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2,2-Bis(4-Hydroxyphenyl)Butane

    • Product Name 2,2-Bis(4-Hydroxyphenyl)Butane
    • Alias Bisphenol B
    • Einecs 202-852-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    451707

    Chemicalname 2,2-Bis(4-Hydroxyphenyl)Butane
    Synonyms 4,4'-Butylidenebisphenol
    Casnumber 77-40-7
    Molecularformula C16H18O2
    Molarmass 242.32 g/mol
    Appearance White crystalline powder
    Meltingpoint 165-168 °C
    Boilingpoint 410.9 °C at 760 mmHg
    Solubilityinwater Insoluble
    Density 1.174 g/cm3
    Refractiveindex 1.603
    Purity Typically >98%
    Pka 10.29 (phenolic OH)
    Flashpoint 230.1 °C
    Ecnumber 201-025-1

    As an accredited 2,2-Bis(4-Hydroxyphenyl)Butane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Opaque, amber glass bottle containing 100 grams of 2,2-Bis(4-Hydroxyphenyl)Butane, tamper-evident cap, labeled with safety and handling instructions.
    Shipping 2,2-Bis(4-Hydroxyphenyl)butane is typically shipped in tightly sealed containers to protect from moisture and light. It should be stored and transported at ambient temperature, in accordance with local regulations. Proper labeling and appropriate safety documentation are required to ensure compliance with chemical handling and shipping standards.
    Storage 2,2-Bis(4-Hydroxyphenyl)butane should be stored in a tightly sealed container, protected from light and moisture. Keep it in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizing agents. Properly label the storage container, and ensure access is limited to trained personnel. Follow standard laboratory chemical storage protocols and local regulations.
    Application of 2,2-Bis(4-Hydroxyphenyl)Butane

    Applications of 2,2-Bis(4-Hydroxyphenyl)Butane in Industrial Manufacturing

    2,2-Bis(4-Hydroxyphenyl)Butane, a specialty dihydroxy compound, serves as a critical raw material in several advanced industrial sectors. Its applications rely on high purity, precise dosing, and strict process compatibility, supporting the creation of high-performance polymers and various specialty chemical products. Below is a detailed overview of its use in key downstream industries, highlighting real formulations, regulatory compliance, integration in manufacturing processes, and end product categories.

    1. Polycarbonate Resin Production

    This material functions as a structural monomer for high-gloss, heat-resistant polycarbonate resins, prized in construction, automotive, and electronics for their dimensional stability and mechanical toughness. As a variation to traditional Bisphenol-A, its controlled introduction modifies molecular weight distribution and improves melt flow for specific molding applications.

    Industry compliance standards

    • ISO 19069-2 (Plastics — Polycarbonate (PC) molding and extrusion materials — Part 2: Preparation of test specimens and determination of properties)
    • UL 746C (Polymeric Materials—Use in Electrical Equipment Evaluations)
    • REACH Annex XVII and SVHC (Substances of Very High Concern, for European market acceptance)
    • RoHS Directive 2011/65/EU (Restriction of Hazardous Substances) for electrical and electronic equipment applications

    Typical usage ratio

    • 2–10 mol% substitution in the bisphenolic monomer feed, adjusted according to target molecular architecture and desired thermal performance

    Downstream process integration

    • Introduced during the interfacial polymerization or melt transesterification step, dissolved and reacted with phosgene or diphenyl carbonate under controlled pH and temperature

    Final product types

    • Engineering polycarbonate sheets and films (for glazing, safety panels, optical discs)
    • Precision-molded automotive components (light housings, interior trims)
    • Electronic casings and connectors requiring flame retardancy

    2. Epoxy Resin Hardener Modifiers

    This raw material serves as a secondary diol modifier in advanced epoxy resin formulations, specifically for electronic encapsulation and high-durability coatings. The introduction of 2,2-Bis(4-Hydroxyphenyl)Butane improves network flexibility and increases impact resistance in the crosslinked matrix, addressing process brittleness in microelectronic and coil impregnation applications.

    Industry compliance standards

    • IEC 61249-2-21 (Epoxy-based resins for printed circuit boards)
    • IPC-4101E (Specifications for base materials for rigid and multilayer PCBs)
    • ASTM D1655 (Epoxy resins in electrical laminates)
    • UL 94 V-0 (Flame Classification Requirements for Plastic Materials)

    Typical usage ratio

    • 3–8 parts per hundred resin (phr), controlled by the target balance of glass transition temperature and impact elongation in the formulated resin system

    Downstream process integration

    • Blended directly with epichlorohydrin and bisphenol A or F during the resin synthesis phase, often prior to the addition of curing agents or hardeners

    Final product types

    • Potting compounds for semiconductor components
    • Electrical coil encapsulants and transformers
    • High-durability industrial protective coatings for steel infrastructure

    3. Specialty Polyester Synthesis

    2,2-Bis(4-Hydroxyphenyl)Butane acts as a co-monomer for synthesizing high-molecular-weight polyesters with improved thermal aging properties and chemical resistance. Polyesters produced with this component demonstrate tailored crystallization behavior, finding uses in applications requiring heat-set stability and low extractables, such as specialty fibers and engineered films.

    Industry compliance standards

    • FDA 21 CFR 177.1590 (Polycarbonate resins for food contact settings, relevant where materials are used in containers or films)
    • ISO 527 (Determination of tensile properties of plastics)
    • OEKO-TEX Standard 100 (Textile safety)
    • EN 1186 (Materials and articles in contact with foodstuffs — Plastics)

    Typical usage ratio

    • 1–12 mol% of total diol content, variable based on crystallinity and hydrolytic resistance specifications in the target polyester system

    Downstream process integration

    • Added during the esterification or transesterification stage, typically with dimethyl terephthalate and aliphatic diols under vacuum and elevated temperatures

    Final product types

    • Specialty polyester fibers (for technical textiles and filtration)
    • Cast or blown polyester films (for release liners, electrical insulation)
    • Heat-stable containers and trays

    4. High-Temperature Polyarylate Polymers

    The material is a necessary dihydroxy building block in the fabrication of polyarylate thermoplastics intended for demanding high-temperature roles. Its incorporation yields polymers with higher glass transition temperatures and increased dimensional retention, promoting use in precision parts for aerospace and industrial environments.

    Industry compliance standards

    • ASTM D5203 (Standard Specification for Polyarylate Resin Molding and Extrusion Materials)
    • ISO 10993 (Biological evaluation of medical devices, applicable for medical-grade polyarylates)
    • REACH (Registration, Evaluation, Authorization and Restriction of Chemicals) for polymer substances
    • UL 94 V-0 (Flammability for high-performance polymers)

    Typical usage ratio

    • 20–50 mol% of dihydroxy content, fine-tuned according to rigidity and thermal endurance targets of the polyarylate copolymer design

    Downstream process integration

    • Charged into the reaction vessel for direct polycondensation with aromatic diacids (like terephthalic or isophthalic acid), with vacuum removal of water byproduct

    Final product types

    • Injection-molded aerospace brackets and fasteners
    • Microwave-sterilizable medical device housings
    • Precision gears and wear components for automation systems

    5. Optical Grade Polymer Intermediates

    In the manufacture of polymers for optical applications, such as lenses and display substrates, this compound introduces controlled refractive indices and transmittance properties. The material’s structural features support downstream fabrication of lightweight, transparent elements used where clarity and impact resistance are essential.

    Industry compliance standards

    • ISO 8980 (Ophthalmic optics — Uncut finished spectacle lenses)
    • EN 166:2001 (Personal eye protection — Specifications for optical clarity and impact resistance)
    • ANSI Z80.3 (Ophthalmics — Nonprescription Sunglass and Fashion Eyewear)
    • RoHS Directive 2011/65/EU for finished electronic and optical components

    Typical usage ratio

    • 6–20 wt% of total diol content in copolymer blends, tailored as per target optical density, haze, and impact modulus criteria

    Downstream process integration

    • Dosed during pre-polymerization of optical copolymer melts, typically followed by melt-extrusion or casting for component shaping

    Final product types

    • Ophthalmic lenses (spectacles, safety goggles)
    • LED light guide panels
    • Transparent instrument housings and display covers
    Free Quote

    Competitive 2,2-Bis(4-Hydroxyphenyl)Butane prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    2,2-Bis(4-Hydroxyphenyl)Butane: A Closer Look at Performance, Purity, and Application

    Getting to the Heart of 2,2-Bis(4-Hydroxyphenyl)Butane Manufacturing

    For those of us with a history in the chemical manufacturing world, some products demand not just technical expertise but a deeper understanding of what our customers face on the ground. 2,2-Bis(4-hydroxyphenyl)butane, commonly known as Bisphenol B (BPB), stands as a material with specialized uses and particular performance characteristics. Over several decades, our line operators and R&D teams have spent countless hours refining each stage of its manufacture, steering every batch toward reliable, repeatable results. Our experience has shown that even small process adjustments—reaction temperature, purification routines, the choice of catalyst—have an outsized impact on final product characteristics.

    Customers often ask how BPB stacks up compared to its better-known cousin Bisphenol A (BPA), and why it occupies an important place in certain resin systems and specialty plastics. Running a chemical plant, we rarely see questions in isolation. No customer needs a theoretical answer. They want honesty about supply stability, batch consistency, and what to expect in final processing.

    Purity, Particle Size, and Process Considerations

    Only a decade ago, the struggle centered on removing trace impurities that compromise polymer performance under heat and mechanical load. BPB’s molecular structure features two hydroxyphenyl groups anchored by a butane link, and these slight differences from BPA redefine both reactivity and downstream properties. With our optimized procedures, our median batch purity has reached over 99.5% (GC area determination), with trace contaminant clusters kept well below international thresholds. This is not only about passing compliance checks; it means fewer gel points in resin manufacturers’ reactors, less downtime for filter cleaning, and less rework due to color and clarity deviations.

    Granule fineness and powder handling present their own set of challenges. Over the years, we learned the hard way that moisture uptake during milling or transfer can introduce off-spec color or even microgels. Our facilities now employ humidity-controlled milling rooms and antistatic systems, ensuring each shipment meets consistent bulk density and flow profiles that matter during dosing, especially in automated compounding lines. We do not believe in overselling “universal compatibility”—BPB lends itself best to applications that require elevated glass transition temperatures or specific resistance to hydrolysis.

    Where It’s Used—and Why Customers Choose It

    Some resin and plastic manufacturers adopt BPB over BPA where the finished polymer must hold up in hostile environments: electrical insulation, high-end composite panels, thermosetting adhesives, and advanced coatings. The extra butane chain within BPB creates steric hindrance, subtly shifting how the molecule reacts during polymerization. The result is a finished product that shows a different thermal profile, a tighter color window, or enhanced chemical resistance, depending on the formulation.

    Over time, we’ve seen certain customers gravitate toward BPB after running into limitations with BPA-based systems—yellowing after extended UV exposure, loss of mechanical strength at elevated temperatures, or stability issues under alkaline conditions. Every application brings its own puzzle pieces, but those using BPB for epoxy resins, high-purity polycarbonates, or certain specialty molding compounds have reported more predictable performance, especially where processing temperatures exceed 180°C or where end-use parts face repeated sterilization.

    What Sets Our BPB Apart from Standard Grades

    Our plant rarely chases volume for its own sake. Since BPB’s market is overshadowed by BPA in sheer tonnage, we focus on quality over bulk. Each reactor turnaround gets supervised sign-off; batch samples spend hours under accelerated aging and filtration stress tests. Over the years, one improvement has proved critical: a multi-step recrystallization, which drives down ortho and meta isomer content. Downstream, this translates to fewer charge-transfer complexes and reduced risk of polymer haze. Many customers come back after struggling with inconsistent performance from suppliers who batch blend off-grade product in an attempt to meet broad spec windows. We’ve shown that tighter controls on melt color and hydroxy-equivalence save money during both compounding and molding.

    The feedback we get is rarely about certificates. Most plant managers or process engineers write to us about the things that keep their lines running—melting uniformity, clean transfer, minimal downtime for filter changes. One segment that stands out—OEMs in electrical and electronics—reported achieving higher insulation resistance and longer service life for printed circuit board laminates. Customers running continuous casting lines appreciate low thermal yellowing and reduced plate-out, both linked to our strict control of trace iron, chloride, and sulfonate levels. These parameters get checked in every lot; our QC labs run more than twenty specific tests before shipment.

    Our Lessons: Troubleshooting and Customer Partnership

    Decoding field problems starts at the reactor but finishes in the lab—and in our customers’ plants. Not long ago, a customer flagged premature brittleness in an epoxy composite. Our technical team coordinated their trials, ran thermal gravimetric analysis, and found trace contamination from a competing BPB batch. The real cause? Higher than acceptable levels of residual catalyst, likely from a skipped wash step at their recent bulk purchase. This came to light only because we trade real batch data and maintain open lines with our customers. Working on root-cause analysis has taught us to never downplay how small shifts in trace impurity or even batch storage conditions can have big consequences for the final product.

    This sort of hands-on troubleshooting doesn’t show up in spreadsheets. Our own workers, with years of experience on milling and purification lines, catch issues early—sometimes a subtle color drift under strong light, sometimes a shift in particle shape that signals a process hiccup. We scrutinize every batch’s FTIR and mass spec results ourselves rather than just outsourcing routine tests. Because our whole approach revolves around accountability, unscripted QC checks, and the willingness to dig into “off-normal” events, our customers trust us as partners, not just as a point of supply.

    BPB and Evolving Regulatory Standards

    Demand for transparency and compliance does not stay still. Over the last several years, regulators have taken a closer look at bisphenol derivatives and their environmental and toxicological footprints. For anyone in this space, regulatory knowledge stands as important as technical know-how. Our own systems keep pace with this—modern tracking of migration characteristics, real-world simulation of leachate, and documentation of heavy metal and residual monomer levels.

    We routinely update our files and collaborate openly with downstream partners who export into North America, Europe, and East Asian markets. Whenever a tox report or environmental study comes out, our technical and legal staff crosscheck it against internal performance data. For customers developing products that must comply with RoHS, REACH, or FDA guidelines, we advise on model formulations already validated against the strictest benchmarks, including limits for total bisphenol release under simulated use. These conversations have shaped how we dose antioxidants, manage trace contaminants, and optimize filtration for minimal extractables.

    The Ongoing Quest for Product Differentiation

    Over the years, countless companies have entered and exited this segment. Yet, experience shows that only those who focus on small-batch control and close customer interaction keep their edge. In our case, we take pride in every lot’s analytical profile. Any experienced operator in a chemical plant knows that reaching for ever-better performance, even at modest scale, begins with stable operating conditions. Our focus on micro-process adjustments—how long to hold end-reaction, the pace of cooling, the purity of solvents—plays a much bigger role in quality than most realize.

    One major value in BPB production, often overlooked, lies in its impact on the color and stability of finished plastics. Hemming in trace iron and other metals, absolutely refusing off-grade or recycled solvent, and running small-batch pilot lots for critical customers, has protected many product lines from costly market recalls. Over the last five years, our lowest-color grades have helped electronics suppliers expand into sectors—including aerospace and automotive interiors—where even a slight shift in color index can mean lost business.

    How BPB Differs From Alternative Bisphenols

    Engineers and scientists looking to design new materials always compare BPB against other bisphenol compounds. BPA remains the volume mainstay, and bisphenol S (BPS) or bisphenol F (BPF) cover other value niches. What makes BPB stand out is its unique balance between rigidity and process flexibility. The butane linker imparts a certain spacing between aromatic rings, which alters polymer structure. Finished resins behave a bit differently: a touch less brittle at low temperatures, with slightly slower cure kinetics, but often greater stability under hot-wet cycling or exposure to solvents.

    With every batch, our lab runs comparative trials—not just chemical purity but functional properties: melt viscosity, UV stability, glass transition, and hydrolytic resistance. Customers in electronics praise BPB for enabling a better balance between rigid encapsulation and shock resistance, something that can make the difference between circuit board failure and field reliability. Processors of specialty adhesives note BPB’s tendency to reduce water uptake and resist yellowing after thermal cycles, which simply can’t be matched by conventional BPA-based blends. Such distinctions may sound subtle, but they translate directly to competitive advantage for our largest users.

    Linking Production Experience with Product Value

    Decades inside a chemical plant shape a certain mindset. We’ve come to see BPB not as a commodity, but as a craft material. Operators develop an eye for what separates a truly clean batch from one riding close to spec limits. In humid summer months, the plant crew doubles checks on the drying hoppers and ramp up their vigilance for cross-contamination. Shifts share notes on minor process tweaks to eliminate color fluctuations. Each change gets documented and discussed, not just for regulatory records but because it sharpens everyone’s technical instincts.

    Visitors walking the production floor see more than pipes and tanks; they see teams that know their product and own their results. Our work on BPB over the years has taught us that trusted supply means not just meeting specs, but keeping promises—fixing problems fast, respecting real-world feedback, and always looking for better ways to serve our customer base. We price based on real manufacturing cost, transparent overhead, and an honest premium for value-added purity and service, not merely what the immediate market will bear.

    Prospects, Challenges, and Future Directions

    Current market dynamics reward innovation, consistency, and trust. With every new requirement from customers—lower extractables, narrower color windows, more detailed traceability—our team rises to meet it, not by taking shortcuts, but by investing in better controls, more data, and closer links with those who use our materials daily. The move toward greener processes has prompted us to study less energy-intensive purification, solvent recycling, better recovery of process heat, and reduction of carbon footprint per ton of BPB produced.

    We expect demand for BPB to shift further into advanced applications. High-performance adhesives, medical device housings, and demanding aerospace thermosets already rely on tight purity and color profiles. Customers relying on government procurement or certification programs need assurance on the back end—real batch traceability and audit trails, not just promises on paper. Our plant has always taken the “show me” approach; walk-throughs and joint lab trials are a part of our offer for serious partners.

    Watching the flow of BPB from refinery all the way to its molded or cured form has widened our appreciation for the end-to-end importance of manufacturing stewardship. Many competitors keep their heads down, chasing price through cut corners, but our experience says the smarter path lies in knowing what matters most to end users: reliability, consistent performance, and a commitment to making things right before, during, and after each shipment.

    Collaborating for Better Outcomes

    One reason for our enduring partnerships comes down to accessibility. Process engineers and technical leads appreciate how we address concerns rapidly, whether by releasing additional batch data or by dispatching our own staff to run pilot trials on customer lines. We believe the best feedback comes from long days spent side by side in production environments. The insights we’ve gained—how BPB interacts with flame retardants, what processing tweaks are needed at different altitudes or humidity, which pre- and post-cure steps optimize mechanical data—have all come from the field, not a catalog.

    Together with our customers, we encounter every new challenge educated by the lessons of past production runs. Fine-tuning BPB quality today amounts to hundreds of small improvements—tighter distillation, better segregation of work-in-progress, direct-line communications between plant chemists and front-line operators. For long-term partners, we even offer customized particle size or targeted trace impurity profiles if their operations demand it. Our position as manufacturer, rather than trader, means we maintain hands-on control over both the details and the big picture.

    Final Thoughts from Inside the Plant

    Every pallet of 2,2-Bis(4-hydroxyphenyl)butane that leaves our dock embodies not just raw chemistry but decades of learned skill, collaborative spirit, and problem-solving. Working daily with both the molecule and the people who depend on it has made us appreciate the difference between generic supply and real world value. From analyzing microtraces in our QC lab to responding directly to a customer’s process hiccup, we bring the benefit of manufacturing experience to each batch delivered.

    As we continue defining the benchmarks for purity, performance, and customer service in this specialized sector, we stay grounded in the tried-and-tested fundamentals: technical mastery, dedicated follow-up, and an unwavering respect for the people who shape the outcome of every final product. 2,2-Bis(4-hydroxyphenyl)butane is more than a line on a datasheet—in our hands, it’s the sum of every lesson learned and every standard raised, one shipment at a time.