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1-Vinyl-3-Ethylimidazolium Hexafluorophosphate

    • Product Name 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate
    • Alias [VEIm][PF6]
    • Einecs 812-216-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    668968

    Chemical Name 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate
    Cas Number 138704-65-8
    Molecular Formula C7H11F6N2P
    Molecular Weight 266.14
    Appearance Colorless to pale yellow liquid
    Density 1.29 g/cm³
    Melting Point -20 °C
    Boiling Point Decomposes before boiling
    Solubility Slightly soluble in water; soluble in organic solvents
    Purity Typically ≥ 98%
    Refractive Index 1.46 (20 °C)
    Storage Temperature Room temperature, protect from moisture

    As an accredited 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle containing 100 grams of 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate, sealed with a screw cap and safety label.
    Shipping 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate is shipped in tightly sealed, chemically-resistant containers to prevent moisture ingress and contamination. It must be handled as a hazardous chemical, with proper labeling and documentation. During transport, it is kept away from incompatibles and stored in cool, dry conditions, complying with all relevant safety and regulatory requirements.
    Storage 1-Vinyl-3-ethylimidazolium hexafluorophosphate should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture and incompatible substances such as strong oxidizers. Protect from light and keep away from heat or ignition sources. Store under inert gas if possible, and label the container clearly. Follow all safety and regulatory guidelines for ionic liquids.
    Application of 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate

    Applications of 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate in Industrial Manufacturing

    1-Vinyl-3-Ethylimidazolium Hexafluorophosphate (VEImPF6) serves as a specialty ionic liquid in several niche chemical processing fields. As a direct manufacturer, we supply this material to clients operating advanced electrolytic, polymer, and catalyst systems. Below, we outline core industrial application segments, highlighting actual compliance, usage, integration, and end-product categories.

    1. Electrolyte Component in Supercapacitor Manufacturing

    Supercapacitor production leverages the unique electrochemical stability and ionic conductivity of VEImPF6. Manufacturers adopt the material for extended cycle life and increased capacitance density. Formulators carefully integrate this ionic liquid into customized electrolyte blends to achieve precise voltage windows, especially for devices requiring reliable high-temperature performance in automotive and consumer electronics.

    Industry compliance standards

    • IEC 62391 (Fixed Electric Double-Layer Capacitors for Use in Electronic Equipment)
    • IEC 61010-1 (Electrical Equipment Safety)
    • RoHS Directive 2015/863/EU for hazardous substances
    • REACH Regulation (EC) No 1907/2006 registration for ionic liquids

    Typical usage ratio

    • 10-30% by weight in mixed organic electrolyte solutions; concentration varies with electrode porosity, separator material, and target capacitance.

    Downstream process integration

    • Dissolves into prepared electrolyte mixtures in controlled dry-room blending tanks.
    • Ensures no residual water contamination, entering the assembly stage for impregnation into electrode/separator stacks prior to casing.

    Final product types

    • Cylindrical supercapacitors
    • Pouch cell supercapacitors
    • Hybrid Li-ion capacitors
    • Battery management modules for EVs and industrial automation

    2. Ionic Liquid Monomer in Advanced Polymer Electrolyte Synthesis

    Polymer R&D teams utilize VEImPF6 as a functional monomer for ionic polymer solid electrolytes. Manufacturers insert it during in-situ polymerization, creating flexible ionic conductive films that excel in all-solid-state batteries and flexible energy storage. The monomer’s vinyl group ensures efficient copolymerization, while the hexafluorophosphate anion maintains high ionic mobility without thermal decomposition, essential for high-throughput membrane casting lines.

    Industry compliance standards

    • UN 38.3 transport test (for batteries with new polymer electrolytes)
    • IEC 62660-2 (Secondary lithium-ion cells for automotive)
    • ISO 14644-1 (Cleanroom production for polymer film extrusion)
    • REACH annexes for polymeric ionic liquids

    Typical usage ratio

    • 5-15 mol% of the total monomer content for direct copolymerization; adjusted to achieve target film flexibility and conductivity as defined by device architecture.

    Downstream process integration

    • Directly introduced into monomer blend before bulk or solution polymerization on continuous reactor lines.
    • Polymer electrolyte sheets then undergo calendaring and lamination, with subsequent QC of ionic transport properties before module assembly.

    Final product types

    • All-solid-state battery separator films
    • Flexible printed energy modules
    • Wearable electronics power films
    • Advanced lithium-metal battery packs

    3. Homogeneous Catalyst Medium for Alkylation Reactions

    Chemical process plants employ VEImPF6 as an inert, recyclable ionic medium for homogeneous catalysis, particularly in Friedel-Crafts and phase-transfer reactions. This medium enables fine control over reaction kinetics, solubilizing transition metal or Lewis acid catalysts while suppressing volatile organic emissions. Operators can separate product layers with greater ease while recovering the ionic liquid for multiple batch cycles.

    Industry compliance standards

    • ISO 9001:2015 process quality certification
    • Responsible Care chemical management
    • National and regional VOC emission limits (e.g., China GB 37822-2019)
    • Specific customer QC protocols for alkylated aromatic purity

    Typical usage ratio

    • Employed at 20-50% v/v relative to total reaction mass; precise ratio determined by substrate solubility and catalytic conversion efficiency requirements.

    Downstream process integration

    • Added directly to the reactor vessel as the continuous ionic phase.
    • Following completion, operators decant product phase and regenerate the liquid phase for reuse with monitored purity via GC/HPLC.

    Final product types

    • High-purity alkylated aromatics
    • Pharmaceutical intermediates
    • Agrochemical bulk actives
    • Flavor and fragrance intermediates

    4. Separator Coating Additive for High-Voltage Lithium-Ion Cells

    Large-scale battery factories incorporate VEImPF6 as a surface-active coating additive for polyolefin and ceramic separators. The additive enhances interfacial wetting with electrolyte and improves ionic passage, which is key for the latest high-voltage cell chemistries. Technicians apply it by roll-to-roll slot-die or dip-coating, precisely controlling deposition thickness and uniformity for consistent electrical performance at cell build-up.

    Industry compliance standards

    • UL 1973 (Safety for Stationary Battery Applications)
    • IEC 62619 (Safety for industrial lithium batteries)
    • RoHS and REACH registration for coatings
    • OEM-specific separator extractables/tolerables specs

    Typical usage ratio

    • 0.5-2.5% by weight in the separator coating formulation; adjusted based on separator base material and targeted ionic impedance.

    Downstream process integration

    • Blended directly into the separator coating solution prior to application.
    • Applied on high-speed coating lines, followed by thermal curing and QC of surface properties and electrolyte uptake before integration into battery roll packs.

    Final product types

    • Ceramic-coated lithium-ion battery separators
    • Next-generation NMC and NCA cell assemblies
    • High-voltage pouch and prismatic cells
    • Grid-storage and automotive battery modules
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    Certification & Compliance
    More Introduction

    Introducing 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate: A Perspective From the Manufacturer

    The Craft of Producing 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate

    The journey to synthesizing 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate begins with meticulous selection and accuracy at every step. Each batch stems from hands-on experience with ionic liquids, built up after years managing the complex interplay between organic cations and anions. Our formulation of this ionic liquid carries the hallmark of consistency and purity that laboratories and industrial plants rely on to keep research and production lines on track. Every molecule that passes our quality control gets there because of direct oversight, insights from trial and error, and a commitment to continuous improvement.

    Over the past decade, we’ve seen interest in functionalized imidazolium salts grow from niche academic work to a pivotal component in many applied settings. Research teams and chemists have shown us what’s possible when a vinyl group combines with an ethylimidazolium cation, paired with a robust hexafluorophosphate anion. We manufacture to target top purity and accurate moisture control, because chemical synthesis doesn’t tolerate shortcuts. Each kilogram we produce undergoes analytic checks for trace metal content and water. Our customers expect reliable melting point range, stable color, and shelf-life; our plant process accommodates this by choosing the highest quality reactants and maintaining cleanroom-level standards along the route from synthesis to packing.

    Molecular Structure and the Impact of the Vinyl Functional Group

    1-Vinyl-3-Ethylimidazolium Hexafluorophosphate stands out in the field of ionic liquids. The structure, with its vinyl group at the 1-position and ethyl group at the 3-position on the imidazolium ring, delivers a fine balance between chemical activity and stability. Unlike simpler imidazolium salts, this molecule brings a reactive site at the vinyl position, which chemists take advantage of in polymerization or surface modification steps. This vinyl group means the ionic liquid doesn’t just dissolve and conduct—it participates, forms bonds, creates new frameworks in situ, unlocking new chemical architectures and possibilities.

    Most conventional ionic liquids act as neutral solvents or conducting media, and their functional groups do little more than influence bulk physical properties like viscosity or melting point. Here, by contrast, the vinyl functionality turns this compound into a handle for molecular innovation. Direct feedback from production partners has shown that the vinyl group boosts reactivity in radical or photoinitiated processes, which can cut process times and lower energy costs.

    Setting Specifications to Support Reliable Performance

    There is a difference between meeting an application’s requirement on paper and supporting it through real-world challenges. That’s something we see whenever we scale-up from test tube to barrel quantities. Our 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate maintains specifications for water, color, and metallic impurities because process chemists in research or pilot settings report real setbacks from trace contamination. Reactivity, especially in radical reactions, can swing dramatically with small uncontrolled variables. That’s why we fix target purity above 99% and use bespoke drying techniques for this class of ionic liquid.

    The hexafluorophosphate anion offers a crucial advantage. It lends hydrolytic stability when compared to alternatives like tetrafluoroborate, especially at elevated temperatures or in the presence of traces of moisture. In our experience, switching to this compound solves several issues of unwanted side-reactions that show up with less stable anions during electrochemical applications or catalysis. Customers working on sensitive electrodeposition or electroorganic synthesis have switched over because the resulting product gives fewer spikes in voltammetry traces and copes better with scale-up under less-than-ideal conditions.

    Why Ionic Liquid Purity and Handling Make All the Difference

    In the world of ionic liquids, small lapses in purity send ripples through outcome and reproducibility. We keep contact points with stainless steel and use inert-atmosphere routes for key stages, based on seeing the effect of oxygen and water uptake firsthand. Lower quality batches in industry often arise from corner-cutting in these costly steps, eroding trust and leaving users with inconsistent results. That’s unacceptable to us. Our staff uses gloveboxes and one-time-use packaging for sensitive orders. Customers working on controlled radical polymerizations or catalysis have pointed out the dramatic difference these precautions make. They get the same yield, every batch, every order, and store the material for longer without amperometric drift or color shift.

    We have worked with chemists across Europe and Asia who set out to polymerize surfaces with vinyl-functionalized cations. Every feedback round and returned sample teaches the same lesson: purity and thoughtful handling spell the line between success and waste. When a user reports reduced reactivity or batch variability, it’s never due to a quirk of the chemistry, but almost always to an overlooked contaminant or moisture lapse. Aftersales surveillance and ongoing dialogue drive our continuous improvement cycle.

    Applications: Unlocking New Pathways in Synthesis and Material Science

    1-Vinyl-3-Ethylimidazolium Hexafluorophosphate straddles several high-value sectors by virtue of its design. Materials scientists and organic chemists harness it for polymer modifications, ionic conducting layers, and designer electrolytes where functional group participation transforms the outcome. In practice, our compound directly supports fabrication of ionically crosslinked polymers for advanced battery separators or responsive membranes.

    We’ve witnessed our clients employ it in the synthesis of polymeric ionic liquids, a niche sector carving out space in energy storage and gas separation. Here, the vinyl functionality serves more than a theoretical role: scientists covalently anchor the imidazolium core to backbones or network matrices. Their work benefits from the controlled reactivity and minimization of side-chain migration or leaching. Routine reports from battery technology labs indicate that membranes incorporating this compound often show higher electrochemical stability, better selectivity, and more reliable performance over time.

    Our role as a manufacturer often extends beyond the shipment of raw material. Many leading-edge projects consult us about optimal polymerization techniques, choice of comonomers, and the best routes for introducing this ionic liquid during synthesis. Because we have tested its behavior in multiple settings—UV, pressure, temperature swings—our input helps customers tune their own processes, whether in membrane fabrication or advanced catalysis. There is pride in seeing projects reach successful scale-up thanks to practical input from our staff who’ve run those same experiments.

    Performance Differences: Vinyl-Functional Versus Standard Imidazolium Salts

    We produce a range of imidazolium-based ionic liquids, but only select compounds carry active vinyl groups. Users of our 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate report three immediate differences. The first is direct reactivity: they can graft, crosslink, or co-polymerize the ionic liquid, embedding it into new structures. Next comes improved adhesion in electrode and surface coating applications—a direct result of the pendant vinyl group interacting with host polymers or surfaces. The third benefit observed is flexibility in tuning physical properties. By adjusting ratios, our partners demonstrate control over glass transition temperature, membrane flexibility, or mechanical strength, all based on how the vinyl group features in their molecular design.

    Comparing to more standard ionic liquids, which lack such reactive handles, our product is not only a solvent or simple ion-transporter. It can act as a bridge to new types of polymers and networks. Application engineers have told us that standard imidazolium salts sometimes limit innovation by their inertness. The move to a vinyl-functionalized cation opens design space; people now create materials with ionic conductivity and responsive behavior unattainable with standard salts.

    Price sensitivity is a real concern, but practical feedback shows that the added cost per kilo is offset by greater adaptability and process yield. Research teams pay closer attention to shelf-life and degradation under real lab conditions. Our analyses of long-term stability show that the hexafluorophosphate variant holds up better than similar methyl or butyl analogs, avoiding the hydrolysis that sometimes plagues tetrafluoroborate-containing compounds after extended storage.

    From Bench to Industrial Scale: Supporting New Developments

    Challenges often arise as academic research jumps to pilot or industrial scale. Batch-to-batch reproducibility, removal of residual solvents, and control over moisture all become far less forgiving above the multi-hundred gram level. Our team tackles these by close monitoring of reaction kinetics, using advanced in-line analytics, and regular upgrades to drying and packaging infrastructure. We keep lines open with scale-up chemists, working through headaches such as aggregation, solubility issues in non-polar environments, and unexpected side-products.

    Process feedback cycles matter. After a customer reported irregularities in viscosity and reactivity when scaling from 50 grams to 500 grams, we jointly traced the problem to subtle differences in post-synthesis washing steps. A switch in solvent quality and changes to anion exchange protocols restored the expected properties in the next run. Such stories show that experience counts for more than certifications or paper specs; a real relationship and process insight often resolve what documentation and certificates simply cannot anticipate.

    Safety and Environmental Impact: A Manufacturer’s Commitment

    Handling hexafluorophosphate-containing ionic liquids requires more than a passing knowledge of safety protocols. We’ve adopted best practice waste management for both production effluents and accidental spills, learning from the pitfalls that tripped up earlier adopters in the ionic liquid sector. It’s not enough just to minimize exposure to strong acids during synthesis; F-containing anions require special consideration for compatibility in lab and plant. Over the years, we have invested in closed-loop systems, down-flow containment, and personal monitoring, fostering a culture where no batch release moves ahead without both analytical certification and a review of any process irregularities.

    Sustainability also means looking beyond the plant gates. Our raw material contracts prioritize supply chain stability and traceability, minimizing risk from fugitive emissions or environmental mishandling upstream. Whenever advances in decomposition or recycling of ionic liquids become feasible, we test those options on our own lines. Some improvements we have implemented were directly suggested by end-users, such as specific absorbent media for spent ionic liquids, reducing both hazardous waste and operational downtime.

    Working With Users to Solve Real-World Problems

    A good manufacturer never works in isolation. Our efforts to keep batches consistent, reduce impurities, and offer technical support draw directly from customer feedback and dialogue. During the last year, one research group using our ionic liquid for advanced 3D printing brought us a challenge in shelf stability under accelerated temperature and humidity. After reviewing storage protocols, we tweaked our packaging to include a new barrier film and desiccant system. The rate of complaints and necessary product returns went down, field engineers stopped fighting unexpected viscosity changes, and the project met its milestones on time.

    Another example comes from an energy storage company integrating functionalized ionic liquids into thin-film electrolytes. Their prototype films showed phase separation due to uncontrolled moisture uptake. By collaborating with their lab and providing incremental batches at various drying levels, we helped them reach a process that consistently yields clear, homogenous films. Years of working through such practical headaches have taught us to favor ongoing technical support over template sales service, as nothing beats real-world test data and open dialogue.

    Differences That Matter in Daily Operation

    Several factors set our 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate apart for scientists and engineers working at the forefront of functional materials:

    Every day, our process engineers and R&D staff bring new insights, sometimes adjusting production steps by just a few degrees or minutes. Those small adjustments, based on customer experience, industry benchmark, and real testing, translate to fewer surprises and more predictability in end-user projects. This product reflects not just technical acumen, but the lived reality of supporting a sophisticated, demanding research community.

    Learning From the Market and Remaining Accountable

    We keep listening. Scientists at the bench, project managers at pilot facilities, and industrial buyers shaping bulk orders all provide valuable commentary on our materials in use. We record every issue, every odd result, and take the time to identify if it arose from our batch, handling, or external factors. Ongoing improvement plans address what we learn, with no batch closed until root causes of deviations are fully addressed.

    We track trends too—demand for greener syntheses, safer production, and materials that tick both performance and sustainability boxes. That leads us to continuous reassessment of upstream and downstream effects, from raw material supply to disposal and recycling. In developing countries, our technical teams have supported the move to cleaner, less hazardous alternatives throughout the entire supply chain. We’re not just pushing a product; we’re advocating for responsible use and innovation that respects human health and environmental priorities.

    Paving New Paths in Chemistry With 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate

    We’ve seen innovation unfold right at the intersection of reliable manufacturing and user ingenuity. Whether it’s enabling complex polymer architectures or simplifying routes to functional coatings, 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate holds its own as a tool for those who value both chemical power and practical results. There are no shortcuts in reaching this standard—just a relentless focus on getting details right, learning from failures, and championing the progress our users make every day.

    From start to finish, every order reflects a collaboration—between skilled production staff, scientists at the bench, and feedback that keeps pushing us toward better performance. We enjoy seeing the creative directions this product takes once it leaves our facility—manifesting as breakthroughs in materials, cleaner energy, and more sustainable manufacturing methods.

    For chemists and engineers venturing into advanced synthesis, next-generation batteries, or novel membrane design, our 1-Vinyl-3-Ethylimidazolium Hexafluorophosphate stands ready—tested, trusted, and constantly improved to serve where it matters.