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4-Aminostyrene

    • Product Name 4-Aminostyrene
    • Alias 4-Vinylaniline
    • Einecs 219-760-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    740353

    Cas Number 6367-64-6
    Molecular Formula C8H9N
    Molecular Weight 119.17 g/mol
    Appearance Light brown to brown crystalline powder
    Melting Point 34-38 °C
    Boiling Point 244-246 °C
    Density 1.06 g/cm3
    Solubility In Water Slightly soluble
    Purity Typically ≥98%
    Synonyms 4-Vinylaniline, p-Aminostyrene
    Refractive Index 1.613
    Flash Point 110 °C

    As an accredited 4-Aminostyrene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 4-Aminostyrene is packaged in a 25-gram amber glass bottle, securely sealed with labeling for safety, handling, and identification.
    Shipping 4-Aminostyrene should be shipped in tightly sealed containers, protected from light and moisture, and kept in a cool, well-ventilated environment. It is classified as hazardous, requiring proper labeling and documentation. Use suitable packing materials to prevent leaks, and comply with all relevant local, national, and international transport regulations.
    Storage 4-Aminostyrene should be stored in a tightly sealed container under an inert atmosphere, such as nitrogen or argon, to prevent oxidation and polymerization. Keep it in a cool, dry, and well-ventilated area, away from sources of ignition, heat, and incompatible substances such as strong oxidizers and acids. Protect it from light and moisture to ensure chemical stability.
    Application of 4-Aminostyrene

    Applications of 4-Aminostyrene in Industrial Manufacturing

    4-Aminostyrene serves as a specialized intermediate in the development of advanced polymers and functional materials. With precise reactivity and compatibility in downstream processing, this monomer supports targeted innovation in coatings, membranes, and specialty resins. Below, we outline distinct industrial applications proven by actual downstream use, each reflecting practical parameters, integration points, and regulatory reference to guide sourcing decisions.

    1. Specialty Conductive Polymers for Electronic Component Fabrication

    4-Aminostyrene functions as a key monomer for synthesizing polyaniline-derived conductive polymers, which find widespread use as anti-static coatings and printed circuit board components. Its amino-substituted aromatic structure promotes strong coupling in oxidative polymerization, ensuring stable electrical properties and prolonged service life in electronic assemblies. Polymers containing this monomer can be processed in high-throughput, continuous emulsion polymerization lines commonly established in electronics materials plants.

    Industry compliance standards

    • IEC 61249-2-21 for base materials in PCB manufacturing
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances)
    • REACH Regulation (EC) No 1907/2006 Annex XVII
    • UL 746E for polymeric materials in electrical/electronic devices

    Typical usage ratio

    • 15–30% of total monomer feed in aniline copolymer systems; adjusted according to desired conductivity and mechanical strength

    Downstream process integration

    • Direct addition to polymerization reactor vessels during emulsion or oxidative polymerization stage after initiator charge

    Final product types

    • Conductive film coatings for electrostatic discharge protection
    • Printable conductive inks for flexible circuit substrates
    • Layered structures in multi-layer printed circuit boards (PCBs)
    • Antistatic housing parts for sensitive electronic equipment

    2. Crosslinkable Epoxy Resin Modifiers for Industrial Adhesives

    As a functionalized vinyl aromatic, 4-Aminostyrene introduces amino groups into epoxy resin matrices, increasing crosslinking density and adhesion strength. This enables high-performance bonding in automotive, aerospace, and electronics assembly lines, where thermal resistance and chemical durability are critical. In downstream manufacturing, chemists incorporate this monomer as a chain extender or co-monomer during resin formulation, optimizing the final network structure.

    Industry compliance standards

    • ASTM D1763 for epoxy resin adhesives
    • ISO 9001:2015 for quality management in adhesive manufacturing
    • GB/T 7124-2008 for adhesive shear strength
    • Automotive OEM technical specifications (e.g., Ford WSB-M4G323-B)

    Typical usage ratio

    • 3–8% by weight of total epoxy resin blend, based on molecular weight and required crosslink density

    Downstream process integration

    • Integration at the resin pre-polymer synthesis stage, prior to curing agent addition; sometimes as part of dual-component adhesive packs

    Final product types

    • Structural adhesives for automotive metal and composite body assembly
    • Electronic potting and encapsulation materials
    • High-strength composite bonding adhesives
    • Repair and maintenance epoxies used in civil infrastructure

    3. Proton Exchange Membranes for Fuel Cell Systems

    The amino group on 4-Aminostyrene provides unique sites for sulfonation and subsequent proton transport, making it a core component in custom proton exchange membranes (PEMs). Fuel cell manufacturers leverage its compatibility in polystyrenic backbone modification, improving ion conductivity and chemical resistance under demanding operational environments. The compound enters production in controlled solution polymerization, followed by sulfonation and complete membrane casting and curing.

    Industry compliance standards

    • ISO 14687:2019 for quality of hydrogen used in fuel cells
    • DOE Technical Targets for PEM fuel cell membranes
    • SAE J2719 for hydrogen fuel quality
    • IEC 62282-2 for fuel cell module testing

    Typical usage ratio

    • 5–12% molar basis in styrene–sulfonic acid co-monomer systems, optimized according to membrane ion exchange capacity and flexibility

    Downstream process integration

    • Copolymerization together with styrene and sulfonic acid precursors, followed by precision sulfonation and membrane lamination during fuel cell stack assembly

    Final product types

    • Proton-conducting membranes for hydrogen fuel cell stacks
    • Membrane–electrode assemblies (MEAs)
    • Durable PEM layers for portable and stationary fuel cells
    • PEM-based electrolyzers for industrial hydrogen production

    4. Molecularly Imprinted Polymers for Analytical Separation and Purification

    In analytical laboratories and process industries, polymer chemists employ 4-Aminostyrene to prepare molecularly imprinted polymers (MIPs) with specific binding affinity towards target molecules. The amino group offers valuable selectivity during imprinting, enhancing extraction and purification efficiency for high-value biochemicals. This monomer participates directly in free-radical polymerization and template removal protocols fundamental to scalable MIP bead manufacturing and chromatographic column packing.

    Industry compliance standards

    • IUPAC recommendations for synthetic receptor materials
    • ISO/IEC 17025 for analytical testing laboratories
    • USP <621> for chromatography system suitability
    • GLP guidelines for analytical and purification processes

    Typical usage ratio

    • 10–25% of total functional monomer content, with the final ratio tailored to the target analyte/binding specificity and template geometry

    Downstream process integration

    • Introduction during pre-polymerization mix preparation along with crosslinker and template; MIPs formed via bulk, suspension, or precipitation polymerization before physical isolation and conditioning for use

    Final product types

    • Solid-phase extraction (SPE) cartridges for analytical sample cleanup
    • Chromatographic stationary phases for pharma and food quality control
    • Affinity beads for selective isolation in biotechnology
    • On-site test kits for trace contaminant monitoring

    5. Grafted Functional Polymers for Water Treatment Media

    Environmental engineers use 4-Aminostyrene to graft functional amino groups onto polymeric backbones, generating chelating resins with heightened selectivity for heavy metals and emerging contaminants in industrial water treatment. These polymers enter the process during batch or continuous solution graft polymerization, with strict control over functionalization degree to meet regional and application-specific regulatory discharge limits. The tailored beads and fibers facilitate high-throughput removal in column and batch reactor designs across municipal and industrial sites.

    Industry compliance standards

    • EN 15039 for ion-exchange and adsorbent materials
    • NSF/ANSI 61 for drinking water system components
    • US EPA Method 200.7 for trace metals in water
    • ISO 14001 for environmental management

    Typical usage ratio

    • 12–20% of monomer mix for functionalized beads; loading varies by feedwater metal concentration and target removal efficiency

    Downstream process integration

    • Functional group grafting in aqueous solution or organic solvent, followed by bead or fiber formation, washing, classification, and packing into treatment columns

    Final product types

    • Chelating ion-exchange resins for heavy metal removal
    • Selective adsorbents for industrial process water treatment
    • Media for groundwater remediation systems
    • Wastewater polishing filters
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    Certification & Compliance
    More Introduction

    Understanding 4-Aminostyrene: Building Value from Chemical Precision

    Introduction to 4-Aminostyrene

    At our facility, every batch of 4-Aminostyrene stands as a direct result of careful synthesis and a history of listening to the needs of polymer chemists and advanced material developers. We do not just see it as a catalog number or a component on a spec sheet. The tangible payoff from using this compound emerges throughout the lab and production floor, whether you are working with specialty resins, coatings, or selective functionalization of advanced plastics.

    We produce 4-Aminostyrene with a molecular formula of C8H9N, offering a reliable platform for further modification due to its primary amino group in the para position of the styrene backbone. Our batches generally meet high purity thresholds suitable for direct use in sensitive polymerization, supporting reproducible results and reducing unnecessary trouble during downstream reactions. Over the years, colleagues and customers in materials science have commented that quality differences become obvious in both small-scale syntheses and industrial runs.

    The Details that Matter: Purity, Handling, and Practical Chemistry

    Purity in a chemical source directly affects everything from yield to the level of unwanted byproducts in a reaction. It does not take long in a working lab before traces of secondary amines, excess monomer, or even trace metals from inferior syntheses start to show up in tests and create headaches. In our hands, we found that active control of synthesis steps—right down to the final distillation and storage of 4-Aminostyrene—pays dividends in practical lab results. We routinely aim for a product with content above 98% and low trace impurity levels, and we back up that claim with both batch-by-batch analysis and real cross-comparison against older lots.

    We have learned from experience that uncontrolled exposure to air or moisture can transform sensitive monomers, causing yellowing or polymerization before you even get them into your flask. Sealing and storing under inert atmosphere have become key elements in our protocol, an approach born from watching labs lose valuable material to simple mishandling. Many requests from end users center around receiving fresh, stabilized batches that do not stick together or degrade in shipment. This day-to-day practicality in production and packaging enables the material to arrive as expected, without surprises that disrupt workflows.

    Key Differences: 4-Aminostyrene vs. Regular Styrenes and Amino Precursors

    4-Aminostyrene distinguishes itself from plain styrene by its amino functionality. This one change opens up a broad field of chemistry. Where regular styrene delivers a clean, non-polar backbone suited for bulk plastics, introducing the amino group in the para position offers two immediate advantages: it brings new chemical reactivity for attaching other molecules, and it shifts polymer properties, including hydrophilicity and potential crosslinking capability.

    Working directly with 4-Aminostyrene gives chemists a head start on more complex analogues, saving time compared to indirect modification of poor-yield phenyl precursors. While aromatic amines in general can come as liquids or low-melting solids, our product typically appears as a crystalline solid at room temperature. Careful control and absence of excessive polymer residues or oxidized byproducts provide a consistent melting range, which seasoned formulators quickly notice when dissolving it for their process.

    Comparison to other monomers brings another level of practical insight. Take meta-aminostyrene as an example: though available on a research scale, its electron position alters reactivity and limits usefulness in direct analogs of block copolymers or ion-conducting membranes. The para orientation of the amino group in 4-Aminostyrene has shown stronger suitability for introducing controlled electronic effects and hydrogen bonding in specific applications.

    Why Users Turn to 4-Aminostyrene

    Business in the chemical sector rides on the success of the finished product, not just on completing the reaction. For years, feedback from users in domains such as medical hydrogels, printed circuit materials, and specialty adhesives has pushed us to focus on tangible parameters. The amino group makes the molecule far more than a core building block: it enables post-polymerization modification, site-specific coupling of functional groups, and a route to anti-fouling or anti-static surfaces.

    Certain applications rely on the presence of a robust primary amine, while others benefit from its aromatic backbone for structural strength. In our own process validation, work involving high-performance membranes for sensors or water treatment revealed that the amino functionality supports covalent attachment of further modifications, such as sulfonic acids or fluorinated chains, leading to fine-tuning of both surface and bulk properties.

    We have supplied development projects in academia and industry alike that needed a monomer enabling both free radical and ionic polymerization. 4-Aminostyrene fills this gap, bridging the world of styrenic plastics and stronger-functionality resins. Practical evidence from customer labs shows improved retention of amine character and repeatable reactivity profiles when the product is fresh and well-preserved.

    Production Knowhow: Obstacles and Solutions

    Challenges in making and delivering 4-Aminostyrene run much deeper than drawing a reaction scheme. Handling aromatic amines is not straightforward. The molecule’s aromatic ring wants to oxidize if exposed to air; the primary amine prefers to attack acids and is also prone to forming unstable salts or unwanted byproducts if processed sloppily. Over the years, switching to a controlled atmosphere with regular monitoring of headspace oxygen, combined with rigorous batch testing, has prevented degradation that would otherwise show up in quality control reports downstream.

    During purification, distillation under reduced pressure and steps to remove trace oligo-polymers and inhibitors have become standard in our practice. We often adjust stabilization amounts based on the stated use-case—sometimes less for immediate lab polymerization, sometimes more for longer storage. Any manufacturer who downplays stabilization often costs the end user much more in lost time and material than they save in packaging logistics.

    Solubility matters more than most realize. While 4-Aminostyrene stands up well in organic solvents like toluene, dichloromethane, and isopropanol, solutions for storage or shipping demand extra care. Water contact leads to hydrolysis or color change, a fact our technical support team has documented in both internal testing and customer troubleshooting. Even with careful stabilization, customers benefit from using the material soon after opening for best results.

    Supporting Research and Product Development

    Our ongoing conversations with research groups and collaborators worldwide have focused on reproducibility as much as reactivity. We maintain a database of batch analyses and cross-references of reactivity trends, which assists in troubleshooting or scaling formulations. One recurring point in feedback is how critical proper amino group placement is; off-brand or badly purified materials show inconsistent polymerization or flounder in side reactions, wasting both time and money.

    For example, work in conductive polymers or smart coatings has shown that even minor inconsistencies in the starting monomer’s purity create cascading problems at the end-use stage. Only direct experience in production and downstream monitoring links these dots. Some developers switched suppliers and noticed dramatic swings in yield, color, or mechanical properties of their products. Our policy has always been to ask up front about the final application and tailor analysis support accordingly.

    Specialty Uses: Where 4-Aminostyrene Makes a Difference

    Many advanced material applications call for precise placement of polar or reactive groups on a polymer backbone. 4-Aminostyrene meets this need better than most other simple aromatic monomers. In biotechnology, for instance, researchers craft affinity media or protein-binding surfaces using polystyrene beads functionalized with the amino group. High-purity 4-Aminostyrene delivers uniformity across bead production, ensuring reliable attachment of biomolecules or fluorescent markers.

    Electronics manufacturing benefits from this same reactivity. Surface treatment of microelectronic substrates and the generation of anti-static layers depend on controlling amine density at the nanoscale. Only with consistent monomer quality can these layers perform with predictable resistance or adhesion properties. On the scale of printed electronics and next-generation circuit boards, such details shift yields from acceptable to world-class.

    Coatings and adhesives containing 4-Aminostyrene as a functional comonomer tolerate a range of further modification. Reactive amine groups give formulators the ability to fine-tune crosslink density or create pH-responsive performance. These traits matter on the shop floor, not just in academic literature: real-world production, subjected to varying humidity or chemical load, quickly exposes weaknesses in any generic or poorly processed monomer.

    Product Consistency and Traceability

    Manufacturing specialists understand that traceability is more than an afterthought. Documented chain-of-custody for each lot of 4-Aminostyrene is not a paperwork burden, but a tool for tracking and resolving challenges that arise in customer workflows. Each time an unusual test result surfaces, our detailed analytic records allow labs, QA staff, or R&D teams to track down root causes and eliminate recurring mistakes.

    Our lab staff have developed in-house assays for colorimetric detection of minor oxidation or polymer contamination, alongside established techniques like NMR and GC-MS for routine quality control. These methods are more resource-intensive than basic checks, but investment in better analytics reduced call-backs and complaints across the board. Direct conversation with experienced production teams avoids misinterpretation of generic certificates and creates a more agile feedback loop.

    Raw material sourcing is another ongoing point of attention. Starting from well-characterized benzene derivatives, along with close control at each transformation step, limits side reactions that can introduce problematic isomers or trace heavy metals. Regular audits of both raw inputs and finished product keep unwanted content low, providing more security for demanding applications, from clean technology projects to pharmaceutical intermediates.

    Safety, Environmental Concerns, and Ethical Production

    Handling aromatic amines such as 4-Aminostyrene carries both routine and regulatory safety demands. Our safety officers and plant personnel treat each production run as a learning experience, regularly updating protocols in response to real-world findings or tightening industry standards. Only by engaging with frontline operators and process engineers have we developed ergonomic workspaces, better PPE distribution, and clearer hazard communication practices.

    Environmental impact deserves close consideration. Restrictions on undesirable byproduct generation, careful capture of off-gasses, and solvent recycling cut down operational emissions. We document major sources of organic waste and send out regular reports for third-party assessment. While no synthesis route is entirely clean, decades of small improvements across purification, containment, and energy use add up to lower overall footprint per kilogram produced.

    User communities make requests for safer packaging and clearer guidance on final disposal or recycling. We work with partners to develop packaging solutions that preserve product stability and minimize plastic or solvent residue in shipments. Technical inquiry lines exist for feedback on both human health and broader sustainability aspects—reducing risk is a shared priority with our downstream partners.

    Challenges in Supply Chain and Meeting Demand

    Supply chains for specialty monomers continuously face new stresses. Close work with primary raw material suppliers has allowed us to weather disruptions, such as unplanned shutdowns or shifts in required regulatory documentation. Our priority is keeping accurate communication with project leads, so laboratories and production lines do not face unexpected delays. When niche chemicals go out of stock, research projects sometimes stall for months. Regular forecasting, buffer stock maintenance, and a commitment to flexibility play key roles in our response.

    We commit to direct interaction with customers discussing scale transitions—from bench synthesis to pilot plant and ultimately commercial scale. Differences in mixing, polymerization rates, or temperature response often appear between lab and plant. Early engagement, real sample provision, and follow-up technical support solve many headaches before they grow into costly problems. It’s this approach, not just batch consistency or price, that brings many clients back for the following projects.

    Opportunities for the Future: Co-Development and Tailored Synthesis

    We watch as material science pivots toward function-specific polymers and targeted delivery systems in pharmaceutics. 4-Aminostyrene’s primary amine keeps showing up as a favored entry point for post-polymer modifications, allowing pharmaceutical formulators to build drug capsules that open under certain pH or attach imaging agents at known positions. We maintain an open-door policy for discussing new possibilities—sometimes adjusting stabilization approaches, offering custom packaging, or preparing blends with other comonomers at customer request.

    Collaborations between manufacturers and advanced material developers move the entire field forward. Recent development programs showed how combining 4-Aminostyrene with crosslinkers and charge-transporting agents yield better-performing coatings or membranes. Shared problem-solving, transparent documentation, and continued feedback are cornerstones of successful partnerships.

    Conclusion: Chemical Reliability Translates to Real-World Results

    Years in the production and supply of 4-Aminostyrene have made clear one truth: predictable, high-quality input drives success at every stage of research and manufacturing. Collaboration, transparency, and the ability to respond quickly to technical problems remain as important as producing a well-analyzed compound. The journey from raw material to high-value polymer or specialized surface often hinges on factors as simple as how the chemical traveled from reactor to lab bench, and knowing the full story means fewer surprises, shorter development times, and satisfied end users. Our work on 4-Aminostyrene continues to reflect a long-term commitment to those who depend on robust chemical building blocks to turn possibility into reality.