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2,5-Dibromo-3-Hexylthiophene

    • Product Name 2,5-Dibromo-3-Hexylthiophene
    • Alias 2,5-Dibromo-3-hexylthiophene
    • Einecs 809-198-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    729764

    Cas Number 125731-66-0
    Molecular Formula C10H14Br2S
    Molecular Weight 341.00 g/mol
    Appearance Light yellow to brownish powder
    Melting Point 40-45°C
    Purity Typically ≥98%
    Density 1.70 g/cm³ (approximate)
    Solubility Soluble in organic solvents such as chloroform and dichloromethane
    Smiles CCCCCCc1c(Br)cscc1Br
    Inchi InChI=1S/C10H14Br2S/c1-2-3-4-5-6-8-7-13-10(12)9(8)11/h7H,2-6H2,1H3
    Storage Conditions Store at 2-8°C, protect from light and moisture
    Hazard Statements H315 (causes skin irritation), H319 (causes serious eye irritation)

    As an accredited 2,5-Dibromo-3-Hexylthiophene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The 5g of 2,5-Dibromo-3-Hexylthiophene is packaged in a sealed amber glass vial, clearly labeled with product and safety information.
    Shipping 2,5-Dibromo-3-Hexylthiophene is securely shipped in sealed, chemical-resistant containers to prevent leakage or contamination. The package is clearly labeled, and accompanied by a Safety Data Sheet (SDS). It is transported according to relevant regulations for hazardous chemicals, ensuring safety during transit. Store in a cool, dry, well-ventilated area upon receipt.
    Storage 2,5-Dibromo-3-hexylthiophene should be stored in a tightly sealed container under an inert atmosphere, such as argon or nitrogen, to prevent moisture and air exposure. Keep it in a cool, dry, and well-ventilated area away from direct sunlight, heat sources, and incompatible substances such as strong oxidizers. Store at room temperature or as specified by the supplier’s guidelines.
    Application of 2,5-Dibromo-3-Hexylthiophene

    Applications of 2,5-Dibromo-3-Hexylthiophene in Industrial Manufacturing

    2,5-Dibromo-3-Hexylthiophene is a key monomer in the synthesis of advanced organic electronic materials, supporting high-performance manufacturing in semiconductors, functional coatings, and precision electronics. Below, we present exclusive, well-established industrial application scenarios, each defined by precise compliance standards, technical formulation guidance, fitment in downstream workflows, and commercially significant end product categories.

    1. Organic Photovoltaic (OPV) Cell Polymer Synthesis

    Leading manufacturers utilize this compound as a regioregular monomer for producing poly(3-hexylthiophene) (P3HT), driving high-efficiency OPV layer fabrication. Exacting process controls enable precise microstructure to maximize charge carrier mobility in solar cell modules, while tightly monitored raw material supply is essential for batch reproducibility demanded by module assemblers.

    Industry compliance standards

    • IEC 61215:2016 for photovoltaic module performance qualification
    • RoHS Directive 2011/65/EU (lead, mercury, cadmium content)
    • REACH Regulation (EC) No 1907/2006 (registration and safety assessment)
    • ISO 9001:2015 for quality management systems in device manufacture

    Typical usage ratio

    • Used at 95–98 mol% in the polymerization mixture for P3HT precursor formulation; proportion adjusted based on chain length control and final OPV layer requirements, with minor co-monomers occasionally incorporated for functional tuning.

    Downstream process integration

    • Enters at the monomer charging step of Grignard metathesis polymerization (GRIM process), followed by purification and dispersion into device-grade ink formulations for roll-to-roll coating or spin casting onto substrate foils.

    Final product types

    • Flexible organic photovoltaic panels
    • Portable solar chargers
    • Semi-transparent solar films for building-integrated photovoltaics (BIPV)
    • Specialty solar modules for low-light and wearable applications

    2. Organic Field-Effect Transistor (OFET) Semiconductor Fabrication

    Circuit designers and device manufacturers depend on this intermediate for high-mobility polymer semiconductors in OFETs, where uniform film morphology and defect minimization are non-negotiable. Customers require monomer grades meeting semiconductor purity criteria and lot-to-lot chromaticity stability for critical integration into printed electronics production lines.

    Industry compliance standards

    • JEDEC JESD22-A114E for electrostatic discharge performance
    • IPC-4101C laminate and prepreg standards
    • IPC-A-600 for PCB acceptability
    • ISO 14644-1:2015 for cleanroom environments during fabrication

    Typical usage ratio

    • Introduced at 90–99 mol% in backbone-forming copolymerizations, with ratio optimized according to intended charge-carrier type (electron or hole dominant) and film uniformity required for sub-micron device architectures.

    Downstream process integration

    • Dosed during controlled monomer addition in Suzuki or Stille coupling reactions, then purified oligomers are solution-processed by slot-die, inkjet, or screen printing onto pre-patterned substrates for subsequent annealing steps.

    Final product types

    • Active matrix organic field-effect transistor arrays
    • Flexible e-paper display backplanes
    • Printed RFID tags and sensors
    • Low-voltage OFETs embedded in smart packaging

    3. Flexible Display (OLED) Anode Buffer Layer Additives

    Display manufacturers require this specialty intermediate for modifying interface layers in OLED stacks. Engineered thiophene-based copolymers, incorporating this unit, optimize hole injection and buffer stability, directly influencing device lifespan and brightness uniformity. Adherence to international restriction of hazardous substances (RoHS) and precise process metrology is mandatory for qualification.

    Industry compliance standards

    • IEC 62341-5-1:2011 for OLED lifetime and reliability
    • RoHS Directive 2011/65/EU
    • CQC Quality Conformance Certification for flat panel displays (China Compulsory Certification in supply chains serving Chinese OEMs)
    • ISO/TS 16949 for automotive display quality management

    Typical usage ratio

    • Dosed at 1–10 wt% in composite buffer layer solutions; precise percentage set through pilot runs correlating to target work-function modulation and desired wetting behavior on ITO (indium tin oxide) substrates.

    Downstream process integration

    • Compound introduced to buffer layer ink blends before slot coating or gravure printing onto anode structures, followed by controlled curing protocols under inert atmosphere to preserve electronic structure.

    Final product types

    • Flexible OLED smartphone displays
    • Curved automotive dashboard panels
    • Wearable flexible screens
    • High-brightness AMOLED TV modules

    4. Sensor and Biosensor Conductive Polymer Matrix

    Medical device and environmental sensor producers rely on this key building block for fabricating sensitive polymer-based transducing layers. Applications focus on precision chemical functionalization and nanocomposite integration to achieve high selectivity, repeatability, and reproducibility. Reliable sourcing directly affects downstream sensor calibration and functional stability over device lifetimes.

    Industry compliance standards

    • ISO 13485:2016 for quality management systems in medical devices
    • EN 60601-1 for electrical safety of medical equipment
    • ISO 10993-1 for biological evaluation of medical devices
    • ECHA REACH compliance for material registration and safe use in the EU

    Typical usage ratio

    • Utilized at 80–98 mol% in polymer backbone formation, with ratio adjusted based on targeted transducing properties and level of sensor functionalization (designed via empirical testing for specific analyte classes).

    Downstream process integration

    • Fed directly into monomer charging systems for electropolymerization or chemical oxidative polymerization, followed by in situ deposition or casting on microelectrode arrays or flexible sensor substrates.

    Final product types

    • Disposable glucose biosensor strips
    • Wearable electronic nose arrays
    • Polymer-coated microelectrode sensors for water and air monitoring
    • Biomedical sensor patches for real-time screening

    5. Antistatic and Electrostatic Discharge (ESD) Coating Formulation for Electronics Packaging

    Producers of high-purity electronic packaging employ this material to synthesize intrinsically conductive polymers tailored for ESD protection. Technicians formulate these coatings to meet strict surface resistivity thresholds, ensuring safe dissipation of static charges in automated handling lines for integrated circuits and display glass, while conforming with both regional and global packaging safety standards.

    Industry compliance standards

    • ANSI/ESD S20.20 for ESD control program requirements
    • IEC 61340-5-1:2016 for ESD in electronic devices
    • JIS C5022 for plastic ESD packaging
    • UL 94 V-0 flammability for packaging materials

    Typical usage ratio

    • Added at 5–30 wt% in base polymer blends depending on whether a transparent or opaque antistatic layer is required, with real-time resistivity testing during pilot production dictating precise loadings.

    Downstream process integration

    • Dispersion into water- or solvent-based coating formulations, followed by spray, dip, or roll-coating onto trays, reels, or barrier films, then subject to controlled thermal curing to lock in conductivity properties.

    Final product types

    • Antistatic wafer handling trays
    • IC chip carrier tapes
    • Protective static dissipative films for display glass
    • Reel-to-reel ESD-shielding packaging
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    Certification & Compliance
    More Introduction

    Introducing 2,5-Dibromo-3-Hexylthiophene

    A Closer Look at One Specialty Chemical

    Manufacturing 2,5-Dibromo-3-Hexylthiophene isn’t a routine batch job. We’ve been making specialty thiophenes for over a decade, so each process step comes from hands-on experience with organic bromination, not off-the-shelf chemistry. Research labs, formulation chemists, and advanced materials engineers count on the purity and consistency of our product. In our industry, small changes in process or starting material can swing the properties of the compound more than theory sometimes predicts. Our production approach maximizes the structural integrity of the final molecule, curbing unwanted side products that upset downstream synthesis of polythiophenes and semiconducting polymers.

    We synthesize 2,5-Dibromo-3-Hexylthiophene using controlled, multi-stage reactions. Our method consistently hits targets for appearance and spectral purity. Average output from our reactor yields a crystalline, high-purity compound with reliable melting point and low residual solvent. Once the reaction completes, the work doesn’t stop at mere filtration. We rigorously wash, dry, and analyze every batch by NMR and GC. Labs benefit from our repeatable results—the same compound profile for every order.

    How 2,5-Dibromo-3-Hexylthiophene Supports Modern Research

    Interest in organic semiconductors has exploded in recent years. One main branch depends on designing conjugated polymers and donor-acceptor structures for thin-film transistors, solar cells, and flexible displays. Our 2,5-Dibromo-3-Hexylthiophene plays an essential role in this evolution. Chemists use this compound as a monomer for Stille and Suzuki coupling reactions to build poly(3-hexylthiophene) and related functional materials. This monomer forms the backbone for many next-generation devices requiring tight control on molecular weights and block lengths.

    We’ve heard from university research teams and industrial innovation labs who bank on this compound for their own new polymer structures and device prototypes. Because impurities or isomers in the starting monomer degrade performance in electronic materials, feedstock purity isn’t just another number—it directly steers device efficiency and reproducibility. Our clients send feedback on their device yields and reproducibility, which helps refine upstream synthesis and handling every year.

    Model and Key Parameters from the Perspective of Production

    We routinely produce 2,5-Dibromo-3-Hexylthiophene in 50-kg lots. The chemical structure is well known in literature: thiophene ring, bromines at positions 2 and 5, hexyl group at position 3. Our process has evolved through persistent work on reaction parameters, bromination conditions, and purification protocols. Effective loading, well-controlled reaction times, and careful post-synthesis separation ensure the product emerges with unambiguous spectral confirmation and no detectable isomeric or halide contaminants.

    Our routine controls include checks on melting range, solubility in key organic solvents, and chromatographic purity. Laboratory reports, confirmed by external analysis, repeatedly show GC purities above 99 percent and low heavy metal content. Occasionally, material sits in the reactor longer than it might elsewhere—we take the extra time to guarantee residual oxidants or off-target bromination don’t creep in.

    Comparing to Other Specialty Thiophenes

    Not every dibromo thiophene is made for electronic materials. Switching the alkyl chain to butyl or octyl, or repositioning bromines on the ring, shifts the polymerization behavior and device output. Experience shows 3-hexyl substituents strike the right balance for processability, crystallinity in thin films, and stability during deposition. Many early researchers tested different chain lengths, but poly(3-hexylthiophene) derived from our monomer has proven repeatably valuable in both academic and commercial settings.

    Raw thiophenes with poorly specified chain lengths or inconsistent halogenation don’t work the same in catalyzed polymerizations. These differences go beyond the numbers on a certificate—they reflect into solubility, film formation, and overall reliability of the organic electronic devices. We see research-scale batches with variable conversions or discoloration; in contrast, customers tell us our well-characterized material helps secure stable yields and sharper device behavior.

    Working for Purity and Reliability

    At our facility, the plant staff shares a particular pride in monitoring every batch. Automated sampling during reaction steps links straight to digital records. Staff troubleshoot the odd batch right at the filtration and washing stations, not from a control room. These hands-on details might not make the marketing brochure, but they matter every time a researcher counts on their thin films assembling as planned.

    From experience, even minor impurities such as trace dibromo or hexyl contaminants harm the physical properties of downstream polymers. Our history with both in-house and customer returns tells us the lowest impurity loads reduce device-to-device variation. Every year, research labs push for stricter specifications, and we use both classic chromatography and modern mass spectrometry to chase down even faint unwanted peaks. Rather than just aiming for “reagent grade,” our standard aims for what enables next-stage fabrication or publication without surprises.

    Understanding the Marketplace and Its Tensions

    The chemical market for advanced materials brings its own challenges. As demand surges for organic electronics, inconsistent batches from casual vendors clog up supply chains. Our team spends time walking prospective users through their purification needs, even when it means pointing out the downside of cutting corners with questionable intermediates.

    Device makers, especially those in photovoltaic and OLED lines, remind us every month: a costly production error doesn’t stem from the final assembly process, but somewhere back along the supply route. Raw materials often sink R&D budgets when unexpected spectroscopic signals pop up just before integration. Having built polymers with our own material, we know how these hidden differences reflect in field-effect mobility or photovoltaic efficiency. Process integrity at scale gives us a rare window into how “small” things in the synthesis can reverberate throughout a commercial project.

    Our Direct Experience in Processing and Shipping

    The logistics team at our site packs 2,5-Dibromo-3-Hexylthiophene directly after final drying and vacuum sealing. We store the material in amber glass under inert atmosphere to preserve stability and keep batch integrity intact for global shipment. Temperature swings and transit times matter. Customers in humid or tropical zones often face clumping and loss of flow in poorly protected containers; we choose packaging systems based on the destination’s climate.

    Returns and complaints spark real investigation on the production floor. If a customer in Northern Europe reports fine particulate or off-color crystals, we hop right on the analysis, comparing before-and-after shipping photomicrographs. Often the difference arises from air incursion mid-shipment or a slip during intermediate drying. By closing these feedback loops, every year’s output surpasses the last for physical uniformity and analytical profile.

    End Uses and Direct Feedback

    We regularly connect with chemical engineers working in fields from organic electronics to advanced coatings. Many share how our 2,5-Dibromo-3-Hexylthiophene integrates as a starting point for fabricating high-performance thiophene-based devices. Some scale up to multikilogram polymerization runs, pressing the same input batch through stepwise coupling and allowing for finely tuned polymer chain growth.

    Application notes the team receives include successful examples in thin-film transistors, OFETs, and flexible solar cells. Researchers supply feedback about reproducible molecular weights, polymer dispersity, and end-capped macromolecules all stretching from the initial monomer purity. Synthetic consistency allows them to chase higher device efficiencies and better stabilities, even as research requirements get narrower and more challenging every year.

    Potential Issues in Supply, and How We Act

    Supply chain headaches challenge every chemical manufacturer sooner or later. Bromine sourcing, thiophene ring supply, and solvent purity can't always be predicted a year in advance. Some years, raw material pricing volatility pushes up costs or squeezes output rates. Facing this, we buffer stock critical intermediates, prequalify secondary suppliers, and test every drum at receipt. Our technical staff refuses to trust lot numbers alone; direct spectroscopy gets performed on every raw barrel, right down to checking for isotopic drift after major regulatory changes in supplier source regions.

    Export rules can change, especially for precursors flagged by customs for unrelated applications. Our compliance team works tightly with global freight partners, monitoring policy maps and trade routes. Customers sometimes worry about delay impacts—if a batch sits in customs or faces a documentary mismatch, direct shipment alternatives and a buffer warehouse reduce headline risks.

    Industry Standards and Our Perspective on Upgrading

    Certification auditors expect documentation at every manufacturing step. ISO-level traceability works in our favor, since every batch carries signed-off analysis and links to operational history. Industry watchdog groups and major electronics companies now want environmental and process security audits, not blank declarations. Our facility has incrementally improved process control and waste minimization every year, not just for compliance, but to reduce surprises in every downstream application.

    Many smaller operations skip process audits in favor of rapid throughput. Based on what we hear from customers and end users, uncontrolled plants risk introducing byproducts that ripple through a client’s own supply chain. We invest in trained process chemists and analytical scientists on each shift. This real-time capacity pays off both in reduced customer questions and higher batch acceptance rates.

    Staff Training and Facility Safety

    Safe handling practices stem from years on the production floor. Each crew member cycles through hands-on training with real incident examples—a leak here, an overcharge there. Only practiced hands can hit the mark batch after batch. The team in our bromination suite works with full personal protective equipment, air monitoring, and automated shutdown for out-of-bounds readings. Safety isn’t a checkbox; it lives in every production record and gets reviewed during routine audits, not just after a rare event.

    Preventing cross-contamination guides our cleaning protocol. Dedicated reactors for thiophene analogues avoid ghost peaks and odd batch results for months afterward. In process-intensive plants, where tank swaps and quick-fixes tempt shortcuts, strict attention to cleaning between runs pays in lower contamination tickets and improved yields for the next product.

    Environmental Considerations in Manufacturing

    Responsible waste management and solvent recovery matter, even more as industry standards tighten. Bromination byproducts and halogenated solvent residues demand careful routing and treatment. Our facility recycles key solvents where possible and tracks every kilogram of waste for external treatment and regulatory reporting. Investment in closed-system transfers and vapor containment reduces off-site impact and helps keep neighborhood and employee health intact.

    We openly share environmental performance figures with our clients, often as part of their own compliance reporting. Keeping our own processes green aligns not just with government expectations, but also with the sustainability goals increasingly written into research grants and industrial procurement policies.

    Future Perspectives from the Bench

    Every year, our R&D group works with clients and internal process engineers to raise the bar on what’s possible with 2,5-Dibromo-3-Hexylthiophene. This means tightening specs, pushing for even smaller residual impurities, boosting process yields, and deploying new purification equipment. No two years look quite the same for feedstock demand, purification technology, or regulatory environment.

    Our team's direct bench experience often sets the direction for the next generation of in-house upgrades. Operator knowledge—built from fixing a stuck pump, or catching off-scale temperature drift in the moment—translates into tested improvements in plant workflow. Regular dialogue with customers helps anticipate changes in device manufacturing trends and emerging application requirements.

    In Summary: Real-World Value from Direct Manufacturing Expertise

    In today’s chemical market, producers face constant scrutiny over reliability, responsiveness, and product character. From years of manufacturing 2,5-Dibromo-3-Hexylthiophene, we’ve learned customers want more than a number on a grade—they want continuity, open technical communication, and proof of expertise behind the product. Our staff counts batch integrity and repeatable processing among personal achievements, knowing both researcher and global manufacturer rely on every lot’s performance.

    Nothing about this work is routine to our team. Every order, every research report, and every device trial that draws from our shipments connects back to real hands and trusted workflow. The goal remains steady: deliver a compound whose properties can be counted on, batch after batch, for customers pushing the boundaries of organic electronics, polymers, and next-generation materials.