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4,4'-Dimethoxydiphenylamine

    • Product Name 4,4'-Dimethoxydiphenylamine
    • Alias N,N-Dimethyl-4,4'-diphenylaniline
    • Einecs 217-422-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    462165

    Product Name 4,4'-Dimethoxydiphenylamine
    Cas Number 101-49-5
    Molecular Formula C14H15NO2
    Molar Mass 229.28 g/mol
    Appearance White to off-white crystalline powder
    Melting Point 103-106 °C
    Boiling Point 370-372 °C
    Solubility In Water Insoluble
    Density 1.14 g/cm³
    Refractive Index 1.613
    Synonyms 4,4'-Bis(methoxy)diphenylamine
    Smiles COC1=CC=C(NC2=CC=C(OC)C=C2)C=C1
    Ec Number 202-944-8

    As an accredited 4,4'-Dimethoxydiphenylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 100g amber glass bottle with a secure screw cap, labeled “4,4'-Dimethoxydiphenylamine”, hazard symbols, and batch information.
    Shipping 4,4'-Dimethoxydiphenylamine is shipped in tightly sealed containers to prevent contamination and moisture exposure. It should be transported under ambient conditions, in compliance with local regulations for handling organic chemicals. Shipping labels must clearly indicate the chemical name and any relevant hazard warnings, as required by safety guidelines and regulatory standards.
    Storage 4,4'-Dimethoxydiphenylamine should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from sources of ignition, heat, and direct sunlight. Avoid storing with oxidizing agents. Ensure containers are clearly labeled and kept away from incompatible substances. Follow all relevant safety protocols and consult the material safety data sheet (MSDS) for detailed storage instructions.
    Application of 4,4'-Dimethoxydiphenylamine

    Applications of 4,4'-Dimethoxydiphenylamine in Industrial Manufacturing

    As a direct manufacturer of 4,4'-Dimethoxydiphenylamine, we support industrial customers with consistent quality and technical experience. This raw material finds proven applications in specialty chemical sectors where its particular properties deliver performance for demanding processes. The following sections detail real downstream application scenarios, including compliance, recommended usage levels, common integration stages, and finished product profiles based on feedback from our long-term partners.

    1. Rubber Antioxidant Systems for Tire and Belt Production

    Major tire and rubber manufacturers use 4,4'-Dimethoxydiphenylamine as a secondary antioxidant to enhance heat aging resistance in high-performance rubber compounds. It acts especially to prevent oxidative degradation during vulcanization and service, extending product service life in tires, conveyor belts, and similar rubber goods exposed to sustained heat and dynamic stress.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management System for manufacturing)
    • REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals – EU regulations)
    • ASTM D1171 (Standard Test Method for Rubber Deterioration – Surface Ozone Cracking)
    • OEKO-TEX Standard 100 (Textile and rubber product safety for restricted substances)

    Typical usage ratio

    • 0.5–1.5 phr (parts per hundred rubber) in final mixing; formula adjusted based on polymer type, degree of unsaturation, and compatibility with primary antioxidants.

    Downstream process integration

    • Added in the internal mixer during the final stages of compounding before the addition of curatives; batch or continuous mixing processes both apply.

    Final product types

    • Radial passenger and truck tire treads
    • Conveyor and transmission belts
    • Heat-resistant rubber gaskets and seals
    • Automotive hoses exposed to dynamic thermal cycles

    2. Lubricant Additive Packages for Engine and Industrial Oils

    In lubricant manufacturing, formulators utilize this material as an amine-based antioxidant to boost resistance to oil oxidation and deposit formation. It supports long-drain intervals and helps maintain viscosity stability under thermal stress in diesel engine oils, hydraulic fluids, and industrial gear oils.

    Industry compliance standards

    • API SN/CK-4 (American Petroleum Institute oil performance standards)
    • ACEA E9 (European Automobile Manufacturers’ Association – Heavy-duty diesel oils specifications)
    • ISO 6743 (Classification of lubricants, industrial oils and related products)
    • OECD Test Guidelines for Chemical Safety

    Typical usage ratio

    • 0.05–0.3 wt% in finished lubricant formulations; dosage varies with base oil composition and performance requirements of engine manufacturers.

    Downstream process integration

    • Introduced as part of the antioxidant additive package during blending, after base oil dehydration but before cooling and filtration to ensure homogenous incorporation.

    Final product types

    • Heavy-duty diesel engine lubricants
    • Industrial hydraulic and gearbox oils
    • Automotive transmission fluids
    • Compressor and turbine oils for power plants

    3. Stabilizer for Polyurethane Elastomer Manufacturing

    This compound serves as a key stabilizer in specialty polyurethane elastomer systems, particularly where thermal and oxidative stability are critical for end-use in automotive bushings, roller coverings, and mining screens. Its methoxy substituents enhance compatibility with polyol and isocyanate blends, limiting prepolymer yellowing and microcrack growth over extended service.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management System certification for PU parts)
    • RoHS Directive (EU Directive 2011/65/EU – Restriction of Hazardous Substances in electronic components)
    • REACH Annex XVII (Restricted substances in polyurethanes)
    • UL 94 (Flammability Standards for plastic materials)

    Typical usage ratio

    • 0.2–0.8% by weight within the polyol component; adjusted according to crosslinking density and specific color-retention specifications.

    Downstream process integration

    • Dispersed into the polyol fraction during pre-blending; stabilized polyol is then reacted with isocyanate in either hot-cast or cold-cure processing lines.

    Final product types

    • Suspension bushings for automotive and industrial applications
    • Polyurethane screen panels for mineral processing
    • Covered drive and idler rollers
    • High-wear mining parts for bulk material handling

    4. Intermediate for Dye and Pigment Synthesis

    Chemical producers use 4,4'-Dimethoxydiphenylamine as a functional intermediate in the synthesis of high-performance azo and anthraquinone dyes. Its substitution pattern allows for effective coupling reactions, yielding colorants with enhanced lightfastness and chemical resistance. This is key for textile, printing ink, and specialized plastic coloration where product durability is mandatory.

    Industry compliance standards

    • ETAD/Eco Passport (Ecological and Toxicological Association of Dyes – Safety criteria for colorant intermediates)
    • OEKO-TEX Standard 100 (Textile and consumer product safety)
    • REACH Regulation (EC 1907/2006 – EU requirements for dye raw materials)
    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals – Manufacturing Restricted Substances List)

    Typical usage ratio

    • Stoichiometric level in coupling stages, often 1.00–1.05 mole equivalent; fine-tuned for yield optimization during laboratory scale-up and industrial synthesis.

    Downstream process integration

    • Introduced in the coupling step after diazotization or amidation, as required by the target azo or anthraquinone structure; followed by subsequent isolation and purification of the dye product.

    Final product types

    • Disperse dyes for polyester and acetate fibers
    • Solvent-based inks for packaging and industrial graphics
    • Plastic color masterbatches for automotive and consumer goods
    • Pigments used in high-durability coatings

    5. Polymer Additive in High-Temperature Resistant Epoxy Composites

    Advanced composite manufacturers select this raw material as a chain-extender and antioxidant in specialty epoxy resin systems to promote network uniformity and suppress thermal-oxidative degradation. It is particularly valued in applications for printed circuit boards, electrical insulation, and aerospace structural parts where enhanced heat stability and dielectric properties are critical for component reliability.

    Industry compliance standards

    • IPC-4101 (Specification for base materials for rigid and multilayer printed boards)
    • UL 94 (Standard for Safety of Flammability of Plastic Materials)
    • RoHS (EU Directive 2011/65/EU on Electronics)
    • IEEE 1580 (Standard for Marine Cable Construction – material selection for insulation)

    Typical usage ratio

    • 0.1–0.7 phr, depending on the targeted glass transition temperature and compatibility with other bifunctional or multifunctional epoxy hardeners.

    Downstream process integration

    • Added during the premixing of epoxy and other curing agents; mixed until homogenous prior to lamination, prepreg processing, or direct casting operations.

    Final product types

    • Epoxy glass-fiber prepregs for PCBs
    • High-performance insulation encapsulants for electronics
    • Aerospace-grade composite laminates
    • Industrial electrical bushings
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    Certification & Compliance
    More Introduction

    4,4'-Dimethoxydiphenylamine: Shaping Specialty Manufacturing

    Introducing 4,4'-Dimethoxydiphenylamine from the Factory Floor

    Every year, at our reactor vessels and filtration suites, the process for producing 4,4'-Dimethoxydiphenylamine becomes a steady rhythm. We know this compound well—it’s more than a chemical formula. Our manufacturing teams watch the color, viscosity, and particle profile, and the results tell us when a batch meets the mark. We always stress careful control over raw material purity, since even small variations affect yields and downstream performance. Those who have handled this product on the filling line can attest to the distinctive, light crystalline nature that results from true process consistency.

    Model, Specifications, and Chemical Confidence

    The material in question is 4,4'-Dimethoxydiphenylamine: a specialty amine, recognized in trade by its CAS number 101-84-8. The purity target never drifts below 99%, and our analytical team relies on HPLC to verify each drum. The melting point registers sharply, often between 94 and 98 degrees Celsius, which signals correct synthesis and careful temperature management in crystallization. Sourcing this level of specification stems from years refining the oxidation and methylation steps, not shortcuts or third-party blends. Those who use 4,4'-Dimethoxydiphenylamine directly demand a product that dissolves and reacts cleanly, reducing waste and avoiding the haze that substandard lots can introduce.

    The available form remains consistent: pale, off-white crystals, free of particulate matter. Moisture content stays below 0.1%, guarded by double-sealed packaging and monitored warehouses that never cross the dew point. The backend packaging crews fill out lot records by hand and inspect each batch for dusting or caking. These small things don’t always register as official “specs,” but for regular customers who expect zero downtime, details like this matter as much as the paperwork.

    Knowing the Market’s Demands for 4,4'-Dimethoxydiphenylamine

    In practice, 4,4'-Dimethoxydiphenylamine rarely exists alone. The largest chunk of annual output feeds into antioxidant intermediates—specifically, rubber antidegradants designed to extend the life of tires, seals, and industrial belting. Our factory doesn’t just synthesize the base molecule and call it a day. We supply producers who require tight particle size control, since fines or oversized crystals disrupt mixing and reaction uniformity at their sites.

    Some years, new projects arise from colorant or pharmaceutical researchers. They request material with even lower trace metal content and narrow melt range. We take these requests seriously and adapt our cleaning and process schedules to keep cross-contamination risks far below industry limits. Being the manufacturer, not a trader, lets us respond to these changing application fields without lengthy approval chains. Staff will recall a batch destined for pilot work in organic electronics: repeated crystallizations, glassware baked between runs, and full traceability for every raw material. These standards don’t result from office memos—they grow from conversations on the plant floor where customers’ needs converge with hands-on knowledge.

    How 4,4'-Dimethoxydiphenylamine Compares on Performance

    On the technical side, many specialty amines overlap in basic properties. The key difference with 4,4'-Dimethoxydiphenylamine stems from the twin methoxy substitutions on the phenyl backbone. This gives the molecule greater resistance to oxidation than less-substituted diphenylamines, directly affecting how it behaves in finished applications. In tire rubber, for example, the stability of this amine reduces the rate at which the rubber matrix degrades from ozone and mechanical stress. This means longer product life out in the field, less cracking, and better color retention.

    The melt point and solubility profile offer advantages over similar diphenylamines. Operators in rubber compounding appreciate that this compound integrates faster at lower process temperatures, which preserves more of the base polymer’s original properties. By maintaining strict particle control, we ensure minimal dusting and easy flow from hoppers to reactors, something bulk handlers bring up at every yearly review.

    There are cheaper ways to provide antioxidant precursors. Some buyers opt for lower-grade, reclaimed material—usually a mixture of diphenylamine isomers with a broader melt range and yellow-tan hues. Inconsistent batches from offshore or brokered sources often need extra filters or process adjustments, sliming down productivity and risking end-product performance. Our clients usually circle back to direct manufacturers with these complaints, and every production supervisor here knows the technical and reputational cost of giving up ground on consistency.

    Product Safety and Handling from an Operator’s View

    Experience at the factory gives a realistic sense of how users interact with 4,4'-Dimethoxydiphenylamine. It’s neither an acute toxin nor a low-hazard filler. Day after day on the line, operators wear nitrile gloves and vapor masks, not just because of regulations, but from respect for clean and safe work areas. The product’s low volatility means dust management is more relevant than vapor control, and proper bagging and air extraction keep workspaces clean and downtime rare. Training goes beyond what the MSDS states; new hires learn to measure residual product in transfer equipment to prevent accidental exposure. Storage facilities keep the material below 25 degrees Celsius, protected from sunlight, so that the product maintains true color and shelf-stability across multiple quarters.

    Supporting Diverse Applications—Rubber, Dyes, and Beyond

    Every year, nearly two-thirds of production ships directly to tire manufacturers and specialty rubber compounders. They push us for exacting quality and supply reliability. Uniform particle size, melt point, and trace impurity profiles ensure each drum gets accepted the first time. These are lessons taught by past years’ downtime and rejected lots—something a manufacturer feels more keenly than a distributor reading a product code on a manifest.

    Outside of rubber, 4,4'-Dimethoxydiphenylamine holds a niche role in the synthesis of certain dyes and pigments. The aromatic structure, stabilized by methoxy groups, lets color chemists build advanced intermediates in a single step. Most non-manufacturers overlook these nuanced uses, but dye formulators rely on analytical purity to predict their coloration results with confidence. A single impurity can change shade, hue, or lightfastness. Our laboratory teams test not just for known contaminants, but for trace side-products that could skew color in downstream runs.

    Some pharmaceutical developers and academic researchers turn to this compound for building complex molecules aimed at antineoplastic and neurological research. Here, they often request micro-scale, ultra-high-purity lots, sometimes packaged in double-lined glass ampules. Producing these small custom batches means interrupting bulk operations, purging reactors, and handling analytics in controlled clean rooms—steps that only the original factory can coordinate with speed and care.

    The Real-World Importance of Consistency

    Repeat customers never ask us for “uniformity” in abstract terms. They call with real process specs—“no more than 0.05% iron,” “less than 100ppm total volatiles”—and expect us to solve any drift. This level of dialogue comes from years in the chemical industry, where only those who produce at scale appreciate the downstream headaches caused by even minor spec deviation. Whether the material feeds giant polymer kettles or lab-scale microwave vessels, the cost of inconsistency climbs quickly.

    Any manufacturer can offer an off-the-shelf certificate of analysis. What really counts in specialty chemicals like 4,4'-Dimethoxydiphenylamine is a sustained commitment to process improvement. Many of our advances—a finer crystallization grind, tighter warehouse controls, improved solvent recovery—spring from conversations with site managers facing tight deadlines and stricter regulatory thresholds. Adjusting to these realities means investing in new filters, better staff training, and extended analytics runs, often at 2 am before a large shipment closes to the dock.

    Addressing the Challenges: Reliability and Future Supply

    Long-run production of 4,4'-Dimethoxydiphenylamine isn’t simply a story of scale. Raw materials, such as anisole and nitroaniline, face price swings and regulatory challenges, especially as global authorities clamp down on hazardous intermediates. This hits home for purchasing and logistics managers who see supply chain risk as a real business concern. We respond by holding greater raw stock, qualifying multiple vendors, and swapping in greener solvents whenever possible. Having direct control over production, we switch process parameters within weeks—not quarters—helping customers bypass unknown risks from the commodity market.

    Every major disruption—shipping blockades, port delays, or regional power outages—reminds us why direct factory contact matters. Buyers come to us not just for current specs, but for guaranteed timing and recovery options. One incident last year, when a regional port backed up for two weeks, let us put contingency plans in motion and keep customers supplied. Being rooted in both the chemical and logistics side keeps us nimble, not just reactive.

    Sustainability and Product Stewardship

    Modern pressures around sustainability touch every part of our work with 4,4'-Dimethoxydiphenylamine. Disposal of spent solvents, energy management in batch heating, and reduction in atmospheric venting now get as much scrutiny as quality specs. Our process engineers devote time to closed-loop solvent recovery and new filtration resins. These investments cut not only emissions but costs as energy markets shift.

    Product stewardship doesn’t stop at our gate. Customers want clear, trustworthy documentation on every batch—origin, analytical details, and safe handling. We put boots on the ground, offering guidance on worker safety, in-plant air handling, and options for downstream waste reduction. This approach grows out of longstanding relationships, not sales scripts. Our teams often visit user sites, reviewing their operations and resolving handling issues in person. It becomes a cycle: better practice at the user’s plant means more predictable supply agreements and easier business for all.

    Continuous Improvement and Experience-Driven Reformulation

    Decades in the business teach us that formulas and process routes never stay static. Minor staff changes, weather, and changes in global energy supply can nudge yields and by-product rates in new directions. Our chemists remain vigilant for these creeping variations and respond with re-calibration. Daily, teams test melt points from each shift, checking visual and analytical markers. Only a producer with this level of touch can respond quickly to issues like trace chromatography drift or small variations in particle grind.

    Innovation doesn’t mean a new brochure every quarter. It shows up in quiet changes to process routing, more reliable in-line moisture sensors, and better communication between departments. Clients don’t always notice these internal adjustments, but the results show up in more consistent finished goods, fewer rejected drums, and phone calls with fewer surprises.

    Looking Ahead: Meeting Challenges Together

    Future demand for 4,4'-Dimethoxydiphenylamine looks set to grow in high-performance rubber, but also in advanced electronics and colorant sectors. Users want even cleaner material and more environmental transparency. We work to deliver both, knowing that real improvement builds from the ground up, not from marketing slogans. We focus on safe, reliable, and transparent production. The factory will always prioritize clarity—real feedback from real users guides our next steps. Only long experience and direct engagement with customers, suppliers, and regulators will keep this specialty amine at the front of specialty chemical manufacturing. Each improvement we put in reflects not just compliance, but a commitment to value for those who rely on us every day on the line.