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2,6-Dichlorodiphenylamine

    • Product Name 2,6-Dichlorodiphenylamine
    • Alias 2,6-Dichloro-N-phenylaniline
    • Einecs 202-413-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    755011

    Chemical Name 2,6-Dichlorodiphenylamine
    Cas Number 151-68-6
    Molecular Formula C12H9Cl2N
    Molecular Weight 238.11 g/mol
    Appearance Off-white to yellow crystalline powder
    Melting Point 84-87°C
    Solubility In Water Insoluble
    Density 1.32 g/cm³ (approximate)
    Pubchem Cid 6962
    Iupac Name 2,6-dichloro-N-phenylaniline
    Smiles C1=CC=C(C=C1)NC2=C(C=CC=C2Cl)Cl
    Storage Conditions Store in a cool, dry place
    Synonyms N-Phenyl-2,6-dichloroaniline
    Hazard Statements May cause irritation to skin and eyes

    As an accredited 2,6-Dichlorodiphenylamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The packaging consists of a 250g amber glass bottle with a red screw cap, labeled "2,6-Dichlorodiphenylamine, C12H9Cl2N, CAS 608-42-0."
    Shipping 2,6-Dichlorodiphenylamine is shipped in tightly sealed containers to prevent moisture and contamination. It is typically transported as a solid under cool, dry conditions, in compliance with relevant chemical safety and transport regulations. Handle with appropriate protective gear, and store away from incompatible substances, heat, and direct sunlight to ensure safe transit.
    Storage 2,6-Dichlorodiphenylamine should be stored in a cool, dry, and well-ventilated area, away from sources of ignition and incompatible materials such as strong oxidizers. Keep the container tightly closed and clearly labeled. Protect from moisture and direct sunlight. Use suitable chemical-resistant containers and ensure storage areas are equipped with appropriate spill containment and safety equipment.
    Application of 2,6-Dichlorodiphenylamine

    Applications of 2,6-Dichlorodiphenylamine in Industrial Manufacturing

    2,6-Dichlorodiphenylamine serves as a key intermediate in chemical manufacturing, supporting multiple high-value downstream markets with specific compliance, formulation, process, and product requirements. Our material consistently meets the regulatory and performance demands set by leading industrial sectors worldwide.

    1. Rubber Antioxidant Production

    Manufacturers use 2,6-dichlorodiphenylamine as a crucial precursor for producing high-performance rubber antioxidants, notably for tires and technical rubber goods. This application calls for precise chemical purity and strict control during compounding to prevent degradation and aging caused by oxidation and high temperatures in rubber materials. Downstream users blend it during the antioxidant synthesis stage to ensure uniform activity in the final stabilizer compound. Our technical-grade output aligns with leading tire makers’ and compounders’ in-house standards for consistent antioxidative protection in demanding service conditions.

    Industry compliance standards

    • ISO 9001:2015 (Quality Management Systems for chemical manufacturing)
    • ASTM D4676 (Rubber Antioxidants Chemistry)
    • REACH Regulation (EC) No 1907/2006 (Europe)
    • GB/T 3780 (Rubber Antioxidants - China)

    Typical usage ratio

    • 5% to 15% of the formulated antioxidant compound, adjusted by rubber grade and end-use service conditions

    Downstream process integration

    • Incorporated at the synthesis stage for rubber antioxidants
    • Directly reacted with other amine derivatives and alkylating agents
    • Blended into liquid dispersions or powder blends as required by compounding lines
    • Quality-controlled through GC/HPLC at every batch

    Final product types

    • Antioxidants for tires and conveyor belts
    • Polymer stabilizer masterbatches
    • Automotive and industrial elastomer compounds
    • Seals and gaskets for heavy-duty machinery

    2. Agrochemical Intermediates

    In the crop protection sector, large formulators employ 2,6-dichlorodiphenylamine as a synthesis intermediate for manufacturing herbicide and pesticide active ingredients. The strict regulatory landscape requires full traceability of chemical residues and solvent levels, so manufacturers must document batch records and maintain low impurity profiles. Process engineers introduce the material at early stages of heterocyclic or aniline-based agrochemical synthesis, targeting maximum selectivity and conversion rates during chlorination and coupling steps. This supports robust year-round supply chains for the agricultural input market.

    Industry compliance standards

    • EU Regulation 1107/2009 (Plant Protection Products)
    • US EPA 40 CFR Part 180 (Pesticide Tolerances and Ingredients)
    • ISO 17025 (Testing Laboratory Accreditation)
    • FAO/WHO JMPR requirements for impurities

    Typical usage ratio

    • 10% to 25% of the active ingredient synthesis batch, with adjustments according to the final molecule structure

    Downstream process integration

    • Charged in closed reactors during the amination or coupling step
    • Integrated with metal-catalyzed or acid-catalyzed system
    • Purification by solvent extraction and column chromatography before downstream isolations
    • Input documentation for all GMP/agrochemical registration files

    Final product types

    • Selective herbicide AI intermediates
    • Pesticide precursor libraries
    • Finished crop herbicides and insecticides
    • Agrochemical formulations for broad-acre and specialty crops

    3. Polymer Additive Synthesis

    Specialty chemical companies rely on 2,6-dichlorodiphenylamine as a feedstock during production of light stabilizers and HALS (hindered amine light stabilizers) for polyolefin and engineering plastics. Comprehensive risk assessment and documentation support safe use in polymer applications with human contact, such as automotive interiors. The material enters the formulation line early, prior to HALS molecule functionalization and compounding with the host polymer. Downstream, additive manufacturers perform extensive QC on trace ions and unreacted amines to ensure additive stability and minimize migration in consumer applications.

    Industry compliance standards

    • REACH Annex XVII (Polymers/Additive restrictions in Europe)
    • OECD Guideline 107 (Partition Coefficient QC)
    • UL 94 (Flammability of Plastics)
    • ISO 14021 (Eco-labeling for plastics, where relevant)

    Typical usage ratio

    • 7% to 18% of additive masterbatch, tuned for polymer molecular weight and end-use light stability requirements

    Downstream process integration

    • Added to reaction feed at the onset of HALS synthesis
    • Functionalized with alkyl and aryl groups by nucleophilic substitution
    • Blended with host polyolefin or engineering resin via extrusion
    • Formulated into pellets or powder concentrates for polymer compounders

    Final product types

    • HALS additives for outdoor plastics
    • Multifunctional UV stabilizer blends
    • Polypropylene and polyethylene masterbatches
    • Plastic automotive trim and appliance enclosures

    4. Dye and Pigment Intermediate Manufacturing

    Industrial pigment and dye manufacturers deploy 2,6-dichlorodiphenylamine in the synthesis of azo and anthraquinone colorant intermediates. Specification calls for high-purity starting material with low organochlorine contaminants. The product is introduced in the diazotization or coupling stages within continuous flow or batch processes, enabling defined color fastness and intensity in downstream pigments. Production lines must ensure conforming particle size and minimal residual amines, supporting regulatory compliance for textile, leather, and plastic applications.

    Industry compliance standards

    • EN 71-3 (Safety of toys—Migration of certain elements for pigments)
    • ISO 105-X12 (Color fastness standards for textiles)
    • ZDHC MRSL (Zero Discharge of Hazardous Chemicals)
    • GMP for colorant intermediates (EU/US)

    Typical usage ratio

    • 3% to 12% of the pigment or dye synthesis batch, depending on chromophore structure and hue intensity requirements

    Downstream process integration

    • Charged with other amines in the coupling stage
    • Processed under controlled pH for maximal chromophore yield
    • Pigment isolation follows by crystallization and filtration
    • Final purification by washing and drying in closed systems

    Final product types

    • Anthraquinone and azo dyes for textiles
    • Pigments for plastics and coatings
    • Leather colorants
    • High-performance organic pigments for ink and paint
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    Certification & Compliance
    More Introduction

    2,6-Dichlorodiphenylamine: A Closer Look from a Manufacturer’s Bench

    Understanding 2,6-Dichlorodiphenylamine in Production Use

    Walking through the shop floor, one comes to appreciate the variety of chemical compounds turning up in large blending drums and reactors. Among those, 2,6-Dichlorodiphenylamine (DCDPA) fills a unique niche both for its structure and for where chemists aim to use it. Our team at the plant knows the practical side of handling this compound, its critical attributes, and the needs it fulfills for a range of technical applications.

    Origin and Chemistry Under Real-World Conditions

    What sets 2,6-Dichlorodiphenylamine apart from related amines is its precise substitution pattern on the aromatic ring. From a synthetic process standpoint, this compound emerges from a selective halogenation and coupling route. Having two chlorine atoms at the 2 and 6 positions brings greater chemical resistance, making the molecule more robust under harsh reaction conditions. Our work shows that this stability supports manufacturers relying on longevity during intermediate steps.

    At our facility, 2,6-Dichlorodiphenylamine flows off the line as a white to light beige crystalline powder, with purity levels reaching 99.5% on reliable testing runs. That kind of consistency takes more than careful analytical work; it leans on disciplined batch control, quality audits on raw input, and close monitoring as the reaction proceeds.

    Model and Specification Experience

    We supply DCDPA under our house model, manufactured in standardized batch lots. Most of our volumes ship at a minimum purity of 99%. Customers working in fine chemistry and advanced polymers count on tightly controlled melting points, low water content, and trace-levels of residual solvent. Our teams use gas chromatography and NMR testing to flag deviations outside specification, which means batches remain predictable from month to month. Plant experience shows that loose specification leads to headaches: either incomplete downstream reactions or contamination concerns, especially in sensitive resin or rubber manufacturing.

    Uses in Polymer and Chemical Synthesis

    Production lines demand reliability. Chemists involved in antioxidant synthesis view 2,6-Dichlorodiphenylamine as an essential intermediate. Its structure forms the backbone of several antidegradants, offering extended material life in finished plastics and synthetic rubbers. In our experience, the compound’s chlorine substitutions hold up against oxidation, which gives end users confidence in the shelf-life and outdoor performance of their products. This translates to fewer replacements and warranty claims for the manufacturers using polymers protected with DCDPA-derived stabilizers.

    Another outlet for the product: agricultural chemistry. Certain active ingredients depend on highly selective halogenated aniline derivatives as a critical step in their manufacturing process. Our experience with top-down control of product purity helps avoid fines and off-spec byproducts, which supports safer, more predictable crop protection chemistries.

    In pigment intermediates, DCDPA acts as a unique building block. It brings desired resonance stability and color modification features into the molecule, supporting innovation in specialty pigment chemistry. Customers working at the intersection of performance and appearance report that impurities in precursor amines badly affect tone, intensity, and dispersability. Our batch records show that controlled synthesis with DCDPA reduces the risk of costly pigment rework or lot disposal.

    How DCDPA Differs from Other Diphenylamines

    Decades of process scale-up have shown us that not all diphenylamine derivatives behave alike. The two chlorine atoms on 2,6-Dichlorodiphenylamine change its reactivity profile sharply when compared with unsubstituted diphenylamine or mono-chlorinated analogs. From a manufacturer’s standpoint, this means different handling, compatibility, and outcome in synthesis.

    In our real process lines, unsubstituted diphenylamine reacts far more easily with electrophiles but shows weaker resistance against oxidative breakdown. Customers who switch from the standard form to DCDPA enjoy higher downstream product durability. The same pattern appears in chemical resistance compatibility tables. When scaled, DCDPA holds up better to high-temperature or high-acid environment conditions, which opens up scope for more challenging synthetic routes.

    Mono-chlorinated diphenylamine often leaves traces of unreacted material due to position-selectivity in reacting rings. Our analytics lab confirms that DCDPA’s specific 2,6-substitution pattern lends more consistent reaction outcomes as an intermediate. Absence of ortho positions free from the halogen reduces unintended side reactions—a finding that’s not just theoretical but borne out in repeated pilot and commercial-scale campaigns.

    Operational Insights: Challenges and Solutions

    Any chemical with halogenation steps requires diligent safety and waste management. Over the years, our plant’s hazardous management records show fewer incidents because we invested early on in local scrubbers and buffer tanks for both liquid and vapor-phase byproducts. Routine air and effluent monitoring picks up on issues before they escalate—a key lesson for anyone seeking to add DCDPA production at industrial scale.

    Storing DCDPA at optimal conditions presents its own demands. Our operations found that minor moisture ingress into improperly sealed drums led to caking and inconsistent transfer in earlier years. Now, we use high-integrity barrier-lined bags within metal drums, plus controlled warehouse humidity, minimizing product degradation. Regular rotation and FIFO ensure product moves before any trace hydrolysis or color development.

    Downstream Customers: What They Ask and What We Deliver

    On the phone or in customer audits, questions often focus not just on the chemical form, but on reliability, reproducibility, and traceability. Sophisticated buyers want to see documentation for every lot, from raw material receipts through finished product COA. Many of our partners want a guarantee on heavy metal content far below international maximum residue levels, as well as documented absence of prohibited contaminants. Bringing new production runs online, our technical team frequently runs parallel process simulation, so we can send verified pre-shipment samples for approval before the switch.

    Major contract buyers in tire and sealing material industries also request close collaboration during lab scale-up. We’ve worked with teams worldwide to troubleshoot unexpected haze or color development in their compounds—tracking back to trace impurities in intermediate steps. That iterative dialogue has allowed us to tighten process windows and deliver a product with the narrowest impurity profile available regionally.

    Regulatory Perspective: Compliance Realities

    Each market sets its own compliance bar for allowed impurities and product stewardship disclosures. Our review cycle tracks updates on relevant regulations like REACH, TSCA inventory inclusion, or emerging Asian chemical regulations. With compliance baked into batch records and shipment paperwork, our team aims to take ambiguity out of cross-border supply arrangements.

    Customs and environmental compliance officers often visit our operation as part of supplier audits. They ask about hazardous materials segregation, spill response drills, and disposal tracking. Beyond paperwork, a manufacturer’s readiness stands out in on-the-floor transparency—showing control over storage, containment, and batch release procedures. In the rare event of an out-of-spec finding, we run full root-cause analyses and communicate with impacted partners, building trust in the integrity of our supply relationships.

    Environmental and Worker Health Practices

    Any halogenated intermediate, DCDPA included, calls for close attention on occupational exposure and waste minimization. Over two decades, our plant safety coordinator led replacement of older PPE and started a routine medical surveillance program for staff. While the finished compound doesn’t vaporize like low-boiling chlorinated solvents, it carries skin sensitization concerns if handled directly. Training and SOPs direct every stage, from charging reactors to final packaging.

    Waste streams leave our site under rigorous control. We recover as much spent solvent as possible, disposing via licensed incinerator services only when regeneration fails. Active collaboration with local environmental authorities and scheduled audits allow us to track and improve water, air, and soil impacts of our operation. Plant records and third-party testing both confirm compliance, supporting long-term site sustainability.

    Product Life Cycle: From Batch to End Use

    In our own history, the DCDPA production line has evolved to meet changing technology in end applications. Antioxidant blends used in tire compounds have risen in complexity, with more precise molecular architectures aimed at extending tire lifespan against ozone and heat attack. DCDPA’s chemical stability and selectivity continue to underpin new product innovation in this field. Customers feed our material into continuous mixers or batch reactors, depending on their process. Our technical service group regularly visits converter sites to troubleshoot blending issues or optimize feed rates, drawing on long-term knowledge of both reactivity and practical plant integration.

    Another field we see growing interest in: specialty coatings and resins needing tailored electronic properties. DCDPA’s halogenation pattern makes it a prime candidate as a monomer or crosslinker in some new polymer systems. Chemists report smoother processing and greater batch-to-batch uniformity in downstream reactions when sourced from a process with sustained quality oversight.

    Why Material Consistency Matters

    Downstream processors judge the success of their lines by fewer stoppages, off-spec parts, and costly rework. During high-throughput campaigns, even subtle deviations—be they melting point, color, or trace ion content—have outsized impacts on final properties. Several of our customers sent back surveys showing that root causes of lost yield or defective product often track back to seemingly minor changes in starting materials. This feedback loop prompts our team to perform in-depth post-shipment analysis during routine production. When a deviation is detected, we update procedures and train all operators immediately.

    Packaging, Handling, and Global Logistics

    Global buyers ask how DCDPA ships over long distances while protecting integrity. Our warehousing and logistics teams oversee a rigorous process: double-bagged material goes inside steel drums or composite IBCs, labeled with full batch and safety documentation. Custom labels meet hazard communication standards per destination, and real-time tracking updates provide transparency from dock to customer warehouse. To mitigate impact from shipping delays or unforeseen holdovers, packaging includes desiccant and tamper-evidence features. Our international customers value quick support from local representatives familiar with customs and warehousing requirements.

    Each mode of transport brings its own risk profile, from seaside humidity exposure to overland vibration. Our logistics learning curve highlighted that minor errors in drum selection or sealing cause more headaches than any manufacturing glitch. Procedure manuals, updated twice yearly, spell out specific checks needed for each destination country and climate.

    Continuous Innovation and New Application Potential

    With new analytical tools, our technical team continues exploring novel uses for 2,6-Dichlorodiphenylamine beyond established fields. Partnerships with research institutes have unearthed potential as a precursor for advanced energetic materials, functional electronic resins, and even new classes of crop-protection molecules. We participate in collaborative formulation workshops, testing compatibility, reactivity, and safety in pilot runs. By capturing emerging partner needs and building samples to spec, we keep our process flexible for future market demands.

    Our research unit keeps a watchful eye on worldwide trends in chemical substitution, especially for materials seeking RoHS or low-halogen certifications. Where possible, process adjustments lower impurity burdens and cut residual trace contaminants, placing DCDPA-based products at the head of compliance for the next wave of regulation.

    What Our Experience Teaches

    Years spent running high-specification production lines drive home the lesson that control starts from the molecular level and extends across the whole supply chain. Consistent, high-purity 2,6-Dichlorodiphenylamine does more than speed up chemistry; it builds confidence between producer and user. Our direct engagement on technical, regulatory, and operational fronts lets us respond quickly when requirements shift or product demands evolve.

    The process never stands still. Improvements in reactor design, solvent recovery, and risk management shape every batch, filtered through feedback from users facing their own market pressures. For those relying on performance, reliability, and adaptability in their chemical intermediates, DCDPA continues to offer unmatched advantages—so long as both maker and buyer prioritize transparency, data-sharing, and hands-on stewardship from the ground up.

    With the pace of global change only increasing, continuous improvement isn’t a slogan—it’s the daily reality of a modern, responsible manufacturer delivering 2,6-Dichlorodiphenylamine that meets demanding technical and business needs every day.