What Our Customers Tell Us

    Most of the 4-Bromotriphenylamine we manufacture moves into organic electronics or as a building block for custom ligands. From first-hand conversations at industry conferences, the feedback hasn’t changed: product reliability and batch transparency matter. Laptops, display panels, or photoconductive layers depend on the reproducibility of fundamental chemicals like this. Missteps at this early stage ripple all the way to finished goods, impacting both R&D and end-user experience.

    In practical terms, one missed impurity irks a developer not because it ruins everything, but because it forces extra rounds of purification or retests downstream. Over time, our R&D staff learned that raw data from applied projects helps close the gap between factory reality and end-use optimization. Debugging the reaction sequence of a new device often comes down to nuances in the starting materials—and we field requests for lot-specific certificates, stability profiles, and even advice on alternate solvents when an unexpected behavior crops up. As a result, communication lines stay open year-round, involving not just sales but technologists and QC experts who can speak the language of synthetic chemistry and scale-up.

    Comparison with Other Amine-Based Intermediates

    In the specialty amines field, triphenylamine serves as a versatile parent molecule. Substituting its skeleton with a bromine atom at the para position, as with 4-Bromotriphenylamine, offers unique reactivity that others in the series lack. Several competitors produce triphenylamine itself or variants carrying nitro, methyl, or iodo groups, and these swap out functionality for different downstream chemistry. The brominated form stands apart in cross-coupling chemistry; it serves both as a directing group for metal-catalyzed C–N or C–C bond formation and a strategic handle for building up larger, more complex molecules.

    From our factory records, feedback suggests that the bromine delivers both activation and selective reactivity—opening doors to Pd-catalyzed Suzuki, Buchwald-Hartwig, or Ullmann-type couplings not possible with unsubstituted or chloro- derivatives. This selectivity means downstream users get better yields and fewer side-products, resulting in less time and cost spent on purification. Compared to iodo-analogs, the cost and handling hazards drop sharply; compared to chloro derivatives, reactivity and conversion rates rise. Over years of regular shipments, our customers reminded us that switching intermediates midstream increases costs and risk, so the pursuit of lot stability and specification matching follows as part of daily production.

    Uses and Customer Innovations

    We see our 4-Bromotriphenylamine feed into a range of next-gen projects. Organic electronics researchers rely on this intermediate to fashion materials that glow brighter, conduct better, and last longer in challenging conditions. For OLED developers, the amine core serves as a central structural unit that supports electron transport. This property translates directly into greater device efficiency and longer working life. Chemists working on organic semiconductors have cited the bromine handle as critical for custom molecular architectures: it enables rapid diversification without sacrifice to molecular stability or planarity.

    On the lab scale, formulation scientists report smooth incorporation into screening programs, especially when moving toward large-scale reactions or new catalysis platforms. Batch transparency, rapid documentation, and so-called “trouble tickets” open the door for fast problem-solving. It’s not unusual for customer R&D teams to invite feedback on competing materials, or present us with a direct side-by-side challenge. Given the space requirement, many appreciate that our product supports high loadings with low insolubles, and reproducible analytical signatures speed up in-process monitoring.

    Production Approach: Experience over Expedience

    Every batch of 4-Bromotriphenylamine that leaves our floor comes with a lineage stretching back to both science and hands-on trial. Rather than stretch the plant thin, we dedicate specialized vessels and equipment just to this product, sidestepping the cross-contamination that can trap less focused operations. We saw early on that cleaning between product runs took time but paid off: purer material means fewer headaches for our best customers.

    Analytical chemists on our team maintain a rigorous verification protocol. This focus does more than catch errors; it shapes a culture in which continuous self-critique feeds real improvement. By measuring trace heavy metals or keeping the halide content in a narrow band, we support not only compliance efforts but also the fragile trust that R&D teams lay on the line with their own investors. The benefit stacks up not in glossy brochures but in reputation and handshakes at trade shows or by word of mouth. People recall good product and attentive service longer than routine claims.

    Facing Industry Challenges with Practical Solutions

    Tighter standards in electronics, stricter environmental rules, and the creeping specter of supply chain bottlenecks motivate our team to dig for robust solutions. Our own experience has shown that sourcing of bromine-containing precursors sometimes hits snags; we work proactively with supply partners, building multi-step verification into every bulk delivery. Alternate suppliers stand ready should political or market events force a change, so our output rhythm holds steady even in periods of international volatility. Diversified supplier networks, ongoing audits, and regular contingency drills allowed us to safeguard customers’ project timelines more than once.

    Handling waste responsibly presents ongoing challenges. Brominated compounds rarely just disappear; they require managed, often multi-stage destruction to satisfy both local and international guidelines. We upgraded our facility over the past decade with new scrubbers and real-time effluent monitoring. The goal remains the same—make a difference in our environmental record not through claims but through measurable outcomes. Visitors touring our operation often point to these systems as the real proof of consistent stewardship. Colleagues from downstream industries engage with our environmental engineers to copy our protocols for their own compliance needs.

    Looking Down the Road: Customer Focus Drives Us Forward

    Standing by the reactors on evening shifts or cross-checking lab data, our production veterans often reflect on how far this field has come. Not long ago, many organics were checked in cursory fashion for color or basic purity. Today, expectations ramp up in line with technology’s advance; reports sent off to clients include signed-off analytical packs, spectral overlays, and reaction histories. Our focus remains on adding value through transparency, shared knowledge, and responsiveness. The connections built with field users often uncover ways to shorten processes, flag cost efficiencies, and reveal hidden sources of variability.

    Customers expect partners to respond when failures occur. Our end-to-end involvement in the manufacturing chain puts us in position to solve problems, not dodge them. Field teams receive reference samples, out-of-spec examples, and troubleshooting support. We even field requests for support during device failure analysis, drawing on years of production data and real-world case studies to guide developers back to reliable performance.

    The pace of materials innovation will not slow. Our engineers keep the factory current with upgrades; process intensification, greener solvents, and safer handling protocols make their way into the daily tools. Investment cycles follow need, not fashion. The reward lands not from a single blockbuster product, but in the daily rhythm of producing material that passes muster in the harshest testing environments. Much of our growth stems from reputation; repeat business routes back to jobs well done and details attended to, rather than catalog samples.

    Future Directions for Industrial 4-Bromotriphenylamine Users

    The future for materials like 4-Bromotriphenylamine depends on contributions from both makers and users. Synthetic chemists under pressure to deliver new molecules for OLEDs, OPVs, or advanced pigments count on stable intermediates—there’s little patience for material variation when schedules are tight. Over the years, we’ve expanded technical sharing sessions, not as marketing, but as mutual learning. Developers, whether in start-up labs or established multinational plants, open their doors to us when they sense shared priorities—cost, reliability, and technical adaptability. Every feedback loop, every site-visit, and every shared production snapshot gets logged, adapted, and folded back into the process.

    We aim to stay at the edge of compliance and practical product support. Our raw material tracking builds in both traceability and retrospective analysis capability, meaning we can explain every deviation and lead customers back through their own process development more efficiently. Audit histories show that trust is earned batch by batch. The peculiar thing about supplying to innovators is that as they push chemistry to new limits, we find they teach us as much as we teach them.

    The wave of next-generation materials demands better foundation molecules. We never view 4-Bromotriphenylamine as simply a “widget.” By refining process detail, listening hard to user experience, and running every batch as though it were going into our own trials, we prove the value of vertical integration. Running the full route from raw material to finished compound gives us not just control, but a holistic view of utility and risk. Our engineers still gather physically to review feedback, run root-cause analyses on any deviations, and seek smarter ways to satisfy the chemists experimenting with tomorrow’s semiconductors or light-harvesting devices.

    Conclusion

    Pride enters chemical production not from size but from detail. 4-Bromotriphenylamine stands as an example of what hands-on attention produces: consistent batches, open data, fast troubleshooting, and lasting customer relationships that withstand pricing volatility and technology shifts alike. Each batch reflects a story—a story of persistent effort, feedback and improvement, and real-world partnership. We produce 4-Bromotriphenylamine with these values at the center, helping innovators worldwide build solutions that matter.