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3,6-Dibromo-9-Ethylcarbazole

    • Product Name 3,6-Dibromo-9-Ethylcarbazole
    • Alias 3,6-Dibromo-9-ethyl-9H-carbazole
    • Einecs 626-644-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    289248

    Product Name 3,6-Dibromo-9-Ethylcarbazole
    Cas Number 92661-30-0
    Molecular Formula C14H11Br2N
    Molecular Weight 369.06 g/mol
    Appearance White to off-white powder
    Purity Typically >98%
    Melting Point 150-154°C
    Solubility Soluble in organic solvents like chloroform and dichloromethane
    Smiles CCN1C2=CC(Br)=CC(Br)=C2C3=CC=CC=C31
    Inchi InChI=1S/C14H11Br2N/c1-2-17-12-8-10(15)6-7-11(12)13-4-3-5-9(16)14(13)17/h3-8H,2H2,1H3
    Storage Temperature Store at room temperature

    As an accredited 3,6-Dibromo-9-Ethylcarbazole factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

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    Application of 3,6-Dibromo-9-Ethylcarbazole

    Applications of 3,6-Dibromo-9-Ethylcarbazole in Industrial Manufacturing

    As a dedicated producer of 3,6-Dibromo-9-Ethylcarbazole, we support high-value manufacturing across several advanced material sectors. The following sections detail the primary industrial uses where our product consistently delivers essential functional performance aligned with industry-specific requirements.

    1. Organic Light-Emitting Diode (OLED) Materials

    OLED panel manufacturers utilize 3,6-Dibromo-9-Ethylcarbazole to synthesize electron-transport and host materials in high-resolution display production. Its chemical structure allows precise tuning of charge mobility and emission properties in device layers, contributing to efficient panel assembly and superior display quality. Downstream integration typically involves multi-step organic synthesis and purification before incorporation into spin-coated or vacuum-deposited emissive layers.

    Industry compliance standards

    • IEC 63241:2021 (Display Devices – OLED Panels)
    • ISO 9001:2015 (Quality Management for Electronic Components)
    • RoHS Directive (EU 2011/65/EU) restrictions (lead, mercury, etc.)
    • JEITA ED-7301 (Japanese OLED Material Standards)

    Typical usage ratio

    • 5–25 wt% in functional layers, with precise ratios set based on desired charge transport balance and target emission wavelength

    Downstream process integration

    • Intermediate for carbazole-based emitter and host material synthesis (Buchwald–Hartwig amination, Suzuki coupling) prior to device fabrication
    • Direct blending into organic solvent formulations for wet-processed (solution-cast) films in OLED stack assembly
    • Thermal vacuum deposition feedstock for discrete device layer formation

    Final product types

    • OLED TV and smartphone panels
    • Wearable display modules
    • Flexible lighting films and automotive interior displays

    2. Advanced Photoconductive Polymers

    Manufacturers of photoreceptors and electrophotographic components employ 3,6-Dibromo-9-Ethylcarbazole for synthesizing carbazole-based monomers and oligomers. The compound functions as a key intermediate in the preparation of high-mobility, charge-transporting materials critical for reliable photoresponse and imaging quality in xerographic printing drums and photodetectors. The downstream process emphasizes monomer incorporation into photoactive polymer backbones via controlled polymerization routes.

    Industry compliance standards

    • ANSI IT9.17-1993 (Stability of Photographic and Imaging Materials)
    • IEC 61988-2-1:2011 (Materials for Photoreceptors)
    • ISO 14001:2015 (Environmental Management for Chemical Processing)
    • REACH Regulation (EC No 1907/2006) registration for industrial intermediates

    Typical usage ratio

    • 1–10 mol% in carbazole-derived monomer synthesis batches; final usage determined by polymerization strategy and desired sensitivity/charge properties

    Downstream process integration

    • Introduction during Grignard or Suzuki cross-coupling for carbazole-based monomer functionalization
    • Direct polymerization into photoconductive layers in coating operations for drum and belt manufacture

    Final product types

    • Electrophotographic drum coatings (copiers, laser printers)
    • Photoreceptors for large-format imaging devices
    • Industrial photoresist components

    3. High-Efficiency Solar Cell Materials

    R&D and commercial solar module producers employ 3,6-Dibromo-9-Ethylcarbazole for advanced donor-acceptor materials within organic photovoltaic (OPV) architectures. By facilitating the synthesis of well-defined conjugated backbones, the material boosts photoactive layer performance and long-term module stability under irradiation. Batch processing targets high-molecular-weight polymers with uniform functionalization and compatibility with scalable roll-to-roll manufacturing lines.

    Industry compliance standards

    • IEC 61215-2:2021 (Design Qualification and Type Approval for PV Modules)
    • IEC 61730-1/2:2016 (PV Module Safety Qualification)
    • TÜV SÜD Certification for Photovoltaic Materials
    • ISO 50001:2018 (Energy Management in Module Manufacturing)

    Typical usage ratio

    • 0.5–8 mol% in precursor blend for conjugated polymer photovoltaic layer; adjusted based on light absorption range and device VOC targets

    Downstream process integration

    • Monomer co-polymerization for donor-acceptor bulk-heterojunction material preparation using catalytic aryl coupling
    • Film casting or ink-jet printing into active solar cell layers under inert conditions

    Final product types

    • Organic thin-film solar modules
    • Flexible PV sheets and building-integrated solar laminates
    • Portable power-generation devices using lightweight OPV cells

    4. Specialty Fine Chemical Synthesis for Pharmaceutical Intermediates

    Active pharmaceutical ingredient (API) manufacturers utilize 3,6-Dibromo-9-Ethylcarbazole in tiny but crucial amounts for the synthesis of specialized carbazole-based intermediates. Its regioselective reactivity supports efficient construction of polycyclic aromatic motifs found in proprietary drug candidates and select industrial catalysts. The downstream process emphasizes high-purity separation and traceability, with all steps executed according to validated synthetic route protocols.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice for Active Pharmaceutical Ingredients)
    • USP–NF Monograph Verification where applicable
    • ISO 22716:2007 (GMP for Pharmaceutical Raw Materials)
    • FDA 21 CFR Part 210/211 (US cGMP for APIs)

    Typical usage ratio

    • 0.1–2 mol% relative to target scaffold; actual loading set by route optimization and scale-up assessment in kg-to-metric ton production batches

    Downstream process integration

    • Incorporated during key cross-coupling and cyclization steps under inert, dry conditions
    • Purified via column chromatography before subsequent heterocycle transformations or coupling reactions

    Final product types

    • Carbazole-derived pharmaceutical intermediates
    • Building blocks for veterinary or orphan drug synthesis
    • Functionalized carbazole scaffolds for R&D in medicinal chemistry

    5. Electroluminescent Polymer Materials for Lighting Devices

    Professional manufacturers in the decorative and functional lighting industry rely on 3,6-Dibromo-9-Ethylcarbazole to construct emissive carbazole units in electroluminescent polymers. Its controlled bromination yields predictable electronic characteristics essential for color accuracy and power efficiency in thin, flexible lighting sheets and signage. Compound integration aligns with multi-component blending during polymerization and post-polymer chain modifications.

    Industry compliance standards

    • IEC 60598-1:2020 (General Safety Requirements for Luminaires)
    • EN 62471:2008 (Photobiological Safety of Lamps and Lamp Systems)
    • ISO 15510:2014 (Raw Material Traceability for Lighting Devices)
    • UL 94 (Flammability Testing of Polymer Materials, where applicable)

    Typical usage ratio

    • 2–12 wt% in pre-polymer blends, with exact ratios set by target emission color and device thickness during scale-up

    Downstream process integration

    • Feeds Suzuki or Stille cross-coupling reactors for polymer backbone synthesis
    • Blended into molten or solvent-based formulations for direct extrusion and film-casting onto flexible substrates

    Final product types

    • Flexible electroluminescent lighting tapes
    • Architectural backlighting panels
    • Custom signage and safety illumination films
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    Certification & Compliance
    More Introduction

    Introducing 3,6-Dibromo-9-Ethylcarbazole: A Step Forward in Specialty Chemicals

    Overview

    3,6-Dibromo-9-Ethylcarbazole stands out in the world of organic intermediates. With its molecular formula C14H11Br2N and a structure featuring two bromine atoms at the 3 and 6 positions on the carbazole ring, this compound makes an impact in advanced material synthesis, especially in the world of optoelectronics and organic semiconductors. Those of us who have watched the evolution of OLED and polymer-based innovations can’t ignore how reliable starting materials have supported all that progress.

    Model & Key Specifications

    At its core, each batch of 3,6-Dibromo-9-Ethylcarbazole comes as a crystalline powder. The brominated carbazole backbone has a melting point near 170 °C, often showing a pale yellow or off-white color. High purity matters here; manufacturers and labs who settle for impure grades can end up with erratic test results and wasted time. As a chemist who has handled analogues, I’ve found purity above 98% vital for consistent coupling reactions, and the stability this molecule offers at room temperature means you can safely store it with minimal fuss.

    Applications that Matter

    This chemical isn't just for academic research—it's shaped real change in organic electronics. In the search for efficient blue emitters for OLED materials, derivatives of 3,6-Dibromo-9-Ethylcarbazole have shown strong electron-donating properties and stable photophysical behavior. The bromine groups open the door to Suzuki and other cross-coupling strategies, which has led innovation in the manufacture of hole-transporting layers and advanced polymers. From hands-on experience in material science labs, selecting the right functionalized carbazole can be the difference between a promising prototype and an unstable device.

    With growing demand for tailored optoelectronic materials, flexibility in molecular design remains crucial. What sets this compound apart is its balance: high reactivity in coupling reactions, chemical robustness, and versatility across a spectrum of synthetic routes. Labs building photovoltaic or electroluminescent devices can count on its compatibility with palladium-catalyzed reactions, giving chemists a reliable toolkit for constructing more complex architectures.

    Differences from Common Analogs

    3,6-Dibromo-9-Ethylcarbazole has key advantages when lined up against its counterparts. Standard carbazole often falls short in reactivity; it lacks the halogen handles that make coupling so straightforward. Mono-brominated carbazoles may offer only limited branching options, while non-alkylated or differently substituted analogs can show less-than-ideal solubility or film-forming behavior. Here, adding an ethyl group at the 9-position improves solubility and processing, making downstream purification steps less of a headache. The twin bromines enable a direct route for dual functionalization, allowing for more advanced polymer designs or the creation of asymmetric molecules needed in modern electronic materials.

    From trial and error in the lab, the switch from non-brominated carbazole to this dibromo version reduces reaction times and cuts down on byproducts. That means less column chromatography, fewer purification headaches, and better overall yields—a win for anyone driven by efficiency.

    Supporting Innovation in Advanced Materials

    A closer look at the literature shows this molecule’s reach. In OLED research, for example, carbazole derivatives like this have been used to design materials with greater charge mobility and improved film stability. The robust framework resists oxidation and photodegradation, key for commercial devices expected to survive repeated cycling. Well-defined substitution with bromine also allows chemists to tune HOMO and LUMO energy levels, a key factor in device engineering for displays and lighting solutions. In photovoltaic research, the right carbazole backbone can nudge power conversion efficiencies closer to commercial reality. Researchers using 3,6-Dibromo-9-Ethylcarbazole can confidently design energy harvesting layers that retain function after long-term exposure to heat or light.

    Environmental Awareness and Safe Handling

    Safety and environmental impact weigh heavily in chemical production and use. Carbazole derivatives, including this product, call for proper laboratory protocol. Gloves, goggles, and good ventilation prevent unwanted exposure. Disposal must align with local chemical waste regulations, given the bromine content. Practical experience in academic and commercial labs has taught the value of responsible use, both for personal safety and regulatory compliance. Choosing highly pure materials helps reduce waste downstream and supports a more sustainable workflow. Some forward-thinking companies have invested in greener synthesis routes; their focus on reduced brominated byproducts and minimized solvent use reflects the industry's changing values.

    Quality, Trust, and Research Integrity

    The importance of quality control can’t be overstated. Reliable supply chains deliver consistent materials that support meaningful research outcomes. I’ve faced setbacks caused by variable purity or batch inconsistencies—and so have many others who depend on high-performance organic semiconductors. By selecting reputable sources, labs help safeguard the credibility of published data and accelerate the adoption of new technology.

    Regular use of analytical techniques such as NMR spectroscopy, HPLC, and elemental analysis ensures that each batch meets the standards needed for high-stakes projects. One study in a major journal highlighted the direct link between material quality and the long-term stability of OLED devices; poor-quality starting molecules led to rapid device failure, high current leakage, and color instability. That kind of evidence shapes daily lab practice—and it shows why 3,6-Dibromo-9-Ethylcarbazole, sourced right, underpins so much contemporary research.

    Potential Challenges and Solutions

    Sourcing specialty chemicals brings real-world hurdles. Shortages, shipping constraints, or inconsistent supply can leave research and manufacturing timelines vulnerable. One practical solution involves building relationships with multiple suppliers and maintaining buffer stock of critical reagents. This reduces risk and keeps workflows steady during disruptions—a lesson many labs learned during periods of global supply chain instability.

    Cost is another variable. Specialty chemicals aren’t always affordable for all research groups. Collaboration and resource sharing—two pillars of the academic experience—can help spread both risk and cost. Joint purchasing agreements between labs or shared inventory systems make a difference, especially for compounds whose demand spikes unpredictably.

    Handling and storage requirements need attention, too. While 3,6-Dibromo-9-Ethylcarbazole offers more robustness than some sensitive reagents, moisture or excessive heat can still cause degradation over time. Using airtight containers and climate-controlled storage extends its shelf life, saves money, and prevents unpleasant surprises at scale. Over the years, simple routines like checking for clumping or discoloration before weighing have helped avert headaches downstream.

    The Human Element: Research, Experimentation, and Progress

    The world of organic synthesis thrives on curiosity and precision. In labs that rely on carbazole chemistry, small things—a flash of inspiration during a late-night experiment, an unexpectedly high yield, a striking new polymer color—can change careers and open up new applications. Having access to dependable building blocks like 3,6-Dibromo-9-Ethylcarbazole enables exploration and creativity. Each gram is the product of careful industrial process, but it also launches new experiments, publications, and ultimately the technologies that shape modern lives.

    Mentoring younger chemists gives a broader perspective. Early-career researchers often discover that the right starting material can ease the steep learning curve of new synthetic techniques. The accessibility and familiarity of products like this encourage experimentation, build confidence, and foster new advances. Sharing experiences, both good and bad, within the research community improves everyone’s results and sharpens future inquiry.

    Looking Ahead: Future Trends

    Digital displays, wearable electronics, and smart lighting all fuel greater interest in carbazole-based compounds. As innovation cycles quicken, so does the importance of modular, reliably functional intermediates. Researchers are starting to explore bio-derived or less hazardous alternatives, but for now, classic molecules like 3,6-Dibromo-9-Ethylcarbazole continue to set the bar for versatility and performance.

    Greater automation in chemical synthesis may one day make it even easier to prepare finely tuned analogs with less waste and higher selectivity. Until then, tried-and-tested intermediates form the backbone of high-throughput discovery platforms and scaling strategies. Sustainable practices and process improvements, like solvent recycling and green chemistry protocols, are gaining traction. Producers who recognize the value of both innovation and responsibility pave the way for safer, more efficient, and more equitable science.

    Choosing the Right Product for Your Needs

    Practical choices in the lab often involve trade-offs; the balance between cost, purity, and supply reliability counts more than glossy catalog photos or marketing lines. Direct experience trumps speculation here. Projects requiring precision—like electronic device fabrication or medical imaging probes—benefit from a robust, high-purity intermediate that doesn’t falter under demanding conditions. As research pushes boundaries, every edge matters.

    Turning insights from the bench into real-world technology still depends on sound decisions at the raw material level. 3,6-Dibromo-9-Ethylcarbazole earns its place in this story not only through chemical structure or clever synthetic pathways, but through the ripple effect of its reliable use in research and new product development. The next generation of breakthroughs—whether cleaner energy, sharper screens, or more durable sensors—starts with smart choices today, and finishes with innovation tomorrow.