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4,4'-Diamino-2,2'-Stilbenedisulfonic Acid

    • Product Name 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid
    • Alias DAS
    • Einecs 203-793-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    404659

    Cas Number 81-11-8
    Molecular Formula C14H14N2O6S2
    Molecular Weight 386.46 g/mol
    Appearance Yellow to yellow-green powder
    Melting Point Above 300°C (decomposes)
    Solubility Soluble in water
    Purity Typically ≥95%
    Ph 1 Solution Approximately 6-8
    Synonyms 4,4'-Diaminostilbene-2,2'-disulfonic acid, DSD Acid
    Application Optical brightener, fluorescent whitening agent
    Odor Odorless
    Density Approx. 1.5 g/cm³
    Ec Number 201-327-3

    As an accredited 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 500-gram white HDPE bottle labeled "4,4'-Diamino-2,2'-Stilbenedisulfonic Acid," with hazard symbols and batch information displayed.
    Shipping 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid should be shipped in tightly sealed containers, protected from moisture and incompatible substances. It is typically transported as a solid powder and classified as non-hazardous for shipping. Standard procedures for chemical transport apply, ensuring proper labeling and documentation according to local and international regulations.
    Storage 4,4'-Diamino-2,2'-Stilbenedisulfonic acid should be stored in a tightly closed container, in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers. Protect from moisture and direct sunlight. Store at room temperature and avoid excessive heat. Ensure the storage area is clearly labeled and complies with chemical safety regulations to prevent accidental exposure or contamination.
    Application of 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid

    Applications of 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid in Industrial Manufacturing

    As a direct manufacturer, we supply 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid (DAS) for critical roles in large-scale chemical and materials industries. Recognized for its high-performance optical and chemical properties, DAS enhances process outcomes across established downstream sectors.

    1. Optical Brighteners for Detergent Formulations

    Major laundry powder and liquid detergent producers use DAS as a core component in the production of stilbene-based optical brighteners, specifically optical brightener CBS-X. It reacts with cyanuric chloride to form fluorescent whitening agents, which integrate into detergent formulations to improve fabric whiteness and enhance visual cleaning effects. Sourcing and process controls must address strict environmental, purity, and brightness index requirements established for textile and household cleaning applications worldwide.

    Industry compliance standards

    • EU Regulation (EC) No 648/2004 (Detergents Regulation)
    • REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
    • US EPA TSCA Inventory Compliance
    • China GB/T 26386-2011 Detergent Additives Standard

    Typical usage ratio

    • 0.05–0.3% by weight in laundry detergent powder formulations
    • Up to 0.5% in concentrated liquid detergents, adjusted based on optical requirements and base powder granulation

    Downstream process integration

    • DAS reacts with cyanuric chloride to synthesize optical brightener CBS-X
    • Brightener slurry or dry powder is incorporated during detergent post-blending or spray drying stages
    • Brightening agent dispersion and stability checked by in-line QC through UV-reflectance measurements

    Final product types

    • Premium laundry powders
    • Concentrated liquid detergents
    • Industrial and institutional cleaning agents
    • Fabric softening detergent pods

    2. Paper Manufacturing and Coating Additives

    Paper mills employ DAS in the synthesis of fluorescent whitening agents (FWAs) for high-brightness paper grades. Its high affinity with cellulose allows consistent incorporation into paper pulp, improving visual brightness in office paper, magazine stock, and specialty grade papers. Integrators must account for the paper regulatory landscape and requirements on migration and leaching appropriate for food-contact and archival paper.

    Industry compliance standards

    • BfR Recommendation XXXVI (Germany) – Paper and paperboard for food contact
    • US FDA 21 CFR §176.170 (Components of paper and paperboard in contact with aqueous and fatty foods)
    • ISO 2470-1 (Brightness measurement of paper and pulp)
    • China GB 9685-2016 Additives in Food Contact Paper

    Typical usage ratio

    • 0.05–0.2% by dry pulp weight for standard office and publication paper
    • Up to 0.3% for high-brightness or specialty coated papers, with dosage adjusted based on target ISO brightness and FWA retention

    Downstream process integration

    • Synthesized FWA solution is dosed directly into the pulp stock before sheet formation
    • Alternatively, DAS-based FWAs are applied as coating additives at the size press or surface sizing station
    • On-line spectrophotometric systems monitor uniformity and optical response throughout the process

    Final product types

    • Multipurpose office xerographic paper
    • Magazine and fine art printing papers
    • Food packaging paperboard
    • High-brightness archival grades

    3. Synthetic Fiber Whitening Agents Production

    Polyester and nylon fiber manufacturers use DAS as an intermediate for trisulfonic or tetrasulfonic stilbene-based optical brighteners during fiber spinning and extrusion. During polymer melt processing, the final FWA produced from DAS remains thermally stable and resistant to migration, maintaining the visual appeal and uniform brightness required by apparel, sportswear, and home textile manufacturers. Regulatory frameworks require all added substances to comply with textile safety standards.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (Textiles free from harmful substances)
    • ISO 16373-2:2014 (Determination of certain azo colorants in textile products)
    • Textile Product Safety Law of China (GB 18401-2010)
    • Global Organic Textile Standard (GOTS) - Relevant to certain microfiber applications

    Typical usage ratio

    • 0.03–0.12% (on polymer weight) for continuous filament spinning
    • Dosage optimized through pilot runs based on polymer type, fiber denier, and UV light fastness targets

    Downstream process integration

    • DAS-derived FWA is incorporated into the polymer chip blend or melt phase before fiber extrusion
    • Post-spin finishing baths may receive additional brightener for desired surface luminosity
    • QC checks for migration, thermal stability, and light fastness in finished fiber tow

    Final product types

    • Texturized polyester filaments for clothing
    • Nylon yarns for hosiery and sportswear
    • Curtain and upholstery synthetic fibers
    • Microfiber cleaning materials

    4. Leather Processing and Auxiliary Finishes

    Leather chemical producers utilize DAS as a precursor for high-purity fluorescent agents required in specialty finishing treatments. These agents enhance visual brightness and whiteness in white crust and pastel leathers, meeting both fashion demands and technical norms for physical and light fastness. Enactment of environmental and product safety standards on heavy metals, amines, and chemical additives governs this sector.

    Industry compliance standards

    • ISO 17075 (Leather—Chemical determination of chromium(VI) content)
    • ZDHC Manufacturing Restricted Substances List (MRSL)
    • EU REACH Annex XVII (restrictions for chemical substances in finished leather goods)
    • EN 16415 (Physical and chemical testing for leather safety)

    Typical usage ratio

    • 0.05–0.2% in base finishing compound formulations, depending on leather type and cover intensity
    • Adjusted within compliance testing to prevent color transfer and optimize light fastness

    Downstream process integration

    • DAS-based brightener synthesized on site or supplied as a commercial FWA
    • Mixed into finishing lacquer or aqueous topcoat immediately before spray or curtain coating step
    • Wet-end application in pickling or neutralization baths selectively used in white or pastel leathers

    Final product types

    • White finished split and grain leather
    • Fashion leather for shoes and bags
    • Automotive and upholstery hides
    • Technical leathers for sports equipment

    5. Textile Dyeing and Printing Chemicals

    Dye and pigment manufacturers leverage DAS in the synthesis of stilbene-based reactive dyes and brighteners, which find downstream usage in textile pad-dyeing, exhaust dyeing, and digital printing. The fluorescent dyes created offer improved shade consistency, enhanced brilliance, and better wash fastness across natural and synthetic fiber substrates. Compliance with international dye safety and residual chemical standards is mandatory for export-oriented mills.

    Industry compliance standards

    • ZDHC Chemical Gateway (Textile chemicals screening)
    • EU Ecolabel for Textile Products 2014/350/EU
    • ISO 14024 (Environmental labels and declarations for textiles)
    • China GB 31701-2015 (Textile safety technical specification for infant textiles)

    Typical usage ratio

    • 0.03–0.2% (on-fiber weight) for reactive dye bath concentrations
    • Higher dosing in digital printing pre-treatments, tailored per print depth/calibration trials

    Downstream process integration

    • Synthesized dye intermediate is entered into high-pressure dyeing, batch dyeing, or continuous pad-application
    • DAS-derived components added during pre-treatment for improved leveling in digital and screen printing
    • QC ensures compatibility on cellulosic, polyester, and blend substrates through test runs

    Final product types

    • Dyed woven and knitted garments
    • Printed home textiles
    • Yarn-dyed sewing thread
    • Children’s apparel and technical textiles

    6. Plastic Processing and Masterbatch Compounds

    Masterbatch and plastics compounders select DAS-sourced brighteners for applications in polymer films, molded goods, and injection-molded components where color fastness and visual enhancement are vital. The brightening agent is formulated for low-migration and thermal stability to meet the needs of consumer packaging, electronics, and automotive interiors. Product and processor compliance adheres to stringent food contact and migration standards.

    Industry compliance standards

    • EU Regulation (EU) No 10/2011 for Plastic Materials and Articles Intended to Come into Contact with Food
    • US FDA 21 CFR §177 (Polymer Additives in Food Packaging)
    • EN 71-3:2019 (Safety of toys—Migration of chemicals)
    • UL 94 (Plastic flammability standards—relevant for electronics and automotive)

    Typical usage ratio

    • 0.01–0.10% by resin weight for film extrusion and blow molding
    • Concentration depends on specific resin (PE, PP, PET, PS) and optical transmission standards

    Downstream process integration

    • DAS-derived brightener is blended into polymer pellets during masterbatch compounding
    • Color concentrate is dosed during extrusion, injection, or blow molding operations
    • QC monitors melt flow, brightness, and migration potential in finished items

    Final product types

    • Food-contact plastic wrap and containers
    • Injection-molded appliance parts
    • Automotive trim components
    • Packaging films and consumer goods housings
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    Certification & Compliance
    More Introduction

    4,4'-Diamino-2,2'-Stilbenedisulfonic Acid: A Manufacturer’s Perspective

    Introduction to Our Product

    In the field of optical brightening agents, 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid stands out and keeps a firm place in our production line. Over the decades, facilities like ours have refined the methods, learned the material’s temperament, and witnessed its impact across industries. Too many times, these specialty chemicals remain anonymous outside the supply chain, but their influence spreads from industrial paper to textiles and detergents. Our experience manufacturing this stilbene derivative offers a viewpoint beyond the usual brochure.

    About the Compound

    4,4'-Diamino-2,2'-Stilbenedisulfonic Acid—sometimes called DAS or DSD Acid—belongs to the stilbene series, known for their strong fluorescence and water solubility. Once, stylistic flourishes in paper or fabric meant adding dyes or bleaches, but those faded or degraded under sunlight. With DSD Acid, that problem no longer dictates the boundaries of colorfastness and brightness. The structure features two amino groups and two sulfonic acid groups on a stilbene skeleton, and this configuration is what creates its remarkable optical activity and compatibility with aqueous processes.

    Years of Manufacturing: What Sets Our DSD Acid Apart

    Producing DSD Acid at scale is less about catalog specs and more about managing the realities of raw materials and handling. Our plant sources carefully-controlled aniline for aminating reactions and tightly regulates the conditions for sulfonation. Deviating by even a few degrees or drifting pH for half a shift can drop the product’s purity below 99%. That’s why we constantly calibrate and validate each batch with both in-house and third-party labs.

    We focus on technical-grade material with typical specifications of white to yellowish crystals, high assay for the active component, and negligible heavy metal impurities. The reality of bulk production: surface appearance can change slightly due to batch variables, but fluorescence and reactivity cannot slip. As manufacturers, we see customers set lower thresholds for iron content and ask about specific byproducts, especially those in quality-driven sectors such as premium detergents or optical paper coatings.

    Usage in Industry: Insights from Production & Application

    Each time a ton of DSD Acid leaves our gates, we know its journey isn’t over. It usually moves straight to optical brightener manufacturers, where it becomes the backbone for products like CBS-X or other stilbene-based fluorescent whitening agents. These agents catch UV light and emit it in the blue region, counteracting yellowness in fabrics and paper. Years of dialogue with downstream users taught us that the demands of detergent and textile application differ significantly—solid state stability matters for detergents, but dispersibility and purity take center stage for textiles and paper processing.

    We spent years trialing particle size distribution and drying methods. Large-scale detergents want free-flowing, non-dusting powder to mix into production lines, where bulk handling is automated and moisture variability can clog machines or disrupt downstream synthesis. Meanwhile, manufacturers targeting high-quality white paper require a purity often above 99%, minimal insoluble matter, and specific levels of residue on ignition, given that insoluble particles can affect paper uniformity and surface finish. Talking to customers who use our DSD Acid for liquid optical brightener concentrates, we refine our process to minimize trace salts, avoiding streaking in the end applications.

    DSD Acid vs. Other Fluorescent Brightener Precursors

    It’s easy to lump stilbene derivatives together, but the differences come into focus during synthesis and end-use. We have seen customers ask for alternatives like 4,4'-dihydroxy-2,2'-stilbenedisulfonic acid or tetrasulfonated analogues. These compounds offer different reactivities: the shape and number of sulfonic groups change water solubility, influence the finishing process, and affect the degree of binding to fibers or paper cellulose.

    DSD Acid has earned its place as the most versatile core for brighteners thanks to its balance of solubility, reactivity, and fluorescence strength. Tetrasulfonic versions bring greater solubility but can reduce binding strength in textiles, causing wash-off or fade over repeated cycles. Other precursors with different functional groups struggle in detergent applications because they require milder process steps, which can sacrifice shelf-life stability of the final brightener. Our product’s structure supports robust performance across diverse processing lines—a fact validated not in data sheets, but in years of continuous plant operation and close feedback from formulation chemists.

    Challenges in Manufacturing, Quality, and Supply Chain

    Producing DSD Acid goes beyond managing a standard chemical reaction. Aniline derivatives bring their own health and safety protocols—strict monitoring of emissions and effluent treatment plants remain part of our everyday reality. Our energy and water usage get robust oversight from both regulators and our internal sustainability teams. At full capacity, keeping effluent within permitted COD and BOD levels remains non-negotiable; we invest in continuous process improvements, such as catalyzed air oxidations and crystallization recycling, to cut the environmental load per ton produced.

    Scrutiny on supply chain reliability has intensified post-pandemic. Import delays once measured in weeks can now stretch into months. Bulk prices for some raw materials fluctuate with oil and commodity cycles, directly affecting production scheduling. When volatility hits, our long-standing relationships with upstream basic chemical producers—plus our own safety stocks—help buffer against scarcity. We often work closely with key clients to project forecasts six months out, adjusting production schedules and raw materials purchasing to keep both inventory waste and stockouts low.

    Sustainability and Corporate Responsibility

    Years ago, waste from DSD Acid synthesis would have landed in simple holding ponds. Now, expectations cover not just regulatory compliance but genuine lifecycle analysis of the product. We track our carbon footprint from incoming aniline through final shipment of crystalline acid. Our investment in closed-loop solvent recovery and heat integration systems cut both emissions and production cost, a benefit which we pass to buyers as competitive pricing and transparent supply chain disclosures.

    As ESG (environmental, social, and governance) reporting now links closely with customer requirements, our focus expands beyond batch-to-batch consistency. Downstream, many detergent and textile brands now expect third-party audits on input chemicals, aiming for full traceability and responsible sourcing. That means our own production teams undergo regular safety and compliance auditing, and customers regularly visit the facility to see that process integrity and documentation truly line up with the paperwork.

    Beyond Basics: R&D and Value Additions

    The need for higher purity, lower toxicity, and better environmental compatibility continues to drive new directions. Our R&D team collaborates with technical partners on cleaner, more efficient synthesis routes. We explore catalytic hydrogenation steps to reduce by-products, and test new filtering media to cut organic residues. Each modification sends ripples through the production chain—sometimes demanding tank cleaning protocols or retraining for operators—yet the long-term gains in product quality justify the effort.

    In response to custom requests, we sometimes tweak crystal morphology or moisture content. For example, detergent producers want DSD Acid with specific flow characteristics, avoiding clumping and improving storage. Large-format consumers, including pulp and paper mills, prefer granulated forms for mechanical dosing. These needs led us to develop variant drying regimes and storage controls, and to field-test various packaging methods. We learned early on that even small variations in handling—humidity during packing, for example—can affect not just ease of use, but shelf-life and final brightener performance.

    Quality Assurance: Day-to-Day Experience

    For us, quality assurance isn’t just checking a box. Real-world chemical manufacturing means schedules run late, machinery sometimes breaks down, and human error can slip past paper procedures. That’s why our quality labs run full HPLC and UV-Vis testing on every batch, aiming beyond minimum specs toward the center of the bell curve. It’s common practice to retain reference samples from each lot for months, in case downstream users need troubleshooting or quality tracing.

    We also field requests for extended product documentation—some customers now need full impurity profiles, photostability studies, or custom toxicology reports. We actively cooperate, supplying what we can from our archives or running additional tests when possible. This level of transparency sits at the core of long-term trust, and we adopt upgrades in analytical techniques as they become available. The feedback from users about off-odors, foaming issues, or even changes in performance under different water conditions feeds directly back into our improvement cycles.

    Logistics: Realities of Global Chemical Supply

    Transporting DSD Acid takes careful logistics planning. Crystalline products face moisture risk, and bulk containers risk abrasion that could cause powdering and dust. We adopted humidity-controlled storage and multiply-lined bags to hold up under long-haul transport—crucial when containers travel weeks by rail and sea to detergent or OBA facilities around the globe. Few end users notice these interventions unless something goes wrong, but our dedicated logistics team checks every shipment’s condition, monitors container seals, and documents chain of custody.

    Whenever regulations shift, such as changes in dangerous goods classifications or customs documentation, our in-house compliance staff reviews protocols and adapts rapidly. We interface directly with port authorities and freight handlers, keeping shipments moving despite new requirements. For decades, chemical moves remained largely unremarkable; now, border controls and digital documentation introduce new bottlenecks and require constant management.

    Future-Proofing DSD Acid Production

    Rising demands for greener manufacturing and supply transparency mean DSD Acid production can’t stay static. We stay alert for regulatory changes on aromatic amines and sulfonated intermediates, planning plant upgrades well before rules take effect. The push from large buyers toward certification schemes—such as bluesign for textiles, or compliance with Nordic Swan for detergents—means our processes must pass tough, audit-driven benchmarks.

    Improvements in energy efficiency, recycling of process waters, and use of alternative feedstocks fill our R&D calendar. Several years ago, we switched part of our operation to use renewable steam for sulfonation reactors, cutting fossil carbon usage. The learning curve included retrofitting insulation and monitoring variations in heating rates, as even slight mismatches can affect yield consistency. As manufacturers, we keep both eyes trained on emerging substitution threats—novel biobased or non-aromatic brighteners—and adapt by upgrading our own process reliability and sustainability.

    Customer Partnership: Dialogue, Not Just Supply

    Customers see more than just the chemical—they see us as steady partners for long-term procurement. We provide not just a technical product but a service promise: delivery on time, traceability, and support for troubleshooting. Often we share lab data with client teams, help troubleshoot blending or formulation issues, or adapt our logistics to mesh with their timelines. This dialog helps identify shifting market needs early, such as requests for non-GMO labels or full compliance dossiers for global regulatory frameworks.

    We encourage technical exchanges at the application level. Chemists from our biggest detergent clients visited our site last year, walking the line and giving feedback that nudged us to upgrade storage humidity controls and adjust the size distribution in our standard product. Their focus on end-user results, rather than just price or spec-points, aligns closely with our manufacturing ethos—continuous improvement informed by real-world results.

    Looking Ahead

    Manufacturing and supplying 4,4'-Diamino-2,2'-Stilbenedisulfonic Acid means more than just running a reactor and shipping bags. It means tackling real-world production challenges, keeping sight of environmental goals, and listening to the people down the supply line. Every batch carries with it the investment of expertise, careful oversight, and ongoing collaboration—all aiming for a product that sets a clear standard in the world of optical brightening, today and as industry needs evolve.