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2,7-Dichlorofluorene

    • Product Name 2,7-Dichlorofluorene
    • Alias Dichlorfluorene
    • Einecs 206-438-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    859045

    Chemical Name 2,7-Dichlorofluorene
    Cas Number 2051-83-0
    Molecular Formula C13H8Cl2
    Molecular Weight 235.11 g/mol
    Appearance White to off-white crystalline powder
    Melting Point 149-151°C
    Boiling Point 384.4°C at 760 mmHg
    Density 1.37 g/cm³
    Solubility In Water Insoluble
    Storage Temperature Store at room temperature, away from light

    As an accredited 2,7-Dichlorofluorene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 25g amber glass bottle with a tight-sealing cap, labeled “2,7-Dichlorofluorene” and hazard warnings, securely packaged.
    Shipping **Shipping Description for 2,7-Dichlorofluorene:** 2,7-Dichlorofluorene should be shipped in tightly sealed containers, protected from moisture and direct sunlight. It must comply with local, national, and international transport regulations for hazardous chemicals. Handle with care, using appropriate personal protective equipment. Store in a cool, dry area, away from incompatible substances and ignition sources.
    Storage 2,7-Dichlorofluorene should be stored in a cool, dry, and well-ventilated area, away from sources of ignition and direct sunlight. Keep the container tightly closed and store separately from oxidizing agents and strong acids. Use chemically compatible, labeled containers and avoid prolonged exposure to air and moisture. Ensure storage complies with local environmental and safety regulations.
    Application of 2,7-Dichlorofluorene

    Applications of 2,7-Dichlorofluorene in Industrial Manufacturing

    2,7-Dichlorofluorene plays a critical role as a specialty intermediate in select downstream manufacturing sectors, offering unique reactivity profiles necessary for advanced material synthesis. We supply this compound to sophisticated processors integrating it directly into their own high-value products. Below, we detail major industrial scenarios utilizing this material, focusing on their compliance expectations, real formulation usage, precise manufacturing integration, and finished product endpoints.

    1. Polyimide Monomer Synthesis for High-Performance Films

    Leading electronics and aerospace companies rely on 2,7-dichlorofluorene as a fundamental intermediate for the production of fluorenyl-based dianhydride monomers, which propagate into polyimide film casting. The rigid core and halogenation pattern impart enduring thermal resistance and dimensional stability, which are indispensable for flexible printed circuit, display, and microelectronic substrate applications.

    Industry compliance standards

    • IPC-4101B (Specification for Base Materials for Rigid and Multilayer Printed Boards)
    • REACH Regulation (EC No 1907/2006) for industrial chemicals
    • RoHS Directive 2011/65/EU for restriction of hazardous substances
    • UL 94 Flammability Safety Standard

    Typical usage ratio

    • Used at 15%–30% molar ratio, as copolymerized with dianhydride and diamine monomers; specific ratios depend on target film thickness and flexibility specifications

    Downstream process integration

    • Enters monomer synthesis via condensation routes with phthalic anhydride derivatives; proceeds to polycondensation for polyamic acid formation, then thermal imidization during film casting

    Final product types

    • Flexible polyimide films for flexible circuits and semiconductor insulation
    • Protective coatings for OLED/LED displays
    • Substrates for aerospace thermal insulation laminate systems

    2. Advanced Liquid Crystal Alignment Layer Additives

    Specialty display panel manufacturers incorporate this compound during the synthesis of specific polyimide resins formulated for LC alignment layers. The dichloro substitution improves photostability and pretilt angle control under high-definition panel fabrication environments, contributing to display uniformity and reduced image sticking.

    Industry compliance standards

    • ISO 9241-305 Ergonomics of visual displays
    • China Electronic Industry Standard SJ/T 11363-2006 for electronic information products
    • Sony Green Partner Standard for display materials

    Typical usage ratio

    • Dosed at 1%–6% by weight in alignment layer resin formulations; fine-tuning depends on the required pretilt angle, curing profile, and panel resolution target

    Downstream process integration

    • Mixed during liquid polyimide precursor polymerization; spin-coated and thermally cured onto ITO glass substrates before LC cell assembly

    Final product types

    • IPS and TFT-LCD display panels
    • OLED backplane alignment coatings
    • High-resolution e-paper display modules

    3. Organic Light-Emitting Diode (OLED) Host Material Synthesis

    Researchers and major optoelectronics firms leverage this raw material in benzofluorene-based arylamine syntheses, which serve as blue-emission host materials in OLED emissive layers. The introduction of chlorine atoms improves charge transport pathways and broadens device operational lifetime under demanding luminance cycles.

    Industry compliance standards

    • IEC 62341-5-1 (OLED Displays – Safety Requirements)
    • JEITA ED-5308 (OLED Quality Assurance for Electronic Displays)
    • California Proposition 65 requirements for consumer electronics

    Typical usage ratio

    • Incorporated at 8%–22% molar fraction during host molecule assembly, adjusted according to photoluminescent efficiency and electronic mobility requirements

    Downstream process integration

    • Used in multi-step Suzuki or Buchwald coupling reactions to construct host matrix structures; purified hosts then deposited using thermal evaporation or solution processing in OLED device layers

    Final product types

    • OLED display panels for smartphones and TVs
    • Wearable flexible displays
    • Solid-state lighting modules based on advanced blue emitters

    4. Functional Dye and Pigment Intermediate for Specialty Colorants

    Producers of high-stability dyes and organic pigments source this compound as a starting material for halogenated fluorene derivatives, which undergo further substitution or fusion reactions to create lightfast, heat-resistant pigment molecules. Applications focus on colorants requiring performance in engineering plastics and automotive coatings, where intense color and environmental resistance are mandatory.

    Industry compliance standards

    • EN 71-3 (Safety of Toys – Migration of certain elements)
    • European Food Contact Regulation (EU) No 10/2011 for indirect contact in plastics
    • ASTM D4303 (Lightfastness Test Method)
    • ISO 9001 certified colorant QC protocols

    Typical usage ratio

    • Serves as 10%–18% of reactant feedstock in pigment precursor reaction batches; adjusted per desired chromaticity index and solvent resistance profile

    Downstream process integration

    • Undergoes electrophilic or nucleophilic substitution to obtain chlorinated or fused dye intermediates; pigment precursors then condensed into target dye molecules, followed by milling and dispersion into polymer carriers

    Final product types

    • Engineering plastics color concentrates (masterbatches)
    • High-performance automotive and industrial coatings
    • Specialty inks for security printing and electronic applications

    5. Specialty Pharmaceutical Intermediate for CNS-Active Agents

    Pharmaceutical manufacturers employ this material as a core scaffold in the construction of certain tricyclic and tetracyclic drug candidates, targeting CNS modulation. The dichlorofluorene backbone is adapted for further functionalization, enabling access to experimental compounds studied in neuropharmacology and psychiatric research pipelines where aromatic rigidity and electronic tuning prove essential.

    Industry compliance standards

    • ICH Q7 (GMP for Active Pharmaceutical Ingredients)
    • FDA 21 CFR Part 211 (Current Good Manufacturing Practice for Finished Pharmaceuticals)
    • USP General Chapters for intermediate qualification

    Typical usage ratio

    • Reactant dosed at 3%–12% by mol in multi-step syntheses; scale controlled by downstream route, with excess minimized to streamline purification

    Downstream process integration

    • Alkylation or amination reactions introduce sidechains, then cyclization and functional group transformation steps build out final API structures; intermediates purified via crystallization or chromatography

    Final product types

    • Study compounds for CNS drug discovery
    • Analytical reference standards for pharmacokinetic profiling
    • Building blocks for patent application compounds
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    Certification & Compliance
    More Introduction

    Introducing 2,7-Dichlorofluorene — Our Commitment to Precision Chemistry

    From Lab Bench to Industrial Scale: The Value of 2,7-Dichlorofluorene

    Working in chemical synthesis for decades has shown us the subtle differences between products that seem similar to newcomers. 2,7-Dichlorofluorene has gradually become one of those compounds that, at first glance, looks like a minor tweak on a familiar backbone. The addition of two chlorine atoms onto the fluorene structure, specifically at the 2 and 7 positions, delivers more than just a shift in molecular weight. Those who handle the intricacies of organic synthesis know that chlorinated fluorenes often bring both opportunities and challenges—flexibility in downstream chemistry, improved stability for intermediates, and less susceptibility to random side reactions when compared to the parent hydrocarbon.

    The pathway to making 2,7-dichlorofluorene isn’t just about running a routine halogenation. Over the years, we have refined how we introduce chlorine atoms to the fluorene, as side reactions can create isomeric mixtures, foul by-products, and unpredictable color responses when exposed to air or moisture. By tuning reaction conditions and purification methods, we consistently generate 2,7-dichlorofluorene with a purity that exceeds market expectations. Our final product is a white to off-white crystalline solid, and every batch passes standard identity and purity checks using techniques such as NMR, GC-MS, and HPLC. Based on our control process, our material generally reaches 99% purity or higher, depending on specific client requirements.

    Practical Applications Backed by Years of Production Experience

    Most folks outside the lab don’t appreciate why those two chlorine atoms matter so much. Synthetic chemists, though, realize this transformation alters electron density and enhances reactivity at specific positions, enabling custom functionalization that wouldn’t proceed cleanly on unmodified fluorene. We see a steady demand from partners working on advanced polymers, specifically those drawing on the rigidity and aromaticity of the fluorene core for optoelectronic components. Chlorine substituents at the 2 and 7 positions lead to better solubility profiles during intermediate steps—something any process chemist wrestling with sticky, insoluble polymer precursors can appreciate.

    Another significant use comes from advanced material research. Many clients order this compound to construct organic semiconductors and specialty resins, where sidechain manipulation through the 2 and 7 positions allows much finer control of electronic properties. The difference between a dull, non-conductive plastic and a high-performance, OLED-compatible polymer often starts with the reliability of specialty building blocks. Only a few positions on the fluorene skeleton consistently deliver predictable outcomes; 2,7-derivatives frequently outperform alternative regioisomers in these applications. Years of feedback from customers support this assertion.

    Model and Specification Consistency — Making the Case for Strict Quality Control

    Every manufacturer claims high standards, but the real test lies in batch-to-batch consistency. For 2,7-dichlorofluorene, we’ve experienced firsthand the pitfalls of letting tiny impurities slip by. Even a trace of isomeric contamination can disrupt catalyst loads, poison coupling reactions, or introduce color bodies into finished films. To address these risks, each batch is assigned a unique lot number, cross-referenced against archived NMR, and stringently tested for residual solvents. Melting point, appearance, and spectral purity are all checked before shipment.

    We maintain a standard model specification for most industrial and research clients: white to off-white powder or crystals, with an assay regularly at or above 99%. Water content never exceeds 0.5% by Karl Fischer. Trace metals and common organic solvents fall below routinely accepted thresholds after drying and recrystallization. Clients working on large-scale synthesis for electronics appreciate that our crystalline form dissolves easily in common organic solvents such as toluene, dichloromethane, and tetrahydrofuran, so they avoid spending extra time on pre-treatment. Every new client receives specification sheets matched to actual batch analysis, not just generic marketing promises.

    What Sets 2,7-Dichlorofluorene Apart from Similar Aromatic Chlorides?

    Decades ago, chemists searching for a functionalized fluorene relied heavily on mono-chlorinated or 9-position substituted analogues. One thing that stands out after years of testing is that the 2,7-chloro pattern is far less prone to unwanted reactivity than mono-chlorofluorenes—notably less susceptible to rapid degradation under strong light or acidic conditions. The molecular symmetry gives a unique advantage in controlling regiochemistry for Suzuki, Stille, Negishi, and other coupling reactions. In practice, this means higher yields, less waste, and greater product homogeneity after scale-up.

    Even subtle changes in the aromatic substitution pattern result in compounds with quite different melting points, solubility, and chemical resistance. For example, 3,6-dichlorofluorene produces intermediates that rarely match the processability and stability demanded in blue emitter manufacturing for OLED screens. Several clients switched from para-chlorinated or di-brominated analogues to our 2,7-dichloro variant specifically to hit targets such as, lower defect rates in thin-film processing and higher glass transition temperatures in polymers. These decisions weren’t based simply on catalog claims—real-world feedback drove these changes after comparative testing in multi-kilogram trial runs.

    Dissecting the Differences — Lessons From The Production Floor

    Lived experience counts in the fine chemical trade. Several years back, one of our long-term partners ran parallel syntheses using various fluorene derivatives for a new photoconductor project. Their workflows revealed that competitors’ supposedly similar products shipped with low-level, persistent impurities—halogenated by-products from uncontrolled reactions—that led to inconsistent batch coloration. Only with 2,7-dichlorofluorene from our optimized plant could they confidently control color and transparency every single time. Our approach? Routine fractional crystallization, confirmed by GC-MS, followed by hands-on inspection rather than relying entirely on automated equipment. Chemists here know the look and odor of perfectly pure fluorene derivatives, and every drum that ships bears traces of this careful, experience-led handling.

    The hands-on part of our operation has taught our team that “good enough” purity may pass regulatory muster but falls short for advanced users. For example, clients in display technologies and photonics demand practically invisible levels of metallic and ionic contamination. Our analytics group built in several extra quality gates after observing how tiny traces of iron or copper could trigger unexpected quenching or color drift in luminescent films. Instead of shipping early, we hold lots back until long-term stability data confirm consistent quality, even through multi-season warehouse cycles. These steps raised our overhead but returned extraordinary long-term loyalty from clients with high-stakes applications.

    Getting More Than a Chemical — Knowledge Sharing and Support

    Reliable supply of any specialty chemical takes more than a properly equipped plant and rigorous controls. Over the years, we’ve found that personal contact with process chemists, not sales representatives, saves time and money for all concerned. Most technical questions—like which solvents best suit dissolution before polymerization, or how to integrate dichlorofluorenes into large-scale photochemical reactions—come directly to our R&D bench team. Years in this trade remind us that process optimization isn’t something to keep hidden. Through open communication, we help downstream users avoid common yield losses, purification headaches, and cross-contamination pitfalls that show up if raw material consistency isn’t locked down.

    New adopters often ask about storage and long-haul shipment. After weathering batches delayed by unexpected port closures and customs holdups, we overhauled our packaging approach. We now use moisture-barrier drums lined with inert liners, and log temperature and humidity excursions during transit. Complex, multi-step reactions can amplify the effects of modest starting material degradation, so we treat packaging as a core production step. User feedback consistently shows that paying attention to details like drum headspace, anti-static liners, and rapid repacking reduces variability further downstream and cuts waste.

    Safety, Traceability, and Ongoing Improvements

    It takes more than technical skill to build a sustainable, safe, and reliable operation. Years of working under stringent regulatory frameworks taught us the value of full traceability. From the inbound chlorine cylinders to final product filling, each unit is accounted for with a digital chain of custody. We keep production records for audits, including both internal checks and independent lab confirmations. Our more demanding clients in pharmaceutical and consumer electronics sectors periodically request random revalidation, which never presents an issue since all critical markers are cross-referenced and digitally archived.

    Safety in handling 2,7-dichlorofluorene draws on generations of cumulative knowledge, not just datasheet warnings. Our process plants are designed with negative-pressure hoods, sealed bulk transfer lines, and chemical-resistant flooring. Personal protective equipment isn’t negotiable—glove changes, mask fit-testing, and emergency response drills run weekly. Technical oversight combined with ongoing team training means we avoid both major incidents and insidious, long-term exposure risks.

    Feedback and Continuous Dialogue Drive Evolution

    Markets for functional aromatic compounds move quickly. Our R&D team receives dozens of requests each quarter—sometimes for even purer grades, sometimes for more rugged packaging, sometimes for documentation tailored to multinational regulatory teams. We track each suggestion and, if several clients highlight similar pain points, adapt production methods accordingly. Last year, a collective push from several OLED R&D labs nudged us to drop residual solvent levels even lower, prompting investment in new drying and testing protocols. The impact was clear: time to first-pass product qualification at the customer site fell sharply.

    Long-term customers tell us what works, and just as importantly, where a competitor’s offering fell short. That candor pushes our chemists and technical operators to aim higher and avoid the complacency that creeps in at scale. It’s not the occasional large order that sustains us—it’s the regular exchanges with technical users who scrutinize every kilogram and aren’t shy about detailed feedback. As a manufacturer with skin in the game, this is how we protect our reputation and grow along with our partners.

    Summary of Key Features: Lessons from the Trenches

    Having made, shipped, and tracked tons of 2,7-dichlorofluorene, we know what to expect from each step of its life cycle. Key advantages stem from a clean substitution pattern, which makes the compound especially well-suited for advanced organic synthesis. Most users report straightforward handling in the lab and clean performance at scale-up. Polymers and resins built from our dichlorofluorene remain clear and colorfast through extended stress testing, a critical factor for electronics manufacturers. Our in-house teams draw from real-life challenges—feedstock supply interruptions, comparative trial failures at customer sites, and regulatory curveballs—that constantly refine our product.

    Downstream users in fields ranging from specialty polymers to electronics frequently credit the smooth integration of our compound into high-value applications to our hands-on attention and continuous process oversight. It isn’t flashy innovation, but steady improvement year after year keeps our product as a benchmark for reliability. We never stop learning from feedback, scientific advances, and the evolving needs of those who convert raw materials into tomorrow’s essential technologies.

    Looking Ahead: Why 2,7-Dichlorofluorene Merits Attention

    2,7-Dichlorofluorene remains a reliable workhorse for those pushing the boundaries of organic synthesis. Our experience tells us there’s always another way to refine purity, improve documentation, support ever-tougher regulatory demands, and tailor packaging for safe global delivery. This ethos places both our team and our product at the interface of evolving science and day-to-day industrial demands. Based on years spent both in the laboratory and on the factory floor, we believe attention to quality and a culture of open technical exchange will remain the deciding factors for customers who expect more than just an invoice and a drum left at the shipping dock.

    Every order reflects trust—a trust earned through thousands of hours in the lab, hundreds of process improvements, and robust, honest partnerships. Chemists know quality when they see it, and raw materials made right power innovations that move the field forward. Our 2,7-dichlorofluorene stands as proof that experience, rigorous oversight, and a willingness to listen make a measurable difference. The future direction of advanced materials and specialty fine chemicals will take many forms, but close attention to foundational building blocks will always matter—a principle confirmed by every successful batch and every long-term client relationship so far.