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2-(Methacryloyloxy)Ethyl Acetoacetate

    • Product Name 2-(Methacryloyloxy)Ethyl Acetoacetate
    • Alias AAEM
    • Einecs '246-934-1'
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    923356

    Cas Number 21282-97-3
    Molecular Formula C10H14O5
    Molecular Weight 214.22 g/mol
    Appearance Colorless to pale yellow liquid
    Purity Typically ≥ 98%
    Boiling Point 252.8 °C at 760 mmHg
    Density 1.144 g/cm³ at 25°C
    Refractive Index n20/D 1.462
    Flash Point 107 °C
    Solubility Slightly soluble in water, soluble in organic solvents (e.g., methanol, acetone)
    Storage Conditions Store in a cool, dry place, protect from light and moisture
    Synonyms 2-(Methacryloyloxy)ethyl acetoacetate; Acetoacetic acid 2-(methacryloyloxy)ethyl ester

    As an accredited 2-(Methacryloyloxy)Ethyl Acetoacetate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The chemical is typically packaged in a 500g amber glass bottle with a secure screw cap and labeled for laboratory use.
    Shipping 2-(Methacryloyloxy)Ethyl Acetoacetate is shipped in tightly sealed containers, protected from light and moisture. It is typically transported at ambient temperature but away from heat sources and oxidizing agents. Classified as a non-hazardous liquid for shipping, standard chemical handling procedures and proper labeling must be followed during transit and storage.
    Storage 2-(Methacryloyloxy)Ethyl Acetoacetate should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from sources of ignition. Protect from light, heat, and moisture. Keep the chemical away from incompatible substances such as strong oxidizers and acids. Store under inert gas if possible, and observe all applicable chemical storage regulations and safety guidelines.
    Application of 2-(Methacryloyloxy)Ethyl Acetoacetate

    Applications of 2-(Methacryloyloxy)Ethyl Acetoacetate in Industrial Manufacturing

    As the direct manufacturer of 2-(Methacryloyloxy)ethyl acetoacetate, we supply this specialty monomer to multiple advanced downstream sectors where precise formulation, strict adherence to regulatory frameworks, and process reproducibility are paramount. Below, we outline the primary industrial domains where this monomer is utilized, detailing standards compliance, exact formulation recommendations, production workflow integration, and typical end products derived from each application.

    1. Radiation Curable Coatings for Electronics

    Leading electronics manufacturers adopt this monomer for UV and electron-beam curable coatings used on device assemblies, display components, and microcircuit protection. Its unique acetoacetoxy group introduces enhanced crosslink density, delivering coatings with superior chemical resistance and minimized outgassing to meet advanced device reliability criteria.

    Industry compliance standards

    • IEC 61086 (Coating Materials for Electrical and Electronic Applications)
    • RoHS Directive (2011/65/EU, Restriction of Hazardous Substances)
    • IPC-CC-830B (Conformal Coating Qualification and Performance)
    • REACH Regulation (EC No. 1907/2006)

    Typical usage ratio

    • 3.0–8.0% by weight of total monomers, adjusted for target film hardness and elongation based on substrate sensitivity and desired cure profile

    Downstream process integration

    • Pre-blended into oligomer and monomer mixtures before UV or EB curing; introduced during low-shear mixing at ambient temperature to prevent premature polymerization; follows with pigment/additive incorporation prior to on-line coating and irradiation

    Final product types

    • Conformal coatings for printed circuit boards (PCBs)
    • Protective layers on touch screens and sensor films
    • Barrier coatings for microelectronics modules

    2. Industrial Adhesives for Plastics Processing

    Specialty adhesives based on this monomer demonstrate tough, low-yellowing bonds and controlled open times, supporting the fabrication of automotive components, consumer electronics, and white goods plastics. Its reactivity enables compounding of pressure-sensitive and structural adhesive systems with elevated thermal and chemical resistance.

    Industry compliance standards

    • ISO 4587 (Shear Strength of Adhesives on Rigid Plastics)
    • ASTM D1002 (Lap Shear Strength of Metal-Adhesive Bonds)
    • GMW16122 (General Motors' Adhesive Performance Standards)
    • REACH Regulation (EC No. 1907/2006)

    Typical usage ratio

    • 2.5–7.0% by weight in acrylic adhesive matrix; tuning depends on final viscosity and green strength requirements for chosen substrate types

    Downstream process integration

    • Introduced after base acrylic prepolymer synthesis and pre-dispersion of fillers; dosed during the reactive compounding stage before crosslinker and initiator addition; followed by vacuum degassing and packaging for downstream assembly use

    Final product types

    • Pressure-sensitive tapes and films for automotive interiors
    • Structural bonding agents for composite or thermoplastic panels
    • Assembly adhesives for consumer electronic housings

    3. High-Performance Waterborne Acrylic Resins

    Producers of waterborne architectural and industrial coatings incorporate this monomer to improve film-forming properties and resistance to chemical staining. Its keto functionality also boosts pigment dispersion stability, helping formulators achieve enhanced gloss retention in high-durability coatings for infrastructure and commercial projects.

    Industry compliance standards

    • GB/T 9755 (Chinese Standard for Synthetic Resin Emulsion Coatings)
    • ASTM D6886 (VOC Content of Paints and Coatings by GC-MS)
    • EN 13300 (Classification of Interior Paints by EN Standards)
    • US EPA 40 CFR Part 59 (National Volatile Organic Compound Emission Standards for Consumer Products)

    Typical usage ratio

    • 1.0–4.0% by weight of resin solids, tailored according to required balance of water resistance, gloss, and open time

    Downstream process integration

    • Added during seed emulsion phase of batch or semi-continuous emulsion polymerization; follows surfactant and buffer charging, preceding primary monomer feed for consistent core-shell structure development

    Final product types

    • Low-VOC architectural wall paints
    • High-gloss industrial coatings for metal or concrete
    • Anti-fouling coatings for exterior infrastructure

    4. Functional Acrylic Resins for Inkjet Inks

    Manufacturers of high-definition digital inkjet inks utilize this monomer to develop resins exhibiting excellent wettability on both porous and non-porous substrates. The acetoacetoxy group increases compatibility with a wide pigment range while improving ink curing rates and decreasing migration in printed packaging.

    Industry compliance standards

    • EN 71-3 (European Migration Standard for Printing Inks on Toys)
    • Swiss Ordinance SR 817.023.21 (Materials in Contact with Food for Packaging Inks)
    • EuPIA GMP (Good Manufacturing Practice for Printing Inks)
    • ISO 2846-1 (Color and Transparency of Printing Inks)

    Typical usage ratio

    • 2.0–5.0% by weight of binder solids; ratio adjusted based on solvent balance for desired print resolution and finish drying speed

    Downstream process integration

    • Post-polymerization addition to acrylic resin solutions; mixed thoroughly with pigment dispersions prior to viscosity adjustment and filtration, then filled in ink reservoirs for industrial digital printing lines

    Final product types

    • High-speed inkjet inks for carton and label printing
    • Direct-to-object inks for packaging and promotional goods
    • Functional barrier inks for flexible food packaging films

    5. Crosslinking Agents in Waterborne Polyurethane Dispersions

    Producers of waterborne polyurethane coatings leverage this monomer as a reactive modifying ingredient to enhance crosslinking capability and improve scratch and solvent resistance. The active methacryloyl and acetoacetoxy functionalities enable formation of high-density, flexible networks, which suit demanding automotive and wood finishing applications.

    Industry compliance standards

    • DIN EN 71-3 (Safety of Toys—Migration of Certain Elements for Coatings)
    • GB 18582 (Chinese National Standard for Indoor Decorative Materials)
    • ISO 7783 (Water Vapour Permeability for Coating Materials)
    • Directive 2004/42/CE (EU VOC Requirements for Coatings)

    Typical usage ratio

    • 0.5–2.0% by weight, adjusted in the chain extension or prepolymer crosslinking step, depending on targeted film hardness and coating thickness

    Downstream process integration

    • Added during the polyurethane prepolymer chain extension phase; subsequently dispersed in aqueous medium with emulsifiers, and incorporated before final neutralization and storage

    Final product types

    • Automotive refinishing clear coats
    • Industrial wood floor varnishes
    • Protective topcoats for flexible PVC substrates

    6. Photopolymer Printing Plate Manufacturing

    Manufacturers of flexographic and letterpress photopolymer printing plates employ this monomer for enhanced post-cure stability and defined image reproduction. The monomer’s structure facilitates efficient copolymerization, contributing to higher crosslinking upon exposure and improved plate longevity under repeated press cycles.

    Industry compliance standards

    • ISO 12636 (Flexographic Printing Plates—General Requirements)
    • FLEXO Global Technical Guidelines (FLEXO Europe)
    • RoHS Directive (2011/65/EU for non-metal plate components)
    • REACH Regulation (EC No. 1907/2006)

    Typical usage ratio

    • 1.5–4.0% by weight in photopolymer resin formulations, optimized for plate thickness and exposure speed during imaging

    Downstream process integration

    • Pre-mixed into photo-reactive resin blends after oligomer selection; processed with photosensitizers prior to casting and UV exposure for polymer network development

    Final product types

    • Flexographic printing plates for packaging films
    • Letterpress plates for security and label printing
    • Digital laser-engraved photopolymer plates
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    Certification & Compliance
    More Introduction

    Introducing 2-(Methacryloyloxy)Ethyl Acetoacetate: Reliability and Performance From the Source

    Meeting Real-World Demands with Consistent Chemistry

    Working every day on the shop floor and in the production lab, we see firsthand how certain specialty chemicals can make or break downstream processes. 2-(Methacryloyloxy)Ethyl Acetoacetate, often abbreviated as 2-MEA, serves as an essential monomer in our line, widely adopted for innovating coatings, adhesives, inks, and specialty resins. With each batch, we've seen end-users benefit from its stable structure and reactivity, supporting polymer systems that need both durability and flexibility. Achieving consistent performance starts right with the careful design and execution during synthesis—something we control every step of the way.

    Product Overview and Specification Insights

    2-MEA arrives to our partners in liquid form. The model we provide delivers ≥98% assay by gas chromatography, and impurity levels, especially free acid and water, consistently fall below 0.5% by weight. Boiling point stands near 295°C at 760 mmHg, and density aligns with 1.13 g/cm³ at room temperature. From temperature-sensitive handling to tailored container sizes, every choice has grown out of feedback we've received from coating engineers and plant managers. We bottle, seal, and transport this product using methods proven to shield against hydrolysis and preserve shelf life; we've also adapted materials of construction to limit leaching and interaction during storage. This hands-on involvement makes a difference for formulators watching for yellowing or unwanted viscosity drift in their blends.

    Advantageous Chemical Behavior Shaped by Manufacturing Know-How

    Many monomers crowd today’s raw materials palette, but only a few combine both the methacrylate and acetoacetate functions in a single molecule. With 2-MEA, the combination leads to real results in crosslinking and adhesion—outperforming similar monomers in multi-component polymerization. The methacryloyloxy group lets it take part in free-radical curing just like methyl methacrylate or HEMA, but the acetoacetate moiety, rarely matched by other monomers, supports additional chemistry. We have customers in wood and metal coatings who’ve seen these effects in stronger chemical bonds and greater scratch resistance.

    Manufacturers often juggle between acetoacetate-functional acrylates and methacrylate monomers for the same job. From our observation, 2-MEA acts as a molecular bridge. Some engineers in our network seek a more hydrolytically-stable methacrylate backbone; others are after the keto-enol tautomerism that acetoacetate brings to the table. We see better dispersibility of pigments, improved toughness in automotive refinish coatings, and more effective adhesion to glass, metal, and engineered wood. The end products remain clear and stable, without the cloudiness or premature degradation linked to lower-purity or mismatched alternatives. That feedback seems to echo through both small-scale and high-volume polymer plants we serve.

    Supporting Cleaner, Greener, Longer-Lasting Formulations

    Sustainability and health concerns drive a lot of decision-making today. With changing environmental regulations, raw material lists are under constant review by EHS departments, and we keep a close watch on both global and local standards. 2-MEA’s low residual monomer content and low odor lend it an advantage in both workplace safety and product sustainability. This enables safer handling for users on the floor—glove, mask, and eyewash still standard, but fewer complaints about strong fumes or skin irritation. Lower migration means less risk for end-users, especially as more of our customers move toward low-VOC and waterborne systems.

    From a green chemistry angle, 2-MEA can serve as a replacement for some higher-toxicity or less-reactive monomers. Downstream, this facilitates production of crosslinked polymers that retain performance longer under UV or chemical exposure. As a result, we notice coatings that require fewer reapplications and hold up in more demanding settings. With every cycle, end users reduce waste through better durability, and the entire value chain cuts down on emissions and disposal frequency. Long-term partnerships with resin formulators prove how the right chemistry pays off in reduced environmental impact.

    Process Perspective: Why Quality Control Makes All the Difference

    A monomer’s reputation quickly grows or falters based on batch-to-batch uniformity, ease of handling, and documentation of every impurity. During our production, we sample continuously for common offenders—free acid, water, residual solvents—using in-house GC and moisture analyzers. Spotting a slight spike in a chromatogram, we tweak our purification, never waiting for customer complaints before we act. Our chemists know the trouble poor purity brings: unexpected crosslinking, haze in clear films, or failed QC tests at a customer’s receiving dock.

    We take pride in the ongoing dialogue with end users who manage large-scale reactors or formulation lines under tight schedules. Several partners even share feedback via our online portal describing smoother reactions, less gelation, and easier cleanup when using our 2-MEA. No one can afford plant downtime from clogged lines or off-spec product. Years of technical support, troubleshooting, and on-the-ground visits have given our engineers an evolving map of how minute differences in purity or moisture content can have outsized impact downstream.

    Application Experience: Where 2-MEA Excels

    The truth arrives every week in field results. End users rely on 2-MEA to bring together tough yet workable resins for automotive topcoats, marine finishes, flooring, and pressure-sensitive applications. Many of our partners working in inkjet and digital printing applications specify this monomer for its ability to provide rapid curing, deep color saturation, and long open pot life. Formulators working with glass fiber composites or advanced laminates report more reliable fiber-matrix interactions and higher impact resistance by integrating 2-MEA into their systems.

    Our own process teams have developed best-practices guides showing the optimum initiator doses, UV lamp setups, and copolymerization ratios for a wide range of uses. Based on shared pilot trials, we’ve seen strong compatibility with acrylated resins, styrene, and a growing list of new biobased intermediates. End-use feedback often highlights better leveling, fewer pinholes, and enhanced weatherability—features not reached with simple methacrylate or acrylate monomers.

    For adhesives, 2-MEA’s mix of flexibility and adhesion delivers value, especially in electronic device assembly, filter manufacturing, and construction sealant applications. We’ve seen some clients refine their processes to cut primer steps entirely when 2-MEA-modified adhesives easily wet complex substrates. This offers time and materials savings right at the end-user’s line. In the polymer-modified cement sector, the unique balance between crosslink density and film toughness stands out, especially for repair mortars, bridge decks, and waterproofing membranes.

    Comparing 2-MEA With Other Monomer Choices

    Across countless production meetings, people often ask us to compare 2-MEA to other popular monomers like hydroxyethyl methacrylate (HEMA), methyl methacrylate (MMA), or plain ethyl acetoacetate. MMA delivers high hardness but less functional diversity and sometimes excessive brittleness. HEMA’s popularity in contact lens and dental resins stems from its hydrophilicity, but it lacks the acetoacetate reactivity that brings lasting adhesion and crosslink potential. Both MMA and HEMA cannot match the reactivity of the acetoacetate group when advanced crosslinking or chelation are required.

    Other acetoacetate-functional acrylates exist, such as acetoacetoxyethyl acrylate (AAEA). We produce both and can lay out the practicality of each. Acrylate-based options display slightly higher reactivity but tend to yellow and degrade under certain light or heat exposures. Methacrylate derivatives such as 2-MEA show more storage stability and deliver a desirable balance of cure speed and resistance properties, especially where clarity is critical. What end-users often realize through experience is that 2-MEA stands out when clarity, color stability, and multipurpose reactivity must be delivered without trading away the benefits of easy processing or formulation freedom.

    Custom Solutions Powered by Technical Partnerships

    Over the years, our relationships have expanded from simple product supply to deep cooperation on new application developments. This means collaborating in real time to tweak molecular weight, loading ratios, or addition order so clients achieve just the right elasticity, resilience, or cure rate. Technical specialists from our plants have traveled with team members from customer facilities during launches of new architectural coatings, screen print formulations, or 2K PU systems. Site visits allow us to troubleshoot directly on the line, see first-hand where separation, foam, or cloudiness may appear, and work shoulder-to-shoulder to get things right.

    We also lend our expertise to pilot testing, helping partners move from bench-scale to full production. With every new project, we test for potential regulatory shifts (REACH, TSCA, etc), labeling updates, or hazard changes to keep our product up to date with customer certification needs. Years of experience in shipping and warehousing chemical intermediates help us anticipate the unexpected, from regulatory audits to emergency supply challenges. Our best practices arise from countless real-world lessons—never a template, always shaped by what lasts and performs best.

    Field-Tested for Your Manufacturing Reality

    2-(Methacryloyloxy)Ethyl Acetoacetate, made in our own reactors and with the oversight of our own QC staff, demonstrates its value not simply in test tubes, but in the hands of the plant crews, the operators, and the researchers who call on it. Our staff knows the real risks that lower-quality or poorly tracked raw materials can introduce—extended downtime, unexpected failures, or rework expenses.

    We serve operations large and small, from multinational polymers corporations to smaller regional resin shops. Since every operation has its own challenges with storage, batching, measurement, and safety, we design logistical solutions to ease worries over temperature control, spill response, and shelf-life management. High-purity batches, robust packaging, and route-specific delivery systems all add up to less waste, faster throughput, and better final yields at customer operations.

    For us, trust builds over countless shipments and open conversations. Multiple customers have asked for third-party audits, and we welcome them—because transparency and open reporting have boosted our standing with partners, regulatory bodies, and internal safety teams.

    Moving Forward: Knowledge, Service, and Consistency

    Chemistry keeps evolving, and every month we learn more from our partners about how 2-MEA unlocks properties in next-generation formulations: tougher floors, longer-lasting paints, smarter adhesives, and more eco-friendly construction products. We see the market shifting toward higher specificity and more performance from every chemical input, making the experience of the supplier just as important as purity and price.

    Manufacturers everywhere feel the squeeze from tighter regulations, stricter customer expectations, and the need to offer products with longer life and better safety numbers. By controlling our process from raw material sourcing through finished product logistics, we support these aims.

    We keep working with you to solve formulation puzzles, respond quickly to line issues, and provide real feedback on how to get the best from 2-(Methacryloyloxy)Ethyl Acetoacetate. Every application—whether a demanding automotive topcoat, a key structural adhesive, or an innovative clear wood finish—offers a new lesson in where this monomer can take us all next.