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HS Code |
118109 |
| Chemical Name | 3-Chlorodiphenylamine |
| Synonyms | m-Chlorodiphenylamine |
| Molecular Formula | C12H10ClN |
| Cas Number | 91-67-8 |
| Appearance | Light yellow to brown solid |
| Melting Point | 56-58°C |
| Boiling Point | 350°C (estimated) |
| Solubility | Slightly soluble in water |
| Density | 1.21 g/cm³ |
| Pka | 4.90 (estimated, for NH group) |
| Structure | Chlorine atom at meta position on diphenylamine |
As an accredited 3-Chlorodiphenylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | The packaging for 3-Chlorodiphenylamine (100g) is a sealed amber glass bottle with a hazard label and tamper-evident cap. |
| Shipping | 3-Chlorodiphenylamine is shipped in tightly sealed containers, protected from moisture and light, and typically packed in accordance with hazardous material regulations. Proper labeling, documentation, and handling precautions are observed to ensure safety during transportation. The shipment complies with local and international chemical transport guidelines to prevent leaks or environmental contamination. |
| Storage | Store 3-Chlorodiphenylamine in a tightly closed container, in a cool, dry, well-ventilated area, away from incompatible substances such as strong oxidizers. Protect from direct sunlight and moisture. The storage area should be equipped with appropriate spill containment measures and clearly labeled. Access should be limited to trained personnel, and appropriate safety equipment should be available in case of accidental release. |
Applications of 3-Chlorodiphenylamine in Industrial Manufacturing3-Chlorodiphenylamine serves as a specialized intermediate in targeted industrial sectors, particularly where aromatic amine derivatives support performance and stability in demanding chemical systems. We supply consistent, industrial-volume grades to global downstream manufacturers, supporting efficient large-scale processes under international compliance frameworks. The following scenarios highlight its established downstream use cases, specifying regulatory status, formulation guidance, process involvement, and finished product types. 1. Rubber Antioxidants for Tire & Technical Rubber GoodsDownstream manufacturers use 3-Chlorodiphenylamine as a core precursor for synthesis of key antioxidants (including substituted diphenylamine types) that stabilize elastomers against oxidative degradation. These antioxidants protect butadiene- and isoprene-based rubbers during mixing, vulcanization, and long-term use, addressing heat, oxygen, and ozone stressors encountered in tire and industrial rubber applications. Sourcing from us ensures traceability to compliance and performance specifications demanded by global automotive and industrial supply chains. Industry compliance standards
Typical usage ratio
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2. Lubricant Additive Manufacturing (Aminic Antioxidants)Leading lubricant formulators rely on 3-Chlorodiphenylamine as a building block for aminic antioxidant additives, which deliver oxidative protection in high-temperature lubricating oils. These advanced additives preserve base oil properties for extended drain intervals and heavy equipment operation, particularly under severe heating and mechanical stress, thus meeting stringent lubricant lifetime and cleanliness specifications. Our controlled supply chain and analytical support enable trusted performance in global additive markets. Industry compliance standards
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3. Synthesis of Fine Chemicals for Agrochemical FormulationsIn select agrochemical manufacturing routes, 3-Chlorodiphenylamine functions as a versatile aromatic amine intermediate for the preparation of custom molecules with pesticidal or herbicidal activity. Its structural features provide handles for further substitution and ring modification, supporting synthesis of various diphenylamine-derived actives. Our plant documentation provides full support for traceability and compliance throughout regulated agrochemical supply chains. Industry compliance standards
Typical usage ratio
Downstream process integration
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4. Dye and Pigment Intermediate ProductionSpecialty dye manufacturers select 3-Chlorodiphenylamine for its role as a coupling component in synthesizing certain azo and anthraquinone dyes, as well as specialty pigments for coatings and plastics. The molecular structure provides color fastness and stability enhancements in finished colorants. We maintain tight control on batch homogeneity and impurity profiles to support coloration performance requirements in regulated industries, including textile coloration and industrial coatings. Industry compliance standards
Typical usage ratio
Downstream process integration
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A lot of talk about fine chemicals focuses on price and competition, but a material like 3-Chlorodiphenylamine calls for precise technical focus. In our own factory, the process starts with carefully sourced aniline and chlorinated intermediates. Over decades, we’ve tested various routes to maintain high purity and consistent molecular structure. Our main offering under model number 3CDPA-99 follows a synthesis route developed by our in-house chemists using direct chlorination and controlled amination. This delivers a product with over 99% assay by GC, bright white powder form, and very low moisture content unmatched by off-the-shelf or blended batches.
Users often overlook the microstructure of such a compound. We dedicate significant time to in-process quality control, not only to meet customer expectations but to reduce the likelihood of side reactions when used downstream. Contaminant levels, particularly trace nitro groups and unreacted starting material, are held below strict parts-per-million marks. This keeps interference in sensitive manufacturing processes—common in pharmaceutical and agrochemical synthesis—to an absolute minimum.
Manufacturing scale gives a unique perspective. Across thousands of batches, we’ve seen that the consistent allure for 3-Chlorodiphenylamine comes from its versatility as a building block in dye, rubber antioxidant, and pharmaceutical intermediate lines. The N-phenylamine backbone stands up well in reduction reactions or coupling steps for more elaborate molecules. In the world of antioxidants for rubber, it brings stability under oxidative stress, directly extending product shelf life. Our technical team often works with end users to dial in the ideal moisture and particle size so blends with rubber compounds are predictable and reproducible.
Customers often come to us requesting minor adjustments in mesh size or trace ion controls—requests unheard of at distributors or resellers. Our protocol allows us to accommodate custom grades, but the core product forms the backbone for most applications, whether it’s downstream bromination, sulfonation, or a direct coupling reaction for dye synthesis. In these real-world settings, off-grade intermediates from generic suppliers have a higher risk of causing batch failure, a costly event most process chemists aim to avoid at all costs.
We hear people ask whether other diphenylamines or even para-substituted analogues work just as well. Take our experience—factories that switch from 3-chloro to 4-chloro or plain diphenylamine often report incomplete reactions or issues with reaction color. The 3-position chlorine imparts specific electronic effects, making certain couplings faster or more selective. In antioxidants, this minor structural change affects long-term heat stability in compounded materials. Over the years, clients running batch reactors have detailed smoother integration when using our 3-chloro grade versus blends or less precisely synthesized analogues.
Pure diphenylamine differs significantly: it lacks the electron-withdrawing effect of chlorine, shifting reactivity and solubility. Testing in our QA labs repeatedly shows that such variations lead to byproduct formation, more challenging downstream purification, and inconsistent yields. We control each manufacturing step—chlorination temperature, reaction time, catalyst type—to ensure reproducibility across every batch. It’s a level of technical vigilance that seldom comes from blending houses or indirect supply.
As a manufacturer, we understand not just purity but how the compound behaves under different regulatory frameworks. Synthetic intermediates that flow into pharmaceuticals face increasing scrutiny regarding residual organics, trace heavy metals, and controlled substance compliance. Our manufacturing line uses closed reactors and HEPA-filtered packaging areas to prevent cross-contamination, which is part of routine quality and traceability audits. Clients from regulated industries—medicine, crop protection—come to us year after year because these standards match or exceed audit expectations: they can pull up batch records and even trace minor parameter changes back to operator shifts.
Industrial users face another challenge: scaling up. Lab-scale samples from brokers rarely match full-production batches in particle distribution or flowability. We’ve fine-tuned drying procedures, sieving, and anti-caking measures to offer a real-world product that actually moves through augers and feeders, not just in the lab but in 10-ton lots. Plant operators dealing with downstream mixing or solvent dissolution frequently find that our bulk lots dissolve with fewer clumps or residue issues. That reliability comes from direct process control and regular equipment maintenance on our shop floor—not from trading paperwork or switching bag suppliers.
Few upstream chemical suppliers are open about their process improvements, but our experience says sharing such details benefits both us and the customers. For example, we once engaged with a major pigment manufacturer who found that the iron level in their existing supply kept causing particle discoloration after heating. Drawing from our in-plant analytical data, we adjusted the chromium-free catalyst blend to lower transition metal residues without raising costs or introducing halide byproducts. Over the next year, their defect rate dropped by half, saving time and money throughout their colorant production chain.
Stories like these repeat across sectors. Agrochemical companies that synthesize specialty herbicides and fungicides look for consistently low halogen content. By working directly with us, rather than a transactional supplier, they tap into cumulative experience from decades in continuous distillation and multi-step batch reaction monitoring. Instead of guessing or settling for typical grades, they communicate their real tolerance thresholds, and we tailor the process just enough to match. Plant managers appreciate the transparency, and formulation chemists get to focus on their own product development instead of troubleshooting raw material variability.
Production doesn’t end after final filtration. One overlooked area is product handling safety, especially as 3-Chlorodiphenylamine carries moderate toxicity typical of aromatic amine derivatives. In the factory, our team receives targeted training not only on dust control and PPE but also in spill recovery protocols. Such practical knowledge gets passed to downstream clients—how to set up their own localized extraction, optimize storage, and prevent cross-contact with incompatible materials. Our packaging facility uses anti-static liners and reinforced drums to make sure the product isn’t compromised from transport vibration or weather. It’s not uncommon for customer technical teams to consult with our plant managers directly, reviewing handling best practices ahead of a new launch.
Some buyers express concerns about shelf stability and unexpected degradation. Drawing from long-term retention samples, we share real storage data, including temperature cycling and humidity exposure results. This honest feedback means less guesswork and fewer headaches for operations teams. Everyone gains from the direct flow of application guidance based on actual test records, not recycled information or marketing brochures.
Over years of manufacturing, we’ve developed more than one use case where 3-Chlorodiphenylamine shows new potential. Our R&D team regularly tests alternate reaction chemistries—nitration, bromination, oxidative coupling—using our material as a base. This upfront research helps establish not only performance parameters but also any side reactions other sources might introduce. Sometimes a batch will reveal new color profiles in non-traditional dye applications or unexpected reactivity in novel antioxidant formulations. We document these nuances and share them with clients who experiment beyond standard protocols.
Consistent batch records often reveal subtle lessons. For repeat users, minor variances in reaction yield or physical appearance hint at upstream adjustments in process control, solvent grades, or even raw material batches. By keeping a direct dialogue open with every customer—be it a small specialty lab or a multinational manufacturer—we identify issues early. Clients rarely face shipping delays or paperwork mix-ups because our whole supplier network is designed around responsive, hands-on troubleshooting.
Feedback from the field matters as much as lab test results. Operators have pointed out packaging damage, asked about anti-caking agents, and suggested new palletizing methods. We take those conversations seriously, investing in newer drum sealing lines, smaller-lot packing for research customers, and even color-coded labeling for quick product differentiation on the factory floor. No part of our workflow sits above critique—on some occasions, machine technicians found that switching drying belt surface coatings helped reduce residual sticking and boosted batch throughput. Such tweaks might sound minor, but years of these micro-improvements add up to cleaner workflows, sharper quality, and fewer product returns.
Along with these logistics-focused upgrades, we carry out periodic process audits: not just on paper, but with practical walk-throughs and sample pulls. This approach uncovers marginal gains that often escape attention, like improved energy control at the reactor or new ways to recycle mother liquor without cross-contaminating the main lot. These gains aren’t theoretical—they show up as smoother order fulfillment, quicker lot release, and tighter analytical reports.
Every material has a story behind it, and for us, 3-Chlorodiphenylamine reflects decades of shared effort. From the chemistry team optimizing yield and purifying fractions, to the warehouse operators making sure orders ship intact, manufacturing here is a human-driven process. Many of our line workers have handled this molecule for over ten years, watching the evolution of reaction norms, solvent swaps for greener alternatives, and new analytics as regulatory limits change. Every improvement, from better solvent recovery units to in-line process monitoring, grows from practical feedback and day-to-day problem-solving.
On the technical support side, deep knowledge of the compound’s applications complements chemical theory. Our team explains not only the ideal use cases but also how to troubleshoot minor incompatibilities, unwanted reactivity, or downstream coloration. Clients sometimes arrive with unexpected questions—from resin stabilization to rare catalysis. We derive answers from empirical testing, not textbook advice. Such relationships only develop through years of practical problem-solving and trusting exchanges.
Unplanned interruptions, like logistics delays or regulatory reviews, can bring a process line to a halt. By controlling every step—reaction, post-processing, testing, packing—we reduce risks before they escalate. Many downstream failures start with undetected off-specification material; a slight pH drift, excess impurities, or missed drying step causes issues on the customer’s end. Our daily focus on batch-by-batch confirmation means fewer surprises all the way to application.
Process safety remains central, especially with aromatic amine products that require safe handling and careful storage. Manufacturing sites often ask about our emergency containment protocols or environmental release controls. We maintain full documentation and staff training on best practices, including safe neutralization and spill prevention approaches. These precautions are based on real experience—not just regulatory checklists—and help reassure clients about the material’s safe integration into their own sites.
The chemical industry continues to shift as sustainability considerations grow. Aromatic amines introduce challenges for waste management and renewables integration. Our operations invest in upgraded scrubbers, solvent recapture systems, and waste minimization strategies that comply with new local and international requirements. These upgrades stem from in-field audits and not from abstract corporate goals. Our staff works on incremental improvements with each project: less waste to landfill, tighter emissions tracking, more recycling of solvent and water streams.
Customers increasingly request documentation on supply chain ethics, environmental impact, and the openness of safety testing data. We answer with direct, transparent reporting based on real inspections and third-party lab certifications. Such transparency builds trust and supports our commitment to responsible manufacturing. We engage regularly with end users on these evolving concerns, discussing trade-offs and possible shifts to greener process routes when technically feasible.
In an industry crowded with traders and brokers, direct manufacturing means more than price and logistics. It means being accountable for every process step and outcome, from raw material sourcing through to the last drum shipped. Our story with 3-Chlorodiphenylamine demonstrates the value of controlled chemistry, open communication, technical innovation, and real-world responsiveness. When end users source from those who live and breathe the product every day, performance, reliability, and safety move from buzzwords to everyday reality. Such partnerships drive long-term growth for both sides—and those lessons, learned on the factory floor, stay relevant year after year.