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3,3',4,4'-Biphenyltetracarboxylic Acid

    • Product Name 3,3',4,4'-Biphenyltetracarboxylic Acid
    • Alias 3,3',4,4'-BPTCA
    • Einecs 219-379-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    208040

    Name 3,3',4,4'-Biphenyltetracarboxylic Acid
    Cas Number 2420-87-3
    Molecular Formula C16H8O8
    Molecular Weight 328.23
    Appearance White to off-white powder
    Melting Point Over 300°C (decomposition)
    Solubility In Water Insoluble or very slightly soluble
    Purity Typically ≥98%
    Boiling Point Decomposes before boiling
    Synonyms 3,3',4,4'-Benzidinetetracarboxylic acid
    Inchi InChI=1S/C16H8O8/c17-13(18)7-1-3-9(5-11(7)15(21)22)10-4-2-8(6-12(10)16(23)24)14(19)20/h1-6H,(H,17,18)(H,19,20)(H,21,22)(H,23,24)
    Smiles C1=CC(=C(C=C1C(=O)O)C(=O)O)C2=CC(=C(C=C2C(=O)O)C(=O)O)
    Ec Number 219-342-9

    As an accredited 3,3',4,4'-Biphenyltetracarboxylic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 25-gram bottle of 3,3',4,4'-Biphenyltetracarboxylic Acid, securely sealed in an amber glass container with hazard labeling.
    Shipping 3,3',4,4'-Biphenyltetracarboxylic Acid is shipped in tightly sealed, chemical-resistant containers to prevent moisture and contamination. It is typically transported as a solid powder and labeled according to relevant regulations. Handle with care, avoiding excessive heat, direct sunlight, and physical shock during transit. Safety data and hazard documentation accompany each shipment.
    Storage Store **3,3',4,4'-Biphenyltetracarboxylic Acid** in a cool, dry, well-ventilated area away from incompatible substances such as strong bases and oxidizing agents. Keep the container tightly closed and protected from moisture. Store at room temperature and avoid exposure to direct sunlight. Use chemical-resistant containers and clearly label all storage vessels to ensure proper identification and handling.
    Application of 3,3',4,4'-Biphenyltetracarboxylic Acid

    Applications of 3,3',4,4'-Biphenyltetracarboxylic Acid in Industrial Manufacturing

    As a specialized manufacturer of aromatic tetracarboxylic acids, we supply 3,3',4,4'-Biphenyltetracarboxylic Acid (BPDA) for high-value industrial chains that demand consistent purity and reliable functional group performance. Below, we present actual deployed scenarios in advanced materials industries, detailing integration requirements, compliance, process points, and formulation data for each sector.

    1. High-Performance Polyimide Film Production

    BPDA is a cornerstone monomer for producing aromatic polyimide films used in electronics, aerospace, and flexible display applications. The rigid structure and multiple carboxyl groups enable synthesis of films with outstanding thermal stability, low dielectric constants, and mechanical strength required for miniaturization and demanding environments. BPDA enters the process during polyamic acid synthesis and significantly influences the imide ring formation, glass transition temperature, and dimensional stability of the resultant films.

    Industry compliance standards

    • IEC 60216 (Thermal endurance properties of polyimide)
    • UL 94 VTM-0 (Flammability requirements for flexible films)
    • RoHS Directive 2011/65/EU (Restriction of hazardous substances)
    • GB/T 13542.2 (Chinese standard for polyimide film materials)

    Typical usage ratio

    • 35-55 mol% of dianhydride component in polyimide composition, adjusted according to target crystallinity and required dielectric properties.

    Downstream process integration

    • BPDA reacts with diamines (e.g. p-phenylenediamine) during initial polyamic acid polymerization, followed by casting and thermal imidization to form finished films.

    Final product types

    • Flexible copper clad laminates (FCCL) for FPC
    • Transparent substrate films for OLED displays
    • Insulation tapes for high-end electronics
    • Space-grade thermal control films

    2. Polyimide Resin for Advanced Composite Materials

    BPDA serves as an essential dianhydride input for polyimide resins used in manufacturing structural composite prepregs for aircraft, satellites, and specialty automotive components. The resulting thermoset polyimides meet flight-level requirements for flame resistance, stability under rapid temperature cycling, and compatibility with high-strength fibers. BPDA’s high rigidity is critical for achieving resin matrices with low coefficient of thermal expansion and high glass transition points.

    Industry compliance standards

    • SAE AMS 3716 (Polyimide resin matrix prepregs)
    • ASTM D6444 (Composite material flammability testing)
    • EN 9100 (Aerospace quality management)
    • REACH Annex XVII (Substances of very high concern restrictions)

    Typical usage ratio

    • 45-60 wt% of total dianhydride feed in polyimide matrix resin; level adjusted based on processability for fiber impregnation and required glass transition temperature (Tg).

    Downstream process integration

    • BPDA reacts with selected aromatic diamines during intermediate ‘varnish’ solution prep, which is then impregnated into carbon or glass fibers and cured to form composite panels.

    Final product types

    • Aerospace structural prepregs and laminates
    • High-temperature composite fastener blocks
    • Carbon fiber reinforced thermal insulation panels
    • Lightweight structural interior parts for high-speed trains

    3. Polyimide Enamel Wire Coatings

    BPDA provides the thermal backbone for polyimide-based coating resins engineered for magnet wire enamels in demanding electrical and electronic equipment. These coatings must achieve continuous service temperatures up to 200–240°C and withstand aggressive solvents and repeated bending stress. BPDA enables formation of resins capable of withstanding Class H and Class N insulation levels when properly incorporated into the enamel blend.

    Industry compliance standards

    • IEC 60317-13 (International standard for polyimide enameled rectangular copper wire)
    • UL 1446 (Electrical insulation system requirements)
    • JIS C 3216 (Japanese polyimide enamel standard)
    • GB/T 4074.1 (Chinese standard for winding wires)

    Typical usage ratio

    • 40-55 mol% BPDA in total dianhydride fraction for wire resin formulation; fine-tuned for layer thickness, flex resistance, and curing conditions per customer process line.

    Downstream process integration

    • Polyamic acid synthesized using BPDA is directly applied as a liquid coating to copper wire, followed by thermal curing cycles to imidize and form functional insulation layers.

    Final product types

    • Class H/N high-temp magnet wires for motors
    • Transformers for railway and traction applications
    • Hermetic compressor winding wires
    • High-frequency communication coil wires

    4. Polyimide Membranes for Gas Separation

    Gas separation technology leverages polyimide membranes synthesized with BPDA to achieve selective permeability, commonly for separating N2 from O2, and CO2 removal in petrochemical and environmental control. The molecular structure imparted by BPDA allows membrane producers to tailor permeability/selectivity trade-off, essential for challenging process gases under pressure and temperature variations.

    Industry compliance standards

    • ISO 9001 (Quality management system for membrane production)
    • ASTM D3985 (Oxygen gas transmission rate through plastic film standards)
    • EN 14181 (Continuous emission monitoring systems for NOx/SO2 separation membranes)
    • Directive 94/9/EC (ATEX conformity for equipment in explosive atmospheres)

    Typical usage ratio

    • 30-50 mol% in polyimide backbone composition, depending on desired selectivity and permeance; ratio modified based on process pressure and temperature requirements.

    Downstream process integration

    • BPDA enters during polyamic acid formation, then cast or spun into hollow fibers or flat sheets, with subsequent thermal or chemical imidization to achieve the required asymmetric membrane structure.

    Final product types

    • N2/O2 separation modules for industrial gas
    • CO2 removal membranes for natural gas processing
    • Olefins/paraffins separation membranes for petrochemical operations
    • Air drying units for precision manufacturing environments

    5. Polyimide-Based Dielectric Materials for Microelectronics

    Microelectronic fabrication demands advanced dielectric materials for interlayer insulation and passivation. Polyimides utilizing BPDA contribute low dielectric constants and superior stability under plasma etch and solder reflow conditions, supporting ever-mounting integration densities and package miniaturization. The monomer precisely controls imide linkage density and planarization, essential for fine-pitch redistribution layers and reliable semiconductor packaging.

    Industry compliance standards

    • IPC-4101 (Specification for base materials in printed wiring boards)
    • JEDEC J-STD-033 (Protection of moisture sensitive devices)
    • IATF 16949 (Automotive microelectronics quality standard)
    • RoHS 3 (EU 2015/863—additional phthalate exclusion)

    Typical usage ratio

    • BPDA accounts for 38–52 mol% of the polyimide matrix; adjusted for target dielectric constant and curing speed to match fabrication process requirements in wafer-level, chip-scale, or module-level builds.

    Downstream process integration

    • BPDA enters during imide precursor synthesis, either for spin-coating or inkjet patterning onto wafers and substrates, followed by precision baking and imidization steps under defined atmosphere.

    Final product types

    • Redistribution layers for WLP/FC-CSP
    • Dielectric interlayers in advanced PCBs
    • Passivation films on CMOS MEMS sensors
    • Insulation layers in automotive ADAS modules
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    Certification & Compliance
    More Introduction

    Introducing Our 3,3',4,4'-Biphenyltetracarboxylic Acid: Performance Rooted in Chemical Precision

    Day in and day out, our team refines the synthesis of 3,3',4,4'-Biphenyltetracarboxylic Acid (BPTCA), drawing on decades of hands-on production experience. There’s a noticeable difference between a product made by those who understand its chemistry and those who simply move boxes. We invest in precision at every turn, making sure our BPTCA remains consistent, clean, and reactive to meet the real needs of material scientists and process engineers.

    True to Its Core: Our Approach to Quality

    BPTCA demands steady hands and well-maintained reactors, not just formulas on paper. Small details make or break quality. If the filtration falters or the recrystallization temperature shifts, purity suffers. We track water content, particle structure, and residual by-products at each step. This ethos grew from problem-solving with our own eyes on the plant floor—nothing gets released unless every technician is satisfied.

    True BPTCA—CAS 2420-87-3—manifests as a white to off-white powder, with a molecular structure built for strong, planar conjugation. Purity levels matter here, settling impurities below 0.1% through iterative crystallization and careful solvent handling. It’s not about inflating purity for a sticker; it’s about maintaining reproducible performance for end users who push these molecules to their limits.

    What Sets BPTCA Apart in Application

    Some compounds exist to react. BPTCA shapes resins designed to withstand severe thermal cycles, forming imide linkages that don’t flinch under heat. Polyimide film creators turn to this acid to forge electrical insulation and protective coatings that maintain their edge at 250°C and often beyond. The compound’s rigid aromatic backbone, paired with four carboxyl groups, marks it as a core building block in these formulations.

    From our experience, success depends on product behavior during polymerization. Unrefined BPTCA disrupts melting points or fosters yellowing during processing, which derails entire batches. Precise, repeatable melting point performance isn’t a marketing line—it’s something end users spot right away. Our team always focused on keeping batch-to-batch variation minute, which explains why resin manufacturers often specify our BPTCA after their own in-lab screening.

    Epoxy and advanced composite producers press for materials that bring dimensional stability and low dielectric loss. Demand in aerospace resins, flexible printed circuits, and chip encapsulation means the starting acid needs clarity, stability, and no contamination. Missteps in particle sizing, flow, or insoluble specks become headaches in scale-up. We learned quickly how to tune our milling, sieving, and handling protocols so customers receive a powder that mixes, disperses, and dissolves as expected—no unexpected clumps or filtration residue.

    Model Choices and Practical Outcomes

    Not all BPTCA is created equal, and real-world results hinge on tight manufacturing parameters. Over the years, we standardized multiple grades: standard grade offers high purity suitable for electronic-grade resins and general polymer production. Some customers need ultralow moisture variants for moisture-sensitive imidization steps, demanding additional drying and more robust packaging. Others request a finely milled particle form for whip-quick dispersion in solvent systems. Our process control lets us scale these variants without “boutique” price tags or reliability compromises.

    Lab teams have come to us with requests for custom particle size or lower heavy metal content—each requiring audit-proof modifications to the process. After one customer flagged copper contamination, we tracked it back to a worn gasket. Fixes come swiftly, and every tweak gets verified by actual finished application testing, not just paperwork. This hands-on way pays dividends for users trying to keep defects low and approval times brisk.

    Working With BPTCA: A Few Hard-Earned Lessons

    Process engineers tend to see more BPTCA batches than anyone else. They’ll spot the way a powder hydrates if a bag was stored carelessly, or pick up on subtle odors that reveal cross-contamination. It’s these on-the-ground details that tend to separate lab theory from shop-floor success. When talking with engineers and procurement managers, we’ve learned the importance of clear communication—particle sizing, flowability, purity, and even packaging all find their way into upstream or downstream headaches if ignored.

    In practice, even a solid BPTCA process gives surprises. Storage conditions, micro-vibrations in the transit warehouse, or slight bag seal shifts during monsoon months can affect moisture content or caking. We avoid vague batch labeling and instead log conditions, batch time, and every deviation. Repeat customers rely on this data to backtrack any processing issues they see. Deep knowledge about how BPTCA interacts with various diamines, the curve of the imidization reaction, or even the air quality impacts from acid dust comes from years on the job, not speculative reading.

    BPTCA vs. Other Tetracarboxylic Acids

    A customer once asked why not just switch to pyromellitic acid or a cheaper isomer. In the plant, we see BPTCA’s molecular symmetry and rigidity translate into films and laminates with less distortion, especially at wide temperature swings. Other tetracarboxylic acids tend to knock flexibility or begin to yellow at stress points. BPTCA’s extended biphenyl core improves dimensional stability, a property crucial for electronics that can’t tolerate micro-cracking or surface warping.

    Compared to 3,3',4,4'-benzophenonetetracarboxylic acid, we notice our BPTCA’s lower incidence of side reactions in polyimide synthesis. Less discoloration and higher dielectric breakdown strength stand out in post-synthesis testing. For glass fiber-impregnated laminates, the end result translates into fewer product returns or failures in field tests. These aren’t theoretical improvements—they come from actual user feedback and our batch QA records stretching back years.

    End-Use Markets and Why Purity Matters

    Electronics firms push their suppliers for lots with absolute traceability and impurity logs. They care if sodium, iron, or silica levels fluctuate. For us, it means stricter raw material vetting and continuous upgrades in water and solvent purification infrastructure. The finer demands from chip packaging giants encourage us to push analytical precision—ICP-MS isn’t an afterthought but just a part of daily work.

    Polyimide’s rise across flexible OLED displays, automotive electronics, and advanced batteries isn’t slowing. Every new device generation calls for better thermal management and circuit reliability. BPTCA stands in the middle of this shift. Makers are keenly aware of cost pressures but refuse to compromise in areas where device failure undermines brand trust. Our history supplying these markets keeps our improvement loop short: we know which lots succeeded, which failed, and why.

    Supporting Innovation Without Risk

    Formulators often test new hardeners, co-monomers, or experimental solvents, and getting BPTCA to dissolve or disperse without residue becomes a real challenge. We keep direct lines open between our plant chemists and end users. A complaint can arrive as a forkful of material stuck in a mixer or as subtle electrical property drift. Both deserve the same attention. Rapid feedback means customers don’t waste weeks blaming their process when the answer depends on how the acid was milled or packaged. Our technical support culture grows out of pride, shared headaches, and plenty of after-hours troubleshooting.

    Researchers driving next-era composites and lightweight structures often lack time for supplier games. They care about reliability and transparency, not just what the label promises. Research batches from us aren’t “off-spec” leftovers; we treat every request seriously, log it in our system, and follow up on results. This two-way feedback cycle led us to refine our drying operations following a single sticky batch in a new resin system. Change happens one lesson at a time—never in isolation.

    Sustainability, Safety, and Compliance: Grounded Practices

    Chemical manufacturing often faces fair questions about sustainability—ours included. Every BPTCA batch gets planned to maximize yield, minimize solvent waste, and capture solid byproducts for future processing or safe disposal. Energy efficiency isn’t a buzzword here; energy meters hang in view of every operator, and abnormal spikes trigger a real look at operations. Audits by regulatory inspectors or industry standards groups aren’t empty rituals—they form part of our regular rhythm.

    BPTCA doesn’t pose the dramatic hazards of more volatile acids. Still, we understand fine dust generated during handling can bring risks. All plant operators receive up-to-date safety briefings tailored to acid handling, and our facilities are designed to minimize exposure risk. Safe packaging and detailed material documentation go out with every lot, informed by actual handling incidents reported over the years. If a customer uncovers a new risk, we work directly with them to document and mitigate the issue, improving both their safety profile and our own process.

    Supply Chain Realities: Earning Trust

    Chemical makers aren’t immune to logistics headaches or upstream fluctuations in key starting materials. Our commitment to BPTCA supply security drove investments in local sourcing, expanded storage tanks, and well-audited supplier audits. Given how thin margins can get in polyimide and related materials, involuntary outages or uncontrolled price surges pose big risks to users. Reliable makers build redundancy and keep open lines with partners—both buyers and upstream suppliers.

    We’ve faced raw material purity shifts from vendors, transportation shutdowns, and customs delays—every time, customer transparency trumped hiding the facts. We share shipment schedules early and keep back-inventory where possible. Production forecasts don’t come from guesswork but are built from decade-long trends and close engagement with key customers’ growth plans.

    Delivering Value the Hard Way

    Some buyers fixate on cost per kilogram. Raw price matters, but it’s only part of the equation—batch-to-batch reliability, complaint-free operation, and after-sale technical support save more than chasing a short-term deal ever could. Every production team member takes pride when lots pass external evaluation or when an end customer sticks with us through next-generation upgrades. Quality is never a slogan, and improvement isn’t a special project—it’s just how we work, every shift, every day.

    Competitors might source indistinguishable-looking BPTCA. Once you’ve run both in a full-scale polyimide plant, subtle differences become obvious—yield consistency, production uptime, downstream resin stability. Users with decades of field data frequently report back on performance, not just initial certificate of analysis results. That feedback shapes the adjustments engineers make to filtration methods, pH control, or packaging improvements that actually serve customers' needs.

    The Road Ahead for BPTCA

    Research in flexible electronics, extreme-temperature adhesives, and novel composite architectures places increasing emphasis on starting monomer quality. BPTCA’s four acid groups and rigid biphenyl core aren’t just points on a spec sheet—they drive real-world reliability in applications that can’t afford failures, from satellites to wearable sensors. Device makers and advanced material producers continue to innovate, and suppliers that understand the stakes don’t view BPTCA as a commodity.

    Our team uses every customer call, complaint, and win as a guide for continuous improvement. That culture—born in chemical shops and pilot plants, not in sales meetings—ensures BPTCA remains more than just a catalog line. For us, the acid tells its story through performance, not just analysis numbers. Those who rely on it for high-value polymers, adhesives, or specialty laminates see the difference not just in their accounting ledgers, but in reliability tests, field returns, and years of uninterrupted production.