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2,5-Dimethyl-2,5-Hexanediol

    • Product Name 2,5-Dimethyl-2,5-Hexanediol
    • Alias 2,5-Dimethylhexane-2,5-diol
    • Einecs 204-664-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    310694

    Cas Number 110-03-2
    Molecular Formula C8H18O2
    Molecular Weight 146.23 g/mol
    Appearance White crystalline solid
    Melting Point 87-90 °C
    Boiling Point 246-250 °C
    Density 0.936 g/cm3 (at 25 °C)
    Solubility In Water Slightly soluble
    Flash Point 121 °C (closed cup)
    Refractive Index 1.446 (at 20 °C)

    As an accredited 2,5-Dimethyl-2,5-Hexanediol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 500g amber glass bottle with a secure screw cap, labeled "2,5-Dimethyl-2,5-Hexanediol," hazard symbols, and handling instructions.
    Shipping 2,5-Dimethyl-2,5-hexanediol should be shipped in tightly sealed containers, protected from moisture and strong oxidizing agents. It is typically transported as a stable, non-hazardous liquid at ambient temperature. Ensure compliance with local, national, and international regulations for chemical transport, and include proper labeling and documentation during shipping.
    Storage 2,5-Dimethyl-2,5-hexanediol should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from incompatible substances such as strong oxidizing agents. Keep the chemical away from heat and sources of ignition. Store at room temperature and protect from moisture. Label containers clearly, and follow all applicable safety and regulatory guidelines for storage.
    Application of 2,5-Dimethyl-2,5-Hexanediol

    Applications of 2,5-Dimethyl-2,5-Hexanediol in Industrial Manufacturing

    As a dedicated manufacturer specializing in high-purity 2,5-dimethyl-2,5-hexanediol, we support a range of established industrial sectors where this diol plays a critical role in advanced formulations and processes. Below are key downstream applications, detailing integration points, compliance standards, dosage ranges, and typical finished products in each scenario.

    1. Polyester Resin Synthesis for Industrial Coatings

    Producers of high-performance polyester resins for industrial coatings incorporate this diol as a chain extender and branching agent to modulate molecular weight, improve hardness, and enhance weatherability. 2,5-dimethyl-2,5-hexanediol is introduced in the polycondensation stage, providing controlled reactivity and minimizing side reactions versus linear diols. Its branched structure contributes to polyester architectures sought in automotive paints, powder coatings, and coil coatings, supporting both solvent-based and powder formulations in accordance with leading sector standards.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • REACH Regulation (EC) No.1907/2006
    • Directive 2004/42/EC on VOC in paints and varnishes
    • ASTM D3029 Polyester Resins Specification

    Typical usage ratio

    • 5–15 mol% of total polyol content, adjusted for target Tg, molecular weight, and flexibility requirements

    Downstream process integration

    • Added to the polycondensation reactor with dicarboxylic acids, other polyols, and catalysts; temperature profile managed to facilitate efficient esterification and minimize gelation

    Final product types

    • Automotive OEM basecoats and clearcoats
    • Industrial powder coatings
    • Appliance enamels
    • Coil coatings for metal panels

    2. Polyurethane Elastomers for Mechanical Components

    Chemical manufacturers utilize this branched diol as a chain extender in polyurethane elastomer synthesis where dimensional stability and hydrolytic resistance are needed, especially in applications subjected to mechanical stress, such as rollers, industrial wheels, and gasketing materials. The unique blend of secondary and primary hydroxyls enables fine-tuning of crosslinking density and flexibility, addressing the critical performance parameters driven by end-user specifications in demanding mechanical applications.

    Industry compliance standards

    • ISO 9001:2015 Quality Management Systems
    • REACH Regulation (EC) No.1907/2006
    • EN 71-3 Safety of Toys (for indirect exposure)
    • UL 746C Polymeric Materials Use in Electrical Equipment (if applicable)

    Typical usage ratio

    • 10–30 wt% of the total polyol component, tuned to hardness and elongation targets in the final elastomer

    Downstream process integration

    • Pre-mixed with other polyols in the batch reactor or continuous mixer, followed by reaction with isocyanates (MDI, TDI); precise temperature and mixing control ensure uniform molecular distribution

    Final product types

    • Casting elastomer rollers and wheels
    • Industrial sealants and gaskets
    • Vibration damping pads
    • OEM flexible couplings

    3. Chemical Intermediate for Alkoxylation in Surfactant Manufacturing

    Large-scale alkoxylation plants employ 2,5-dimethyl-2,5-hexanediol as a starter molecule for the controlled addition of ethylene oxide or propylene oxide, yielding specialty surfactants with tailored HLB (hydrophilic-lipophilic balance) for metalworking fluids, emulsion polymerization aids, and defoaming agents. Its branched geometry impacts the hydrophobic portion and enhances the thermal stability of resultant nonionics, supporting critical downstream production processes.

    Industry compliance standards

    • ISO 14001:2015 Environmental Management Systems
    • REACH Regulation (EC) No.1907/2006
    • OECD Guidelines for the Testing of Chemicals (biodegradability)
    • EN 9120:2018 Surfactants – Industrial Applications

    Typical usage ratio

    • 2–6% by mass in the charge to the alkoxylation reactor, relative to total surfactant batch size; adjusted for chain length and final application requirements

    Downstream process integration

    • Fed into pressurized stainless steel reactors for stepwise alkylene oxide addition; degree of alkoxylation controlled via in-line NIR or GPC for targeted molecular weight

    Final product types

    • Metalworking fluid additives
    • Nonionic emulsion stabilizers
    • Foam control agents for process fluids
    • Specialty cleaning surfactants

    4. Plasticizer Synthesis for Flexible PVC Compounds

    Specialty plasticizer manufacturers incorporate this diol in the esterification process with phthalic or adipic acids to yield plasticizers that offer improved migration resistance and long-term flexibility in flexible PVC applications. The branched nature reduces volatility and provides enhanced heat-aging properties, delivering consistent plasticizer performance especially in wire & cable, automotive interiors, and specialty sheetings where regulatory and processing requirements are increasingly stringent.

    Industry compliance standards

    • REACH Regulation (EC) No.1907/2006 (Annex XVII - Restrictions on phthalates)
    • EN ISO 14372:2022 for plasticizers
    • UL 62 for flexible cords and cables (if used in wire & cable coatings)
    • RoHS Directive 2011/65/EU

    Typical usage ratio

    • 10–25 mol% relative to total alcoholic reactants in the plasticizer synthesis; adjusted based on desired compatibility and softening characteristics

    Downstream process integration

    • Charged to batch or continuous esterification reactors with corresponding acids and catalysts; reaction monitored for acid value and purity before integration into PVC compounding lines

    Final product types

    • Flexible PVC insulation for wire & cable
    • Automotive upholstery materials
    • Flexible vinyl floorings
    • Protective sheeting products

    5. Modifier in Unsaturated Polyester Resins for Composite Applications

    Producers of unsaturated polyester resin systems for fiber-reinforced composites use this diol to modulate viscosity, reactivity, and mechanical performance. Its inclusion modifies crosslink density, resulting in composite matrices with enhanced impact and flexural strength, suitable for demanding end-use markets like transportation, building panels, and marine construction. The raw material enters at the resin prepolymer stage, directly influencing long-fiber composite performance in both pultrusion and hand lay-up technologies.

    Industry compliance standards

    • EN ISO 9001:2015 for production control
    • REACH Regulation (EC) No.1907/2006
    • EN ISO 178:2019 for mechanical properties of plastics
    • ASTM D638 for tensile properties in composites

    Typical usage ratio

    • 3–8 mol% of total glycol content in unsaturated polyester resin formulations, tailored to targeted reactivity and mechanical balance

    Downstream process integration

    • Added during initial polycondensation, fully incorporated before end-capping to control monomer content and final viscosity

    Final product types

    • Glass fiber-reinforced polyester panels
    • Marine composite components
    • Low-profile automotive parts
    • Industrial pultruded beam profiles
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    Certification & Compliance
    More Introduction

    2,5-Dimethyl-2,5-Hexanediol: Introducing a Reliable Alkyl Diol Solution

    Years of Making Consistent, Purified Diol for Industry Progress

    Every batch of 2,5-Dimethyl-2,5-Hexanediol that leaves our factory reflects decades of process refining and persistent raw material scrutiny. In our experience, the diol market demands much more than a minimum-purity certificate; the real value rests on stability, lot-after-lot homogeneity, and careful management of micro-impurities. Many end users in coatings, adhesives, and plastics don’t realize the headaches poor diol compatibility brings until surfactant behavior, cure rates, or viscosity curves stop matching up. Our approach combines upstream hydrocarbon distillation with repeated product fractionation, which eliminates critical traces of aldehyde or acid byproducts commonly seen from less selective syntheses. By investing in these purification steps, we see our customers avoid gels, haze, and color drifts. Technicians have said that predictable molecular architecture makes downstream process management less stressful, whether they focus on polyurethane crosslinking, polyester resins, or specialty lubricant bases.

    Real-World Applications Drive Our Formulation Choices

    2,5-Dimethyl-2,5-Hexanediol shows up most frequently on our shipping documents for polyurethane additives, coating modifiers, and as a specialty co-monomer. Large panel manufacturers illustrate the importance of a low moisture profile in this diol, since water can catalyze unwanted side reactions and degrade mechanical performance. Since our diol passes through molecular sieves before packaging, the final water content consistently tracks below 0.05%. Formulators in industrial coatings have thanked us directly; low-water lots help boost shelf stability and keep pigment dispersions from settling out. Once, a customer working with high-solids acrylics reported much improved gloss retention after switching to our high-control batches.

    Long-chain alkyl diols like this one offer low-volatility behavior and desirable compatibility with many resin systems. In several years of resin co-development, our teams compared 2,5-dimethyl isomers to more linear hexanediol structures. Shorter, unbranched diols accelerate crystallinity and can cause films to turn brittle. Adding methyl substituents at the 2 and 5 positions changes the melting range and results in softer, more flexible bulk products. That flexibility unlocks application potential in thermoset resins and polyurethane elastomers, especially for goods expected to withstand repeated impacts or temperature shifts.

    We also watch the automotive and electronics sectors expand their demand for this diol’s high-temperature performance. A key aspect involves its resistance to hydrolytic degradation. Polyesters and polyurethanes derived from our product hold up in damp or acidic environments longer than analogs built from simple glycols. The structure hinders hydrolysis at the reactive end groups—engineers noticed that electronic encapsulants produced from our diol maintain dielectric integrity despite cycles of humidity testing and continuous electrical load.

    Understanding Model and Specifications—Why Tight Control Matters

    End users often ask whether tighter analytical thresholds make an operational difference. Over the years, we have witnessed how trace byproducts in commodity diols—especially linear or lightly-branched variants—introduce fouling in polyol reactors. For 2,5-Dimethyl-2,5-Hexanediol, our typical GC analysis shows purity exceeding 99.5%, with the sum of other isomers and related alcohols held below 400 ppm. Odorless and colorless appearance consistently signals batch stability. Because only the isomer with dimethyl groups at the 2 and 5 carbons provides ideal viscosity and softening point for critical resin curing, purity translates directly into process yield.

    Routine particle sizing ensures zero crystallization during storage. Viscosity and melting point analysis—done for every production batch—safeguards ease of blending in automated reactors. By listening to issues flagged by plant operators, we shifted our drying cycle and package in nitrogen-flushed drums; this adjustment decreased field reports of clumping in cold-weather regions. Laboratory and pilot-scale users appreciate that our product melts cleanly at 124–126°C, has a density near 0.92 g/cm3 at room temperature, and stays pourable even in modestly heated holding tanks. These details only emerge after hours of watching automated lines and interviewing partners down the supply chain.

    Comparing 2,5-Dimethyl-2,5-Hexanediol to Other Diols

    We regularly field questions about how our 2,5-dimethyl offering stacks up against other diols such as 1,6-hexanediol or cyclohexanedimethanol. During head-to-head pilot runs, linear 1,6-hexanediol, a common polyester intermediate, tends to accelerate resin crystallization and can induce clouding or embrittlement at higher concentrations. The extra methyl groups in 2,5-Dimethyl-2,5-Hexanediol interrupt this behavior. They introduce steric hindrance at the reactive site, which slows down unwanted crosslinking and increases flexibility. Finished elastomers handle repeated compression or elongation without cracking, and cast coatings show improved toughness under thermal cycling.

    Cyclohexanedimethanol, while highly desirable for increasing resin weatherability, comes with a higher price tag and can make processing more difficult due to its bulkier, ring-based structure. In contrast, our 2,5-dimethyl version balances melt flow, handling behavior, and shelf price—making it a more attractive option for manufacturers seeking flexibility and clarity without losing out on processability or cost control.

    Some engineers consider diethylene glycol or short-chain glycols, but those alternatives generally raise volatility, toxicity, or water pickup—risking defects, yellowing, or environmental impact downstream. Our focus on 2,5-dimethyl derivatives helps end-users achieve low-emissions targets and avoid byproduct issues tied to glycols with lower flashpoints or more pronounced odor profiles. Having worked with both product families, we see fewer complaints regarding workplace air quality and downstream product emissions with our hexanediol, especially in tightly controlled applications.

    Real-World Feedback from Coatings, Plastics, and Resins

    Coatings formulators frequently express frustration with batch-to-batch variability, especially where suppliers cut corners on dehydration or settle for mid-grade raw stocks. Over several decades, we have learned that investing in front-end distillation and aggressive impurity rejection pays back throughout the value chain. Several partners in the powder coatings space note cleaner extrusion in their twin-screw reactors, reduced downtime due to “plate-out,” and less yellowing of clear coatings after switching to our diol. In the automotive plastics segment, one processor reported tensile retention improved by over 15% after transitioning from a generic blend to our high-purity grade.

    A polyurethane foam manufacturer in the insulation sector recounted problems with unwanted foam collapse and inconsistent open-cell structure linked back to poorly controlled raw material moisture. By controlling water below strict thresholds and using on-site FTIR verification, we supplied a solution that eliminated two weekly line shutdowns, saving both energy and labor. Our team continues to gather these stories to refine purification steps—including the vapor-phase stripping and polish filtration methods refined from line operator observations.

    Plastics compounders in outdoor goods, from recreation to construction, remark on how clarity and long-term surface gloss align closely with the structure and purity of feedstock diol. In one case, a compounder tracked how diol changes led to measurable yellow index drift in polycarbonate blends; once they settled on our purified 2,5-dimethyl-2,5-hexanediol, yellowing stabilized, and complaints from downstream buyers fell off noticeably. It’s stories like these that shape the standards by which we judge every production run, rather than marketing platitudes or generic promises.

    Supporting Better Factory Practices and Eco Goals

    Sustainability pressure keeps increasing across chemicals supply chains. Over the years, partners in construction materials, automotive, and textiles identified diol selection as an underestimated factor in reducing waste and off-specification scrap. The lower volatility profile of 2,5-dimethyl-2,5-hexanediol helps facilities contain organic emissions, meeting more stringent regulatory caps now present across North America, Europe, and parts of Asia. Production partners observed consistently lower VOC emissions per ton of resin manufactured compared to glycol or less-branched alternatives—a direct result of our tight boiling point consistency and low-residual aldehyde content.

    We routinely assist firms looking to phase out higher-toxicity raw materials or cut back on process waste. Our purification methods, established through trial and local environmental feedback, mean less risk of hazardous byproduct buildup in process streams. One resin blender, under regulatory audit, shifted exclusively to our 2,5-dimethyl-2,5-hexanediol; follow-up reports showed improved compliance and a drop in required solvent stripping volumes, which had previously climbed due to shifting feedstock impurity.

    Green chemistry isn’t just a buzzword among our teams. Technical process engineers on our floor design recovery and reuse cycles for off-gas, recycle process filtrate where possible, and cut freshwater demand in every batch run. These improvements don’t always show up in technical data sheets, but customers have come to value consistent quality delivered with knowledge of evolving environmental expectations.

    Lessons Learned and Forward-Looking Efforts in Diol Manufacturing

    Chemicals manufacturing remains unforgiving. Missed moisture check? The next day, whole batches of foam collapse or resin coats fail. Rushed purification? Weeks later, pigment floats and line managers waste thousands fixing process hiccups. Our experience teaches that small investments in analytical vigilance pay big dividends as downstream performance and reliability for partners in dozens of industries. This isn’t just a theory proved in the lab—it’s real consequences for reputation, safety, and economics.

    Spending time in both the control room and the warehouse, our crews know how moving even a single specification up a notch—reducing volatiles, shifting isomer ration, squeezing a melting point’s variability—leads to tangible, everyday reliability. Operators managing coatings lines or foam reactors confirm that our approach, combining gradual historical tweaks with close customer feedback, keeps rejected lots rare and troubleshooting simple.

    We see a future where 2,5-Dimethyl-2,5-Hexanediol isn’t just another polymer intermediate, but a cleaner, more versatile molecular building block for greener resins, stronger gels, and lighter, safer plastics. Already, the spread of additive manufacturing, advanced composites, and bespoke elastomers hinges on raw material predictability and expanded safety envelopes. Our goal is to stay at the forefront, refining both product and process to support whatever requirements tomorrow brings, from electric mobility to microelectronics or next-generation coating systems.

    Every Lot, Every Drum: Accountability Through Transparency

    In the world of chemical production, lasting trust rarely comes from price or paper specs. With 2,5-Dimethyl-2,5-Hexanediol, customers work with a team that exposes every relevant variable. Regular audits ensure every lot receives double-checked GC and Karl Fischer runs, packaging teams record drum weights and seal numbers, and logistical staff checks every label and manifest for full traceability. Problems get identified, not buried, and our staff regularly hosts open sessions with field engineers, technical buyers, and regulatory officers to adapt practices for both current, and emerging market needs.

    In summary, 2,5-Dimethyl-2,5-Hexanediol has become a go-to for customers looking to elevate final product quality in coatings, adhesives, plastics, resins, and beyond. Each improvement to our process comes from direct dialogue with the manufacturers who rely on our diol for more durable, flexible, and environmentally sound products. As a long-term manufacturer, holding to these standards isn’t just about regulatory compliance or market share, but about keeping every promise made, from sample to full-load shipment.