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2,2-Bis(Hydroxymethyl)Propionic Acid

    • Product Name 2,2-Bis(Hydroxymethyl)Propionic Acid
    • Alias DMPA
    • Einecs 223-980-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    254613

    Chemicalname 2,2-Bis(Hydroxymethyl)Propionic Acid
    Abbreviation DMPA
    Casnumber 4767-03-7
    Molecularformula C5H10O4
    Molecularweight 134.13 g/mol
    Appearance White crystalline powder
    Meltingpoint 186-190°C
    Solubilityinwater Very soluble
    Boilingpoint Decomposes before boiling
    Phvalue 2.5-3.5 (1% solution)
    Density 1.32 g/cm³
    Odor Odorless

    As an accredited 2,2-Bis(Hydroxymethyl)Propionic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The chemical is packaged in a 25 kg white fiber drum with a secure plastic inner liner, clearly labeled with product and hazard information.
    Shipping 2,2-Bis(Hydroxymethyl)Propionic Acid is typically shipped in tightly sealed containers, protected from moisture and contamination. Standard packaging includes drums or bottles made of compatible materials. The chemical should be stored and transported at room temperature, away from incompatible materials, with appropriate hazard labeling and documentation as per relevant regulations.
    Storage 2,2-Bis(Hydroxymethyl)Propionic Acid should be stored in a tightly closed container in a cool, dry, well-ventilated area, away from sources of ignition and incompatible substances such as strong oxidizers and bases. Protect it from moisture and direct sunlight. Use appropriate personal protective equipment when handling to prevent skin and eye contact. Always follow relevant safety guidelines and local regulations.
    Application of 2,2-Bis(Hydroxymethyl)Propionic Acid

    Applications of 2,2-Bis(Hydroxymethyl)Propionic Acid in Industrial Manufacturing

    2,2-Bis(Hydroxymethyl)Propionic Acid, widely referenced as DMPA, supports advanced chemical synthesis across several manufacturing chains due to its high reactivity, dual hydroxyl and carboxylic groups, and strong water dispersibility. As a direct manufacturer, we ensure consistent quality suited for precise formulations in downstream sectors. Below, we detail major industrial application scenarios, focusing on critical process details and compliance for each use case.

    1. Waterborne Polyurethane Dispersions for Coatings

    DMPA enables the production of self-dispersing polyurethane prepolymers, creating robust, environmentally compliant waterborne coatings for wood, leather, automotive, and industrial surfaces. The material acts as a hydrophilic chain extender, providing distinct hydrolytic stability and improved chemical resistance in finished dispersions, and complies with strict VOC and emission regulations in global markets.

    Industry compliance standards

    • EU REACH Regulation (EC) No 1907/2006
    • United States EPA 40 CFR Part 59 - National Volatile Organic Compound Emission Standards
    • China GB 18582-2020: Indoor Decorating and Refurbishing Materials–Limit of Harmful Substances of Interior Wall Coatings
    • ISO 9001:2015 Quality Management

    Typical usage ratio

    • 1.5–4.5% by total polyurethane prepolymer mass; formulators adjust within this range depending on target particle size, emulsion stability, and crosslink density.

    Downstream process integration

    • Incorporate DMPA during polyol and diisocyanate reaction in prepolymer synthesis before neutralization and dispersion in water; neutralization with tertiary amines (e.g., triethylamine) follows for ionic stabilization.

    Final product types

    • Waterborne polyurethane topcoats for automotive and electronics casings
    • Low-VOC architectural wall paints and wood lacquers
    • Glossy and matt flexible plastic coatings
    • Leather finishing agents for apparel, furniture, and automotive trim

    2. Polyester Polyol Synthesis for Reactive Hot-Melt Adhesives (HMA)

    Manufacturers integrate DMPA as a diol monomer in polyester polyol reactions to create hydrophilic segments, allowing for improved miscibility and bonding in reactive HMA formulations. This material provides unique branching architecture, facilitating formulation of adhesives with enhanced initial tack strength, moisture resistance, and substrate compatibility under demanding curing conditions.

    Industry compliance standards

    • FDA 21 CFR 175.105 (Adhesives) for indirect food contact
    • ASTM D1876 (Peel Resistance of Adhesives)
    • DIN EN 923: Adhesives Terminology
    • ISO 14001: Environmental Management

    Typical usage ratio

    • 0.7–2.0% based on the total mass of polyester monomers; levels refined for targeted softening points and viscosity profiles of the adhesive strips or beads.

    Downstream process integration

    • Add DMPA directly to the polyol synthesis reactor with other polyols and dicarboxylic acids, catalyzing under controlled temperature to achieve designed molecular weight and acid value profiles prior to isocyanate capping.

    Final product types

    • Reactive hot-melt adhesives for packaging and bookbinding
    • Automotive interior assembly adhesives
    • Woodworking and construction bonding tapes
    • Electronics component lamination adhesives

    3. Alkyd Resin Modification for Waterborne Paints

    By incorporating DMPA, alkyd resin manufacturers achieve stable water dispersion without sacrificing molecular weight control or final film flexibility. This approach eliminates need for VOC-heavy co-solvents, yielding environmentally compliant solutions for decorative and protective coatings where traditional alkyds would not meet stricter emission and hazardous content requirements.

    Industry compliance standards

    • EU Directive 2004/42/EC: Limitation of Emissions of Volatile Organic Compounds
    • China GB 24408-2020: Waterborne Coatings for Automobiles
    • ISO 16000-9: Determination of the Emission of Volatile Organic Compounds from Building Products and Furnishing
    • EN 927-1: Paints and varnishes - Coating materials and coating systems for exterior wood

    Typical usage ratio

    • 1–3% relative to total alkyd chain-building monomers; levels adjusted based on branched structure need versus process viscosity control in the water-dispersing stage.

    Downstream process integration

    • DMPA reacts with fatty acid and polyol blend in the alkyd cook, followed by neutralization and high-shear dispersion in water phase after polyesterification.

    Final product types

    • Waterborne alkyd wood stains and varnishes for décor applications
    • Metal anti-corrosion primers and finish coatings
    • Industrial water-based enamels
    • Protective topcoats for agricultural equipment

    4. Cationic Electro-Deposition (CED) Coating Resin Synthesis

    DMPA supports advanced waterborne resin structures required in cationic electrodeposition, widely adopted for corrosion protection in automotive and heavy machinery industries. The acid’s dual functional groups improve resin dispersibility and film uniformity at optimal bath pH ranges—critical for high-throughput automated coating lines.

    Industry compliance standards

    • ISO 12944-5:2018 - Corrosion Protection of Steel Structures by Protective Paint Systems
    • GB/T 13452.2-2008: Determination of the film thickness of paints
    • SAE J2334 - Cosmetic Corrosion Lab Test
    • IATF 16949:2016 – Automotive Quality Management System

    Typical usage ratio

    • 1–3% relative to cationic polymer backbone; establishes anionic anchoring for salt formation, with the exact amount set according to resin charge density and desired particle size distribution.

    Downstream process integration

    • DMPA incorporates during resin polymerization before neutralization with organic amines, forming a water-dispersible prepolymer that is filtered and processed into CED coating baths.

    Final product types

    • Automotive body primer coatings (e-coat lines)
    • Heavy-duty machinery corrosion-resistant coatings
    • Appliance chassis primer layers
    • Coated pipes and rebar for infrastructure applications

    5. Ion-Exchange Resin Intermediate for Membrane Production

    Formulators apply DMPA as a functional branching monomer in the synthesis of ion-exchange resins where its carboxyl moieties impart controlled hydrophilicity and ion transport capability. This application serves industries reliant on specialty membrane systems for water purification and process separation under regulated quality and performance controls.

    Industry compliance standards

    • NSF/ANSI 61: Drinking Water System Components - Health Effects
    • EU Regulation (EU) 2019/1021 on Persistent Organic Pollutants
    • ISO 9001:2015 for quality system management in polymer manufacturing
    • China’s GB/T 19249-2003 Water Treatment Cation-exchange Resins

    Typical usage ratio

    • 0.5–1.5% relative to total monomer content during resin polymerization; level optimized to balance mechanical integrity versus ionic exchange rate as validated in downstream membrane performance tests.

    Downstream process integration

    • DMPA added at initial batch charge or premixed with other branching agents before cross-linking in suspension or solution polymerization reactors for ion-exchange resin beads or membrane casting solutions.

    Final product types

    • Cation and anion-exchange membranes for fuel cells
    • Industrial water purification cartridges
    • Desalination plant membrane elements
    • Separation resins for pharmaceutical processing

    6. Polyurethane Dispersion for Textile Finishing

    In textile manufacturing, DMPA-improved polyurethane dispersions enhance water-based PU topcoats, imparting softness, abrasion resistance, and color fastness. Neutralized dispersions allow direct application onto synthetic and natural fabrics under compliance with global consumer safety and emission standards in textile finishing processes.

    Industry compliance standards

    • OEKO-TEX® Standard 100 – Product Class I-IV
    • ZDHC Manufacturing Restricted Substances List (MRSL)
    • GB/T 32610-2016: Technical specification for daily protective masks (for coated fabrics)
    • ISO 4920: Determination of Resistance to Surface Wetting (Spray Test)

    Typical usage ratio

    • 2.0–4.0% in PU polymer solids; selected based on fabric porosity and targeted coating thickness for hand-feel and stretch properties.

    Downstream process integration

    • Add DMPA to the prepolymer synthesis phase before neutralization and inverse emulsion dispersion. Finished dispersions undergo filtration and quality control checks prior to high-speed padding/coating lines.

    Final product types

    • Faux leather and coated textile for apparel
    • Water-repellent uniform and workwear fabrics
    • Functional performance outerwear coatings
    • Medical and protective garment linings
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    Certification & Compliance
    More Introduction

    Understanding 2,2-Bis(Hydroxymethyl)Propionic Acid from the Source

    A Closer Look at Our Manufacturing Process

    Some chemicals leave a mark of consistency and reliability in the market. Working with 2,2-Bis(Hydroxymethyl)Propionic Acid (DMPA) for years gives a unique perspective on what matters most for end users. From the earliest synthesis steps to the final purification, DMPA production calls for careful control of reaction times, temperatures, and material sourcing. Each batch moves through a series of checks, not just because customers ask for tight specifications, but because our experienced team has learned that even minor shifts in pH or temperature can cause downstream problems with application results. Where others might accept a broader range, we see the benefit of spending extra hours to get consistent, high-purity material—this translates directly to smoother workflows in end-user applications.

    What Makes 2,2-Bis(Hydroxymethyl)Propionic Acid Unique

    There’s no need to rehash what every chemical catalog says. Let’s focus on real-world qualities that stand out. DMPA, with the molecular formula C5H10O4, brings a balance of solubility and reactivity that allows formulators to handle it with confidence. The bifunctional hydroxyl groups and the carboxylic acid group together make this compound a favorite for those looking to modify polymer backbones or increase hydrophilicity in polyurethanes and acrylics.

    Comparing DMPA to products like trimethylolpropane (TMP), we find that DMPA doesn’t only provide additional sites for crosslinking. Its acid functionality enables unique reaction pathways—not every competitor offers this dual reactivity. Over the years, customers come back for the reproducibility and versatility: DMPA soldiers on in dispersing agents, coatings, adhesives, and waterborne systems without the surprises that sometimes come from less rigorously manufactured intermediates.

    Consistent Specifications, Practical Benefits

    We manufacture and supply DMPA in both fine crystalline and granulated forms. Each has strengths, and decades of direct feedback from users has shaped our production choices. The fine crystalline material offers rapid dissolution in water or solvents, especially useful in high-throughput environments and automated dosing systems. Granulated grades are less prone to dusting, which appeals to teams working with less automated setups or trying to minimize airborne exposure during handling.

    Purity speaks for itself here. Our DMPA runs with a minimum purity of 99.0%, by HPLC analysis, and typical moisture levels under 0.5% as measured after packaging. Consistently low levels of inorganic residues mean fewer worries about foaming, color development, or unpredictable catalyst response at scale. Our lab team screens every lot for color using standardized APHA methods—expect water-white product that won’t tint finished polymers or dispersions, even under lower loading.

    Why Reliable DMPA Matters for Waterborne Systems

    Polyurethane dispersions (PUDs) thrive or fail based on the quality of their internal emulsifiers and chain extenders. Over and over, DMPA slots into these formulations because it enables stable, transparent dispersions while still maintaining mechanical integrity. We’ve seen formulators report direct improvements in film clarity and flexibility after switching to our product, simply due to the absence of off-spec contaminants common with less controlled manufacturing routes.

    It’s not just theory. Years ago, a major coatings producer faced inconsistent particle sizes and phase separation in their waterborne PU line. After switching their DMPA source (ours), particle measurements stabilized and finished films became more durable. DMPA’s carboxyl group, neutralized prior to dispersion, imparts the anionic charge essential for stable water dispersions, while the two hydroxyl groups become part of the polymer backbone, building internal strength. Without reliable DMPA, the tightrope between flexibility and chemical resistance can become impossible to walk.

    Performance in Coatings, Adhesives, and Beyond

    In coatings, the trend toward low-VOC systems places greater demand on every reactive monomer. DMPA supports higher solubility in water, allows for better pigment wash-in, and acts as a co-monomer to introduce functionality. Unlike monomers such as acrylic acid or hydroxyethyl acrylate, DMPA’s branched structure introduces less viscosity build-up during polymerization, so mixing and application run smoother. This may sound incremental, but on a production line even a few percent of viscosity improvement cuts hours from cleaning and downtime.

    DMPA offers some unassuming advantages in hot melt adhesives and sealants. Its high purity and narrow particle size minimize filter clogging, which keeps lines moving and maintenance intervals farther apart. Chlorine- or sulfur-bearing impurities, which crop up in some lower-tier DMPA, never make it past our final filtration and quality screens, so users don’t run into unwelcome surprises down the road.

    Other common polyols or chain extenders—such as neopentyl glycol or 1,4-butanediol—bring their own strengths, but DMPA’s extra acid group unlocks formulation strategies those cannot reach. This distinct feature enables progressive developments in responsive coatings and functional adhesives.

    Customization through Experience, Not Guesswork

    Over time, specialty applications lead to questions: can the product be tailored for unique solubility, low dust, or specific reactivity? In our plant, adapting DMPA doesn’t involve changing something for novelty’s sake. It means tweaking pH during precipitation, adjusting particle gradation, or selecting specific drying conditions—all guided by past project data. For customers building high-gloss or highly-flexible finishes, we’ve learned to keep trace elemental impurities as low as technically feasible, because even a few ppm of transition metals can turn white polymers yellow after years in sunlight.

    Not all production runs are the same. Detailed batch records, cross-checked by our senior technicians, mean reproducibility from one lot to the next. Some users require tailored moisture targets or controlled bulk densities; these are not “one size fits all” parameters carved out for brochure copy—they are the result of direct requests from users with specific needs, and we’ve learned they pay dividends in productivity.

    The Differences Between DMPA and Other Polyols

    Anyone blending polyols for resins or dispersions finds a crowded toolbox: from simple diols like ethylene glycol to branched options like trimethylolpropane. DMPA stands out for being both a dihydroxy and a monoprotic acid, offering greater flexibility in crosslinking reactions and ionic modification. Get a batch of DMPA with insufficient purity or the wrong crystal morphology, and pump filters clog, final dispersions become cloudy, or reaction times drift all over the place.

    Other polyols may deliver similar hydroxyl content by weight, but can’t match DMPA’s balance of reactivity and downstream process stability. Because DMPA introduces an acid group, it enables effective salt formation, improving process control for water-dispersible systems. Over the years, feedback from producers of automotive coatings and technical textiles has highlighted this difference—no replacement delivers the same combination of fast reaction, pH control, and low color pickup.

    Meeting the Challenges of Scale-Up

    On the plant floor, every batch size brings new variables. Small-volume laboratory conditions are forgiving, but moving to batch or continuous plant production reveals which DMPA supplies hold up through mixing, transfer, and in situ reactions. Many customers tell us stories of product consistency: whether they’re blending 25 kg batches for routine coatings tests or managing multi-metric-ton reactors for PUD production, product from our lines dissolves and reacts as expected, without strange sediment or color issues. This reliability comes not from luck, but from experience in scaling up batch sizes and confirming that process water, raw material grade, and even air humidity levels have to be controlled precisely.

    Automation has changed a lot about chemical manufacturing. Gravity-fed conveyors and enclosed transfer lines reduce dust and variability, but only if the feedstock comes in a stable, consistent form. Our DMPA arrives with controlled bulk density and minimal caking, so automated feeders or batch blenders don’t jam. This may seem a small point, but it makes the difference between one experienced operator running a production line with confidence or troubleshooting for hours due to an inferior raw material.

    Regulation, Safety, Environment

    Producers now face more scrutiny on chemical sourcing, downstream impact, and worker safety than ever before. Within our own operation, DMPA manufacture remains a tightly controlled process. Dusting risk is kept low by custom granulation settings, and packaging is designed for both stability and ease of emptying. For waterborne and low-emission processes, our DMPA offers a route to compliance with ever-tougher VOC guidelines, and the low impurity profile further supports closed-loop recycling and safe water discharge.

    Environmental responsibility reaches beyond just compliance. Each drum or pallet that leaves our dock is tracked for traceability, so users can match every shipment back to testing records and certificate data. Over the past decade, the drive for VOC controls and greener materials pushed us to further tighten our in-process controls. Our team keeps up with regulatory updates and regularly participates in industry forums and working groups, so challenges get translated into product improvements as quickly as possible.

    Feedback from Our Partners Drives Progress

    Custom products are shaped by the technical and practical challenges shared by partners and users. From customer audits to plant visits, we listen to chemists and operators who assemble and test their own systems. If an adjustment in crystal size cuts their reaction time by minutes or eliminates clumping on storage, we build these learnings into our process maps and training.

    Over the years, our R&D group has developed analytical protocols well beyond the standard melt point or hydroxyl number. Infrared scans, trace metals by ICP, and water activity measurements reveal differences invisible to basic wet chemistry but critical in final product performance. These refinements didn’t come out of the blue; they developed from on-the-ground collaboration and an openness to help users test, troubleshoot, and optimize.

    Raw materials from direct sources allow for quick tweaks and problem solving that big distribution chains struggle to provide. The operators who have spent decades with us—running reactors, troubleshooting filters, maintaining analytical logs—bring up issues and propose ways to improve sampling or reduce handling time. Their expertise threads through every lot, and many a final inspection sign-off still carries notes passed from operators who caught a deviation before it ever became a field complaint.

    Building Value through Experience

    It’s easy to list technical advantages, but the ultimate measure lies in repeatability and evidence. Material matches its certificate. Labs and shop floors run longer, troubleshooting drops, and end product performance tracks with expectations. These benefits grow not just from the technical details of carboxylic acid and hydroxyl groups, but from years of manufacturing vigilance, customer insight, and a willingness to invest in better process control.

    Raw technical specs do not deliver success on their own. It takes operators with practical know-how, chemists reading between the lines of titration curves, and plant managers willing to adopt changes from anecdotes picked up during real-world troubleshooting. DMPA succeeds in advanced coatings, adhesives, and dispersions because the people crafting it pay attention to more than just numbers on a certificate—they aim to deliver material that performs batch after batch, application after application.

    Directly shaping each stage of product handling, from raw acid synthesis to the drying and packing line, gives our team a backward and forward view of what makes DMPA truly reliable. Listening to what works in a user’s plant environment, as well as responding quickly when a batch needs a special lot release or re-testing, means our product isn’t just manufactured but actively improved in partnership with the industry.

    Conclusion: The Role of Trusted Manufacturing

    2,2-Bis(Hydroxymethyl)Propionic Acid provides more than a set of chemical functions on paper. It bridges the gap between laboratory ideal and production reality. Backed by a team that combines long-term manufacturing discipline with an open ear for customer feedback, every lot that leaves our floor reflects both a technical lineage and years of lived experience. DMPA that meets or exceeds requirements saves time, reduces rework, and enables innovation— not as an abstract promise, but by proving itself, one drum at a time, in factories and labs around the world.