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4,4'-Bis(Bromomethyl)-Diphenyl Ether

    • Product Name 4,4'-Bis(Bromomethyl)-Diphenyl Ether
    • Alias Bis-bromomethyl ether
    • Einecs 'EINECS 247-255-6'
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    902527

    Chemicalname 4,4'-Bis(Bromomethyl)-Diphenyl Ether
    Casnumber 5384-21-4
    Molecularformula C14H12Br2O
    Molecularweight 372.06 g/mol
    Appearance White to off-white crystalline solid
    Meltingpoint 95-98°C
    Solubility Insoluble in water; soluble in organic solvents
    Density 1.65 g/cm3 (approximate)
    Purity Typically >98%
    Synonyms 4,4'-Oxybis(bromomethyl)benzene
    Ecnumber 226-381-2
    Storageconditions Store at room temperature, in a dry and well-ventilated place
    Hazardclass Harmful if inhaled or swallowed

    As an accredited 4,4'-Bis(Bromomethyl)-Diphenyl Ether factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250g of 4,4'-Bis(Bromomethyl)-Diphenyl Ether is packaged in a sealed amber glass bottle with a secure screw cap and safety labeling.
    Shipping 4,4'-Bis(Bromomethyl)-Diphenyl Ether is shipped in tightly sealed, chemical-resistant containers to prevent leakage and contamination. Packaging complies with international regulations for hazardous materials. It should be transported in a cool, dry environment, away from incompatible substances, and clearly labeled according to safety guidelines for brominated organic chemicals.
    Storage 4,4'-Bis(Bromomethyl)-Diphenyl Ether should be stored in a cool, dry, well-ventilated place, away from heat, sparks, open flames, and incompatible substances such as strong oxidizers. Keep the container tightly closed and protected from moisture. Store in a dedicated chemical storage cabinet, preferably one designed for hazardous or reactive materials, and label the container clearly to prevent accidental misuse.
    Application of 4,4'-Bis(Bromomethyl)-Diphenyl Ether

    Applications of 4,4'-Bis(Bromomethyl)-Diphenyl Ether in Industrial Manufacturing

    As a direct manufacturer of 4,4'-Bis(Bromomethyl)-Diphenyl Ether, we have in-depth experience supporting its integration into advanced industrial formulations. Our expertise covers multiple downstream production chains where this specialty intermediate brings targeted chemical properties to high-performance end products. Below, we outline the main industrial sectors and specific utilization scenarios where our material consistently delivers on stringent manufacturing requirements.

    1. Flame Retardant Additive for High-Temperature Thermoset Resins

    Manufacturers of epoxy and phenolic molding compounds frequently incorporate our compound as a reactive flame retardant, particularly in electronics and transportation components where high LOI (limiting oxygen index) and stringent fire-safety demands must be met. The brominated functionality reacts covalently in resin curing, providing reliable char formation without leaching or migration under service conditions.

    Industry compliance standards

    • IEC 60695-11-10 (Fire hazard testing for plastics in electrical equipment)
    • UL 94 V-0/V-1 (Flammability standards for plastic materials)
    • EN 45545-2 (Railway applications: requirements for fire behavior of materials and components)
    • REACH Annex XVII (Restricted substances in flame retardants)

    Typical usage ratio

    • 2% to 8% by weight, determined by substrate polarity, targeted flame rating, and required mechanical properties. Higher loadings may be used for strict vertical burn resistance.

    Downstream process integration

    • Added to the prepolymer or resin blend during the liquid mixing phase, prior to catalyst or hardener introduction. For powder composites, incorporated in the preformulation step by dry mixing and extrusion.

    Final product types

    • Printed circuit board laminates (rigid, flex-rigid)
    • Electrical encapsulants
    • Automotive under-hood connectors and housings
    • Railway seat and interior panels

    2. Synthesis Intermediate for Specialty Polymeric Flame Retardants

    Industrial producers of poly(aryl ether)-based flame retardant modifiers utilize our raw material to introduce bromomethyl functionality in key backbone monomers. This supports downstream copolymerization processes, delivering finished polymers with permanently bonded halogenated groups for long-term flame suppression without plasticizer migration.

    Industry compliance standards

    • ISO 1043-4 (Flame retardant polymer classification codes)
    • RoHS Directive (2011/65/EU) (Restriction of hazardous substances in electrical and electronic equipment)
    • GB/T 2408 (Chinese standard for burning behavior of plastics)
    • ISO 9001:2015 (Quality management for intermediates and reaction polymers)

    Typical usage ratio

    • Stoichiometric ratios as defined by intended copolymer structure, typically providing 0.8 to 1.2 equivalents of the brominated monomer per mole of reactive comonomer in step-growth reactions.

    Downstream process integration

    • Introduced during the monomer synthesis step, followed by direct coupling with bisphenols or diphenyl ethers, which then enter condensation polymerization reactors for chain extension, yielding the functionalized polymer backbone.

    Final product types

    • Flame retardant poly(ether ether ketone) (PEEK) compounds
    • Brominated polyarylethersulfones (BPSU, BPSF)
    • Custom brominated copolymers for aerospace adhesives

    3. Curing Agent in High-Performance Epoxy Formulations

    Our material serves as a functional crosslinker within selected two-component and one-component epoxy systems, especially in adhesives and coatings for heavy-duty industrial and electronic applications. Its brominated methylene groups participate in the epoxy ring opening reaction, giving enhanced halogen incorporation and supporting robust crosslinked networks while boosting flame resistance.

    Industry compliance standards

    • IPC-4101 (Specification for base materials for printed boards)
    • ASTM D5048 (Standard test methods for epoxy resin adhesives)
    • IEC 61249-2-21 (Halogen-free base materials limits in PCBs)
    • Quality systems: ISO/TS 16949 for automotive electronics

    Typical usage ratio

    • 1% to 5% by total resin weight, balancing flame retardancy and mechanical strength; precise proportioning based on resin equivalent weight and desired glass transition temperature.

    Downstream process integration

    • Dispersed into the resin matrix during the component blending step, prior to mixing with hardener and/or accelerating agents; supports batch and continuous plant operations.

    Final product types

    • Flame retardant electronic potting and encapsulation materials
    • Automotive electronics adhesives
    • Protective circuit board varnishes and coatings

    4. Additive for Wire & Cable Insulation Compounds

    Cable and wire extrusion manufacturers use our compound as a reactive flame-retardant additive in PVC, TPE, and elastomeric insulation and sheathing materials to comply with demanding safety standards for industrial, consumer, and communications wiring. The chemical structure supports halogen release under fire, limiting propagation while maintaining required physical qualities for extrusion and long-term field service.

    Industry compliance standards

    • UL 1581 (Reference standard for electrical wires, cables, and flexible cords)
    • CSA C22.2 No. 210 (Appliance wiring material products)
    • IEC 60332-1-2 (Tests for flame propagation of wires and cables)
    • EN 50267-2-1 (Halogen acid gas emission tests)

    Typical usage ratio

    • 3% to 9% by weight depending on compound base resin type, gauge size, and target flame spread or low-smoke certification; adjusted according to end-product flexibility and dielectric requirements.

    Downstream process integration

    • Fed into twin-screw or Banbury mixing extruders along with base resin, plasticizers, and secondary flame-retardant synergists; followed by pelletization and melt extrusion into insulation or jacket profiles.

    Final product types

    • Power cable outer insulation
    • Data and communication cable sheaths
    • Flexible appliance cords
    • Fire-safety rated flat and round wire

    5. Modifier in Engineering Plastics for Electrical and Electronic Housings

    Our material is incorporated in the melt compounding of high-heat-resistant thermoplastics, such as polybutylene terephthalate (PBT) and polycarbonate blends, for electrical and electronic device enclosures. This application requires stable integration to meet electrical tracking resistance and flame retardancy needed for global appliance and consumer electronics safety certification.

    Industry compliance standards

    • UL 746C (Polymeric materials—use in electrical equipment)
    • IEC 60335-1 (Safety of household and similar electrical appliances)
    • EN 60950-1 (Safety of information technology equipment)
    • RoHS compliance (2011/65/EU)

    Typical usage ratio

    • 1.5% to 6% by compound weight, determined by the minimum ignition time requirement and balance with mechanical impact retention in the final article.

    Downstream process integration

    • Incorporated into engineering polymer blends during high-shear melt blending prior to injection molding or extrusion, ensuring homogeneous distribution and controlled particle dispersion.

    Final product types

    • Household appliance bodies and panels
    • Computer and consumer electronics casings
    • Switchgear housings
    • Automotive relay and control modules
    Free Quote

    Competitive 4,4'-Bis(Bromomethyl)-Diphenyl Ether prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    4,4'-Bis(Bromomethyl)-Diphenyl Ether: A View from Our Plant Floor

    Looking at the Product Behind the Label

    At our facility, 4,4'-Bis(Bromomethyl)-Diphenyl Ether often goes by its in-house shorthand “BDE-2BrM”. Every time we walk past the gleaming tanks and the careful calculations on the boards, we remember how much work goes into bringing out a product with such precision. The model we supply, often associated with CAS number 3296-90-0, starts off as clear, off-white crystals that catch the light under the warehouse lamps. Teachers in chemistry schools sometimes call it a specialty aromatic bromide, but on our floor it's a building block for real-world stability, performance, and reliable fire resistance.

    Understanding the Chemistry That Matters

    Working with BDE-2BrM demands a steady hand and accurate ratios. Its chemical structure — two benzene rings bridged by an ether linkage, each ring bearing one bromomethyl group in the para position — gives it a predictable and effective chemical behavior. Compared to unhalogenated ethers, this difference drives flame retardancy and opens up downstream transformations. We've learned through the years that the purity of our batches routinely tests above 98.5%. That margin makes a difference for customers who base their own quality on ours.

    The product’s molecular weight rests around 345.98 g/mol, and it’s engineered to lie within a melting point range of 81 to 85°C. These numbers can look arbitrary on paper, but in the field, slight deviations risk runaway reactions, clumping, or dusting that create headaches in the next stage. Some products in this class arrive in various forms—fine powder or crystalline solid. By focusing on consistency, we target handling properties that reduce operator exposure and improve dosing accuracy during processing.

    Practical Applications: What Customers Actually Do with BDE-2BrM

    Fire retardant manufacturing tops the list, especially in high-performance epoxy and polyester resins. BDE-2BrM’s symmetrical structure and high bromine content, approaching 46% by mass, let polymer chemists reach flame test thresholds without constantly tweaking formulations. Our partners in the wire and cable compounding sector use it in masterbatches to meet LOI (Limiting Oxygen Index) requirements. In circuit boards, it helps resins pass UL-94 V-0 without toxic side reactions. Across the shop, production records trace demand spikes to new building codes or stricter regulations in electronics.

    Our plant team also finds strong demand from manufacturers of specialty coatings. Customers come to us looking to create a stable interface between halogen moieties and polymer chains, especially where flexibility and clarity matter as much as retardancy. Some projects even ask for custom micron sizing to improve dispersal in unusually viscous systems. We’ve worked side-by-side with technical teams to dial in these features, tweaking process parameters and batch cooling rates for a final product that fits their lines.

    In pharmaceutical research, intermediates based on BDE-2BrM enable access to complex scaffolds for molecular design. Researchers appreciate the dual bromide reactivity—both sites can be selectively functionalized, letting them explore molecular libraries with fewer synthesis steps. Academic groups sometimes use the compound as an example when teaching students about selective halogenation and ether chemistry; though for us, it's less about textbook theory and more about clean conversions at every stage.

    Real Differences from Similar Products

    A few core differences set 4,4'-Bis(Bromomethyl)-Diphenyl Ether apart from the broader field of brominated aromatic ethers. Some competitors base their flame retardants on ortho or meta isomers. Those isomers sometimes cause irregular melting behavior and less predictable solubility in process solvents. In several projects, side-by-side evaluations showed our para-linked product gives cleaner incorporation into resin backbones, translating to fewer mechanical failures when tested by molding or thermal cycling.

    Unlike many older-generation brominated flame retardants, BDE-2BrM doesn’t carry persistent environmental legacy—its reactivity ensures faster transformation and less bioaccumulative risk if handled and processed according to best industry guidelines. Plant operators know this property firsthand; routine workplace monitoring constantly checks for fugitive emissions or spills, and mitigation systems focus on real containment rather than broad, unmeasurable dispersal.

    From a practical side, comparisons often come down to stability on the pallet, grain size, and batch-to-batch purity. We’ve worked with chemists frustrated by unwanted color shifts, tackiness on storage, or “ghosting”—residual odors—traced back to less-regulated product sources. We commit to regular lot validation, and our process repeats the same distillation, drying, and sieving steps for every batch. Our lab logs bear this out: analytical HPLC, GC, and carbon-bromine ratio checks never get skipped.

    The Manufacturing Side: Learning from Each Batch

    From day one, our team worked out methods to scale up BDE-2BrM without losing control over the details. We maintain reaction schedules with strict oversight. Ambient moisture and ambient air oxidation sabotage more than one batch of brominated compounds—this became clear in our early days, causing surface yellowing or drifts in melting range. Tighter control on the drying stage and handling under inert gas fixed most issues; automation in filtration and packaging cut human error.

    We source starting materials—diphenyl ether and bromomethylating agents—from longstanding partners. Our storage rooms track every drum’s batch history to uncover any anomaly. Not every shipment passes; strict impurity profiling lets us send suspect lots back well before they reach our reactors. After years of fine-tuning, reactions now run cleaner, safer, and produce higher overall yields. More experienced operators often guide new staff through this process, flagging subtle changes in color, viscosity, or even the sound of the reaction—signs only someone who’s worked the line for years will catch.

    Why Quality and Traceability Matter

    Our approach relies on transparency at every step. Product identification, impurity tracking, and real-time analytics help meet customer expectations while standing up to market scrutiny. Many export markets put a microscope on halogenated aromatic compounds, both for end-use safety and environmental management. Certificates speak to analysts, but customers who visit our plant look beyond paperwork. Consistent crystallinity, handling safety, and low-dust formulation all come from hands-on adjustments and thousands of hours of collective team experience.

    Traceability forms the backbone of our accountability. Every package leaves our facility with documented lineage, connection to retained reference samples, and analytical results. Over the years, several customers have chased down batch discrepancies—sometimes caused by their own logistics, sometimes from upstream issues. By maintaining open records and supporting verification testing, we build trust beyond contractual terms. Product recalls might grab headlines, but in daily life, prevention through record-keeping and diligence keeps both us and our partners thriving.

    Responding to Industry Challenges and Evolving Demands

    Environmental and safety standards continue tightening. Not long ago, customers prioritized maximum bromine content and rapid throughput. Today’s discussions spend as much time on REACH and RoHS compliance as they do on bromination efficiency. We keep teams updated on any regulatory movement. Every legislative notice finds its way into our production review—halogen emissions, storage requirements, downstream compatibility, all parsed before implementation.

    In our experience, legacy manufacturing methods sometimes overlook worker safety during scale-up. We learned early that even a well-designed process can go sideways if dust control or fume containment falls short. Our plant features negative pressure work zones, closed handling systems, and personal exposure tracking. We draw on third-party toxicology reviews and update PPE protocols every time research uncovers better protective tech. Employee health sits next to throughput on our dashboard. Real injury and absentee incident records show the difference this makes over time.

    Supply chain reliability stands front and center. Disruptions in 2020 and 2021 spotlighted the weak points in global chemical logistics—raw material delays, customs holdups, even climate-driven shipping hiccups. We developed local stockpiling and created backup supply channels for key precursors. As customers now push for just-in-time delivery or need spot consignments, our readiness to adjust sourcing and batch timing helps buffer against the outside world’s unpredictability.

    Supporting Customers Through Practical Collaboration

    Direct conversations with end-users shape our understanding more than any conference or industry report. Frequently, customers outline technical hurdles: improving flowability in extrusion, preventing caking in humid storage, scaling up surface area for solution processing. We’ve set up feedback loops where product engineers and plant chemists share real results. Sometimes, a tweak as simple as modifying cooling rates yields a sharper particle size cut; other times, nuanced additives prevent off-coloration without compromising performance.

    Long-term partnerships come from shared risk and honest assessment. Several clients invite our technicians on-site as new product lines come online. We’ve found that hands-on troubleshooting—rather than canned troubleshooting guides—lets us learn where material flow bottlenecks or residue issues crop up. After major projects, debrief sessions generate new process tweaks for both sides. This cross-learning spurs the refinements that put our product just ahead of the generic market.

    Commitment to Environmental Responsibility

    Today’s chemical plant answers to more than production quotas. Our own investment in waste treatment, solvent recovery, and careful emissions tracking grows every year. We keep records on discharge, containment, and air scrubber integrity—data, not promises, build credibility with both authorities and neighbors. Participating in community forums and opening up for third-party EH&S audits builds transparency. Several times, post-audit findings drove improvements in secondary containment or material transfer practice. These changes carried through to visible product quality and employee morale.

    End-of-life impacts can’t be ignored. We work with downstream recyclers wherever possible, advising on the safe depolymerization of brominated compounds once products reach their useful lifespan. Our research partnerships tackle questions around alternative disposal, such as hydro-debromination or incineration with adequate flue gas treatment, limiting the release of problematic byproducts.

    Looking Forward: How Production Will Evolve

    Market and regulation won’t stand still. The push for even safer, greener fire retardant systems drives our internal R&D pipeline. We run pilot projects on partial debromination, alternative halogen additions, and blend compatibility with eco-labeled base polymers. Every new approach must undergo the same rigor—bench-scale, then batch-scale, then real-world plant testing. This takes patience, investment, and acceptance that not every innovation becomes commercially viable right away.

    Stakeholders—customers, regulators, local communities—all count on the reliability of our word and our product. We meet regularly with industrial consortiums and research collectives to stay ahead of upcoming trends. Some of our team members mentor young chemists through internships, passing on lessons about chemical stewardship alongside technical discipline. This culture—from the shift leader to the R&D bench—drives our plant’s long-term vision.

    Conclusion: A Product Made by Real People, for Real Use

    Every sack of 4,4'-Bis(Bromomethyl)-Diphenyl Ether leaving our docks carries a story of trial, refinement, and teamwork. Our reputation relies on delivering a product that behaves as promised—batch after batch, year after year. By paying attention to the habits, challenges, and priorities of our customers, we earn a place in their formulations and a seat at the table when standards shift. All the theory, documentation, and compliance work matters, but at heart, the difference comes down to the pride and accountability of the people who make the product. We plan to keep building on that foundation as expectations and possibilities keep rising.