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2-(Perfluorooctyl)Ethyl Methacrylate

    • Product Name 2-(Perfluorooctyl)Ethyl Methacrylate
    • Alias Zonyl TM
    • Einecs 401-850-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    333391

    Cas Number 2144-53-8
    Molecular Formula C12H11F17O2
    Molecular Weight 538.20 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point 151°C (at 760 mmHg)
    Density 1.55 g/cm3 (at 25°C)
    Flash Point >100°C (closed cup)
    Purity Typically ≥98%
    Solubility Insoluble in water; soluble in organic solvents
    Refractive Index 1.360 - 1.380 (at 20°C)
    Melting Point -18°C
    Storage Temperature 2-8°C, keep tightly closed
    Functional Groups Methacrylate, perfluorinated alkyl chain
    Odor Characteristic, faint

    As an accredited 2-(Perfluorooctyl)Ethyl Methacrylate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 500g of 2-(Perfluorooctyl)ethyl methacrylate is supplied in a sealed, amber glass bottle with a tamper-evident cap.
    Shipping 2-(Perfluorooctyl)Ethyl Methacrylate is shipped in sealed, chemical-resistant containers under ambient conditions. As a fluorinated monomer, it is classified as a hazardous material and must be handled in accordance with relevant regulatory guidelines, including labeling and documentation. Ensure shipment avoids direct sunlight, heat, and sources of ignition. Suitable for ground or air transport.
    Storage 2-(Perfluorooctyl)Ethyl Methacrylate should be stored in a tightly closed container in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, open flames, and sources of ignition. It should be kept away from incompatible substances such as strong oxidizers and acids. Protect from moisture and store at temperatures recommended by the manufacturer, ideally under an inert atmosphere to prevent polymerization.
    Application of 2-(Perfluorooctyl)Ethyl Methacrylate

    Applications of 2-(Perfluorooctyl)Ethyl Methacrylate in Industrial Manufacturing

    2-(Perfluorooctyl)Ethyl Methacrylate is a fluoroalkyl monomer used to impart superior water, oil, and stain repellency in high-performance polymers, coatings, and specialty materials. As a manufacturer specializing in advanced monomer synthesis, we supply this raw material for several industrial sectors with distinct regulatory, formulation, process, and product requirements.

    1. High-Performance Textile Finishes

    Textile finishers use 2-(Perfluorooctyl)Ethyl Methacrylate to create durable water- and oil-repellent coatings on fabrics for outdoor gear, uniforms, upholstery, and technical textiles. The monomer copolymerizes with acrylate or methacrylate resin systems, producing a covalently bonded protective layer that withstands home and industrial laundering. Application processes include pad-dry-cure techniques and exhaust methods, requiring precision to meet fastness ratings and regulatory fluorine emission limits.

    Industry compliance standards

    • OEKO-TEX® Standard 100 Annex 6
    • ZDHC MRSL Version 3.0 (Zero Discharge of Hazardous Chemicals)
    • EU REACH Regulation (1907/2006/EC)
    • ISO 14419:2010 (Oil repellency)

    Typical usage ratio

    • 0.5–5 wt% based on fabric weight, adjusted to achieve performance ratings; concentrations higher than 5% may require post-cure washing to minimize free fluorine content.

    Downstream process integration

    • Added via emulsion or solution into finishing bath during pad or spray application, followed by controlled drying at 100–120°C and thermal crosslinking at 150–170°C.

    Final product types

    • Rainwear, outdoor apparel, hospital fabrics, filtration textiles, performance upholstery, military uniforms.

    2. Protective Architectural and Industrial Coatings

    Paint, lacquer, and industrial coating manufacturers use the monomer to boost hydrophobic and oleophobic properties in coatings for stone, concrete, glass, and metals. By copolymerizing with acrylic or urethane systems, it generates durable, low-surface energy films that resist graffiti, fouling, and environmental degradation. Coating formulators must balance fluorinated monomer dosage to meet slip, gloss, and recoatability targets, while complying with industry and environmental requirements.

    Industry compliance standards

    • ASTM D6578/D6578M–13 (Graffiti Resistance)
    • EPA VOC Regulations (40 CFR Part 59)
    • GB/T 9754-2007 (Paints and varnishes — Specular gloss)
    • EN 1504-2:2004 (Surface protection systems for concrete)

    Typical usage ratio

    • 1–4 wt% of total polymer content, tailored for target repellency and film formation; lower ratios favor gloss retention, higher ratios for maximum repellency.

    Downstream process integration

    • Added during copolymerization or post-polymerization blending before dispersion into the final coating formulation and subsequent application by spray, roller, or dipping.

    Final product types

    • Anti-graffiti coatings, stain-resistant wall paints, anti-fouling marine coatings, exterior stone and masonry sealers, high-durability floor varnishes.

    3. Electronic Device Encapsulation and Conformal Coatings

    Electronics manufacturers utilize this monomer in the production of hydrophobic and dust-resistant coatings for printed circuit boards, sensors, and mobile device enclosures. These coatings improve reliability in humid, corrosive, or high-salinity environments by preventing ingress of moisture and contaminants. The precision required in formulation directly affects surface tension, film uniformity, dielectric strength, and manufacturability parameters like sprayability and cure schedule.

    Industry compliance standards

    • IPC-CC-830C (Qualification and Performance of Electrical Insulating Compounds for Printed Wiring Assemblies)
    • RoHS Directive (2011/65/EU)
    • UL 746E (Polymeric Materials – Electrical Insulation Systems)
    • IEC 61086 (Coating materials for electrical purposes)

    Typical usage ratio

    • 0.3–2 wt% relative to binder solids, adjusted for coating thickness and target dielectric performance; excess can affect adhesion and reworkability.

    Downstream process integration

    • Dispersed in prepolymer mixtures for conformal coating, applied by dip, spray, or selective coating heads, and thermally or UV-cured in cleanroom environments.

    Final product types

    • PCB conformal coatings, sensor moisture barriers, display panel sealants, encapsulated microelectronic modules.

    4. Leather and Synthetic Leather Finishes

    Producers of leather and synthetic leather employ the monomer to enhance resistance to oil, water, stains, and soiling in automotive, apparel, and luxury accessories. It serves as a co-monomer in polyurethane or acrylic emulsions, delivering repellency without significant alteration of appearance or feel. Production lines implement precise metering and blending, ensuring compliance with consumer safety and environmental fluorocarbon restrictions.

    Industry compliance standards

    • EN ISO 15797:2018 (Leather — Physical–chemical tests — Determination of water resistance)
    • ISO 2418:2021 (Leather — Chemical, physical and mechanical tests — Sample preparation)
    • Automotive OEM chemical compliance lists (e.g., VW TL 226, Ford WSS-M99P17-A4)
    • California Proposition 65

    Typical usage ratio

    • 0.5–2.5 wt% of total polymer solids; formulation fine-tuned with crosslinkers or plasticizers based on end use abrasion and repellency requirements.

    Downstream process integration

    • Blended into finishing topcoats or transfer coatings during resin synthesis, applied by roller or curtain coater, then thermally or UV cured on substrate.

    Final product types

    • Automotive leather seats, high-end handbags, footwear uppers, protective work gloves, travel goods.

    5. Specialty Paper and Packaging Coatings

    Producers of food-contact papers, release liners, and industrial packaging integrate this fluoroalkyl methacrylate in surface treatments to provide oil and grease barrier properties without compromising printability or recyclability. The application must balance barrier efficiency with regulatory restrictions on fluorinated compounds, as well as maintaining good adhesion and surface energy for downstream printing and laminating.

    Industry compliance standards

    • US FDA 21 CFR 176.170 (Components of paper and paperboard in contact with aqueous and fatty foods)
    • German BfR Recommendation XXXVI (Paper and board for food contact)
    • EN 13432:2000 (Packaging - Compostability and Biodegradability)
    • China GB 4806.8-2016 (National Food Safety Standard for Food Contact Paper and Board Materials)

    Typical usage ratio

    • 0.2–1.2 wt% relative to dry paper mass; typically optimized to the minimum effective dose to meet migration and barrier requirements within allowable fluorine limits.

    Downstream process integration

    • Added into aqueous or solvent-based barrier coating formulations, applied in size press or blade coating during paper or board finishing, followed by controlled drying.

    Final product types

    • Greaseproof food wraps, bakery papers, fast food packaging, release liners for pressure-sensitive adhesives, industrial packaging with oil-resistant performance.
    Free Quote

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    Certification & Compliance
    More Introduction

    2-(Perfluorooctyl)Ethyl Methacrylate: A Perspective from the Source

    Introduction

    Not every raw material has seen the inside of a reactor as many times as 2-(Perfluorooctyl)Ethyl Methacrylate. Our team’s experience working directly with this specialty monomer means we understand more than just its chemical structure. Years in the sector have shown us what this product can do, where it shines, and why formulators keep coming back to it. In this commentary, we’ll cover what this material brings to the table, outline practical uses, and underscore how it sets itself apart from others in the methacrylate and fluorochemical families based on real-world manufacturing and customer performance data.

    What Sets 2-(Perfluorooctyl)Ethyl Methacrylate Apart?

    Compared with standard methacrylates, the difference begins with the molecule’s long-chain perfluorinated segment. Adding this to the backbone transforms a simple monomer into something much more sophisticated. We produce this material at high purity, controlling not only the major components but also minimizing byproducts that can otherwise interfere with polymer performance. Years of process optimization have led to sharp product consistency, so every batch supports exacting applications in coatings, textiles, and specialty films.

    Traditional methacrylates like methyl methacrylate or butyl methacrylate can give mechanical strength and adjust the hardness or flexibility of a polymer, but they usually fall short when facing chemical resistance or water repellency challenges. Incorporating fluoroalkyl chains onto a methacrylate increases both oleophobic and hydrophobic properties. Surfaces treated with homopolymers or copolymers containing 2-(Perfluorooctyl)Ethyl Methacrylate shed water, oil, and many stains that standard acrylics absorb. Our firsthand studies and steady supply to manufacturers in the textile finishing and electronics sectors have proven this again and again.

    Specifications Rooted in Production Experience

    We consistently produce 2-(Perfluorooctyl)Ethyl Methacrylate under tightly controlled conditions to keep purity levels high and acid-value low. The most common model we offer, FMA-C8-99, consistently achieves a minimum assay of 99% through fractional distillation after precise reaction monitoring. Average molecular weight and GC purity match analytical benchmarks drawn from independent verification. Lab staff draw samples at each batch to ensure no drift from the standards we’ve set through years of experience.

    Storage stability and shelf-life have been refined through both lab investigations and follow-ups with end users. Sensitive to light and heat, the material retains its properties best when filled in opaque, sealed containers with inert gas blanketing. By monitoring temperature excursions during storage and transport, we’ve reduced the risk of premature polymerization and off-color formation—a lesson learned from early attempts that skipped proper quality checks.

    Practical Uses Backed by Industry Knowledge

    Years of direct supply to fiber mills, electronics coaters, and performance paper producers have shown us that 2-(Perfluorooctyl)Ethyl Methacrylate stands out in three main areas: dirt resistance, improved weatherability, and barrier creation. On synthetic textiles, adding as little as 1–3% by weight creates durable repellency without changing the feel of the final fabric. Finishing lines often co-polymerize it with acrylates or urethanes to retain breathability. We’ve seen this firsthand, working with mills to tweak cure conditions and match fiber types, especially when durable repellency required balancing handle, drape, and fastness against repeated washing cycles.

    In optics and electronics, solvent-based or UV-curable coatings gain longer life spans thanks to the perfluorinated tail on the methacrylate. While non-fluorinated acrylics degrade under acids or solvents, films that incorporate our monomer can fend off etching, resist ghosting, and reduce cleaning intervals. We often consult with R&D staff facing delamination or clarity loss with traditional monomers. Direct addition of 2-(Perfluorooctyl)Ethyl Methacrylate in formulations provides improvement using the same plant equipment, with no need for exotic cure cycles or special handling beyond light and oxygen exclusion. These improvements translate into real-world savings, especially where rework costs eat into product margins.

    The paper industry uses our monomer for specialty packaging, especially where migratory oil or flavor protection is critical. Standard acrylic coatings might allow permeability, but the fluorinated structure here acts like a microscopic barrier, stemming migration and preserving contents longer. Labs run aging and migration tests with side-by-side controls, and our monomer’s performance regularly beats out non-fluorinated alternatives by a wide margin.

    Meeting Environmental and Regulatory Challenges

    Regulatory requirements are changing fast. Discussions about PFAS-related materials ripple through every advanced chemistry sector. Strict control of residual monomer and critical attention to polymer end-use align with our daily batch certification process. Our production team tracks perfluorooctanoic acid (PFOA) and other possible impurities down to levels well below regulatory thresholds laid out by regions like the EU and North America. Years of factory optimization mean less off-gassing and lower risk of trace contamination—something less certain in imported, poorly documented material drawn from inconsistent sources.

    We engage with regulatory bodies and customer auditors by supporting every shipment with up-to-date traceability and analytical data. We don’t make unrealistic claims about zero emissions or abandoned legacy chemistries—experience says transparency and incremental improvement win more trust over time than any marketing slogan. By collaborating directly with users—be they textile mill technicians or packaging material scientists—we help adapt formulations to meet shifting requirements, and we pass along new data as soon as it’s available from analytical labs and regulatory bodies. While competitors restrict collaboration, our direct manufacturing experience means we're on-hand to work through reformulation exercises together.

    We also research and test new co-monomer blends that lower fluorinated content without compromising essential barrier properties. Some advances center around shorter-chain perfluoroalkyl equivalents. Others look at grafting strategies to maximize repellency at lower loadings. Each of these techniques gets run through our own pilot reactors under full process monitoring, and we report all data—good and bad—back to our long-term partners, so their product launches can keep pace with evolving global guidelines.

    Real-World Differences: 2-(Perfluorooctyl)Ethyl Methacrylate vs. Other Products

    The world of fluorinated methacrylates centers on chain length, substitution pattern, and molecular weight. Experience in the reactor shows that the eight-carbon backbone of 2-(Perfluorooctyl)Ethyl Methacrylate captures the right balance between repellency and processability. Shorter chains like C4 or C6 lose performance in harsher environments, especially when exposed to aggressive solvents or repeated abrasion. Longer chains tend to gum up process lines, with slower copolymerization kinetics and higher volatility concerns. Our formulation teams have fine-tuned process conditions to avoid these pitfalls, and our customers have reported fewer maintenance shutdowns and more reliable performance in field conditions.

    Compared with fluorinated acrylates, methacrylate versions resist chain scission and heat a bit better. This makes them suitable in higher-cure, UV-resistant, or electrical-insulating finishes. Feedback from electronics component makers points to longer insulation lifetime and better surface stability than with lower-cost, shorter-chain methacrylate options. In textiles, feedback from mass finishing lines confirms that repellency stays uniform after repeated laundering cycles—something less consistent with generic fluorinated acrylate co-polymers or direct fluoropolymer topcoats.

    Some ask why the industry doesn't switch entirely to less fluorinated or non-fluorinated side chains. We sympathize with the need for sustainability, but customer data clearly shows there are yet no direct replacements that retain oleophobicity and durability at the same level, especially in exposed outdoor conditions or high-value packaging. Transparency about these tradeoffs forms the basis of our partnership approach rather than simply chasing trends.

    Supply Assurance and Scalability

    Raw material volatility disrupts many industries. As on-site manufacturers, we control sourcing of perfluorooctyl iodide and methacryloyl chloride, giving us scheduling stability and tighter supply chains compared to repackagers. We’ve invested in redundancy—dual reactors, scalable distillation columns, and 24-hour run capabilities—to weather everything from raw material shortages to energy fluctuations. This means our customers don’t face sudden stock-outs or unexplained quality drift even when global supply chains get squeezed.

    Direct feedback loops between our production engineers and technical sales teams close the gap between laboratory theory and what works at the ton scale. Over the years, we’ve adjusted batch sizes, resin compatibility, and storage formats based on customer scale-up trials and continuous-use experience. These iterative improvements don’t show up in spec sheets but make a difference in large-scale operations where downtime or off-spec shipments handicap a product’s real-world success.

    Supporting Product Innovation

    Many of our long-term partners started by benchmarking this monomer against other fluorinated or non-fluorinated methacrylates, often at the pilot stage. Drawing on our deep reservoir of run data and batch tracking, we walk customers through first-run dosages, polymerization schedules, and end-use testing. Our technical team supports pilot plants with shipment-ready material and hands-on troubleshooting, not just with theoretical advice but with process tweaks informed by many cycles of real production.

    For specialty applications—like anti-fingerprint coatings for touchscreens or self-cleaning surfaces in architectural glass—we maintain a database of performance outcomes. This record saves new developers time and keeps them clear of pitfalls that sometimes follow textbook substitutions. Not every methacrylate stands up to both harsh UV and daily abrasion; our material’s long service in fielded applications points to more than just numbers in a data sheet.

    Future Directions and Industry Trends

    Green chemistry is reshaping specialty monomer manufacturing. While perfluorinated chains remain central to many high-performance coating formulations, we continually look for ways to lower environmental impact without compromising on quality. Our approach starts by maximizing conversion in the reactor, reclaiming residuals, and keeping emissions in check. We invest in R&D around partially fluorinated and non-fluorinated analogs but bring each new molecule to market only when testing shows no drop in utility or reliability for the end user.

    We encourage customers to share field failure data and emerging regulatory pressure points. In turn, we support them with technical data packages, reformulation guidance, and rapid sampling as industry needs evolve. Our outlook remains practical: proven performance counts, but so does the right direction for environmental footprint and customer trust. Through firsthand experience, we know that the right specialty monomer—produced under real accountability—can keep industries moving forward even as regulations, consumer tastes, and new technologies push standards ever higher.

    Conclusion: The Manufacturer’s Commitment

    From lab bench to bulk tank, every batch of 2-(Perfluorooctyl)Ethyl Methacrylate reflects trial, verification, and direct contact with the factories depending on it. We see first-hand how the product responds to real-world challenges, whether those concern performance, compliance, or supply stability. Customers benefit from open communication and continuous improvement, not just a formula on paper. In our experience, this direct connection drives both innovation and peace of mind—partners know where their specialty chemistry comes from and what it can do, now and into the future.