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2-Naphthoic Acid

    • Product Name 2-Naphthoic Acid
    • Alias β-Naphthoic acid
    • Einecs 202-096-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    471255

    Chemical Name 2-Naphthoic Acid
    Cas Number 93-09-4
    Molecular Formula C11H8O2
    Molecular Weight 172.18 g/mol
    Appearance White to off-white crystalline powder
    Melting Point 214-216 °C
    Boiling Point 390 °C (decomposes)
    Density 1.344 g/cm³
    Solubility In Water Insoluble
    Solubility In Organic Solvents Soluble in ethanol, ether, benzene, chloroform
    Pka 3.98
    Iupac Name naphthalene-2-carboxylic acid
    Pubchem Cid 7809

    As an accredited 2-Naphthoic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging for 2-Naphthoic Acid (100g) is a sealed amber glass bottle with a tamper-evident cap and clear labeling.
    Shipping 2-Naphthoic Acid is typically shipped in tightly sealed containers to prevent moisture absorption and contamination. It should be stored and transported in a cool, dry, well-ventilated area, away from incompatible substances. Handle with appropriate personal protective equipment. Comply with local and international regulations for the transport of chemicals.
    Storage 2-Naphthoic Acid should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from incompatible substances such as strong oxidizing agents. Keep the container away from sources of ignition and protect from moisture. Store at room temperature, avoiding excessive heat and direct sunlight. Ensure proper labeling and access only to trained personnel to maintain safety.
    Application of 2-Naphthoic Acid

    Applications of 2-Naphthoic Acid in Industrial Manufacturing

    As a direct manufacturer of 2-Naphthoic Acid, we supply this specialty carboxylic acid to critical sectors that demand high-purity intermediates for advanced synthesis. The following industrial scenarios reflect verified downstream uses, focusing on compliance, formulation, production workflow, and end products recognized in global markets.

    1. Synthesis of Optical Brightening Agents (Whitening Fluorescent Dyes)

    Major whitening agent producers utilize 2-naphthoic acid as a cornerstone intermediate in the manufacture of stilbene-based fluorescent dyes for papermaking, textiles, and detergents. Incorporation of this acid follows sulfonation and condensation steps to impart high-brightness characteristics, while meeting industry regulations on purity and trace contaminants in end-use applications.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006 (Europe)
    • China GB/T 12486—Textile Whitening Agent Standards
    • OEKO-TEX® Standard 100 - Class II: Dyes in Contact with Skin
    • FDA 21 CFR 176.170 - Components of Paper and Paperboard in Contact with Food

    Typical usage ratio

    • 5–15% of total dye intermediate batch, adjusted by brightness requirement and downstream condensation route

    Downstream process integration

    • Added during the key condensation phase with stilbene or biphenyl substrates, prior to final sulfonation and granulation

    Final product types

    • Paper and pulp brighteners (OBAs)
    • Textile whitening dyes (mainly for cotton, polyesters, and blends)
    • Laundry detergent fluorescent additives

    2. Intermediate for High-Performance Pigments

    2-naphthoic acid is specifically employed in the synthesis pathway for organic pigments, notably azo and naphthol-based reds and oranges used by coatings, ink, and plastics compounders. Its introduction into the diazotization and coupling sequence controls shade purity, enhances thermal stability, and enables pigment producers to achieve market-driven color performance within regulatory mandates.

    Industry compliance standards

    • EN 71-3: Safety of Toys—Migration of Certain Elements
    • ROHS Directive 2011/65/EU (Restriction of Hazardous Substances)
    • ISO 787-24: General Methods of Test for Pigments and Extenders
    • US FDA 21 CFR 178.3297 (Colorants for Polymers)

    Typical usage ratio

    • 8–20% of coupling component mass, modified based on pigment series (naphthol reds, oranges) and performance requirements

    Downstream process integration

    • Feeds into the coupling step after diazotization, followed by filtration and milling to form the pigment cake; purity impacts disperse stability

    Final product types

    • High-performance organic pigments (Naphthol AS Red, Pigment Red 170, Pigment Orange 5)
    • Inkjet and flexographic inks
    • Masterbatches for plastics and synthetic fibers
    • Automotive and industrial coatings

    3. Raw Material for Pharmaceutical Intermediates

    Chemical manufacturers in the pharmaceutical sector employ 2-naphthoic acid as a key intermediate for synthesizing active pharmaceutical ingredients (APIs) and specialty heterocyclic scaffolds, especially in anti-inflammatory and CNS pipelines. Strict adherence to GMP and validation protocols governs its introduction into multistep, solvent-intensive syntheses, where the acid undergoes activation or cyclization depending on the target API precursor.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice Guidance for Active Pharmaceutical Ingredients
    • WHO GMP Guidelines
    • Ph. Eur. (European Pharmacopoeia) standards for intermediates
    • US FDA cGMP (Title 21 CFR Parts 210 & 211)

    Typical usage ratio

    • Varies from 12–35% of precursor batch weight depending on specific synthetic route and target molecule; routinely modulated via in-process analytical monitoring

    Downstream process integration

    • Introduced as carboxyl component during amide, ester, or lactam formation reactions prior to subsequent ring closures or coupling chemistry; typically followed by purification and solvent switch

    Final product types

    • Pharmaceutical intermediates for nonsteroidal anti-inflammatory drugs
    • Pyridine and isoquinoline derivatives for CNS applications
    • Building blocks for cardiovascular and metabolic drugs

    4. Precursor in Agrochemical Formulations

    Leading agrochemical compounders use 2-naphthoic acid for the synthesis of plant growth regulators and selected selective herbicides, integrating its aromatic carboxylic scaffold in sites that require photostability and systemic activity. Compliance checks throughout toll and in-house synthesis ensure absence of regulated residues and structural analogs as per local agricultural legislation.

    Industry compliance standards

    • FAO/WHO Specifications for Plant Protection Products
    • China GB 2763—National Food Safety Standard Maximum Residue Limits for Pesticides
    • US EPA FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act)
    • REACH Annex XVII—restrictions on chemical residues

    Typical usage ratio

    • 3–10% of core intermediate blend, adjusted based on synthesis route for targeted regulator or herbicide; verified with downstream bioactivity assays

    Downstream process integration

    • Charged into the ring formation or acylation step, typically after halogenation or nitration of aromatic core, before product crystallization and formulation

    Final product types

    • Auxinic plant growth regulators
    • Aromatic ring-based pre- and post-emergence herbicides
    • Intermediate components in bioactive agro formulations for cereals and specialty crops

    5. Advanced Polymer Additive Synthesis

    Chemical processors in the polymer additives industry leverage 2-naphthoic acid for producing stabilizers and UV absorbers, targeting high-performance plastic and rubber compounds. Featuring a rigid aromatic core and functional carboxyl, the acid enters condensation steps that define compatibility and enhance photo-resistance of downstream modifiers—an essential property for automotive, construction, and technical films.

    Industry compliance standards

    • EU Regulation (EU) No 10/2011—Plastics Intended for Food Contact
    • ISO 4892-2:2013 - Plastics—Methods of Exposure to Laboratory Light Sources
    • ISO 1043/1—Plastics and Rubber Standardized Additive Nomenclature
    • UL94 Flammability Tests for Additives in Polymers

    Typical usage ratio

    • 5–18% of intermediate reaction mass in polymer additive precursor; adapts with end-use UV and heat resistance specifications

    Downstream process integration

    • Reacted with alkylating or sulfonating agents during additive core formation, prior to extrusion or solvent blending of additive concentrates

    Final product types

    • Polymeric stabilizer masterbatches
    • UV absorber compounds for polyolefins and engineering plastics
    • Performance additives for elastomer and synthetic rubber goods
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    Certification & Compliance
    More Introduction

    Introducing 2-Naphthoic Acid: A Perspective from Chemical Manufacturing

    Our Approach to 2-Naphthoic Acid

    In the chemical manufacturing industry, every product tells a story about the precision, reliability, and practical benefits that are achieved on the production floor. 2-Naphthoic Acid is a compound that often plays an understated but pivotal role in our clients' processes. Over the years, we have devoted significant resources to refining our methods, recognizing that each batch reflects not only our technical capability but also our commitment to our customers’ goals.

    2-Naphthoic Acid carries the formula C11H8O2 and, as experienced producers, we have learned that purity and consistency define its value in industrial applications. Many colleagues in research and production say that even slight differences in quality can impact their end results. We take every measure to control impurity profiles and batch-to-batch reproducibility, with robust checks from raw material selection through final packaging.

    Product Specifications and Quality Control

    Consistent performance begins with specifications that make sense for real-world chemistry. We supply 2-Naphthoic Acid in the 99%+ purity range, in crystalline powder form, with melting points typically between 240 and 244°C—based on rigorous analytic verification. Moisture control ranks high on our list because excess water content can interfere with downstream applications, especially in organic synthesis or dye intermediates. Typical moisture levels in our shipments are kept well below industry benchmarks.

    People often ask about particle size or solubility. In practice, we see most users requesting a medium-fine powder, finding this grade balances safe handling and optimal reaction rates. The acid shows good solubility in organic solvents like ethanol, ether, and benzene, but resists dissolution in water, which is an important differentiator in formulations that need selective solubility.

    Main Uses: Experience from Industrial Practice

    Years in the industry have shown us the versatility of 2-Naphthoic Acid. As a building block, it streams into several sectors, supporting the synthesis of dyes, pigments, and organic intermediates. Manufacturers in the dye industry often rely on it for creating disperse and vat dyes, because the naphthalene ring structure helps produce stable, vibrant colors when combined with other ingredients. Fine chemical producers use it as a key precursor for more complex aromatic compounds, including certain pharmaceuticals and specialty polymers.

    We frequently receive inquiries from research institutions. They trust our 2-Naphthoic Acid when embarking on catalytic studies and exploring new organic synthetic pathways. Its predictable reactivity allows for repeatable results, especially in carboxylation or condensation reactions.

    Compared to generic naphthoic acids or mixed isomers, the 2-position on the ring system gives unique regioselectivity, which can translate into different product outcomes. For example, many synthetic chemists note that 2-Naphthoic Acid helps them avoid side reactions common with 1-isomers, especially when using strong bases or during heat-intensive steps.

    Distinctions Among Similar Aromatic Acids

    Not all naphthoic acids behave the same in the laboratory or in industrial plants. Over the years, we have engaged in dozens of customer dialogues comparing 2-Naphthoic Acid with other structurally-related aromatics, such as 1-Naphthoic Acid or benzoic acid derivatives. Some chemists expect near-identical behavior, but find that shifting the carboxyl group to the 2-position alters reactivity patterns, solubility, and the propensity for side-product formation.

    One area where 2-Naphthoic Acid stands out is in the synthesis of anthraquinone dyes. The position of the carboxyl group directly influences both color yield and purity. Many plants avoid 1-Naphthoic Acid in these routes, having learned that controlling by-products becomes more challenging during high-temperature steps. By contrast, the 2-isomer supports cleaner conversions and lower impurity loads downstream.

    In applications requiring amide or ester formation, our clients report that 2-Naphthoic Acid demonstrates greater selectivity and fewer processing complications compared to the 1-isomer or benzoic acids. This advantage simplifies purification, shortens reaction times, and minimizes solvent waste—a factor driving both environmental benefits and operating cost savings.

    Production Realities: Raw Materials and Environmental Considerations

    Honing a manufacturing process for 2-Naphthoic Acid requires careful raw material selection and waste management. We source naphthalene feedstocks with traceability in mind, prioritizing those with fewer polycyclic aromatic impurities. Oxidation control is crucial; excess oxidants can create unwanted over-oxidized by-products or lower the overall yield. In our plant, technicians follow strict protocols to maintain optimal temperature and oxygen levels through every stage.

    Sustainability is a growing concern among clients, especially those exporting to regions with strict regulatory regimes. By investing in real-time emissions monitoring, closed-loop solvent recovery, and solid waste reduction, we cut down both environmental risks and production costs. Sharing transparent data with our partners fosters trust, and improves the industry as a whole.

    Challenges in Consistency and Scale-Up

    Scaling up from pilot batches to full-scale production often exposes hidden difficulties. We have learned that solvent selection and reaction time adjustments can have significant effects on yield and particle morphology. Inconsistent agitation or subpar crystallization steps lead directly to off-spec product. Real-world experience taught us the value of hands-on operator oversight, not just relying on automation or theoretical models.

    Clients involved in pharmaceuticals and electronics frequently seek tighter impurity profiles than bulk dye manufacturers. Maintaining batch-to-batch traceability is not optional here. We employ advanced HPLC and GC methods to monitor trace-level contaminants. Learning from earlier years, we fine-tuned drying and filtration methods to prevent cross-contamination with other aromatic acids, and to protect product integrity against airborne particulates during packing.

    Packaging, Handling, and Storage

    In daily operations, the way product moves from our final reactors to the customer site matters as much as the chemistry. Fine crystalline powders like 2-Naphthoic Acid demand careful handling to avoid clumping or dust. We rely on lined fiber drums and sealed PE bags, making the container selection based on real feedback from logistics partners and users. Most end-users want bulk packaging between 25-50kg, based on handling equipment and inventory throughput.

    Safe transport comes down to environmental control and labeling clarity. Over the years, we have responded to multiple requests for anti-static lining and moisture-proof layers, particularly for long-distance or cross-border shipments. Shelf life remains stable for at least a year in unopened containers stored in cool, dry conditions. Still, periodic batch testing remains a non-negotiable to ensure performance on arrival.

    Practical Advice for Safe and Efficient Use

    Clients new to 2-Naphthoic Acid sometimes underestimate the need for PPE and effective dust control. The compound doesn’t carry the same acute hazards as stronger acids or solvents, but repeated exposure to aromatic acids calls for respect. Proper local exhaust, gloves, and face protection keep employees safe—this advice comes not only from regulations but from firsthand cases where preventable mishaps occurred.

    We emphasize the importance of accurate weighing, especially in small- to mid-scale syntheses, since even small deviations influence yield and downstream purification. Experience has shown that gradual charging into well-agitated solvents yields more manageable reaction profiles and cuts down on clumping or foaming. Avoiding excess heat helps maintain product stability, particularly in continuous processing setups.

    Case Studies: Industry Applications

    Dye manufacturing provides one of the clearest illustrations of 2-Naphthoic Acid’s impact. One major plant shifted from a blend of isomers to our product, aiming to simplify their purification and avoid recurring color inconsistencies. Within six months, they saw a 12% increase in product yield and lower waste, along with positive feedback from downstream textile clients who remarked on the consistency of batch coloration.

    The pharmaceutical sector presents a different set of challenges and benefits. In the case of non-steroidal drug synthesis, one production team standardized on our high-purity 2-Naphthoic Acid as an intermediate. Their switch focused on reducing potential nitrosamine precursors, a point of increasing regulatory scrutiny worldwide. Process simplification led not just to cost reduction, but also to faster regulatory approval due to lower impurity levels.

    Specialty polymers provide another success story. One customer in engineering plastics found that 2-Naphthoic Acid helped produce high thermal stability grades, thanks to its aromatic ring. This property became a differentiator in their automotive segment, opening new lines of product development previously out of reach due to lower-temperature alternatives.

    Supply Chain Resilience and Customer Support

    Few products exist in isolation from global trends. We have seen how shifts in raw material pricing, shipping bottlenecks, and regulatory changes affect not only us, but also our customers’ production plans. We commit to holding core stocks of 2-Naphthoic Acid at strategic sites and communicating transparently if supply chain pressures emerge. This policy arose from years of feedback when global logistics were less predictable.

    Routine technical support stands as another key part of our service. Our chemists assist partners with troubleshooting, optimizing process parameters to make the best use of product properties. From solubility questions to waste minimization advice, our willingness to share practical know-how often prevents costly trial and error on the customer end.

    Looking Ahead: Market Trends and R&D Investment

    The future for 2-Naphthoic Acid relates closely to advances in downstream industries. As dye standards evolve, especially with ecological impact tracking, our R&D team remains focused on even tighter impurity controls and alternatives for solvent recovery. For pharmaceutical and specialty chemical makers, the drive for higher specificity and regulatory compliance steers us toward more precise analytical controls and traceability reporting.

    We collaborate directly with university labs and industrial partners, making our plant available for pilot runs when required. Co-development programs target greener synthesis methods and innovative end-uses for 2-Naphthoic Acid and its derivatives. Our belief in open technical collaboration has led to several co-patented processes that raise the bar for both efficiency and environmental responsibility.

    Commitment to Responsible Manufacturing

    Sustainable production forms the backbone of our operation. We take participation in local audits, international certification, and continual operator training as non-negotiable. Many customers share these priorities, and together, we advance best practices in safe handling, waste minimization, and product stewardship. Over time, such principles lead not just to compliance, but to improved reliability and mutual trust across the value chain.

    2-Naphthoic Acid will continue to play a foundational role in numerous sectors, from colorants to specialty chemicals and advanced materials. Our ongoing investment in technology, people, and partnership ensures that every shipment reflects both the science of chemistry and the art of collaboration. By sharing our knowledge and learning from each customer’s feedback, we seek not just to supply a product, but to strengthen the bond between real-world manufacturing and technological progress.