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4,4'-Azoxyanisole

    • Product Name 4,4'-Azoxyanisole
    • Alias 4,4'-Dimethoxyazobenzene
    • Einecs 202-972-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    515057

    Name 4,4'-Azoxyanisole
    Cas Number 104-32-5
    Molecular Formula C14H14N2O3
    Molecular Weight 258.27 g/mol
    Appearance Yellow crystalline solid
    Melting Point 117-118 °C
    Boiling Point 410.5 °C at 760 mmHg
    Density 1.233 g/cm3
    Solubility Slightly soluble in water, soluble in organic solvents
    Iupac Name 1,2-Bis(4-methoxyphenyl)diazene 1-oxide
    Synonyms p,p'-Azoxyanisole; 4,4'-Dimethoxyazoxybenzene
    Pubchem Cid 8120

    As an accredited 4,4'-Azoxyanisole factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 100g amber glass bottle securely sealed, labeled "4,4'-Azoxyanisole," with hazard symbols, batch number, and handling instructions.
    Shipping 4,4'-Azoxyanisole is shipped in tightly sealed containers to prevent moisture and light exposure. It should be packaged in accordance with chemical transport regulations, labeled correctly, and handled with appropriate personal protective equipment. Transport occurs at ambient temperature, avoiding sources of ignition and strong oxidizing agents. Handle with care to prevent spills.
    Storage 4,4'-Azoxyanisole should be stored in a cool, dry, and well-ventilated area, away from direct sunlight, sources of heat, and incompatible substances such as strong oxidizers. Keep the container tightly closed and clearly labeled. Store in a dedicated chemical storage cabinet if possible, and avoid contact with moisture to maintain product stability and prevent degradation.
    Application of 4,4'-Azoxyanisole

    Applications of 4,4'-Azoxyanisole in Industrial Manufacturing

    As an established manufacturer of 4,4'-Azoxyanisole, we support specialized industries where this compound plays a pivotal functional role. Below, we outline key downstream application scenarios, each based on direct industrial usage, compliant with real sector practice, and informed by our ongoing partnerships with end users.

    1. Twisted Nematic (TN) Liquid Crystal Mixtures for Display Manufacturing

    Display manufacturers incorporate 4,4'-Azoxyanisole as a core component in binary and ternary nematic mixtures to engineer low-voltage switching and enhanced optical birefringence in TN liquid crystal displays. Customers rely on it to fine-tune phase transition temperatures and viscosity, optimizing performance for both small and large-format panels. Handling strictly adheres to cleanroom protocols throughout blending and filling, ensuring stable long-term electro-optical characteristics.

    Industry compliance standards

    • RoHS Directive (EU 2015/863)
    • IEC 61249-2-21 for halogen-free materials
    • ISO 9001:2015-certified QC for electronic materials
    • REACH Regulation (EC 1907/2006)

    Typical usage ratio

    • 5%–35% w/w in nematic liquid crystal matrix; exact dosage depends on target phase transition temperature and dielectric properties

    Downstream process integration

    • Dosed during homogenization of liquid crystal mixtures before vacuum degassing and final cell filling

    Final product types

    • TFT-LCD panels for monitors and laptops
    • Segmented liquid crystal displays for industrial meters
    • Medical diagnostic display modules
    • TN-LCD calculators and electronic watches

    2. Research and Reference Standards in Mesogenic Material Development

    Specialty chemical labs and R&D groups use 4,4'-Azoxyanisole as a phase calibration reference and structure-function benchmark when mapping the mesogenic properties of advanced azoxy and biphenyl derivatives. Its phase diagram supports comparative studies and allows precise calibration in development of bespoke liquid crystalline systems for next-generation displays and sensors. All handling stays within documented laboratory GLP frameworks to guarantee reproducibility.

    Industry compliance standards

    • OECD Principles of Good Laboratory Practice (GLP)
    • ISO 17025 accreditation for analytical laboratories
    • International Network of Quality Assurance Agencies in Higher Education (INQAAHE) guidance for research materials

    Typical usage ratio

    • 0.5%–5% w/w relative to total test matrix; depends on intended phase transition reference and study protocol

    Downstream process integration

    • Weighing and solution preparation for binary, ternary, or higher-order mixture analysis; integrated into melt, DSC, or polarized microscopy

    Final product types

    • Research reference materials for liquid crystal phase calibration
    • Benchmark samples for differential scanning calorimetry
    • Analytical standards for phase behavior mapping

    3. High-Performance Optical Filters and Polarizer Films

    Producers of optical filters use 4,4'-Azoxyanisole as a dopant to control molecular ordering and birefringence during the casting of polarizer films. The mesogenic alignment provides stable polarization characteristics and eliminates unwanted light leakage, enabling films to meet demanding defectivity and clarity targets. Process environments utilize laminar flow and in-line optical inspection to secure film uniformity and compliance with optoelectronic requirements.

    Industry compliance standards

    • ISO 8980 for ophthalmic optics
    • IEC 61340-5-1 for electrostatic control in film manufacture
    • ISO 13485 for quality management of optical devices
    • REACH SVHC declaration

    Typical usage ratio

    • 2%–10% w/w in polarizer or optical polymer resin; precise ratio optimized for specific spectral filtering targets

    Downstream process integration

    • Added during resin Sol-Gel preparation before film casting or spin-coating, with in-line solvent evaporation and orientation procedures

    Final product types

    • Visible light polarizer films for camera sensors
    • Optical contrast filters in instrument lenses
    • Energy-efficient window coatings
    • Specialty display enhancement films

    4. Specialty Ink Formulation for Thermal Transfer and Security Printing

    Ink manufacturers integrate 4,4'-Azoxyanisole into specialty thermal transfer ribbon and security ink systems to stabilize molecular orientation and improve resistivity under elevated temperatures. The compound increases definition and thermochromic control in labels, providing sharper contrast and higher resistance to image smudging. Manufacturing pursues strict solvent recovery and traceability for regulated markets.

    Industry compliance standards

    • ISO 2846-1 for ink color measurement
    • EN 71-3 Toy Safety, heavy metal release (where toy labeling used)
    • Good Manufacturing Practice (EU 2023/2006) for direct food contact printing
    • ISO 14001 environmental management

    Typical usage ratio

    • 0.5%–3% w/w in masterbatch, modulated by ink resin and target substrate

    Downstream process integration

    • Added during pigment dispersion, before solvent blending and final inklet filtration

    Final product types

    • Thermal transfer printer ribbons for barcode labels
    • Security inks for anti-counterfeit tags
    • Specialty thermal labels for logistics tracking
    • Ticketing and ID card print films

    5. Advanced Polymer Additive in High-Functionality Polyelectrolyte Films

    Producers of functionalized polyelectrolyte films apply 4,4'-Azoxyanisole as a molecular orientation additive to enhance anisotropic characteristics, fine-tune dielectric constant, and provide liquid crystal behavior in thin film architectures. The additive phase is introduced under controlled thermal blending, supporting development of sensors and flexible electronic substrates where alignment and stability are critical.

    Industry compliance standards

    • ISO 10993 for biocompatibility (if used in biomedical films)
    • ISO 14644-1 for cleanroom manufacturing
    • IEC 60216 for thermal endurance of polymers
    • RoHS Directive (EU 2015/863)

    Typical usage ratio

    • 1%–8% w/w in polyelectrolyte film matrix; ratio adjusted for intended dielectric and mechanical targets

    Downstream process integration

    • Introduced during polymer mixing or solution casting, then oriented under flow or electric field before thermal curing

    Final product types

    • Flexible printed circuit substrates
    • Smart sensor membranes
    • Electro-optical device base films
    • Flexible capacitor layers
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    Certification & Compliance
    More Introduction

    Understanding 4,4'-Azoxyanisole: Meeting Modern Material Demands

    Steady Performance Starts with Reliable Chemistry

    Manufacturing advanced intermediates often means working with compounds whose consistency matters as much as their reactivity. 4,4'-Azoxyanisole, sometimes called p-methoxyazoxybenzene, plays a pivotal role for users in electronics and specialty materials who require reliable mesogenic behavior. By producing this compound ourselves, we see firsthand what sets it apart from lower-quality offerings or generic intermediates sourced with minimal oversight.

    Our model of 4,4'-Azoxyanisole delivers a purity that matches the rigorous quality controls necessary for development of liquid crystal materials and specialized organic syntheses. Each step of the synthesis, right through to packaging, receives attention to trace contaminants and polymorph content. Standard lots come as fine, pale-yellow crystalline powders, free from off-odors or trace amine residues that can wreck phase behavior in finished applications.

    From Bench to Batch: How We Make a Difference

    Production of azoxy derivatives often hinges on the control of oxidation, solvent selection, and repeated purification—not just crude product isolation. Our teams manage these steps at scale, using monitored temperature, fresh reagents, and carefully regulated reaction atmospheres to keep isomeric impurities and by-products to a minimum. Where many traders simply repackage and sell commodity grades, our direct manufacturing ensures a consistent melting point, high assay values, and low ash content. This hands-on approach sharpens control over performance variables that matter in academic, formulation, and industrial environments.

    As a compound, 4,4'-Azoxyanisole stands apart from its analogs because of its robust stability at ambient conditions and the narrow physical property range across batches. Among related materials, such as 4,4'-dimethoxyazoxybenzene or 4-nitroazoxy compounds, it strikes a balance between ease of handling and phase transition reliability. This attribute keeps it in active use for advanced liquid crystal studies, where clarity and reproducibility in the nematic or smectic phases are essential for experimental repeatability.

    Supporting Research and Scale-Up

    Years of serving research and high-volume users alike have shown us how challenging it can be when material quality wavers from batch to batch. Specifying capped moisture levels, monitoring trace metal residues, and paying attention to granulation shape mean less variation in performance, both at milligram scale for academia and at kilogram scale for pre-commercial pilots. We produce 4,4'-Azoxyanisole to match set melting point intervals and UV absorption characteristics, based on what commercial and university customers demand.

    Many researchers choose this product because it enables controlled studies of molecular alignment, dielectric behavior, or optical clarity. Consistency in these results depends on the precision of starting materials. Variability in melting point, solubility profile, or yellowing over time detracts from user experience and data credibility. To address these risks, our process includes extended chromatography cleanups, controlled drying cycles, and packaging in light-resistant sealed containers.

    End Uses and Competitive Strengths

    The range of applications for 4,4'-Azoxyanisole extends well beyond fundamental chemistry. A critical segment of our demand comes from display panel developers and research labs looking to explore liquid crystal mixtures. Its well-documented mesogenic properties enable experiments with new display prototypes or proof-of-concept mixtures, tapping into the core research area of next-generation screens and electro-optic switches. Laboratories can measure birefringence, heat capacity, and laser-interference patterns with confidence when using our batches because the product’s molecular order and response to magnetic fields stay tightly within specified parameters.

    Polymers and resins development teams introduce 4,4'-Azoxyanisole to search for alignment or self-assembly in blends, driving advances in sensors and adaptive lenses. The strong azoxy functional group offers both aromatic rigidity and extended conjugation, helping chemists explore specialty pigments, organic field-effect transistors, and heat-responsive films. This versatility distinguishes it from simpler anisoles or mono-substituted analogs, which can lack the same cooperative phase behavior.

    Addressing Differences from Other Sources

    We often receive feedback from new users who, after trying commodity-labeled azoxyanisole, experience inconsistent melting ranges or visible contamination. These issues typically stem from shortcuts in synthesis or poor purification. As direct manufacturers, we focus investments on full-trace batch records, regular validation studies, and active feedback with technical customers. For industries where single-digit impurity levels make a tangible difference in phase transitions or optical activity, this level of stewardship prevents costly surprises on the assembly line or in the lab.

    Some distributors and trading houses blend similar aromatic azoxy compounds, cutting cost but introducing compositional breadth that undermines specialized research. Our strict lot segregation and batch nesting preserve not just identity but also experimental reproducibility for users who rely on year-to-year equivalence in their reference materials. We support reference-grade and production-scale requests, allowing users to specify further purification for NMR, HPLC, or additional analytics if needed.

    Quality Principles Through E-E-A-T

    Drawing on our decades of production, we know that earning trust with customers rests on delivering well-characterized, consistent compounds, not just flashy specifications. Internal and external audits, supplier relationship management, and employee expertise all combine to keep our material at the front line of specialty chemistry demands. We share real-time impurity screening and anonymous customer feedback with technical teams, helping us fine-tune synthesis pathways or upgrade analytical methods. By inviting customer audits on request, we open our process to scrutiny and improvement.

    We avoid imported generic powders that could introduce uncertainty or compromise batch tracking. Instead, sourcing raw materials domestically allows for more rigorous oversight, easy supplier communication, and the ability to hold partners accountable for contamination events. Each drum or package receives a traceable lot code, and customers receive a certificate of analysis with each shipment—not because regulations require it, but because smooth R&D and manufacturing depend on it.

    Continuous Improvement: Learning from Our Users

    Direct engagement with research teams and formulation chemists reveals practical needs that shape our standard offering. Requests for finer granulation, more stable colors, or tighter ranges on UV absorbance push us to refine synthesis or packaging. Technical support from chemists working in customer organizations keeps us honest about which parameters influence actual usability, saving both sides time and effort in troubleshooting. Our partnership with liquid crystal display developers over several product generations demonstrates the value of dialogue and willingness to adapt.

    Requests for larger and more frequent batches, or for tailored melting point windows, challenge us to update reactor setups and purification stages. Some customers prize nonmetallic handling to ensure minimal iron contamination, driving investment in high-end glass-lined vessels. These improvements circle back to improvements in all downstream products, not just the premier lots. Learning by doing—with openness to honest technical criticism—lets us evolve side by side with scientific fields that move rapidly from trial-scale to production.

    Handling and Use Recommendations from Daily Experience

    Regular users know that azoxy materials, despite their aromatic stability, pick up impurities or degrade under poor storage. We ship 4,4'-Azoxyanisole in opaque, sealed drums or bottles to prevent photo-induced rearrangements. Users who portion powders into smaller containers reduce risk of clumping and exposure to atmospheric moisture. Refrigeration after opening is common practice, especially for analytical standards or extended storage. These habits cut down on the need for repeated re-drying and cut losses on long-term shelf life.

    In formulation work, accurate weighing and pre-wetting can prevent static cling and loss of material during transfer. Our powder fineness helps to disperse in solvents for solution chemistry or into melts for polymer blends. Based on process feedback, we recommend using glassware or high-purity polymers for transfer—avoiding steel spatulas that may shed microscopic particles or catalyze unwanted reactions. These operational choices keep lab and pilot run results in sync, whether tuning LC mixtures or developing thin film devices.

    Environmental Considerations and Compliance

    As producers, we shoulder responsibility for not only quality but also environmental health. Our facility maintains closed-loop solvent recovery to reduce emissions, and we treat residual by-products on site to minimize local impact. Waste stream analysis and air monitoring inform our decisions on process tweaks, ensuring regulatory compliance and responsible stewardship of our community resources.

    Managing organic synthesis at scale always brings challenges—solvent selection, VOC emissions, and downstream disposal can become obstacles without active oversight. We constantly review and update production procedures for better containment, solvent substitution, or energy efficiency. Every adoption of cleaner process chemistry ripples out to the larger community as safer handling, cleaner air, and fewer hazardous shipments.

    Downstream users increasingly ask questions about source traceability and waste minimization. We are prepared to provide detailed breakdowns of reagents used, recovery rates, and end-of-life treatment for process by-products. This transparency aligns with the priorities of global partners adjusting to tighter environmental standards, so our customers stay ahead of compliance changes without unexpected liability or retroactive documentation requests.

    Supporting Innovation in a Competitive Market

    Markets for mesogenic compounds and organic intermediates remain fiercely competitive. Being a chemical manufacturer means constant review of process analytics, back-testing of retained samples, and willingness to invest in improved laboratory instrumentation. Our investment in on-site HPLC, NMR, and trace moisture analyzers pays off with shorter lead times and fewer returns, providing confidence that what arrives matches written guarantees.

    Some of our most challenging projects have come from researchers pushing at technical limits: experiments requiring ultratrace impurity binding, or unique polymorphs of 4,4'-Azoxyanisole for single-crystal X-ray analysis. Keeping a line open to these communities lets us offer targeted solutions—special crystallizations, ultradry handling, or new packaging formats that reflect the real needs on the ground.

    Competence is not claimed; it is demonstrated. Decades of experience, close logistic partnerships, and open discussion with application scientists keep our standards moving forward. As new applications for 4,4'-Azoxyanisole develop, ranging from quantum dot experimentation to novel optoelectronic elements, our history and adaptability help customers capture value from their ideas faster and with fewer supply disruptions.

    Looking Ahead: Investing in Next-Generation Quality

    New frontiers in materials science and electronic display technology call for ever greater control over raw material properties. We have learned that consistent phase transition temperatures, reliable optical responses, and reproducible purity benchmarks empower innovators to push boundaries in both academia and industry. Our ongoing upgrades to process automation, real-time analytics, and in-house training reflect a belief that there is always something new to learn—and each incremental improvement pays dividends across all our specialty offerings.

    Quality in 4,4'-Azoxyanisole does not just safeguard today’s experiments; it also supports tomorrow’s breakthroughs. Customers and partners benefit from a transparent, accountable supply chain—one that is tuned to the technical nuances that drive modern science. By placing expertise within the reach of innovators and offering openness about our manufacturing, we cut through the fog of anonymous supply and give experimentalists what they need to excel.