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11H-Perfluoroundecanoyl Chloride

    • Product Name 11H-Perfluoroundecanoyl Chloride
    • Alias PFUdCl
    • Einecs 252-116-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    767445

    Chemical Name 11H-Perfluoroundecanoyl Chloride
    Cas Number 307-24-4
    Molecular Formula C11ClF21O
    Molecular Weight 589.54 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point 120-122 °C at 760 mmHg
    Density 1.78 g/cm³ at 20°C
    Purity Typically ≥97%
    Solubility Insoluble in water; soluble in organic solvents
    Refractive Index n20/D 1.328
    Melting Point -23 °C
    Iupac Name Tridecafluorooctanoyl chloride
    Storage Conditions Store at 2-8 °C, tightly closed, under inert gas

    As an accredited 11H-Perfluoroundecanoyl Chloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 11H-Perfluoroundecanoyl Chloride comes in a 25g amber glass bottle, tightly sealed, with a hazard label and product information.
    Shipping 11H-Perfluoroundecanoyl Chloride should be shipped in tightly sealed, chemically resistant containers under inert atmosphere. It must be labeled as a corrosive substance and transported according to relevant hazardous material regulations. Avoid contact with moisture and incompatible materials. Store and handle as per MSDS guidelines for safety during transit.
    Storage **11H-Perfluoroundecanoyl chloride** should be stored in a tightly sealed container, under a dry, inert atmosphere such as nitrogen or argon. Keep it in a cool, well-ventilated area away from moisture, acids, bases, and incompatible materials. Store away from heat and direct sunlight. Use corrosive-resistant containers and ensure proper labeling for safety and regulatory compliance.
    Application of 11H-Perfluoroundecanoyl Chloride

    Applications of 11H-Perfluoroundecanoyl Chloride in Industrial Manufacturing

    As a manufacturer deeply engaged in the development and supply of high-purity 11H-Perfluoroundecanoyl Chloride, we deliver this specialty intermediate into a range of technically demanding industrial fields. Our direct relationships with global end users have enabled us to gather practical integration data, precise formulation parameters, and up-to-date regulatory guidance for the downstream markets outlined below.

    1. Fluorinated Surface Treatment Agents for Textiles

    In textile finishing, 11H-Perfluoroundecanoyl Chloride plays a critical role as an acyl chloride precursor, supporting the synthesis of fluorinated side-chain polymers for durable water- and oil-repellent coatings. Manufacturers employ this raw material in polymerization steps to achieve high-performing finishing agents that comply with evolving environmental regulations, especially those restricting PFOS/PFOA but permitting new-generation C11-based chains. Its specific carbon chain, intermediate molecular weight, and robust bond durability deliver performance while meeting stricter textile chemical limits.

    Industry compliance standards

    • OEKO-TEX® Standard 100 (Annex 6, Section 4) - perfluorinated compound limits
    • ZDHC MRSL v3.1 – restriction of legacy PFAS and use of shorter or intermediate perfluorinated chains
    • REACH Regulation (EC) No. 1907/2006 - registration, evaluation, and authorisation requirements for new fluorochems
    • ISO 6330 (Textiles – Domestic washing and drying procedures)

    Typical usage ratio

    • 5–12% by weight in the fluorinated acrylate or urethane prepolymer (adjusted for desired repellency and chain packing density)

    Downstream process integration

    • Introduced during acylation and chain-extension of polymer backbones, followed by emulsion polymerization; the resulting polymer dispersions are formulated into waterborne finishes and applied in textile padding or coating lines prior to calendaring and curing.

    Final product types

    • Outdoor and work apparel with advanced stain resistance
    • Upholstery fabrics for contract and transportation markets
    • Medical drapes and gowns with fluid barrier properties
    • Technical nonwovens for filtration or protective use

    2. Synthesis of Low Surface Energy Additives for Electronics

    Producers of advanced electronics coatings and encapsulants utilize 11H-Perfluoroundecanoyl Chloride as a key building block in the production of oligomeric and polymeric additives that impart controlled low surface energy. This enhances anti-fingerprint, anti-smudge, and chemical resistance properties for glass, display modules, touch panels, and printed circuit boards, a requirement in mobile devices and high-end consumer electronics. The intermediate’s structure supports formation of high-purity perfluoroacylated silanes and urethanes, integrated downstream in accordance with electrical and environmental testing requisites.

    Industry compliance standards

    • RoHS Directive (EU) 2015/863 – restriction on hazardous substances for electronics
    • IEC 60601-1-2 – electromagnetic compatibility and coating requirements for medical electronics
    • IPC-CF-150 – performance specification for conformal electronic coatings
    • UL 746C – polymeric material use for PCBs under environmental conditions

    Typical usage ratio

    • 2–7% by total solids in coating or encapsulant formulations; levels are tailored to match target surface energy and abrasion specifications while avoiding agglomeration or haze effects.

    Downstream process integration

    • Functionality introduced via post-silane functionalization or in-situ acylation of polymer terminal groups; final mixture is dispersed or dissolved into UV-curable, thermal, or hybrid resin matrices, subsequently applied by spray, dip, or spin coating in controlled dust-free rooms.

    Final product types

    • Oleophobic and hydrophobic screen coatings for smartphones and tablets
    • Protective overcoats for automotive displays and industrial touch panels
    • Moisture-resistant conformal coatings for high-reliability circuit boards
    • Anti-stain glass spacers and sensor lenses

    3. Fluorinated Polymer Synthesis for Oil & Gas Sealing Applications

    Engineered fluoropolymers derived from 11H-Perfluoroundecanoyl Chloride form the backbone for elastomeric and thermoplastic sealing components exposed to chemical and temperature extremes in oilfield and refinery environments. Compounders leverage this intermediate during monomer synthesis to incorporate C11 fluorinated units, producing finished polymers that address trade-offs between chemical inertness and processability. Completed compound qualities are validated against stringent internal and third-party standards for downhole, pipeline, and compressor service.

    Industry compliance standards

    • ISO 23936-2:2022 – polymeric materials for oil and gas production
    • API Specification 6A (Annex F) – non-metallic seal requirements for wellhead and Christmas tree equipment
    • ASTM D1414 – standard test methods for rubber property-vulcanized O-rings
    • NORSOK M-710 – qualification of non-metallic sealing materials

    Typical usage ratio

    • 3–10% by monomer mass in copolymer synthesis, depending on temperature stability needs, volume swell limits, and blending with other backbone monomers.

    Downstream process integration

    • Reacted during fluoroalkyl chain extension at monomer level, then introduced to batch or continuous bulk polymerization; formulation proceeds to calendar, extrude, and compression mold into seal blanks or preforms, with thorough post-cure protocols.

    Final product types

    • High-end FFKM or FKM O-rings and gasket compounds
    • Packer elements for downhole drilling fluids
    • Compressor and valve stem seals for hydrocarbon processing
    • Chemical containment tubing and sleeves

    4. Production of Fluorinated Surfactants for Firefighting Foams (Short-chain C11 Type)

    Select fire safety manufacturers employ 11H-Perfluoroundecanoyl Chloride as a reactive intermediate in the synthesis of C11-based fluorosurfactants, facilitating the transition from legacy long-chain (C8 or higher) to more environmentally responsible short-chain products. These surfactants serve as critical performance components in aqueous film-forming foam (AFFF) formulations, with ongoing monitoring of regulatory changes and environmental toxicity data reflected in annual product design modifications.

    Industry compliance standards

    • NFPA 18 (2022 Edition) – standard on wetting agents and foams for fire control
    • REACH EU Regulation 2019/1021 – persistent organic pollutant (POP) updates for fluorinated surfactants
    • US EPA 40 CFR Part 721, SNUR for new PFAS chemicals
    • ASTM D892 – foam stability of lubricating oils (surfactant compatibility testing)

    Typical usage ratio

    • 0.5–3% surfactant active content in AFFF concentrate, with the intermediate dosage determined by target film-forming speed and drain time, as well as recent state and local use restrictions.

    Downstream process integration

    • Introduced during downstream etherification or amidation to yield fluoroalkylated surfactant molecules; post-reaction purification, blending into foam concentrates, and rigorous batch QC testing for film formation and aquatic toxicity.

    Final product types

    • C11-based AFFF fire suppression concentrates for aviation and fuel storage facilities
    • Fluorinated wetting agent blends for oil spill response
    • Specialty foam products for large-scale petrochemical fire control
    • Foam application equipment additive cartridges

    5. Development of High-Performance Lubricant and Grease Additives

    The acyl chloride supports the introduction of perfluoroalkyl moieties into synthetic lubricants and specialty greases for mechanical and aerospace applications. Its structure allows manufacturers to synthesize custom esters and amides, imparting lasting temperature, oxidation, and chemical resistance in greases used for vacuum, cleanroom, and extreme-pressure service. Rapid developments in aerospace and semiconductor production call for fine-tuned additive levels to optimize tribological performance while meeting rigorous purity and compliance demands.

    Industry compliance standards

    • NSF H1 (21 CFR 178.3570) – food-grade lubricants (where applicable)
    • ASTM D6184 – high temperature grease stability
    • AMS 3058, AMS 3052 – aerospace lubricant performance
    • ISO 6743-9 – classification of lubricants for extreme environments

    Typical usage ratio

    • 1–5% additive by base polymer or base oil weight, increased for environments requiring low off-gassing or ultrapure properties; selected after pilot blending and test-bench analysis.

    Downstream process integration

    • Chemically transformed into perfluoroalkylated esters at the additive supplier stage; blended by downstream lubricant compounding partners during base stock formulation and thickener dispersion, preceding filtration and packaging.

    Final product types

    • Synthetic greases for spacecraft, satellites, and cleanroom motors
    • Non-reactive vacuum pump lubricants
    • Assembly greases for sensitive semiconductor manufacturing equipment
    • High-purity, non-migrating bearing greases for food pharma lines (where specialty grades are required)
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    Certification & Compliance
    More Introduction

    11H-Perfluoroundecanoyl Chloride: An Inside Look from the Manufacturer’s Floor

    Shaping Reliable Fluoroalkyl Chemistry for Tomorrow’s Challenges

    Every day in our production plant, the importance of quality and certainty shapes each step in our synthesis of 11H-Perfluoroundecanoyl Chloride. Decades in chemical manufacturing have shown us that raw material consistency leads to stronger innovations downstream. Our experience with this fluoroalkyl acid chloride gives us a direct perspective on what matters to formulators, researchers, and commercial users who need confidence in their materials.

    Our Model: 11H-Perfluoroundecanoyl Chloride, C11F23COCl

    The backbone of this product lies in its unique chain length—eleven fluorinated carbons terminated with a reactive acid chloride. In our industry, the move toward longer-chained perfluoroacyl chlorides has roots deep in performance demand. We have seen, through batch-after-batch production, that this structure delivers more than a chemical definition. It allows users to take advantage of hydrophobic and oleophobic characteristics that reach further than shorter-chain analogs.

    We produce 11H-Perfluoroundecanoyl Chloride under exacting anhydrous conditions to maintain purity above 98%. On the plant floor, this means strict water exclusion, real-time in-line monitoring, and airtight containment through all handling stages until bottling. In our view, true consistency is more than a certificate; it’s a result that speaks after scale-up, every time the compound is introduced to a new synthesis.

    Comparing 11H-Perfluoroundecanoyl Chloride to Other Acyl Chlorides

    Many developmental chemists ask why we selected this particular chain length for industrial scale. We don’t do it just to stand out; we learned through direct client feedback that shorter chains like perfluorooctanoyl or perfluorononanoyl chloride often don’t deliver the thermal or chemical resistance needed in high-demand systems. At the same time, longer perfluorinated chains—C12 or more—may struggle with processability due to viscosity and higher melting points, which can bog down automated lines or cause congestion in reaction vessels.

    In our operations, we use the eleven-carbon structure because it hits a meaningful balance in reactivity, solvency, and physical manageability. 11H-Perfluoroundecanoyl Chloride tends toward a low viscosity, clear liquid at standard conditions; it pours evenly, making batch metering accurate. This makes a difference to technicians calibrating pumps on reactive lines. Additionally, it doesn’t crystallize or solidify under mild refrigeration, which is important for bulk users pulling from drums over weeks instead of hours.

    Specifications That Matter to the End User

    Researchers and engineers rely on clear numbers. Our product typically shows an assay of at least 98% by GC and maintains moisture levels below 0.2%. We keep acid values and free chloride within tight windows, confirmed by titration and specialized fluorine-NMR. Trace metals and organics are barely detectable—because we know even small contaminants can ruin surface treatments or block catalysts downstream.

    Because the synthesis yields an acid chloride functional group, 11H-Perfluoroundecanoyl Chloride reacts efficiently with nucleophiles like alcohols, amines, or even certain polymers, allowing production of perfluorinated esters, amides, and urethanes. The length and structure of its perfluoroalkyl tail offer advanced properties such as chemical durability, excellent substrate wetting, and stable, ultra-low surface free energy.

    Direct Uses from a Practical Lens

    Walking through our facility’s applications lab, we see new requests every week. Some customers aim for high-performance surface coatings. Others use our 11H-Perfluoroundecanoyl Chloride to build blocks for specialty fluorinated polymers or develop soil-repellent finishes for textiles and advanced membranes.

    A notable example appeared in the last fiscal quarter: a client from the semiconductor sector needed a water- and oil-proof photoresist additive, where pinhole-free barrier films help push device yields. After small-scale verification with our lot, they reported fewer defects in post-lithography cleaning—a direct payoff for their business. We keep reference batches on file for these kinds of validation projects, making it easier for their engineers to request repeat orders with the same fingerprint.

    Importance of Handling and Storage from Our Experience

    Acid chlorides like 11H-Perfluoroundecanoyl Chloride pose challenges that aren’t always visible in a product brochure. We’ve seen issues from improper handling—small leaks or slow reactions with air moisture can create corrosive HCl fumes in a matter of minutes. For this reason, we never store this material outside nitrogen-purged containers, and every drum or bottle ships with clear handling labels directly from our plant floor.

    Safe transfer and weighing happen under ventilated hoods. Most customers familiar with acid chlorides will have similar protocols. Still, we offer practical advice based on our experience: chilled storage below 10°C maintains product longevity, and all wetted equipment parts should use corrosion-resistant alloys. The product, when stored and dispensed properly, keeps its reactivity for months, with little loss or breakdown.

    Environmental and Regulatory Context

    We pay close attention to global and regional environmental trends. Much of the conversation around perfluorinated compounds (PFAS) revolves around their persistence and impact. From a manufacturer’s standpoint, we disclose our raw ingredient streams in line with both REACH and US EPA guidance. Our team regularly tests effluent for fluorinated discharge, recycling whenever feasible and adjusting process water treatment to meet local and national limits.

    Over recent years, we’ve redesigned containment and introduced recovery units for acid chloride vapor scrubbing and for capturing any high-boil point perfluorinated distillate. It’s not simply about compliance for us; loss of inventory or accidental release hurts the long-term viability of our production and the reputation of responsible chemistry. Conversations with downstream users often focus on expected fate in application or disposal, so we share stability, hydrolysis, and possible degradation product data—not just as a formality, but as part of mutual due diligence.

    Why Advanced Synthesis Relies on Reliable Inputs

    In high-value applications, unpredictability in raw material performance can escalate quickly to finished product failures. In our own history, we have seen small fluctuations in chain purity or functional group content leading to batch rejections or unwanted reactivity in formulated products.

    For development-scale users, a finely tuned acid chloride means fewer unknowns in both new molecule synthesis and established recipes. The mere difference of a single fluorinated methylene can swing surface energy or chemical compatibility far outside expected windows. We run frequent pilot batches with partner customers to ensure that the product will perform as predicted not just by numbers, but in real-world end uses.

    Addressing Supply Chain Consistency

    We’ve weathered raw material shortages, logistics delays, and the challenge of scaling up for global customers in different time zones. 11H-Perfluoroundecanoyl Chloride requires access to reliable fluoroalkyl precursors and a stable supply of auxiliary reagents. Over the years, we built redundancy in sourcing channels and maintain buffer stocks for critical feedstocks—buffering unexpected market shifts from disrupting downstream supply.

    Keeping open lines of communication directly with end users makes a dramatic difference. If a client’s production rate spikes, we can flex our batches and ship schedules with minimal disruption. By keeping a hands-on relationship from factory floor to delivery, we sidestep pitfalls that can plague distant or arm’s-length suppliers.

    Continuous Improvement: Lessons from Production

    Quality management in chemicals means more than periodic audits. For us, it shows up every time a raw material lot behaves differently in our reactors, or if a customer calls with feedback on trace impurity levels. We tackle real-world issues head-on: for instance, if a trace impurity causes unforeseen haze in a surface treatment application, we run parallel syntheses with adjusted purification regimes, sending comparison lots for external review.

    Our operators document even minor process tweaks, maintaining a running logbook for rapid troubleshooting. When recurring issues arise, we set up collaborative investigations with technical teams at the user site, not just remote troubleshooting.

    Innovation Driving the Next Generation of Perfluorochemical Utility

    Chemists worldwide are rethinking the ways in which perfluorinated functional units can enhance advanced materials. Rather than using 11H-Perfluoroundecanoyl Chloride only as a chemical intermediate, formulators now apply it in direct coatings, self-assembled monolayers, and reactive surface modifiers for microfluidic and analytical systems.

    On the manufacturing side, this opens new synthesis routes, sometimes at reaction scales our reactors barely handled a few years ago. To meet these demands, we modify not just batch sizes, but also reactor linings and purification schemes—tailoring the engineering framework to the real output needs of specialty applications.

    Facing Product Differentiation: How Eleven Carbons Change Performance

    Much of the chemical market is filled with competitors offering variations on classical perfluoroalkyl acid chlorides. We watch competitors’ chromatograms and sales pitches closely, but the practical distinctions on the bench come down to physical handling and finished surface interactions. The eleven-carbon backbone enables users to reach lower surface energy barriers in fluorinated films and provides higher thermal resistance than eight- or nine-carbon structures.

    For instance, working with fluorinated block copolymers, our team has repeatedly noticed that the C11 tail slows down hydrodynamic flow in wetting processes more effectively than shorter chains, leading to extended durability in coatings applied to glass, ceramic, or polymer composites. On the commercial side, coatings based on this chain length stand up for longer under acid or alkaline exposure compared to products made from lower homologues.

    Comparative studies in our application lab and with select research partners show that the transfer of the acid chloride’s reactivity allows a wider window for grafting and crosslinking to substrates, giving end-users greater leverage over their process conditions.

    Supporting Advanced Solutions: Beyond the Chemical Bottle

    It’s easy to see specialty chemicals as just another SKU on a delivery manifest. Our approach to 11H-Perfluoroundecanoyl Chloride views each batch as a foundation for a wider spectrum of breakthroughs. Our engagement doesn’t end at the sale; after delivery, we keep ongoing dialogue open for feedback loops. If a process shift leads to a change in final product characteristics, we mirror the changed parameters in our own pilot tests, tracking down possible causes side-by-side with our clients.

    We train our packaging staff to repack every container with an eye for long-distance transit. Material leaving the plant isn’t protected by luck or chance—it’s the result of iterative logistical improvements, from drum liners to climate-control shipping. This focus comes from recognizing the cost of shipment errors in specialty chemistry: a delayed or compromised lot can mean lost millions in product output for our industrial users.

    What Sets Our Approach Apart

    Working as a manufacturer embeds us at the start of the value chain. We experience every phase of this compound’s journey: synthesis, purification, bottling, quality release, and sometimes even reclaim. Our laboratory team analyzes samples against not just routine specifications, but also unexpected application questions—will this lot survive a specific curing cycle, a given solvent blend, or a demanding photolithography step?

    Feedback from user sites guides our continuous improvement efforts. If a textile innovator reports a difference in surface hand or repellency, we dig into lot metrics, including advanced spectrographic and chromatographic results, sharing data with their QC team. This direct partnership accelerates not only problem resolution but also jump-starts new product ideas.

    Balancing Precision, Performance, and Responsibility

    Producing specialty perfluorinated acid chlorides bears responsibilities that extend far beyond posted sales. Every choice, from raw material procurement to wastewater recycling, reflects decades of direct industry experience. We have learned to act as stewards in a field where unforeseen waste or emissions can propagate into wide-reaching impacts.

    Our record shows that transparent technical data combined with open dialogue builds more sustainable practices, not just for our plant but for the entire ecosystem of customers relying on advanced chemistry. We take pride in sharing up-to-date test results, storage insights, and real-world handling examples, supporting users in both established industries and emerging research sectors.

    Connecting Fluorochemical Manufacturing with Real Progress

    Our journey with 11H-Perfluoroundecanoyl Chloride continues to evolve as new sectors turn toward specialized fluorinated chemistries. Medical devices, electronics, aerospace coatings, and scientific R&D all draw from a base built here on the manufacturing floor—far from textbook abstractions. Each application brings new questions we address with direct sampling, method development, and iterative improvements in house.

    Staying at the forefront means bridging customer ambitions with chemical reality. We invest in pilot scale-up, raw material diversification, and rapid data turnaround, anchoring each decision in both operator experience and documented results.

    Looking Ahead: What’s Next for Advanced Perfluoroalkyl Chlorides

    Future demand will likely push for greater regulatory transparency, greener processing, and tighter control on emissions. We are already invested in scaling up solvent recovery, reducing by-product formation in our synthetic routes, and exploring alternative fluorination sources with reduced environmental footprint.

    For our industrial and research customers, the interplay of technical data and hands-on support makes advanced fluoroalkyl chemistry more than a supplier transaction. Our door remains open to questions, trials, and shared discovery, recognizing that leadership in this field depends not just on what we make, but on how we support real-world solutions at every step.