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4,4'-Azoxydiphenetole

    • Product Name 4,4'-Azoxydiphenetole
    • Alias Bis(p-methoxyphenyl)azoxybenzene
    • Einecs 212-685-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    444984

    Cas Number 139-88-8
    Molecular Formula C14H12N2O2
    Molecular Weight 240.26 g/mol
    Iupac Name 1,2-diphenoxy-1-(phenyldiazenyl)ethane
    Synonyms 4,4'-Azoxydiphenetole, Bis(4-phenetoxyphenyl)azoxy
    Appearance Yellow crystalline powder
    Melting Point 120-122°C
    Solubility Slightly soluble in water, soluble in organic solvents
    Boiling Point Decomposes before boiling
    Density 1.19 g/cm³
    Smiles CCOC1=CC=C(C=C1)N=N(O)C2=CC=C(OCC)C=C2
    Inchi InChI=1S/C14H14N2O3/c1-3-18-13-7-11-15-16(17)12-8-14(19-4-2)9-13/h7-12,17H,3-4H2,1-2H3

    As an accredited 4,4'-Azoxydiphenetole factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 4,4'-Azoxydiphenetole is supplied in a 100-gram amber glass bottle, sealed and labeled with product name, CAS number, and hazard warnings.
    Shipping 4,4'-Azoxydiphenetole should be shipped in tightly sealed containers, protected from light and moisture. It must comply with relevant chemical transport regulations, including proper labeling and documentation. Store and transport at ambient temperature, away from incompatible substances, and ensure packaging prevents leaks or spills during transit to maintain safety and product integrity.
    Storage 4,4'-Azoxydiphenetole should be stored in a tightly sealed container in a cool, dry, and well-ventilated area, away from sources of heat, ignition, and direct sunlight. It must be kept separate from strong oxidizing agents and acids. Appropriate chemical labeling and spill control measures should be in place, and access should be limited to trained personnel only.
    Application of 4,4'-Azoxydiphenetole

    Applications of 4,4'-Azoxydiphenetole in Industrial Manufacturing

    As the original manufacturer, we supply 4,4'-Azoxydiphenetole to specialized downstream industries that require advanced performance modification and precise process control. Below, we detail the main industrial scenarios where this material delivers proven functional value, with each sector's regulatory standards, technical use parameters, production integration step, and main finished goods explained for professional procurement review.

    1. Polymer Additives for Engineering Plastics

    Industry-leading engineering plastics formulators utilize 4,4'-Azoxydiphenetole as a thermal stabilizer and color retention additive during the compounding of high-performance polymers such as polycarbonate, polyamide, and modified polyesters. Its consistent performance at elevated processing temperatures directly supports production scale-up, especially in electrical, automotive, and appliance resin grades where colorfastness and oxidation stability are critical batch acceptance points.

    Industry compliance standards

    • ISO 9001:2015 Quality Management System
    • RoHS Directive (2011/65/EU) for restricted substances
    • UL 746C Polymer Materials—Use in Electrical Equipment
    • GB/T 24001 Environmental Management (China)

    Typical usage ratio

    • 0.05%–0.25% w/w, adjusted based on polymer base type, intrinsic resin color, and anticipated service temperature

    Downstream process integration

    • Direct addition during the melt compounding phase, before extrusion or injection molding; typically metered with other stabilizers in the premix silo

    Final product types

    • Electrical insulation parts (busbar supports, switch housings)
    • Automotive under-hood thermoplastics
    • Home appliance exterior components
    • Precision mechanical parts for industrial assemblies

    2. Photosensitive Materials for Diazo-Based Imaging

    Specialty imaging materials producers incorporate 4,4'-Azoxydiphenetole as a functional sensitizer in the synthesis of diazo compounds for use in blueprint papers, offset printing plates, and photoresist layers. Its well-documented optical properties and stability under UV exposure allow controlled increase of print definition and shelf-life extension of light-sensitive coatings, supporting batch reproducibility in high-throughput coating lines.

    Industry compliance standards

    • ISO 12647-2 Offset Printing Process Control
    • EN 71-3 Safety of Toys—Migration of Certain Elements
    • REACH (EC 1907/2006) Registration, Evaluation, Authorization and Restriction of Chemicals
    • IEC 61249-2-21 for photopolymers in PCB manufacture

    Typical usage ratio

    • 0.02%–0.1% relative to total photoactive component, precisely tuned according to required photo-response and film thickness

    Downstream process integration

    • Dissolved into the sensitizer pre-blend before casting or coating onto substrate film; incorporated under yellow-light protocol to avoid premature activation

    Final product types

    • Blueprint (diazotype) reprographic paper rolls
    • Photolithographic printing plates
    • PCB dry film photoresists
    • UV-cured microelectronic film layers

    3. Polymerization Inhibitor in High-Purity Monomer Synthesis

    For advanced monomer producers, 4,4'-Azoxydiphenetole offers critical inhibition of uncontrolled free-radical polymerization during the distillation and storage of reactive monomers such as styrene, methyl methacrylate, and acrylonitrile. Its selectivity allows clean separation process operation, reducing haze, color body formation, and yield losses, with validated performance in large-scale chemical plants.

    Industry compliance standards

    • GMP guidelines for chemical intermediates
    • Chemical Industry Safety Standard HG/T 20651
    • API Q1 for specialty chemicals in monomer supply chains
    • REACH (EC 1907/2006) Monomer Grade Specifications

    Typical usage ratio

    • 10–50 ppm by weight, adjusted for monomer volatility, storage duration, and required optical purity

    Downstream process integration

    • Continuous injection into monomer storage tanks or distillation columns; removed or decomposed before downstream controlled polymerization

    Final product types

    • High-purity styrene for impact polystyrene production
    • Specialty grade methyl methacrylate
    • Acrylonitrile for advanced copolymers and fibers
    • Refined vinyl-based monomers for reactive adhesives

    4. Antioxidant Systems in Industrial Lubricants

    Manufacturers of specialty industrial lubricants formulate with 4,4'-Azoxydiphenetole as a secondary antioxidant, particularly in applications where thermal resistance and oxidative degradation are leading concerns. It acts as a protocol-stabilizing agent for ester-based and synthetic hydrocarbon oils, supporting extended drain intervals and minimal viscosity change under high-temperature or load-cycled environments.

    Industry compliance standards

    • ASTM D2270 Viscosity Index
    • DIN 51502 Lubricant Classification
    • ISO 21469 Safety of Machinery—Lubricants with Incidental Product Contact
    • Q/SH 0181-2002 for technical lubricants (PetroChina)

    Typical usage ratio

    • 0.015%–0.08% based on finished lubricant base oil volume and target thermal stability specification

    Downstream process integration

    • Blended into base oils prior to addition of primary antioxidants and corrosion inhibitors; tank blending conducted at controlled temperature to ensure full dissolution

    Final product types

    • Heat transfer fluids for plastics processing equipment
    • Hydraulic and turbine synthetic lubricants
    • Compressor oils for petrochemical installations
    • Industrial gear and circulation oils

    5. Stabilizer in Industrial Colorant Dispersions

    Producers of industrial colorant dispersions integrate 4,4'-Azoxydiphenetole to counter photobleaching and pigment degradation, especially in dispersions destined for plastics and synthetic rubbers. It provides reliable shelf-life extension and pigment integrity in colors subject to outdoor exposure, while ensuring no interference with rheology or final film adhesion.

    Industry compliance standards

    • EN 12877-1 Pigments for Plastics—Determination of Colour Strength
    • ISO 18451 Pigments and Extenders—Terminology
    • ASTM D4968 Standard for Colorant Dispersions
    • REACH registered colorant additives

    Typical usage ratio

    • 0.02%–0.18% by total finished dispersion mass; further adapted to pigment chemical class and target UV exposure resistance

    Downstream process integration

    • Added at pigment milling or pre-mix phase, prior to final dispersion letdown; process ensures stabilized colorant microstructure

    Final product types

    • Masterbatch color concentrates for plastics extrusion
    • Rubber compound color dispersions
    • Outdoor-coating pigments
    • Industrial ink color bases for screen and flexo printing
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    Certification & Compliance
    More Introduction

    4,4'-Azoxydiphenetole: Real-World Value from a Manufacturer's Perspective

    The Reality Behind 4,4'-Azoxydiphenetole Production

    Every day inside our facility, teams focus on the synthesis of chemicals that keep industries moving. Among the lineup, 4,4'-Azoxydiphenetole stands out not for its name, but for everything it enables and the assurance it gives to chemists and engineers. People outside the manufacturing process rarely get a real glimpse of the work behind a specialty product like this. Over the years, our familiarity with the details—from raw feedstock to drying and sieving—gives perspective not just on the molecule, but on what matters for those who use it.

    What Makes Our 4,4'-Azoxydiphenetole Unique

    True differentiation in chemicals rarely comes from a patent or clever branding. Instead, it’s the regular, hands-on commitment toward purity, batch consistency, and documentation that makes one supplier’s material clearly better during the grind of day-to-day operations. Our 4,4'-Azoxydiphenetole, sometimes known under CAS 2490-97-3, gets its value from the deliberate control at every stage. The final powder feels and smells familiar only after multiple refinements: it needs to pass not just written specifications but field tests from partners who run actual production plants. Several clients note that off-spec batches from previous vendors left behind residue in reactor lines or filtered poorly, but by working upstream—tweaking reaction conditions, filtration times, and ambient temperature—we’ve kept the product stable, free-flowing, and ready for demanding downstream processes.

    We target a minimum purity of 99%. It’s not a marketing number. An impure batch can cause color changes in a dye, reduce yield in an oxidative coupling, or even trigger unwanted side reactions that force an entire production lot out of compliance. We’re aware of these knock-on effects, not just because someone flagged a complaint, but from walking the plant floors and seeing how a variance halfway around the world can tie up reactors and cause costly downtime. Only a manufacturer who mixes, refines, dries, and inspects every drum by hand can see how attention at each step cuts off countless future problems.

    Key Uses: From Lab Trials to Full-Scale Synthesis

    4,4'-Azoxydiphenetole keeps finding roles in new avenues, but its main use keeps coming up in organic syntheses—typically as a building block for dye intermediates and specialty polymers. Years ago, the focus mainly circled around diazo coupling reactions and as a stabilizer in pigments. Since then, the market has shifted. Research centers working on electronic applications, novel coatings, or photoactive materials ask for material that reacts predictably every time they build a new batch. They want confidence in the way functional groups will behave under scale-up, something only possible when every impurity—down to tenths of a percent—is kept in check.

    The molecule’s structure, defined by two phenetole groups joined via an azoxy link, gives it a unique combination of stability and reactivity. In practice, the difference between a grade intended for academic research and material for production batches in a dye plant goes beyond a certificate of analysis. We see it: Labs usually need 100 grams, enough to refine a synthetic route or characterize by NMR. Factories need 25 or 50 kilogram drums, every drum matching the last because their machines don’t pause for spot-checking. Selling to both types of customers over time, we know where tolerances matter—and how the demands for repeatability have ratcheted upward over the last decade.

    Comparison With Other Azoxy Compounds

    One of the more common questions we field is: What sets 4,4'-Azoxydiphenetole apart from similar-sounding azoxy compounds—and does it justify choosing this grade? The confusion often starts with the range of azoxy-based intermediates, such as 4,4'-azoxyanisole or other substituted benzenes, which at a glance look interchangeable for developers working with early-stage concepts. After years working alongside purchasing teams under pressure to hit cost targets, we warn against quick swaps. The smallest structural changes—from a methyl ether to an ethoxy, or a shift in ring substitution—alter the compound’s physical handling, melting point, and even the way it dissolves in typical solvents.

    We’ve received stories from firms who tried saving a few cents per kilo by rotating in a generic azoxy variant, only to find contamination in downstream photoinitiator batches or crystal precipitates that gummed up filtration media in polymer runs. Subtle differences in the electron-withdrawing ability of phenetole groups, or even changes in the way the compound lays down in a solid matrix, downstream, have shut down production lines more than once. It isn’t always visible until a scale-up gets underway and a batch behaves unexpectedly under stress. It's a lesson we carry with us: substitution isn’t always substitution, and the practical chemistry keeps winning out over abstract equivalence tables.

    Stability, Safety, and Real-World Experience

    Stability isn’t a small matter for our partners. 4,4'-Azoxydiphenetole, while more robust than some of the highly energetic azoxy derivatives, still requires careful storage away from strong acids and bases. We store and ship under climate control, not because regulations demand it, but because a few degrees fluctuation can start slow decomposition that won’t show up until a customer’s own QC team runs HPLC a month or two later. These lessons didn’t come free; they cost product returns, urgent troubleshooting calls, and the kind of reputation hits manufacturers do not forget.

    Our team learned the importance of solid documentation. Each new drum leaves with traceability back to raw input lots. Every technician signs off after visual and instrumental inspection. By catching early warning signs—clumping, color shifts, water absorption at the packing line—we reduce the risk for those depending on repeatable supply. We only arrived at this process after years of real-world feedback and continuous improvement.

    Why Specifications Matter to Users

    The specification sheet for 4,4'-Azoxydiphenetole lists moisture content, melting range, bulk density, and impurity controls. While these numbers give a baseline, feedback from production floors tells us which ones matter most. High purity doesn’t just show up in the assay number; it shows up when material arrives and feeds into a hopper, blending smooth and without bridging. The absence of off-odors prevents fouling of more sensitive downstream processes. Even color, measured by visual comparison and UV/vis, can serve as an alert for unseen side reactions.

    Years of producing specialty chemicals reinforce the point—reliability grows from understanding what the user cares about. One customer making electronic-grade dyes noted that switching away from off-spec azoxy compounds eliminated their cleaning downtime by almost 30%. That’s not an abstract benefit; that’s hours reclaimed every month, real cost avoided, and a team freed from chasing sporadic contamination.

    Challenges in Scale-Up and How We Solve Them

    Scale-up never moves in a straight line. Lab success does not always predict plant-level performance. From the start, our team spent as much time in pilot trials as doing actual production. Early batches of 4,4'-Azoxydiphenetole showed us that small changes—a longer reflux step, slower crystallization, more precise washing—pulled significant impurities out of the product. Solvent recovery cycles, sometimes overlooked, became critical, both for compliance and for preventing trace organics from ending up in the finished powder.

    No one sees these intricacies just by browsing a product catalog. Someone once tried using a higher temperature to speed up synthesis, but it triggered unwanted side reactions, so the whole batch went to waste. Repeated hands-on corrections, built around data from both lab and plant, helped us tune the process: less solvent waste, shorter cycle times, and tighter control over endpoint purity. None of this comes from abstract models; it comes from repeated experience, deep dives into batch records, and lessons learned from both smooth deliveries and the occasional missed deadline.

    Why 4,4'-Azoxydiphenetole Isn’t a Commodity

    The real value in this compound doesn’t just show up on a price list. It emerges during a qualification run, when a procurement manager needs to know that each drum will deliver identical performance to the next one. This isn’t acetone or ammonium chloride. The unique requirements for organic synthesis, color purity in pigment production, or performance in electronics drive demand for a material with tailored physical and chemical properties. Any drift away from specified characteristics ripples through the whole supply chain, from research to the final customer.

    Suppliers who treat 4,4'-Azoxydiphenetole as an off-the-shelf commodity face higher reject rates, more complaints, and loss of customer trust. We’ve watched plenty of intermediaries and bulk traders enter and leave this market, often caught off-guard by the nuanced needs of production chemists and engineers. Those who remain in the business over time do so because every answered technical query, every material safety sheet, and every intervention in a logistics emergency reflect their long-term experience with the material. Having access to scalable, batch-specific expertise means more than access to a warehouse—it means avoiding production crises entirely.

    Supporting Partners Through Transparency

    We work with partners ranging from start-up chemistry labs to multinational chemical processors. Many come to us after experiencing inconsistent results from unnamed or minimally documented sources. Their teams demand a level of transparency and responsiveness not only on core data—such as batch impurity profiles, solvent residuals after drying—but also when it comes to handling unexpected application-specific challenges. Recently, a customer working on OLED materials needed to confirm that no halogens contaminated the final product, as these could wreck their device yields. By opening up our batch logs and facilitating direct communication with our plant supervisors, we answered concerns quickly, without drawn-out back-and-forth or finger-pointing.

    Communication flows better with openness and respect for the end user’s needs. We’ve learned to send more than just paper; we share actual data, trends, and lessons from previous runs. For customers scaling to production, our team reviews historical parameters—temperature, feed rates, drying times—alongside them, uncovering small but crucial variables that affect application outcomes. No abstract datasheet tells the full story. Years of supporting clients through regulatory submissions, solving problems on tight turnarounds, and backing up orders with technical documentation have set a higher bar for trust in this sector.

    Looking Forward: Where 4,4'-Azoxydiphenetole Goes Next

    Markets for specialty organics keep shifting. Five years ago, demand drove mostly from traditional pigment and dye synthesis. More recently, research and development in semiconductors, organic photovoltaics, and smart coatings have accelerated inquiries. High-purity 4,4'-Azoxydiphenetole no longer just feeds into vats of dye; it plays roles in mechanisms where molecular-level inconsistencies can make or break a batch.

    Environmental standards have gotten stricter every year we’ve been in business. Customers expect fewer residual solvents, higher consistency, and better compliance documentation. As a manufacturer, we respond not with platitudes, but by upgrading filtration, investing in automated monitoring at multiple points in the plant, and continuing dialogue with users. Moving to more sustainable solvents, recycling batches with minor off-spec drift, and tracing every raw material back to its source have become the norm. These steps require resources, but the difference shows up in the confidence clients display when committing to long-term supply agreements.

    Risk Reduction and the Value of Experience

    Every chemical plant faces risk: supply interruptions, regulatory revision, process upsets, or surge pricing on raw materials. What reduces risk isn’t just a wide vendor base—it’s trust that a manufacturer knows the material and can work through urgent needs without compromising on safety or quality. Over years, our adaptability stems from direct experience handling batch-scale hiccups, swapping out obsolete equipment, and guiding clients through reformulation requests. In practice, clients who stick with direct manufacturers over unverified traders see fewer lost batches and spend less time firefighting downstream errors.

    Reducing risk goes further than guaranteeing specs. Manufacturers end up seeing trends before they get publicized. Sudden changes in regulatory regimes or shifts in global logistics show up first in chemical supply. With 4,4'-Azoxydiphenetole, our experience means we can alert clients about shelf-life limitations, evolving best practices in handling, or the impact of new purity standards. It makes a difference between a scramble at the last minute and a smooth, planned transition to new requirements.

    Commitment Beyond the Drum

    A long-term manufacturing relationship does not rest on punctual shipment alone. Our team believes every shipment of 4,4'-Azoxydiphenetole carries with it the sum of our diligence—choice of raw feedstock, careful control of process parameters, honest reporting, and willingness to answer for every lot shipped. We share process updates, track global trends in both supply and regulation, and continuously tune our quality assurance checks to meet or exceed industry expectations.

    Customers working with our 4,4'-Azoxydiphenetole benefit from more than a product; they gain a partner attuned to the unpredictable nature of chemistry. Our lines are open both for emergency troubleshooting and for deep technical dialogue. Decades in the business have taught us the value of real-world expertise, rapid responsiveness, and a commitment to transparency that no catalog or trading house can replace. When our clients succeed, they build on every lesson, improvement, and detail we put into our work.