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2-Ethyl-1-Hexanethiol

    • Product Name 2-Ethyl-1-Hexanethiol
    • Alias 2-EHT
    • Einecs 211-234-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    877861

    Chemical Name 2-Ethyl-1-hexanethiol
    Cas Number 15520-10-2
    Molecular Formula C8H18S
    Molecular Weight 146.30 g/mol
    Appearance Colorless to yellowish liquid
    Odor Strong, unpleasant thiol odor
    Boiling Point 188-191°C
    Melting Point -65°C (approx.)
    Density 0.845 g/cm3 (at 20°C)
    Refractive Index 1.452 (at 20°C)
    Flash Point 73°C (closed cup)
    Solubility Insoluble in water; soluble in organic solvents
    Vapor Pressure 1.5 mmHg (at 25°C)
    Purity Typically ≥98%
    Synonyms 2-Ethylhexane-1-thiol

    As an accredited 2-Ethyl-1-Hexanethiol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle containing 500 mL of 2-Ethyl-1-Hexanethiol, sealed with a screw cap and hazard labeling.
    Shipping **2-Ethyl-1-Hexanethiol** is shipped in tightly sealed containers, typically made of glass or high-density polyethylene, to prevent leaks and exposure. It should be handled with caution as it is flammable and has a strong odor. Proper labeling and compliance with transportation regulations for hazardous chemicals are required during shipping.
    Storage 2-Ethyl-1-Hexanethiol should be stored in a cool, dry, well-ventilated area, away from heat, open flames, and incompatible substances such as oxidizing agents. Keep the container tightly closed and properly labeled. Store in a corrosion-resistant container, as the chemical may react with metals. Avoid exposure to moisture and direct sunlight to prevent degradation and ensure safety.
    Application of 2-Ethyl-1-Hexanethiol

    Applications of 2-Ethyl-1-Hexanethiol in Industrial Manufacturing

    2-Ethyl-1-Hexanethiol serves as a key C8 mercaptan intermediate in multiple chemical production sectors. As an original manufacturer, we support high-volume and custom-grade supply for critical downstream processes where sulfur-containing groups are essential to performance, reactivity, or process control. Below are the principal application scenarios with specific technical notes for industrial users.

    1. Polymerization Chain Transfer in Emulsion Polymer Production

    Industrial polymer producers deploy 2-Ethyl-1-Hexanethiol as a chain transfer agent to manage molecular weight and particle properties in emulsion polymerization systems. This mercaptan structure benefits acrylate, styrene, and SBR latexes by providing targeted polymer properties matched to film application and binding performance. Its reactive functionality allows precise adjustment of chain length in the aqueous phase. Processing engineers dose this thiol in controlled ratios in the reactor, directly affecting MWD (molecular weight distribution) and branching—resulting in reproducible batch qualities for pressure-sensitive adhesives, coatings, and paper impregnation.

    Industry compliance standards

    • REACH registration (EC 1907/2006) for manufacturing/import/use in Europe
    • TSCA inventory listing for US production and import compliance
    • ISO 9001 and ISO 14001 quality and environmental management for producer validation
    • Compliance with RoHS Directive 2011/65/EU for electrical component adhesives

    Typical usage ratio

    • 0.05%–0.5% by weight of total monomer in latex formulations
    • Ratio adjusted based on target viscosity, monomer type, and desired glass transition temperature
    • Lower ratios for high-strength binders, higher end for softer acrylic dispersions
    • Addition required at early or staged feed for consistent batch-to-batch results

    Downstream process integration

    • Charged directly into pre-emulsion or seed latex phase
    • Metered in with monomers during continuous or semi-batch polymerization
    • In-line mixing with surfactants to ensure uniform distribution before polymerization
    • Residual control by stripping or post-polymerization neutralization

    Final product types

    • Pressure-sensitive adhesive emulsions for labels and tapes
    • Paper and textile binders used in nonwoven manufacturing
    • Latex paints and architectural coatings
    • Co-monomer for tire cord adhesives in SBR-based formulations

    2. Synthesis of Metal Extractants for Mining and Hydrometallurgy

    Specialty extractant manufacturers utilize 2-Ethyl-1-Hexanethiol as a critical thiol precursor for metal chelation agents. The thiol group provides sulfur affinity for noble and heavy metals, enabling the development of selective organic extractants employed in solvent extraction units. Process chemists synthesize these organosulfur compounds via alkylation or functionalization of the thiol, achieving targeted selectivity for copper, nickel, or precious metal ion separation. Controlled functional group integration improves phase separation and strip efficiency in closed-loop hydrometallurgical operations.

    Industry compliance standards

    • OECD guidelines for new chemical assessment in mining applications
    • EPA TSCA Section 5 (USA) new use reporting for mining chemicals
    • Certified analytical purity under ISO 17025 for quality traceability
    • Material compatibility confirmation under ISO 11114-1 for chemical equipment

    Typical usage ratio

    • Thiols typically incorporated at 10–30% by weight in extractant product formula
    • Extraction agent loading depends on ore composition and targeted selectivity
    • Adjustments according to pH and aqueous/organic phase ratios
    • Concentration refined in pilot trials to optimize metal loading and phase transfer

    Downstream process integration

    • Used as a raw intermediate in multi-step synthesis of extractant molecules
    • Formulated in organic phases for use in mixer-settler or SX/EW circuits
    • Metal-loaded extractant fed to stripping operations for metal recovery
    • Supports closed-loop process engineering, minimizing waste and reagent loss

    Final product types

    • Copper, nickel, cobalt and precious metal extractants
    • Organic phase reagents for SX (solvent extraction) plants
    • Ion-selective separation agents for precious metal refining
    • Hydrometallurgical dissolution and separation aids for rare earth processing

    3. Auxiliary Agent in High-Performance Lubricant Additives

    In the lubricant formulation sector, additive developers incorporate 2-Ethyl-1-Hexanethiol as a sulfur donor in the manufacture of high-pressure and anti-wear additives. The thiol moiety reacts in thioesterification or oxidative coupling to form sulfurized derivatives, such as sulfide-containing esters or thioethers, that enhance load-carrying and anti-scuffing behavior in metalworking fluids or gear oils. Quality control specialists analyze sulfur content and active fraction post-reaction by potentiometric titration and chromatography, ensuring efficacy for demanding industrial and automotive lubrication conditions.

    Industry compliance standards

    • API/ASTM D5185 for additive and finished lubricant sulfur content
    • ACEA and ILSAC specifications for engine oils
    • ISO 9001 traceability in additive manufacturing
    • Registration under REACH and TSCA for additive ingredients

    Typical usage ratio

    • 2–8% by weight in additive concentrates (depending on target sulfur level)
    • Formulated as 0.2–2% in finished lubricant after blending
    • Ratio selected based on tribology lab test results and engine specification
    • Adjustment according to compatibility with base oil and co-additives

    Downstream process integration

    • Reacted in batch sulfidation processes for thioester and thioether synthesis
    • Formulated into calcium or zinc-based anti-wear additive packages
    • Dosed in concentrate or top-treated before homogenization in base oil
    • Monitored for active sulfur by wet chemistry analysis prior to blending

    Final product types

    • Automotive engine and transmission oils with enhanced EP/AW properties
    • Industrial gear oils and hydraulic fluids
    • Metalworking lubricants for machining and stamping
    • Greases for heavy equipment and energy sector machinery

    4. Intermediate in Custom Agrochemical Synthesis

    Chemical synthesis laboratories and contract agrochemical companies employ this thiol as a building block for specialty pesticides, especially for organosulfur herbicide and fungicide active ingredients. The mercaptan group provides the necessary reactivity for acylation, alkylation, or oxidative coupling reactions during active ingredient synthesis. Formulation chemists use real-time NMR and LC-MS monitoring to optimize conversions and minimize by-product formation. The modular C8 backbone enables tailored molecular design for selective crop protection products and low environmental persistence profiles.

    Industry compliance standards

    • EU Regulation (EC) No 1107/2009 on the placing of plant protection products
    • US EPA 40 CFR Part 180 for pesticide active registration
    • Good Laboratory Practice (GLP) OECD 21 for active synthesis
    • ISO 9001 for active ingredient supply chain quality management

    Typical usage ratio

    • 5–25% by weight for specialty intermediates in multistep active substance synthesis
    • Ratio adapted based on route selection and desired yield per batch
    • Adjusted to minimize formation of side products in closed reactor systems
    • Optimization based on pilot plant data from lab scale-up

    Downstream process integration

    • Charged as key thiol intermediate in the formation of S-containing heterocycles
    • Used in one-pot or two-step condensation with aromatic or alkylating agents
    • Purification by distillation or crystallization before formulation
    • Tested for active sulfur and purity to meet regulatory data package requirements

    Final product types

    • Custom organosulfur herbicide and fungicide active ingredients
    • Precursor for thiocarbamate or dithiocarbamate crop protection products
    • Intermediate for niche insecticidal compounds with targeted action
    • Sulfurated adjuvants in advanced agrochemical formulations

    5. Specialty Chemical Synthesis for Flotation Reagents in Mineral Processing

    Reagent manufacturers targeting the mining sector use this C8-thiol as a functional intermediate in the synthesis of xanthate and dithiophosphate flotation agents. The strong sulfur-metal interaction facilitates selective separation of sulfide ores in copper, lead, and zinc beneficiation operations. In process plants, reagent engineers convert this mercaptan into functionalized sulfur compounds, optimizing hydrophobicity, solubility, and selectivity for flotation performance. Quality assurance teams control the resulting reagent’s purity and stability through HPLC and Karl Fischer testing, supporting efficient ore/slag separation under industrial scale constraints.

    Industry compliance standards

    • REACH Annex II requirements for manufacture and use in mineral chemicals
    • ISO 9001 for reagent manufacture QA/QC
    • US EPA requirements for copper, lead, and zinc beneficiation chemical registration
    • MSHA and OSHA chemical safety standards for flotation circuit use

    Typical usage ratio

    • 5–15% by weight as a precursor in reagent synthesis
    • Final dosing in flotation cells typically at 0.01–0.05% w/v of pulp volume
    • Adjustment based on ore sulfide fraction and desired selectivity window
    • Process engineers confirm final ratio in bench piloting before full-scale adoption

    Downstream process integration

    • Synthesized into dithiophosphate or xanthate reagents by sulfurization or phosphorylation
    • Blended with auxiliary surfactants for improved bubble–particle attachment
    • Dosed into pulp stream upstream of flotation cells
    • Residual monitored in tailing discharge for environmental compliance

    Final product types

    • Copper, lead, and zinc flotation collectors
    • Dithiophosphate and xanthate reagents for mineral beneficiation
    • Specialty flotation reagents for precious and rare earth ore processing
    • Sulfur-based process promoters used in complex sulfide mineral systems
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    Certification & Compliance
    More Introduction

    Introducing 2-Ethyl-1-Hexanethiol: A Practical Look from the Manufacturer’s Floor

    A Real-World Take on 2-Ethyl-1-Hexanethiol

    From our experience on the manufacturing floor, daily work with 2-Ethyl-1-Hexanethiol offers perspective beyond what you’ll find in catalog entries or generic technical briefs. The substance stands out in our lineup for how it performs and interacts with other materials, and decades working with its production and application teach you why precise chemistry matters in everyday industry.

    Chemical Profile and Production Consistency

    2-Ethyl-1-Hexanethiol falls under the family of alkyl thiols, and what sets it apart begins with its chemical structure. This particular molecule contains an eight-carbon skeleton with a straight chain capped by a thiol group. That configuration gives the liquid a sharp, recognizable odor, and a broad reactivity profile. In our facility, we maintain strict control over purity — not just for specification sheet compliance but so users see the same performance batch after batch. Small traces of sulfur-based byproducts or related alcohols change how it behaves in the field, especially in sensitive downstream processes like organic synthesis, so keeping these at bay forms a foundation of quality.

    Typical product shipped from our lines sits between 98% and 99.5% assay. Water and acidity (as measured by acid value) stay below low thresholds, because early customers taught us that even minor hydrolysis spoils a catalyst system or throws off sensitive polymer chemistry. Color is monitored too, as discolored product often points to degradation or metal catalyst remnants, recognized by those who troubleshoot fouling reactors or blocked filters.

    Industrial Uses Shaped by Experience

    Most requests for 2-Ethyl-1-Hexanethiol we see come from polymerization initiators, lubricant additive makers, and surfactant synthesis. Industry often overlooks how even slight impurities or moisture content influence reactions. For example, in synthesizing metal extraction reagents, the thiol group must react in full—no side reactions allowed. Chromatography and evaporation tests in our quality lab show how batch consistency determines yield and shelf life for those customers, so our teams run checks accordingly.

    In lubricant chemistry, 2-Ethyl-1-Hexanethiol plays a dual role: it helps with extreme pressure performance and acts as a corrosion inhibitor. It takes only a small touch of uncontrolled sulfur content to push a gear oil from smooth operation into corrosion territory, so our process engineers work closely with additive manufacturers to test and refine blends. In polymerization, particularly in emulsion systems, chemists rely on the precise chain transfer capability of this compound to achieve targeted molecular weights and branching. We have learned that small differences in purity show up as inconsistent product properties, traced back to the quality of starting thiols—an issue we address at the source.

    Comparisons That Matter: What Sets 2-Ethyl-1-Hexanethiol Apart

    Compared to more common thiols such as n-hexanethiol or the shorter chain 1-butanethiol, working with 2-Ethyl-1-Hexanethiol brings distinct benefits. The branching at the second carbon leads to lower volatility, which shows up as reduced odor impact in plant spaces and improved safety profiles. Storage losses drop, and environmental controls become less of a headache.

    This molecule’s bulk helps it act as a more stable intermediate than smaller or linear thiols. In practice, those using it for metal extraction or as intermediates in organic synthesis see improved selectivity and reduced side products. The higher molecular weight means evaporation at process temperatures is negligible compared to lighter thiols. Plant operators notice fewer escapes through vents or seal leaks, a simple but important economic factor in scale production.

    Why Purity and Consistency Set Our Supply Apart

    Manufacturers like us know there’s a wide range of quality on the market, often tied to shortcut production methods. Recycled feedstocks or uncontrolled reaction steps lead to mixtures peppered with isomers and impurities—nothing but trouble for process engineers downstream. We only use carefully selected, high-purity feed alcohols in our process. Tight column separation and online monitoring of product streams trim out off-specual tranches before they reach the drums. Not every supplier does this, but feedback from our long-term industrial partners drives that commitment.

    We also keep close communication with users. If new applications in electronics or specialty polymers present with unexpected byproducts, we can adjust production parameters to address the real-world impact, such as adjusting reaction times, improving washing, or switching catalysts. Not all thiol producers take this hands-on approach, but we have seen that responsiveness keeps downtime low for our partners and maintains confidence with regulators.

    Material Handling and Practicalities from the Plant Floor

    Anyone familiar with alkyl thiols knows the strong odor signals a leak or spill long before sensors chirp. Over the years, our team has tailored drum designs and transfer methods to minimize exposure without complicating bulk use. Customers who appreciate straightforward packaging—whether in ISO tankers or stainless drums with vented closures—avoid unnecessary headaches. We recommend sealed transfer lines, and many users opt for closed-loop loading, since the volatile nature can quickly permeate working areas. Our safety teams train on prompt spill response, recognizing that strong odors can flag hazards but also help with early containment.

    Addressing Challenges Seen Over Decades of Manufacturing

    Every specialty chemical brings operational quirks. For 2-Ethyl-1-Hexanethiol, high reactivity of the thiol group means compatibility with storage materials matters. Through trial and error, we have found that high-grade, lined carbon steel meets requirements for long-term storage, while aluminum and many plastics experience unwanted degradation. Near-reactors, glass-lined vessels remain the standard to prevent polymer fouling, and this continues to prove reliable. Leaks and emission concerns drive us to run continuous monitoring of warehouse air, maintaining sulfur levels far below regulatory limits.

    We also engage with environmental engineers to ensure that our vent treatment neutralizes any stray emissions before release. Lessons from past incidents sparked investments in multi-stage activated carbon filters, and close monitoring confirms these changes work. This reduces not just environmental impact, but community complaints, which helps us stay on good terms with neighbors and local authorities.

    Working with User Feedback to Refine the Product

    Direct discussions with industry users have taught us where product outperforms or falls short. Paints and coatings customers, for example, have flagged variations in odor and color as quality issues, even when basic purity remains within spec. Our response involved improving stabilization packages and copper-stripping protocols, since trace metals magnify color formation and prompt shelf-life complaints. In agricultural synthesis, formulators report improved yields with our higher-purity batches, compared with uncontrolled imports. This confirms the value of putting resources into final quality control, not just bulk scale.

    To support partners using automated dispensing or inline blending, we developed reliable product density and viscosity profiles. Batch certificates include this data, ensuring pumps meter correctly and avoid blockages. Over time, this small detail has yielded fewer formulation variances and less downtime compared to suppliers providing only basic specification ranges.

    Industry Integration and Value in Complex Syntheses

    As a key intermediate, 2-Ethyl-1-Hexanethiol fits into a wide mesh of supply chains beyond the obvious chemical uses. In the mining sector, extractant blends depend on selectivity, and small tweaks in starting material impact extraction efficiency and waste. Polymer producers rely on it to give precise molecular weight control. Surfactant manufacturers use it as a precursor in specialty detergents, where chain branching improves stability in harsh environments. Working across these industries exposes us to the downstream impacts of even minor product changes, keeping us tuned for new demands and regulatory shifts.

    With new focus on lower VOC footprints across manufacturing, the relatively lower evaporation rate gives customers a way to achieve emission targets while staying productive. Consultation with regulatory advisers has shown us these changes reduce permitting complications in several regions.

    Safety and Regulatory Considerations from Longterm Practice

    Raw materials with potent odors like 2-Ethyl-1-Hexanethiol prompt initial concern over exposure standards and incident prevention. In our facilities, we rely on direct-line exhaust frameworks, secondary containment, and air treatment systems upgraded after a thorough hazard review. Training programs emphasize response speed and awareness, with frequent drills. We keep a running log of near-miss reports to catch new risks before an issue escalates. Customers often report back that our guidance reduces both near-miss frequency and the size of insurance premiums, a practical win for all involved.

    On the regulatory front, registration under global chemical inventories stays current, including thorough reviews for any byproducts or trace contaminants. We update documentation to match regional safety, transportation, and storage requirements, so bulk users don't hit snags during shipping or customs clearance.

    Comparing to Alternative Molecules: The Real Cost/Benefit

    In specialty chemistry, alternatives to 2-Ethyl-1-Hexanethiol exist, but few combine all its advantages. Shorter chain thiols undercut it on cost but miss on volatility and stability. Bulkier thiols cost more and offer diminished reactivity. Over years of manufacturing and troubleshooting end-user processes, we've seen time and again that the balance of branching and chain length in our molecule provides downstream savings in catalyst use, finer control in polymer synthesis, and fewer headaches in regulatory compliance.

    End users in adhesives and coatings have reported that switching to this thiol from others reduces the off-gassing period and customer complaints. Small batch blending companies cite the easier handling and lower waste rates compared to more volatile or less pure options. These are not claims from data sheets—the feedback comes from decades of order history and technical visits.

    Improving the Product with Industry-Driven Innovation

    Unlike generic resellers, as a manufacturer we have teams working on incremental improvements every year. Process upgrades—like continuous distillation, online vapor monitoring, and catalyst recovery—add up to higher yield and purer product. Advanced spectroscopic controls allow us to detect impurity loads below what was possible a decade ago, giving customers new confidence when moving into tighter regulatory regimes or more sensitive downstream chemistry.

    A strong team, familiar with the quirks of this chemistry, means we don’t just adjust on paper but on the floor. Real-world feedback gets incorporated into batch records and future runs. Safety and sustainability teams push for less waste, improved emissions control, and safer packaging. Customers benefit from this loop, seeing stable prices and fewer disruptions, even as industry expectations move.

    Looking Forward: Meeting New Demands and Sustainability Goals

    Modern manufacturing faces expectations for cleaner, safer, more sustainable products. For 2-Ethyl-1-Hexanethiol, continuous feedback from global industry users points out where improvements matter most, from trace-metal content to emissions profile. We stay engaged with certification bodies and upstream suppliers, ensuring not only that product meets internal standards, but also aligns with expanding environmental and health benchmarks.

    Process changes such as lower-temperature synthesis, solvent economization, and closed-loop packaging systems have reduced energy use and waste. Regular review with sustainability partners keeps us aligned with industry shifts, so we offer customers not just a commodity, but a reliable, responsible source built on genuine experience.

    Direct Support and Real-World Solutions for Industrial Users

    One advantage of manufacturing at scale with direct technical involvement comes from troubleshooting ability. We offer users technical collaboration on integration into new processes, deal directly with questions about long-term storage, and help troubleshoot when results differ from expectations. This stems from practical engagement, not just abstract knowledge. In turn, our partners share application insights—these spur us to maintain and expand capabilities, so the product continues delivering in changing environments.

    Why Experience and Consistency Mean Safety and Savings

    New entrants often overlook the tight link between product consistency and operational safety. As manufacturers, every specification and process tweak reflects lessons from years of working with large-scale chemical production. Equipment, quality controls, and testing standards all evolve based on feedback and incidents—consistency in 2-Ethyl-1-Hexanethiol saves time, money, and frustration at every step.

    Final Thoughts from the Factory Perspective

    Making 2-Ethyl-1-Hexanethiol isn’t just about meeting a technical data sheet. It draws on decades of factory experience: meeting regulatory checks, refining plant safety, supporting industry troubleshooting, and adopting proven technologies. Ultimately, every customer who chooses our supply over generic shipments signals that experience, hands-on process adjustment, and continuous oversight matter when precision and safety pay off downstream.

    Standing behind our product means more than watching it leave the gate. It means tracking its journey through industry, collecting outcomes and reactions, and building production improvements into every new shipment. This approach defines our place in the advanced chemical manufacturing chain—and reflects what 2-Ethyl-1-Hexanethiol offers to industries demanding dependability and integrity.