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4,4'-Dichlorodiphenyl Disulfide

    • Product Name 4,4'-Dichlorodiphenyl Disulfide
    • Alias Bis(4-chlorophenyl) disulfide
    • Einecs 221-079-2
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    849155

    Iupac Name 1-chloro-4-[(4-chlorophenyl)disulfanyl]benzene
    Molecular Formula C12H8Cl2S2
    Molecular Weight 303.23 g/mol
    Cas Number 844-52-6
    Appearance Off-white to yellow crystalline powder
    Melting Point 137-141°C
    Solubility In Water Insoluble
    Density 1.41 g/cm³
    Purity Typically ≥98%
    Odor Odorless
    Synonyms 4,4'-Dichlorodiphenyl disulfide; Bis(4-chlorophenyl) disulfide
    Storage Temperature Store at room temperature
    Ec Number 212-688-7

    As an accredited 4,4'-Dichlorodiphenyl Disulfide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 500g package is a sealed amber glass bottle with a hazard label, product name, and safety information clearly printed.
    Shipping 4,4'-Dichlorodiphenyl Disulfide is typically shipped in tightly sealed containers to prevent moisture ingress and contamination. It should be packed according to local and international chemical transport regulations, handled with care, and stored in a cool, dry location, away from oxidizing agents. Proper labeling and hazard communication are essential during shipping.
    Storage **4,4'-Dichlorodiphenyl disulfide** should be stored in a tightly closed container, in a cool, dry, and well-ventilated area. Protect from direct sunlight, moisture, and incompatible materials such as strong oxidizing agents. Store away from food and drinking water. Proper labeling and secure shelving are essential to prevent spills and accidental exposure. Use secondary containment to manage potential leaks or spills.
    Application of 4,4'-Dichlorodiphenyl Disulfide

    Applications of 4,4'-Dichlorodiphenyl Disulfide in Industrial Manufacturing

    4,4'-Dichlorodiphenyl Disulfide (DCDPS) serves as a specialty intermediate across several industrial value chains where disulfide and aryl chloride functionalities enable demanding polymerization reactions and specific engineering properties. As a direct manufacturer, we ensure consistent supply and adherence to international standards to support the most technically advanced downstream sectors.

    1. High-Performance Polysulfone and Polyethersulfone Resins

    DCDPS is a critical monomer in producing high-performance thermoplastics like polysulfone (PSU) and polyethersulfone (PESU), supporting thermal stability, flame resistance, and chemical compatibility. These advanced engineering polymers require precise control of disulfide bridge content for targeted mechanical and dielectric behavior. Our customers integrate this raw material to meet stringent global standards for industrial plastics in electrical, food-contact, and medical-grade components.

    Industry compliance standards

    • ISO 9001:2015 Quality Management System
    • UL 94 (Flammability Rating for Plastics)
    • FDA 21 CFR 177.1655 (Polysulfone Resins for Food Contact Applications)
    • REACH Regulation (EC 1907/2006, SVHC compliance verification)

    Typical usage ratio

    • 10–50% w/w as a direct monomer in backbone structure; actual proportion adjusted for target molecular weight and required sulfone/disulfide balance

    Downstream process integration

    • Charged directly in the polymerization reactor with bisphenol compounds and sulfonation agents, followed by melt or solution condensation polymerization

    Final product types

    • Membrane-grade PSU and PESU chips
    • High-temperature electrical insulation films
    • Medical device housings compliant with FDA requirements
    • Transparent food-contact containers and filters

    2. Sulfur-Based Rubber Vulcanizing Additives

    DCDPS enters the production of specialty rubber chemicals focused on vulcanization systems where finely tuned sulfur–chlorine reactivity provides enhanced crosslinking for synthetic and natural rubber blends. Rubber compounders use this input to manufacture tires, belts, and gaskets with advanced heat-aging resistance and precise elasticity profiles for automotive and industrial uses.

    Industry compliance standards

    • ASTM D3182 (Rubber—Compounding Materials)
    • ISO 14001 (Environmental Management in Rubber Manufacturing)
    • EU REACH Annex XVII (Use restrictions for certain organochlorines)
    • IATF 16949 (Automotive Quality Management)

    Typical usage ratio

    • 0.5–3.5 phr (parts per hundred rubber); ratio varies depending on blend composition, filler loading, and mechanical requirements

    Downstream process integration

    • Introduced during the internal mixing or open mill compounding stage, followed by downstream vulcanization with other accelerators and sulfur donors

    Final product types

    • High-modulus rubber sheets for gasket and sealing applications
    • Automotive tire tread and sidewall compounds
    • Oil-resistant conveyor and transmission belts
    • Anti-abrasion rubber rollers

    3. Advanced Epoxy Resin Curing Agents

    Epoxy system formulators leverage DCDPS as a hardener or modifier to achieve increased chemical, heat, and solvent resistance in finished two-component and powder-cured epoxy systems. Its aryl disulfide structure facilitates toughened network formation, widely adopted for creating coatings and laminates specified for aggressive chemical service or demanding infrastructure applications.

    Industry compliance standards

    • ASTM D1652 (Epoxy Resin—Viscosity and Curing Analysis)
    • EN 1504-2 (Protection Systems for Concrete Structures)
    • RoHS 2011/65/EU (Restriction of Hazardous Substances in Electrical/Electronic Equipment)
    • ISO 9001 (QA for Resin Formulation and Blending)

    Typical usage ratio

    • 3–12% by weight relative to total resin solids; fine-tuned to achieve specified crosslink density and heat distortion temperature

    Downstream process integration

    • Added during pre-blending or reaction with epoxy oligomers, followed by curing at controlled temperature profiles in either solvent or powder application setups

    Final product types

    • Chemical-resistant tank and vessel linings
    • Protective anti-corrosion coatings for marine and industrial assets
    • High-strength composite laminates
    • Encapsulation materials for power electronics

    4. Intermediate for High-Purity Dye Manufacturing

    DCDPS acts as a multifunctional intermediate for the synthesis of complex sulfur- and chlorine-bearing dyes, which require narrow impurity profiles and consistent isomer content for reproducible coloration and resistance attributes. Manufacturers in the specialty dye sector incorporate this building block into routes towards high-stability colorants used in plastics, fibers, and technical textiles destined for regulated sectors.

    Industry compliance standards

    • Oeko-Tex® Standard 100 (Textile Safety Requirements)
    • EN 71-3 (Safety of Toys—Migration of Certain Elements)
    • REACH Annex XVII (Dye restrictions including azo and halogenated compounds)
    • ISO 14001 (Responsible dye manufacturing)

    Typical usage ratio

    • Stoichiometric (100% molar equivalent) as a coupling agent or aromatic core, dosage tailored to targeted chromophore structure and shade requirements

    Downstream process integration

    • Charged to sulfide or chlorination reaction steps; participates in subsequent coupling condensations or cyclizations, then follows purification by recrystallization or chromatography

    Final product types

    • Technical-grade organic dyes for engineering plastics
    • Fiber-stable textile dyes
    • Industrial-grade pigments for automotive coatings
    • High-performance colorants for inkjet and digital printing systems

    5. Synthesis of Liquid Crystal Polymer (LCP) Intermediates

    Engineered as a chemical scaffold in LCP precursor production, DCDPS introduces rigidity and defined axis alignment required for high-Tg and anisotropic melt-processing resins. Specialty polymer producers add this molecule to pathways for aromatic copolyesters and copolyamides to meet global electronics and micro-molding requirements.

    Industry compliance standards

    • IEC 61249-2-7 (Electronic Substrate Materials)
    • UL 94 V-0 (Flame Rating for Thin Film and Insulating Laminates)
    • ISO 1043-1 (Identification of Plastics—Liquid Crystal Polymers)
    • RoHS (Lead-free and Halogenated Compound Restrictions)

    Typical usage ratio

    • 5–20 mol% as a backbone monomer; selected according to crystal orientation, melt-processability, and required mechanical strength

    Downstream process integration

    • Reacted in the oligomer-polymer condensation process alongside biphenols and aromatic acid chlorides, followed by precise catalyst and temperature control to yield high-purity intermediates

    Final product types

    • Microelectronic connectors and sockets
    • High-frequency printed circuit board laminates
    • Precision gears and micro-molded structural parts
    • Lightweight electrical insulation tapes
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    Certification & Compliance
    More Introduction

    4,4'-Dichlorodiphenyl Disulfide: Versatility and Reliability from the Manufacturer’s Floor

    Deep Roots in Our Production Process

    Every batch of 4,4'-Dichlorodiphenyl Disulfide we ship starts with high-purity raw chlorobenzene and sulfur chloride. We watch each step from charging the reactors, managing the precise addition of reagents, right on through to controlled cooling and filtration. Plant managers check for off-color or unusual odors out of habit. Our technical crew always tests the intermediate before finishing the final crystallization phase. For decades, the same methods shape our output: gentle heat ramps, calibrated agitation, and a focus on achieving solid particle size. No shortcut or trick substitutes for hands-on process control, and from this careful work, the white crystalline powder of 4,4'-Dichlorodiphenyl Disulfide emerges.

    What Sets Our Product Apart

    Most people familiar with organic intermediates in the rubber and plastics sector have worked with diphenyl disulfides at some point. Yet, 4,4'-Dichlorodiphenyl Disulfide stands out in industrial applications due to the modified electronic structure from the chlorine atoms. Down on the floor, this means a more robust behavior during mixing and less residue in finished products. Compared to ordinary diphenyl disulfide, our chlorinated variant remains stable at higher processing temperatures. Our customers value this stability because it preserves mechanical properties in heat-intensive processes.

    Handling chlorinated disulfides in an active factory environment often raises concerns about purity or consistency. Employees don’t like to spend overtime cleaning up after poor crystallization. We keep our product in a range above 99% assay, never skimping on purity checks. The result is a powder that pours without lumps and dissolves evenly, whether fed into a compounding line or dissolved for downstream synthesis. This is not a small detail. Chemists tell us their yield seems to rise with our lot, simply because fewer by-products form during vulcanization or crosslinking.

    Common Applications that Reward Consistency

    Compounders in the rubber sector find the chlorine-functional disulfide familiar from their work with older accelerator systems, especially in specialty elastomers. The chemical structure lends itself to controlled crosslinking, resulting in tire carcasses that meet surprisingly strict modulus requirements. Cable manufacturers experiment with alternative crosslinkers every year, but the old hands stick with 4,4'-Dichlorodiphenyl Disulfide for its predictable scorch time and cleaner curing profiles. Splice failures and product haze drop when the manufacturing process uses high-purity versions of this compound.

    Plastics processors also come back to it when working with high-performance resins. We see the highest demand spikes when the major molding lines focus on heat and chemical resistant applications. Whether destined for a fuel-resistant gasket or an anti-corrosive pipe, this compound supports reliable performance because the chlorines shield against unwanted oxidation pathways. We rarely hear complaints of yellowing or surface defects in batches with our product, a testament to years spent refining filtration and washing techniques.

    What Quality Looks and Feels Like

    People walk the plant with samples in hand, tapping piles to check for caking or tracking the dust when poured. Rejects happen if the color shifts to cream or the odor slips away from the neutral. Operators trust their experience as much as the digital analyzers hooked to the quality control lab. The learning curve for production always comes down to two things: temperature discipline on the reactors and patience in filtration. Factory veterans see the difference in how fast our product moves through their feed hoppers and the neatness of their end product. In the open market, some lots hardly resemble the true material, carrying faint yellow hues or sticky textures that spell trouble in the next process step.

    We never discount the role of packaging and storage, either. Cardboard drums tend to shed fibers. Poly lined sacks block out humidity, so the powder stays loose and fresh. By the time material reaches the client’s door, we want the handling experience to match expectations—a detail as critical as the purity of the powder inside.

    Who Benefits Most from This Material?

    Small batch custom rubber mixers, multinational tire plants, and technical plastics converters form the core clientele. Custom elastomer recipes that call for fine-tuning of curing times or tighter controls on heat resistance show the strongest results. Tire producers value it for its contribution to slow, even curing that extends tread and casing life. These aren’t theoretical benefits; field reports track lower failure rates and higher re-treadability where the right crosslinkers are used.

    Thermoplastic applications, particularly in wire coatings or specialty films, also show strong performance metrics when using true 4,4'-Dichlorodiphenyl Disulfide. Engineers see the difference when processing window edges, automotive belts, or sealed chemical containers. In each of these sectors, the right intermediary chemicals deliver long-term field stability and less downtime.

    Why Precision Synthesis Matters

    We take pride in the tight controls set up across every phase of the operation. A difference in reaction timing or an unbalanced wash can lead to persistent trace solvents or unwanted by-products hiding in the finished powder. Reactions are not left unattended, and no shipment goes out until every specification checks out in our in-house labs.

    A few years ago, fluctuating sourcing of base chlorobenzene created a hiccup in one facility. The resulting batch, run with a less pure feedstock, showed strange drying behavior and failed to blend correctly in downstream lines. We immediately doubled back: ran extra chromatograms, re-calibrated suppliers, and tweaked agitation cycles. Since then, we audit incoming materials to avoid a repeat. Friends in the trade sometimes ask why we’re so rigid on inbound quality. Our answer is simple—a missed impurity hurts the client and ruins a month’s worth of careful work.

    Distinguishing Features: More Than Just a CAS Number

    4,4'-Dichlorodiphenyl Disulfide can pass casual inspection by name alone, but close inspection reveals its real differences. The most notable distinction from standard diphenyl disulfide shows up both in process ease and downstream product durability. The extra chlorines make a world of difference—the melting point holds up under hotter temperatures, and chemical resistance in polymers rises measurably. Local university polymers labs have confirmed improved oxidative resistance of vulcanizates made with this compound over basic disulfides.

    In comparison to other functional disulfides, ours produces fewer volatile by-products, leading to less equipment fouling and lower emissions during large-scale rubber processing. Mixer operators report fewer deposits along extruder heads. This saves time on clean-outs and translates hands-on into higher uptime for continuous lines.

    Managing Environmental and Handling Concerns

    Operating as a manufacturer, the realities of chemical handling are never far from mind. We have seen the full lifecycle in our own facilities and on client sites alike. Responsible handling means routine checks for equipment leaks, regular training for shift workers, and rigorous waste stream controls. Disposal of off-spec material proceeds in-line with evolving country regulations. Years ago, we added vapor control steps after some early monitoring showed trace emissions during dry transfers. This taught us to focus on both safety and long-term stewardship.

    We share handling tips openly with our users—not out of regulatory fear, but from pragmatism learned in daily operations. Gloves, dust masks, and good ventilation are standard protocol here, and we recommend the same in client mixing pits. We bag and seal product under nitrogen on the plant floor after multiple incidents made it clear that humidity spikes can clump even well-made powder. Tight process and attention to safe handling keep our sites running, year after year, with no serious incidents.

    Getting Reliable Supply

    In our experience, the most serious headaches clients face come from missed deliveries or sudden spec changes. Every plant in our network supports buffer stocks. If a reactor goes down in one city, shipments continue from another. It is standard to log reagent lots, staff shift details, and finished product assay data for each batch. Customers appreciate knowing that our records run deeper than the minimum paperwork. Last year, a shipping lane froze up unexpectedly. Thanks to distributed inventory and planning, our production commitments stayed on track. These days, continuity counts more than ever.

    Technical support remains a non-negotiable for ongoing partnerships. Our application engineers visit customer plants, audit glovebox purging, and check dosing lines. We value this technical dialogue because field issues resolve faster with real-world insight. One of our long-standing clients introduced a new rubber grade and struggled with dispersion. Together, we traced the issue back to an incorrect pre-mix sequence—not with the compound itself, but with outdated feeder technology. These learnings cut across sectors and continue to sharpen our approach.

    Focus on Safer, Smarter Chemistry

    The years have made us cautious, but also confident in the proven chemistry of chlorinated diphenyl disulfides. New product development keeps aiming for better performance: lower VOCs, tighter particle distribution, and tailored customer blends. The core molecule, though, hasn’t changed all that much—because at its heart, stability and known performance remain king.

    Adopting new safety and environmental practices grows more pressing. We’ve fitted outprocess lines with online monitoring, and waste recovery systems pull chlorinated compounds away from the wastewater stream. Collaborative efforts with customers continue in research projects aimed at boosting recovery in crosslinker washes and exploring greener solvents. Every so often, a new regulatory twist presses us to innovate. We view it as motivation, not a hurdle.

    Conclusion: Standing with Our Clients in the Field

    Experience breeds appreciation for chemicals that perform as expected, batch after batch. 4,4'-Dichlorodiphenyl Disulfide offers more than a simple building block: it supports long production runs, cleaner outputs, and more reliable results in critical applications. Its value comes into focus most clearly among those who have chased erratic suppliers and lived through production plant headaches caused by contaminated or poorly processed raw materials. Our commitment to rigorous process control, open engagement with plant engineers, and safety-first operations ensures that this key ingredient continues to empower industry advances.

    Our team keeps learning, both from new science and from the steady feedback streaming back through customer lines. It’s this steady improvement, rooted in hands-on manufacturing, that drives both product quality and long-term trust in the work we do. Experience has taught us the true value of dependable raw materials, not just in numbers or specs, but in the hard realities of daily industrial life. 4,4'-Dichlorodiphenyl Disulfide stands as a testament to what careful manufacturing, practical knowledge, and ongoing dialogue with our customers can deliver.