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3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate

    • Product Name 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate
    • Alias TFMA
    • Einecs 809-930-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    746386

    Productname 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate
    Casnumber 873430-67-0
    Molecularformula C14H13F13O3
    Molecularweight 458.23 g/mol
    Appearance Colorless to pale yellow liquid
    Purity ≥98%
    Boilingpoint Estimated 149°C at 760 mmHg
    Density 1.5–1.6 g/cm³ (at 20°C)
    Refractiveindex nD20 ~1.370
    Solubility Insoluble in water; soluble in organic solvents
    Functionalgroups Methacrylate, perfluoroalkyl, hydroxyl
    Storagetemperature 2–8°C
    Flashpoint >100°C

    As an accredited 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 25 grams, sealed with Teflon-lined cap, featuring hazard labels, chemical name, CAS number, and handling instructions.
    Shipping The chemical **3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate** is shipped in tightly sealed, chemical-resistant containers under cool, dry conditions. All packaging complies with relevant hazardous materials regulations and includes clear labeling and safety data sheets to ensure safe transport. Handle with care to prevent leaks or exposure during transit.
    Storage Store **3-(Perfluoro-5-methylhexyl)-2-hydroxypropyl methacrylate** in a cool, dry, and well-ventilated area, away from direct sunlight, heat sources, and incompatible substances such as strong oxidizing agents. Keep the container tightly closed and properly labeled. Protect from moisture and freezing. Use and store only in well-ventilated areas and avoid exposure to excessive temperatures to prevent polymerization or decomposition.
    Application of 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate

    Applications of 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate in Industrial Manufacturing

    3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate delivers performance-enhancing properties to various high-tech manufacturing sectors. The following application scenarios represent core commercial uses based on field adoption and technical feedback from industrial clients.

    1. Fluorinated Polymer Additive for High-Performance Coatings

    In the formulation of specialty coatings for aerospace and electronics, this methacrylate derivative acts as a fluorine-rich monomer, enhancing solvent resistance, anti-stick properties, and weatherability. Production teams dose it directly into acrylic or polyurethane matrix systems to achieve required hydrophobicity and decrease surface energy for demanding substrates. Downstream processors utilize this ingredient during resin pre-mixing, ensuring targeted performance in finished coatings.

    Industry compliance standards

    • ASTM D6886 (VOC content measurement for coatings)
    • REACH (EC) No 1907/2006 for fluorinated chemicals
    • EN 13523-10 (coil coating resistance)
    • ISO 12944 for corrosion protection systems

    Typical usage ratio

    • 2–8 wt% in binder solids, fine-tuned according to substrate type and required repellency levels

    Downstream process integration

    • Introduced during pre-polymerization or post-polymer modification phases in coating reactors
    • Requires precise dosing and thorough blending prior to curing or crosslinking

    Final product types

    • Anti-graffiti architectural coatings
    • Corrosion-resistant aircraft coatings
    • PCB protective varnishes
    • UV-curable industrial floor finishes

    2. Modifier in Advanced Lithographic Photoresist Formulations

    Semiconductor manufacturers employ this specialty monomer to tailor the etch resistance and pattern fidelity of chemically amplified resists. The perfluorinated chain increases plasma durability and reduces line edge roughness during etching. Photoresist chemists incorporate this component within resin blends or copolymer synthesis, optimizing for performance requirements at sub-10 nm nodes in advanced wafer fabrication lines.

    Industry compliance standards

    • IATF 16949 (Quality management for automotive semiconductors)
    • SEMI C23 (Photoresist chemical purity)
    • IEC 60749-10 (test methods for IC manufacturing chemicals)
    • RoHS Directive (restrictions for electronics manufacturing)

    Typical usage ratio

    • 0.5–3 mol% in copolymer backbone or up to 4 wt% in total resist solids, optimized by feature size and developer chemistry

    Downstream process integration

    • Added to resist resin synthesis batch
    • Can be post-functionalized onto pre-polymer prior to solvent blending and spin-coating

    Final product types

    • 193 nm ArF immersion photoresists
    • EUV photoresists for 7nm and below logic ICs
    • Negative-tone patterning polymers
    • Plasma-resistant dielectric resists

    3. Surface Modifier in Membrane Manufacture for Chemical Processing

    Membrane technology producers utilize this raw material as a functional comonomer to increase fouling resistance and chemical durability in microfiltration and ultrafiltration media. The perfluorinated group imparts strong hydrophobicity, reducing organic adsorption and boosting flux stability in aggressive process streams. It enters the casting solution during dope preparation, where membrane engineers set feed ratio based on required separation profile and cleaning protocol.

    Industry compliance standards

    • NSF/ANSI 61 (potable water system components)
    • ISO 9001 (quality management for filtration manufacturing)
    • USP Class VI (if used in biotech filtration)
    • FDA 21 CFR 177.1520 (polymeric surfaces in contact with food, where applicable)

    Typical usage ratio

    • 1–6 wt% of polymer mass in dope formulation, with levels adjusted for pore size and targeted surface chemistry

    Downstream process integration

    • Direct addition to casting solution for phase inversion or TIPS/NIPS methods
    • Crosslinking or post-polymerization as a functional graft may be deployed on finished membranes

    Final product types

    • Hydrophobic MF/UF membranes for industrial water recycling
    • Solvent-resistant gas separation membranes
    • Membranes for oleophobic filtration
    • Specialty anti-fouling filtration units for chemical plants

    4. Monomer for Low Surface Energy Fiber Sizing in Technical Textiles

    Producers of advanced technical fibers use this monomer in custom sizing and finish recipes, aiming to impart water- and oil-repellent properties critical for automotive, filtration, and protective garment applications. The functional group allows direct copolymerization into sizing agents or surface finishes, applied after melt spinning or as a finishing bath. Quality control groups monitor surface energy and runoff performance based on targeted OEM specifications.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (textile safety)
    • ISO 1833 (fiber blend quantification)
    • ISO 14419 (oil repellency testing)
    • EU REACH Annex XVII (fluorinated compound restrictions for textiles)

    Typical usage ratio

    • 1–5 wt% relative to total sizing formulation, modified based on fiber type and repellency requirements

    Downstream process integration

    • Mixed with base emulsion and crosslinker, applied as a dip or spray finish
    • Thermofixation at 110–150°C required for durable coating

    Final product types

    • Automotive seat and air bag fabrics
    • Oil-resistant filtration media
    • Protective workwear textiles
    • Outdoor gear shell fabrics
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    Certification & Compliance
    More Introduction

    3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate: A Chemist’s View

    Fluorinated Innovation in Methacrylates

    Over the past decade, our team has poured significant energy into refining the chemistry behind fluorinated methacrylates. The market often asks for materials that solve not just one, but three or four problems at once: higher weather resistance, easier processing, and lower surface energy. Most conventional methacrylates fall short once you start ramping up demands on repellency or long-term durability. That's where 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate comes in.

    In lab after lab, floor to floor, liquid handling to solid formulations, one thing stays consistent: customers fight to keep their surfaces cleaner, coatings more robust, and polymers less prone to staining or fouling. With this product, we’ve seen formulators and industrial partners pull off surface finishes that surprise even the seasoned specialists. In our own testing, it stands up to harsh acids, oils, and the constant abrasion from repeated use. It isn’t just about survival—this monomer adapts, letting coatings last under actual field conditions.

    Real-World Demands: Beyond Standard Methacrylates

    Ask anyone on our technical team about the biggest frustrations in finishing or coatings work, and you’ll hear about the limitations of standard hydroxypropyl methacrylates. They serve well enough in mundane applications, but they don’t cut it in aerospace, advanced electronics, or medical devices. Our 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate brings a fluoroalkyl side chain with a C7 backbone and methyl branching. Each batch that leaves our plant features this precise architecture—achieved after years spent troubleshooting everything from emulsion instability to side-reaction drift on aging distillation lines.

    It takes an experienced synthesis crew to secure both purity and yield on such a specialized molecule. Through continuous development, we’ve optimized solvent systems, reaction controls, and purification steps to limit oligomer residues and color bodies. The apolar perfluoroalkyl group drastically lowers surface energy, and experienced formulators recognize the difference when it comes to scratch resistance in plastics or reduced smear in touch panel manufacturing.

    Handling and Integration: Not Just Academic Principles

    Every drum that ships out has a traceable history. In our operations, maintaining batch consistency presents a challenge—this monomer is more sensitive than generic acrylates both to oxygen and trace moisture. We never ignore the handling nuances. Our plant operators know that even a minor slip lets peroxide initiators wreak havoc on quality, from color to mechanical strength. Real production environments rarely look like textbook diagrams; our experience tells us that fine-tuning the vacuum phase or checking for minute thermal gradients during scale-up makes all the difference.

    When our R&D and quality control labs test 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate in co-polymerization projects, we see the enhanced water and oil repellency come through on panels, films, and molded shapes. End users often point out the improved anti-fingerprint properties compared to standard hydroxypropyl or methyl methacrylate alternatives. Process engineers mention better flow under UV-cure conditions, as well as lower volatility, which leads to higher monomer-to-polymer conversion rates. Unlike commodity acrylics, this molecule can toughen surfaces without building up unwanted residues or attractants for static charges.

    Specifications That Translate to Actual Value

    We don’t rely on brochure buzzwords to measure the quality of 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate. Instead, we back each lot with actual spec sheets and audited analytic results. The monomer lands in a colorless to pale yellow state, with hydroxy and methacrylate values that fall within demanding tolerance bands. Viscosity measurements hold steady batch after batch—we keep the molecular weight distribution within tight limits by dialing in every reactor run. Our background in process chemistry means that we never take for granted how minor variations in pressure or feed timing might lead to large swings in downstream performance.

    Customers working in UV-curable systems tell us they care about two metrics: cure speed and final properties. We tested composite panels side-by-side, and the perfluorinated monomer displays significantly improved contact angles over standard options. Fingerprint and stain resistance on optical devices also reach new levels, a result we’ve verified through thousands of hours of durability cycling and accelerated weathering. For medical device exteriors or electronics housings, the chemical backbone shrugs off repeated disinfection treatments—this isn’t just an academic distinction. Facility teams tell us about rejected parts from alternative sources, and every time a customer pulls a panel from a harsh chemical bath and sees no sign of attack, months of plant-side development feel worthwhile.

    What Sets It Apart: Molecular Details into Practice

    On paper, thousands of methacrylate derivatives sit within reach. The reason we keep 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate on our campaign schedule year after year comes down to its unique effect on final product properties. The chemistry behind the C7 perfluoroalkyl chain with methyl substitution offers a combination of low surface energy and high mobility within blends. After curing, the fluoro segments migrate towards the air interface—our own surface analysis proves this. The outcome: more robust resistance to fouling, lower dirt pickup, fewer cleaning cycles, and less irreversible surface damage.

    In the polymer markets, the difference between a near-perfect batch and a generic one shows in every test. Polymers incorporating this monomer outperform competitors in applications that demand self-cleaning, anti-graffiti, or easy-release properties. In each case, the improvement doesn’t come at the expense of processability or compatibility. From the installation of new reaction columns to on-floor troubleshooting with our plant operators, we’ve tackled issues like late-stage gelation and phase separation by developing both the process and the product in parallel.

    Environmental resistance marks another area where we see clear differences. Exposure to solvents, oils, acids, or UV light gradually breaks down typical methacrylates. Over years, our monomer has demonstrated long-term resistance—parts resist yellowing, softening, and chemical swelling. This durability finds favor in aircraft interiors, automotive panels, and precision optical coatings.

    Usage in Application: Shared Experience from the Field

    Engineers running high-throughput extrusion or casting lines have reported fewer line stoppages and less downtime related to die fouling or filter plugging. By blending our monomer in at low percentages, they often see greater improvements than by overusing less efficient additives. We’ve spent time on their production floors, walking through issues together. One pattern repeats: replacing other fluorinated or silicone additives with our methacrylate reduces both raw material costs and rejects. Surface treatments that once needed multiple layers now hit the customer’s target in a single pass, especially in display coatings or water-repellent glass.

    Customers working with adhesives highlight improved spread and better wet-out without sacrificing final cured bond strength. In one case, a packaging firm saw package sealing speeds increase after switching to a copolymer using 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate. Printing companies mention sharper image edges after surface pre-coating with the new blend, along with fewer adhesion failures in end-use environments. Our samples always include extensive training and formulation advice, since the technical success of the monomer often comes down to small tweaks in processing parameters or batch-mixing habits on the customer side.

    In electronics and optical applications, customers push the boundaries of what their devices can handle. The monomer associates strongly within the resin matrix, lowering refractive index without sacrificing mechanical strength. In AR/VR optics, cleanability and non-tack surfaces translate directly to user comfort and lower service costs. Our own testing regime includes tens of thousands of wiping cycles and repeated contact with skin oils, soda, alcohol, and rapid humidity swings—results consistently produce lower haze and clearer panels versus standard alternatives.

    Regulatory Trust through Hands-On Verification

    As manufacturers, we know the importance of regulatory compliance and safety. All production lots of 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate undergo thorough screening for specified impurities, and we test for residual solvents and heavy metals. Our internal Environmental Health and Safety teams constantly review the latest chemical regulations in key jurisdictions. We never ship products without confirming conformance to customer and regulatory requirements. This diligence helps our industrial partners keep their own compliance records clean and ensures that downstream audits never produce surprises.

    Over the years, we have worked alongside regulatory experts and customers to adapt our process controls and documentation. Auditors have full access to manufacturing histories and analytical data. We keep a transparent chain through every stage. Our familiarity with fluorinated chemistries means we anticipate evolving rules and put control measures in place before they become legal minimums. By focusing on traceability and information sharing, our customers gain confidence that the products they formulate from our monomer meet both performance and compliance expectations.

    Differences that Go Beyond Formulation

    It would be simple to say this specialty monomer stands out just because of its perfluoro chain, but our deeper experience gives a more nuanced answer. Many so-called “fluorinated” methacrylates land on the market featuring less fluorination or poorly distributed functional groups. Some bring in higher chain mobility at the cost of thermal resistance, while others lack adequate hydroxy functionality and compromise on crosslinking density. In contrast, 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate balances chain length, methyl branching, and hydroxy propyl positioning to allow vigorous polymerization, robust network build-up, and effective interfacial migration. Field failures due to delamination, chalking, or loss of repellency show up less often—our customers report measurable improvements year after year.

    Years of process experience have taught us how subtle differences in input quality or plant operating conditions affect the outcome. Our lots are engineered for tight reactivity and conversion window controls. Additive manufacturers and resin producers regularly highlight our material in their performance reports, calling attention to its role in reducing maintenance costs, improving product pride, and helping end users achieve more sustainable performance. Replacing multiple additive packages with a single, well-designed monomer brings savings not just in procurement, but in waste management, rejected lots, and returns.

    Problems We’ve Solved, Lessons Learned

    The manufacturing world doesn’t give free passes. We gained our reputation not just from lab work, but from what happens when things go wrong. Past efforts to mimic the performance of our perfluorinated methacrylate with conventional chemistries resulted in coatings that either underperformed or broke down under field abuse. Early versions of this monomer suffered from shelf aging—a lesson that led us to redesign packaging and storage protocols, complete with built-in headspace protections and temperature-controlled distribution. At one point, we tackled complaints about inconsistent viscosity from a large coating manufacturer. Tweaks in reactor feed rates and improved water removal fixed the issue across all product lines.

    We’ve seen challenges with incorporation rates in high-solid systems. In response, our development team worked closely with both end-users and pigment suppliers. A new line of pre-dispersed pigments partnered well with our monomer, eliminating separation and speckling at the point of use. Such fixes rarely happen without ongoing partnership—every lesson in quality goes back into improving process reliability. No technology stands still, and the history of this product is shaped by hard-won experience.

    Looking Forward: New Applications, Stronger Partnerships

    Our experience has shown again and again that pushing the chemistry further opens up entirely new markets. As industries demand cleaner, longer-lasting, and ever more functional surfaces, 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate forms the nucleus of next-generation product development. We collaborate with partners across fields: automotive, aerospace, consumer electronics, and biomedical devices. Each project brings unique requirements, and understanding the limits of the chemistry opens opportunities for tailored solutions.

    Research partners have started exploring the use of our monomer in energy sector components, where weathering and oil fouling present constant challenges. Universities targeting bioinspired coatings now use the molecule to mimic lotus effects in polymeric films. In 3D printing, its low surface energy allows for easier part release and higher print definition. We join our customers in thorough application trials and follow-up evaluations, sharing knowledge and aligning product enhancements with end-use needs.

    In conclusion, our story with 3-(Perfluoro-5-Methylhexyl)-2-Hydroxypropyl Methacrylate isn’t just about an advanced molecule, but about the decades of constant learning and responsive engineering behind every drum we manufacture. We invite new partners to challenge its limits and to work together on the next era of surface and material innovation—anchored in the shared experience of hands-on manufacturing expertise.