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1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol

    • Product Name 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol
    • Alias Perfluorododecan-1,12-diol
    • Einecs 444-360-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    725056

    Chemical Name 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol
    Molecular Formula C12H4F22O2
    Molecular Weight 584.13 g/mol
    Cas Number 19732-15-7
    Appearance White to off-white solid
    Boiling Point No data available (decomposes)
    Melting Point 69-71 °C
    Solubility In Water Insoluble
    Density 1.8–1.9 g/cm3 (approximate)
    Flash Point >110 °C
    Functional Groups Diol, perfluoroalkyl
    Smiles C(O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CO
    Ec Number 243-603-7

    As an accredited 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol, 10g, is supplied in a sealed amber glass bottle with a tamper-evident cap.
    Shipping 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol is typically shipped as a solid or viscous liquid in sealed, chemical-resistant containers. It should be handled and transported under standard regulations for industrial chemicals, avoiding exposure to heat and moisture. Ensure appropriate labeling and documentation, following all pertinent safety and environmental guidelines.
    Storage **1H,1H,12H,12H-Perfluoro-1,12-dodecanediol** should be stored in a tightly sealed container, away from moisture and incompatible substances, in a cool, dry, and well-ventilated area. Keep away from strong bases, acids, and oxidizing agents. Protect from direct sunlight and sources of heat. Properly label the container and ensure secondary containment to prevent environmental release in case of spills.
    Application of 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol

    Applications of 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol in Industrial Manufacturing

    1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol serves as a key fluorinated diol intermediate in specialized industrial sectors due to its unique combination of chemical resistance, surfactant behavior, and ability to impart durable hydrophobicity. As the manufacturer, we focus here on well-established downstream applications where its structure and performance have become essential to production processes.

    1. High-Performance Fluoropolymer Precursor for Surface Treatment Agents

    Industrial formulators integrate this raw material in the synthesis stages of high-performance fluoropolymer coatings and treatments. It provides sites for urethane formation or copolymerization, building durable, low-surface-energy barriers against water, oils, and aggressive chemicals. These attributes meet advanced requirements in electronics, architectural glass, and specialty textile sectors, where weatherability and resistance to fouling are critical. Post-polymerization, the product enables reactive coating baths or is blended with other polymers under controlled temperature and atmospheric conditions, meeting closely monitored procedural benchmarks.

    Industry compliance standards

    • REACH Regulation (EU) No 1907/2006 for fluorinated intermediates
    • RoHS Directive 2011/65/EU for electrical and electronic applications
    • ASTM D4541 for adhesion of coatings on metallic substrates
    • GB/T 30693-2014 regarding volatile organic compound (VOC) emissions in coatings

    Typical usage ratio

    • 2–8 wt% as a diol monomer during fluoropolymer synthesis, adjusted for chain length and final surface energy target

    Downstream process integration

    • Incorporated directly during prepolymer formation for polyurethanes or polyesters
    • Co-polymerized with non-fluorinated monomers in melt or solution-phase reactions
    • Processed post-synthesis in blending tanks for water/solvent-based treatment formulations
    • Applied during controlled dip or spray coating steps with in-line curing

    Final product types

    • Anti-graffiti architectural glass panels
    • Hydrophobic and oleophobic films for electronic device displays
    • Protective coating systems on industrial metalwork
    • Finished water-repellent textiles for outdoor technical garments

    2. Additive in Oil & Gas Extraction Chemicals

    Downstream chemical formulators use this compound to create advanced surfactant blends and demulsifiers, primarily for upstream oilfield operations. Its perfluorinated segments disrupt interfacial tension, stabilizing emulsions under high temperature and salinity, and withstand exposure to hydrocarbon streams in enhanced oil recovery fluids and drilling muds. Dosages vary based on crude type, reservoir conditions, and blend compatibility, where it often accompanies nonionic or anionic co-surfactants for specialized flow assurance properties.

    Industry compliance standards

    • API RP 13B-1/ISO 10414-1 for drilling fluid composition and control
    • OECD 301 ready biodegradability testing
    • Global GHS for transport and labeling of fluorinated chemicals
    • REACH focus on persistent, bioaccumulative, and toxic (PBT) substance restrictions

    Typical usage ratio

    • 0.1–2.5 wt% in demulsifier or surfactant additive blends, with adjustments based on oil viscosity and formation water properties

    Downstream process integration

    • Blended into base surfactant concentrates during heat-controlled mixing
    • Injected batch-wise or continuously into reservoir fluids at wellheads
    • Monitored through on-site fluid compatibility testing and interfacial tension measurement
    • Tracked in system-wide additive inventory control logs per field regulations

    Final product types

    • Enhanced oil recovery (EOR) surfactant packages
    • Emulsion-breaking agents for crude separation
    • Corrosion-inhibiting additives in completion fluids
    • Drilling fluid components for high-salinity wells

    3. Intermediate for Fluorinated Personal Protective Equipment (PPE) Finishing

    Manufacturers of industrial PPE utilize 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol as a building block for permanently attached water- and chemical-repellent finishes. Through controlled polymerization and crosslinking with polyurethanes or acrylics, it ensures high durability after laundering and exposure to aggressive industrial agents. Regulatory acceptance hinges on limiting extractable fluorochemicals and demonstrating consistent film formation throughout finishing lines, where precise formulation and finishing process controls are central.

    Industry compliance standards

    • OEKO-TEX Standard 100 for restricted substances in textile finishes
    • ISO 6330 for textile domestic laundering durability
    • EN 13034 for protective clothing against liquid chemicals
    • NIOSH/OSHA hazard assessment for chemical exposure limits

    Typical usage ratio

    • 0.5–4.5 wt% active solids in final finish bath, based on textile type and target repellency level

    Downstream process integration

    • Emulsified or dissolved in polymer pre-mixes before padding or spraying onto woven or non-woven fabrics
    • Subjected to controlled drying and curing (120–180°C) to ensure crosslinking and performance stability
    • Tested post-finishing in in-house quality labs for repellency durability and extractables
    • Integrated into inline monitoring with automated chemical feed systems

    Final product types

    • Class 3 chemical-resistant coveralls
    • Oil- and water-proof industrial gloves
    • Protective shoe covers and gaiters
    • Flame-resistant outerwear for chemical plant personnel

    4. Fluorinated Oligomer Production for Electronic Encapsulation Materials

    In semiconductor and electronic component manufacturing, this diol acts as a key segment in custom-synthesized fluorinated oligomers. The resulting oligomers exhibit ultra-low dielectric constant, high weathering resistance, and compatibility with high-purity epoxy or silicone resin matrices. Manufacturers precisely meter the raw material by molar ratio during oligomer synthesis, affecting final chain length and property control. Strict procedural documentation ensures reproducibility required by electronics OEMs.

    Industry compliance standards

    • IPC-4101B for base materials in printed circuit boards
    • UL 94 for flammability of encapsulant resins
    • ISO 10993 for cytotoxicity of electronic device encapsulants (where used in medical-grade electronics)
    • IEC 61249-2-21 for halogen-free insulation materials

    Typical usage ratio

    • 10–40 mol% based on target oligomer structure and performance, with feed rate controlled by reaction kinetics and final dielectric constant target

    Downstream process integration

    • Metered as part of the oligomerization step using nitrogen-purged reactor systems
    • Monitored for molecular weight growth before end-capping and purification
    • Blended into encapsulant resin premixes in Class 100 cleanroom facilities
    • Quality assurance validated by dielectric property testing on finished encapsulation films

    Final product types

    • Potting compounds for integrated circuit protection
    • Low-k dielectric layers in multilayer printed circuit boards
    • Encapsulation sheets for OLED displays
    • Protective resins for automotive sensor modules

    5. Modifier for Specialty Fluorosurfactants Used in Firefighting Foam

    Manufacturers of Class B firefighting foams employ this diol as a chain extender or modifier during the production of high-efficiency fluorinated surfactants. Its integration provides thermal stability and stable foam formation under high temperature incident conditions, while also minimizing hydrocarbon spread in fuel spill fires. Formulation requires strict dosage control for environmental compliance, especially when aiming to meet evolving restrictions on per- and polyfluoroalkyl substances (PFAS).

    Industry compliance standards

    • NFPA 18 and UL 162 for foam concentrates and firefighting foam system approval
    • EN 1568-3 for foam performance on hydrocarbon fuel fires
    • OECD 301F for inherent biodegradability testing
    • ECHA guidelines for restricted PFAS content

    Typical usage ratio

    • 0.2–2.0 wt% within the fluorosurfactant component, refined through small-scale foam performance trials

    Downstream process integration

    • Reacted as a co-monomer in fluorosurfactant synthesis
    • Integrated during aqueous concentrate formulation immediately post-synthesis
    • Monitored for chain length uniformity via NMR and refractive index in batch QC
    • Sampled in final foam test runs according to NFPA procedures

    Final product types

    • Aqueous film forming foam (AFFF) concentrates
    • Alcohol-resistant foam for aviation and storage tank incidents
    • High-expansion fire suppression systems for petrochemical facilities
    • Portable fire extinguisher foam refills
    Free Quote

    Competitive 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    Introducing 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol: Built for Reliable Performance in Modern Manufacturing

    Understanding 1H,1H,12H,12H-Perfluoro-1,12-Dodecanediol

    1H,1H,12H,12H-Perfluoro-1,12-dodecanediol is a specialty diol used in high-demand environments across coatings, electronics, and advanced materials manufacturing. With a chemical structure featuring twelve carbon atoms and a strong perfluorinated backbone, this diol offers a unique blend of hydrophobicity and chemical stability that opens new possibilities in processing and design.

    Our experience producing and refining this molecule shows clear performance advantages compared with standard hydrocarbon or partially fluorinated diols. Where traditional diols can falter in the face of aggressive environments—salt spray, acids, bases, solvents—perfluorinated chains help the backbone withstand stress. This strength gets built into finished coatings and polymers; it resists swelling, weathering, and breakdown over time, which matters in real-world applications.

    Specifications and Quality

    We manufacture 1H,1H,12H,12H-perfluoro-1,12-dodecanediol to rigorous internal standards. Each production batch undergoes high-purity distillation and multiple purification steps to remove unwanted byproducts or trace organics, protecting downstream processes and end-product quality. Our qualified team monitors key physical properties—molecular weight, melting point, and functional group conversion—to ensure the finished diol matches performance expectations with every shipment.

    From the earliest days of synthesizing small lots for fluoropolymer innovators, we recognized that specifications do more than fill a standard sheet. Color, viscosity, and residual moisture content all contribute to how this specialty diol behaves on the line or in custom research. We work closely with formulators and engineers in demanding sectors—electronics, medical devices, aerospace, and advanced coatings—to maintain open channels with those relying on our material.

    Years of experience taught us that "specification" cannot be treated only as a check-box or routine report. Residual acid or unconverted intermediates, even at levels below detection by common tests, may lead to downstream stability issues under high heat or in high-voltage environments. Our laboratory team regularly partners with customers to pinpoint the source of anomalies, iterate purification, or fine-tune the degree of fluorination.

    The Science Behind its Performance

    Perfluorinated diols distinguish themselves at the molecular level. Each hydrogen on the carbon chain—except at the terminal positions—has been replaced by a fluorine atom. These carbon-fluorine bonds are among the strongest in organic chemistry, creating a surface and backbone that shed water, resist oil, and refuse to take up acids or bases. The diol functions at the chain ends allow this material to participate in condensation reactions, urethane bridging, and advanced surface covalency.

    For formulators developing durable coatings or membranes, these chemical properties are not theoretical talking points. We have watched customers test samples in high-salinity marine coatings, finding that perfluoroalkyl diol segments remain intact where regular polyether or polyester diols break down. In battery separator films, where moisture uptake must be meticulously controlled and high voltage stability is non-negotiable, this molecule delivers a level of performance that reduces costly failures and field returns.

    Unlike partially fluorinated alternatives, the fully fluorinated backbone resists creeping elution of oligomers or leaching under stress. The molecular uniformity achieved in our controlled process means reduced lot-to-lot variance—a factor that gets noticed in automated manufacturing where any deviation can trigger process alarms or lead to off-spec material.

    What Sets Our Perfluoro-1,12-Dodecanediol Apart

    We have been in the trenches with chemists, material scientists, and process engineers facing the reality of scale-up and fielding performance. Compared with shorter-chain fluorinated diols or conventional hydrocarbon diols, 1H,1H,12H,12H-Perfluoro-1,12-dodecanediol passes through aggressive process steps—high temperature polycondensation, harsh catalyst exposure, repeated cycling—retaining its functional groups and backbone integrity.

    Customers switching from C8 or C10 analogs remark on the longer perfluoro chain’s effect on flexibility, surface energy, and compatibility. We see the longer chain translate into enhanced barrier properties and less cold-flow or drift in harsh environments. The typical melting point ensures it is easy to handle with common equipment, unlike some high-melting fluoropolymers that demand unique infrastructure.

    Environmental and safety demands keep evolving. Increasingly, clients look for materials that deliver strong performance without persistent environmental concerns. We produce our perfluorodiol with an eye on byproduct minimization and a deliberate focus on production wastewater and emission treatment. The manufacturing team has invested in recovery and abatement technologies to ensure that what leaves our site does not burden the environment. Customers regularly ask detailed questions about process controls and waste minimization, and we encourage this scrutiny—it pushes us to refine our operation while supporting our partners’ own sustainability goals.

    Real-World Uses and Industry Experience

    1H,1H,12H,12H-Perfluoro-1,12-dodecanediol is not a general feedstock; its main use cases come in technical formulations that live under stress. We have seen success in the following:

    We do more than ship containers; our technical group actively supports trials and scale-up, helping with dosing, melting, and compatibility checks as customers move from small pilot runs to commercial production. If a process presents unexpected foaming, haze, or viscosity changes, we dig deep, run in-house simulations, and travel to customer sites to observe real flow conditions. The feedback loop from application to plant back to molecular design keeps us focused on the true value this fluorinated diol delivers.

    Innovation often stems from addressing gaps or failures in legacy technology. Traditional organics reach performance plateaus in sectors like outdoor protective coatings, fuel cell membranes, and biomaterials. We worked on projects where PU coatings failed after brief sun exposure or where membranes fouled rapidly in municipal water processing. After introducing our perfluorodiol into these systems and tweaking the polymer matrix, we saw lifespans double or triple with less call for shutdown or replacement.

    Application variances also matter. Not every customer wants maximum chain length or high fluorine density. Through direct dialogue, we tune hydroxyl group ratios, control chain length distribution, and sometimes recommend intermediate blends or hybrids. This exchange means every batch reflects years of learning and adaptation, not an off-the-shelf commodity.

    Working with Leading Developers and Manufacturers

    Long-term partnerships have sharpened our focus. The electronics sector, for instance, places strict demands on insulation reliability and defect elimination in wafer coatings. Medical device clients prioritize biocompatibility, leachables, and microstructure—properties shaped by each step in synthesis and purification. Aerospace and automotive tiers push for resilience in performance coatings combined with weight savings and compatibility with lightweight metals like aluminum or magnesium alloys.

    Our manufacturing approach responds to these needs, not just in product consistency but in open-door technical support, ongoing education, and joint problem-solving. Years of process optimization have enabled us to deliver not just stable material, but reliable supply—essential when partners build schedules and product launches around tight supply chains.

    Over time, we have invested in both people and technology: expanding laboratory capabilities for advanced chromatography and spectroscopy, hiring chemists with direct industry formulation experience, and refining our analytics protocols with customer feedback in mind. The learning rarely flows in one direction. Feedback from a failed processing run or a materials testing setback triggers internal reviews and prompt, open troubleshooting conversations. Our willingness to adapt, admit faults, and improve together with clients builds trust and gets reflected in every kilogram of finished diol we ship.

    Comparing to Other Products and Addressing Key Challenges

    1H,1H,12H,12H-Perfluoro-1,12-dodecanediol stands out against regular hydrocarbon diols, as well as shorter-chain or less pure fluorinated analogs. The extended perfluorinated chain produces stronger surface effects—lower critical surface tension, greater repellency, and less absorption or gradual permeation of aggressive chemicals. In sectors where contaminants or migration can compromise an entire assembly, this translates to reduced recalls, fewer customer complaints, and greater peace of mind for engineers down the line.

    Compared to other perfluorinated diols, processing and downstream reactions can differ: longer chains confer more flexibility and better heat resistance, but improper blending or flaws in functional group conversion may cause reactivity mismatches, phase separation, or crystallization. Our extensive in-house and field experience helps us identify and resolve these issues before they cause broader problems. One point that became clear over the years—direct simple substitution from other diols rarely works. Our technical dialogue starts with understanding polymer matrix, processing windows, end-user needs, and so avoids costly restarts or wasted time.

    We have seen the pitfalls that come from buying from unqualified brokers or importers unable to explain their materials’ genesis. Unreliable supply, untraceable byproducts, and confusing labeling cause unnecessary headaches for those who rely on world-class materials. Our focus remains on transparency and education. Data sheets matter, but so do stories of success and lessons from the occasional setback. We do not shy from sharing both.

    Sourcing always matters—customers in advanced manufacturing need peace of mind not just in performance, but in compliance with their own regulatory and audit requirements. Our traceable batch systems, regular process audits, and chain-of-custody documentation support supply chain integrity and regulatory confidence. As PFAS regulation continues to evolve, customers need confidence their suppliers can withstand scrutiny; we invest heavily to keep processes aboveboard, documentation clear, and customer questions answered with candor.

    Technical Support and Ongoing Collaboration

    We stand by every batch with clear technical documentation and unfiltered access to our chemists and engineers. Over decades, this open-door approach meant we could solve application challenges that no data sheet or third-party broker could anticipate. From the first inquiry to the nth repeat order, we value two-way exchange—customers feed back real-world outcomes, asking us to refine our process or even develop variations that address sector-specific issues.

    Our internal commitment extends to visiting customer plants, running pilot trials, and sharing best practices on safe material handling. We believe advanced specialty chemicals cannot be treated as mere catalog items; ongoing dialogue shapes best results and minimizes surprises. Where problems arise, we jump in—our field technical team gets involved in process audits, troubleshooting, and training partner staff on optimal handling and blending practices.

    Future applications continue to broaden as our partners push into new fields—flexible electronics, antifouling marine surfaces, hybrid membranes for desalination and separation. We support academic collaborations and commercial R&D teams alike, eager to see how our diol’s unique properties can advance new technologies and improve global standards for reliability, longevity, and environmental responsibility.

    Commitment to Transparency and Continuous Improvement

    Supplying to advanced manufacturers means more than filling orders; it is a process of continuous engagement, dialogue, and course correction. We foster relationships that prioritize joint problem-solving and information sharing. Our team remains reachable and responsive throughout the development and scale-up process. Whether an engineer faces unexplained haze after film casting or a project lead plans the next product iteration using a modified backbone, we support each step.

    Mistakes and surprises will happen—chemical manufacturing remains complex at every scale. But we treat every call or technical report as a learning moment. Openness, humility, and technical rigor keep us moving forward—helping to discover blind spots, revalidate assumptions, and build solutions that work under real-world conditions.

    We drew these lessons from decades of manufacturing and partnership. No specification ever caught every reality of field use; no batch ever worked flawlessly for every customer out of the gate. What brings lasting value is openness, technical competence, and a focus on outcome and relationship, not just sale.

    Looking Ahead with Confidence

    Priorities continue to shift across markets; performance once cast as ‘advanced’ becomes a baseline expectation as regulations tighten and operating environments grow harsher. Long-term users of 1H,1H,12H,12H-Perfluoro-1,12-dodecanediol share a common thread—success built not merely from a single purchase, but from a partnership grounded in truth, technical depth, and a willingness to tackle new challenges together.

    We invite those searching for a proven, reliable path forward in high-performance materials to learn from our experience, challenge our assumptions, and build the next generation of products together. 1H,1H,12H,12H-Perfluoro-1,12-dodecanediol continues to prove its worth in the field, project after project, batch after batch.