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4,4'-Sulphonylbis(2,6-Dibromophenol)

    • Product Name 4,4'-Sulphonylbis(2,6-Dibromophenol)
    • Alias Dibromobisphenol S
    • Einecs 221-543-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    107277

    Chemicalname 4,4'-Sulphonylbis(2,6-Dibromophenol)
    Casnumber 80-60-4
    Molecularformula C12H6Br4O4S
    Molecularweight 588.86 g/mol
    Appearance White to off-white powder
    Meltingpoint 309-312°C
    Solubilityinwater Insoluble
    Boilingpoint Decomposes before boiling
    Density 2.62 g/cm³
    Purity Typically ≥98%
    Synonyms Tetrabromobisphenol S, TBBPS
    Ec Number 201-290-8
    Smiles C1=C(C(=CC(=C1Br)O)Br)S(=O)(=O)C2=C(C(=CC(=C2Br)O)Br)

    As an accredited 4,4'-Sulphonylbis(2,6-Dibromophenol) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for 4,4'-Sulphonylbis(2,6-Dibromophenol), 100g, features a sealed, labelled amber glass bottle inside a protective cardboard box.
    Shipping 4,4'-Sulphonylbis(2,6-Dibromophenol) should be shipped in tightly sealed containers, protected from moisture and physical damage. Label as a chemical substance and follow all applicable regulatory guidelines for transport. Store and ship in a cool, dry place, away from incompatible materials, following local and international hazardous material shipping protocols.
    Storage 4,4'-Sulphonylbis(2,6-Dibromophenol) should be stored in a cool, dry, and well-ventilated area, away from sources of ignition and incompatible substances such as strong oxidizers. Keep the container tightly closed and clearly labeled. Protect the chemical from moisture and direct sunlight. Use appropriate personal protective equipment when handling. Store in accordance with local regulations and safety guidelines.
    Application of 4,4'-Sulphonylbis(2,6-Dibromophenol)

    Applications of 4,4'-Sulphonylbis(2,6-Dibromophenol) in Industrial Manufacturing

    As a chemical manufacturer with extensive experience in halogenated bisphenol compounds, we support a range of industrial sectors with large-scale supply of 4,4'-Sulphonylbis(2,6-Dibromophenol). Below, we detail its main proven application routes as relied upon by formulating industries, addressing pivotal regulations, technical integration, and downstream manufacturing approaches in actual customer settings.

    1. Flame Retardant Additives for High-Performance Epoxy Resins

    Producers of circuit board laminates and encapsulation compounds incorporate this specialty halogenated bisphenol to impart reliable flame retardancy while maintaining glass transition temperature and mechanical stability in cured epoxy systems. The compound’s structure provides reactive bromine while ensuring chemical compatibility with both Bisphenol A-based and novolac resin matrices processed under elevated curing temperatures typical in electronics substrate fabrication.

    Industry compliance standards

    • UL 94 (Standard for Safety of Flammability of Plastic Materials for Parts in Devices and Appliances)
    • IEC 61249-2-21 (Halogen-free Base Materials in Printed Circuit Boards)
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances in Electrical and Electronic Equipment)
    • IPC-4101D (Specification for Base Materials for Rigid and Multilayer Printed Boards)

    Typical usage ratio

    • 5-18 phr (parts per hundred resin), depending on required flammability rating (e.g., V-0 in UL94) and board thickness.

    Downstream process integration

    • Dissolved or melted into epoxy oligomer system at the pre-polymer preparation stage, before mixing with curing agent and fiberglass prepreg impregnation or press-molding.

    Final product types

    • Copper clad laminates (CCL) for printed circuit boards
    • Encapsulation compounds for semiconductor and LED packaging
    • Glass fiber reinforced epoxy composites for industrial electronics

    2. Flame Retardant Modifier in Engineering Thermoplastics

    The additive is adopted by direct polycondensation or melt blending to enhance the fire safety of polycarbonate and polyesters such as PET and PBT, especially in sectors where demanding ignition resistance and thermal stability are essential, including electrical appliance housings and transportation components exposed to operational heat and electrical risks. Its symmetrical structure allows for good dispersion and stable compatibility during production without significantly impairing mechanical performance or transparency.

    Industry compliance standards

    • EN 45545-2 (Fire Protection on Railway Vehicles)
    • IEC 60335-1 (Safety of Household and Similar Electrical Appliances)
    • REACH Regulation (EC 1907/2006) Substances of Very High Concern assessment
    • ASTM E162 (Surface Flammability of Materials Using a Radiant Panel Apparatus)

    Typical usage ratio

    • 3-12% by weight, optimized according to polymer type, molding conditions, and flammability requirement (e.g., GWIT, GWFI ratings).

    Downstream process integration

    • Incorporated during melt compounding in twin-screw extrusion lines for masterbatch or direct compounding, or added as a reactive intermediate during resin synthesis for integrated fire resistance.

    Final product types

    • Electrical insulation parts (switches, sockets, relays)
    • Automotive under-the-hood connectors
    • Household appliance housing and structural supports

    3. Reactive Flame Retardant in Thermosetting Polyester Laminates

    Large-scale producers of unsaturated polyester resins and their glass fiber laminates use this dibromo compound as a co-monomer, covalently integrating fire retardancy into the molecular backbone. This approach improves long-term migration resistance of flame retardant functionality, achieving durable performance even under high humidity and elevated temperatures relevant in industrial and marine sectors.

    Industry compliance standards

    • ASTM E84 (Standard Test Method for Surface Burning Characteristics of Building Materials)
    • DIN 5510-2 (Fire behavior and fire side toxicity for railway vehicle materials)
    • UL 723 (Test for Surface Burning Characteristics of Building Materials)

    Typical usage ratio

    • 3-10 mol% relative to polyester unsaturation, fine-tuned to balance flame performance versus mechanical strength based on final laminate thickness and expected load-bearing.

    Downstream process integration

    • Introduced during resin synthesis as a reactive co-monomer in the polyesterification reactor, preceding or simultaneous with glycol introduction, then compounded with glass fibers prior to sheet or filament winding fabrication.

    Final product types

    • Flame resistant cable trays for industrial power distribution
    • GRP paneling for marine structures and public transport interiors
    • Architectural fire barrier boards

    4. Intermediate in Specialty Polymer Synthesis for High-Temperature Insulation

    Leading suppliers of high-grade specialty polymers use this compound in the production of poly(arylene ether sulfone) derivatives and other advanced engineering resins where both high bromine content and sulfone linkages enhance dimensional and dielectric stability at continuous operating temperatures exceeding 180°C. The raw material’s rigid, aromatic-brominated structure supports downstream processing demands such as injection molding and extrusion in technical composite markets facing persistent heat and electrical stress.

    Industry compliance standards

    • IEC 60695-11-10 (Test flames – 50 W horizontal and vertical flame test)
    • ISO 1043-4:2011 (Plastics — Symbols and abbreviated terms — Part 4: Flame retardants)
    • UL 746C (Polymeric Materials – Use in Electrical Equipment Evaluations)

    Typical usage ratio

    • Used stoichiometrically as a dihydroxy monomer (100% replacement or partial substitution, 10-50 mol%) in high-performance resin synthesis, customized according to desired molecular weight and backbone functionality.

    Downstream process integration

    • Charged with bisphenol and sulfone intermediates in condensation reactors, driving formation of high molecular weight polymers via step-growth polycondensation; product then pelletized for direct use in technical molding lines.

    Final product types

    • Thermal insulation components for industrial switchgear
    • Flame retardant high-frequency circuit substrates
    • Custom-shaped insulators used in electrical grid and aerospace assemblies

    5. Synergist in Halogenated Flame Retardant Systems for Polyurethane Foams

    Upholstery and transportation foam manufacturers adopt this specialized bisphenol as a synergist in combination with standard brominated polyols and phosphorous-based additives to heighten foam's fire resistance. It stabilizes open cell structure and delivers improved after-flame suppression for products challenged by strict ignition and smoke evolution rules, especially in public building and aviation seating applications.

    Industry compliance standards

    • BS 5852 (Methods of test for assessment of the ignitability of upholstered seating by smouldering and flaming ignition sources)
    • FAR 25.853 (Flammability Requirements for Aircraft Recirculating Air Units and Seats)
    • CAL TB117-2013 (California Technical Bulletin Covering Flammability of Upholstered Furniture)

    Typical usage ratio

    • 0.5-3 weight%, adjusted based on foam density and synergistic flame retardant formulation (in conjunction with TCPP, TDCPP, or brominated polyols).

    Downstream process integration

    • Premixed into the polyol blend at the metering step, reacting in-situ during polyurethane foam expansion and curing on slabstock or molded foam lines.

    Final product types

    • Passenger train and aircraft seat cushions
    • Flame retardant flexible PU foams for office and cinema seating
    • Insulating block foams for commercial buildings
    Free Quote

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    Certification & Compliance
    More Introduction

    4,4'-Sulphonylbis(2,6-Dibromophenol): Dependable Support for Advanced Polymer Applications

    Shaping Quality With Every Batch

    Producing chemicals that serve the real needs of our customers starts well before the reactors warm up. For us, 4,4'-Sulphonylbis(2,6-dibromophenol) is an old acquaintance in the lineup. After years spent mastering each step of its production, we’ve learned what matters most: purity, reliability, and performance when incorporated into end-use materials. The market sometimes knows this material by its model BPS-DBP, but in every case, it brings its distinctive mark: a solid balance of heat stability and fire protection, especially in specialty engineering plastics.

    What We Learned From the Factory Floor

    Most high-end demands for 4,4'-Sulphonylbis(2,6-dibromophenol) come from the thermoplastics and thermosetting resin industries. We recognize immediate expectations — consistent particle size, precise bromine content, and a white or off-white appearance that lets colorants shine without interference. We moved away from outdated handling protocols, setting up a clean, closed reaction system, and installing tailored purification routes to reduce trace-level contaminants and colored impurities.

    Because heat-sensitive polymers cannot tolerate excessive process residues, we ensure residual solvents and low-volatility impurities remain under strict internal thresholds. Every shift checks the melt flow and color indices, not only with instruments but also by trained eyes. The engineers on our team compare lot-to-lot consistency against reference benchmarks. We have head chemists with decades of combined experience; their attention to moisture and ash keeps most common nonconformance claims at bay.

    Where Precision Meets Innovation

    The most common application for our product lies in flame-retardant systems for polycarbonate, epoxy resins, and select unsaturated polyesters. Through long partnerships with downstream compounding plants, we’ve fine-tuned the balance between brominated phenol content and sulfone backbone. Our customers rely on the fact that the dibromo functional groups don’t just boost flame retardancy — they also provide robust compatibility with high-performance matrix monomers. Our product supports the strictest regulatory requirements for Building and Electronics markets, especially where halogen content demands fine traceability and full documentation.

    We own every step, from bromination of the phenolic substrates to final sulfonyl coupling. Granulation and sieving methods deliver either fine powder or granular forms, as specified. Each format brings slightly different advantages: powders blend efficiently in melt-processing, while granular versions reduce dust and improve flow in automated dosing feeders.

    Our Hands-On Approach to Product Quality

    The first time we scaled up 4,4'-Sulphonylbis(2,6-dibromophenol), controlling reaction exotherms proved more challenging than lab tests had suggested. Today, our reactors run on feedback-based controls — every temperature spike resolves within moments thanks to in-line monitoring. Whether it’s a 200-kilogram or multi-ton batch, we dedicate sampling personnel to every tank. If analytical results stray from our standards, the lot gets reworked or held aside, no exceptions.

    Water absorption causes issues when compounding this material in polycarbonate and epoxy blends. Over time, we reduced water content in our final product below 0.15%. Shelf life now stretches well beyond industry norms, even without aggressive desiccants. Our packaging boys know what a real ‘tight seal’ must look like — double polyethylene liners and drums lined with moisture barriers, shipped only under dry conditions.

    Occasionally, customers ask about managing fines or dusty byproducts. We handle this at the in-house site with filtration systems, vacuum dust collectors, and dust-scavenging additives whenever required. We monitor bulk density and flow regularly. Under-sieve fractions get recycled immediately, protecting the consistency downstream for compounders aiming at high-throughput extruders.

    Spotlight on What Sets It Apart

    It is tempting to stack all brominated bisphenols in one category, but that misses the particular edge our sulphonyl-bridged, 2,6-dibromo variant brings to composites and specialty polymers. Take alternatives like the more common tetrabromobisphenol A — it offers a somewhat different thermal profile and sometimes higher reactors can release impurities when heated beyond recommended temperatures. Our product, by comparison, doesn’t only resist fragmentation at processing temperatures up to 300 °C; it contributes fewer volatile by-products in emissions testing.

    The sulfone bridge doesn’t simply stabilize the dibrominated aromatic units. This backbone also improves compatibility with certain sulfone-based matrix materials, making our product the go-to choice for manufacturers creating advanced copolymer resins and select high-performance composites. This is critical for end goods needing a balance of mechanical toughness and flame resistance over a long service life.

    Manufacturers who once used simple bisphenol derivatives tell us about improved clarity, smoother dispersion, and cleaner “melt” properties since switching to our product. Epoxy resin processors report fewer outgassing problems and reduced microcracking in challenging environmental conditions. Not all additives perform like this, and these details only surface with hands-on use and deliberate process controls.

    Attention to Environmental and Safety Demands

    Sustainable and responsible manufacturing now dominates many of our customer requests. As REACH, RoHS, and additional local directives grow stricter, our lab teams track traceability, document all raw material sourcing, and guarantee that every batch contains only the bromine and sulfonyl content stated. We perform downstream modeling of bromine release and migration through standardized protocols.

    While brominated substances have come under scrutiny for environmental persistence, our formulas never include unnecessary additives or plasticizers. All spent process fluids and captured dust return to our waste treatment section instead of entering local water systems. Since we maintain in-house testing labs, customers can access certificates of analysis and supplemental third-party verification without delay, supporting confidence in downstream compliance audits.

    Serving Compounders, Laminators, and OEM Processors

    Most orders for 4,4'-Sulphonylbis(2,6-dibromophenol) serve custom compounding outfits and resin formulators. Their shops run demanding mixing and shaping lines. We learned quickly that no two plants tackle flame-retardant compounding in the same way, and we tailor lot sizes, pack-out configurations, and shipment schedules to fit everything from test batches to full-scale campaigns.

    Our technical specialists visit customer sites, offering on-the-ground troubleshooting — from integrating new dosing technology to modifying upstream pre-mixing protocols. Caustic residues or improper polymer ratios can impact dispersion, and we coach operators through these hurdles. A direct line to our process engineers ensures feedback from the field moves straight to manufacturing, not stuck in a sales pipeline or external warehouse. Sometimes it means small layout changes, sometimes full system design upgrades, but it always starts with a batch-level understanding of the product.

    Trust Built Over Decades

    From the earliest days, we saw how off-the-shelf products rarely delivered the reliability customers wanted. Each complaint — hard clumps, spotted color, low melting point — forced us back to small-lot trials, laboratory cross-checks, and even visits to end-users’ lines. Out of those repeat cycles came the controlled steps and close records we keep today. Our chemists introduced fresh reagent sources, switching to higher-standard bromine and sulfonyl intermediates after analysis uncovered trace-level contamination in an old supplier batch.

    We spend time comparing chromatographs, FTIR spectra, and physical test reports batch by batch, looking not just for “pass/fail” but for small variations that might impact color, strength, or shelf stability. Those old, tough lessons built the discipline required to meet certification standards. The audits our partners demand do not discourage us; they reinforce our commitment to documentation and product fidelity. Over years, as electronics and plastics companies shifted requirements, we kept every process update logged and validated.

    From Factory to Customer – Smooth, Reliable Supply

    Direct manufacturing allows us to adapt to real-world constraints without delay or extra middle steps. We maintain buffer stock for regular customers. As global demand shifted through recent supply chain fluctuations, we avoided most raw material bottlenecks through steady supplier relationships built across decades. Bulk orders can be covered from either local or port-side warehouses, which maintains tight control over logistics. Small-lot customization happens routinely, whether the request concerns particular bagging instructions or drum labeling.

    Backed by our continuous process lines, shipments move cleanly from reactor discharge, through multiple filtration and drying systems, and on to packaging — checked for moisture, particle uniformity, and appearance at every hand-off. Final outgoing lots sit in dry storage, sealed against the sort of humidity that can undermine product performance right at the user’s site.

    Looking Forward: Product Evolution and Customer Demands

    The baseline recipe we use for 4,4'-Sulphonylbis(2,6-dibromophenol) rarely stands still. As customers push for higher clarity, more stable colors, or reduced emissions, we experiment with process changes before ever suggesting them for production. Co-precipitation techniques, different solvent-recovery routes, and low-residue filtration all change the texture or utility in subtle ways. We designed a small development section in the plant devoted to pilot batches and new methods. When a flaw shows up in the finished product, the changes get fully documented, retested, and traced back to raw materials before signing off on a modified run.

    The diversity of requests from compounders and resin formulators keeps us vigilant. From requests for pure-white, ultra-low-halogen grades to custom blends with microfine talc or stabilizers, every challenge adds another thread of expertise to our practice. Our approach favors careful, small-batch scaleups before full adoption, reducing the chance of costly production or customer downtime.

    Real People, Real Results

    Work in chemical manufacturing often runs on learned routines more than spreadsheets or distant, abstract targets. Employees on the ground become experts through repetition and attention to details: judging powder flow, inspecting color changes, and learning the subtle odor difference between lots. Their pride shows in the rare batch that leaves the line below expectations — that is when everyone from shift chemist to packaging operator brings their experience to corrective action.

    We invite customers to audit our facility, inspect analytical data, or talk shop about the tough aspects of their manufacturing line. These direct conversations help us improve product design. If a resin formulator reports a solubility issue, or if an extruder notices unexpected outgassing, these signals influence how we control our own manufacturing. Our willingness to embrace feedback and change the process is what has helped us build a product line with a reputation for reliability.

    Closing Thoughts: Why We Focus on the Details

    Every ton of 4,4'-Sulphonylbis(2,6-dibromophenol) we supply reflects the patience, adaptability, and honesty we bring as a direct manufacturer. No round of process controls, no additional lab check, no feedback loop from customer trials is ever “good enough” to skip. We take pride in shipping a product that helps our partners build longer-lasting, safer, and more reliable components.

    It has never been easy to build something consistent in a field where every feedstock, process temperature, and market regulation shifts. By dedicating ourselves to transparency, careful documentation, and genuine dialogue with industrial partners, we strengthen not only our product quality but also our relationships in the supply chain. Anyone looking to source 4,4'-Sulphonylbis(2,6-dibromophenol) benefits from a supplier who stands behind every drum with both a history of manufacturing expertise and a real will to drive chemical innovation forward.