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1-Vinyl-3-Dodecylimidazolium Bromide

    • Product Name 1-Vinyl-3-Dodecylimidazolium Bromide
    • Alias [HMIM]Br
    • Einecs 620-780-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    804036

    Chemical Name 1-Vinyl-3-Dodecylimidazolium Bromide
    Cas Number 855110-32-6
    Molecular Formula C17H31BrN2
    Molecular Weight 359.35 g/mol
    Appearance White to off-white powder
    Melting Point Approximately 70-80°C
    Solubility Soluble in water and polar organic solvents
    Ionic Nature Ionic liquid (imidazolium salt)
    Storage Conditions Store in a tightly sealed container in a cool, dry place
    Purity Typically >98%
    Boiling Point Decomposes before boiling
    Density Approx. 1.1 g/cm³
    Synonyms 1-Vinyl-3-dodecylimidazolium bromide; [C12VIm]Br

    As an accredited 1-Vinyl-3-Dodecylimidazolium Bromide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The chemical is supplied in a 25g amber glass bottle with a secure screw cap and a detailed safety label for 1-Vinyl-3-Dodecylimidazolium Bromide.
    Shipping 1-Vinyl-3-Dodecylimidazolium Bromide is shipped in tightly sealed, chemical-resistant containers to prevent moisture absorption and contamination. Packaging complies with international hazardous materials regulations. Shipments include appropriate labeling, handling instructions, and safety documentation. Store and transport at room temperature, away from direct sunlight, oxidizing agents, and incompatible substances to ensure product stability and safety.
    Storage **1-Vinyl-3-Dodecylimidazolium Bromide** should be stored in a tightly sealed container, away from moisture and direct sunlight, in a cool, dry, well-ventilated area. Avoid exposure to heat and incompatible materials such as strong oxidizers. Ensure containers are properly labeled and protected from physical damage. Store in accordance with local regulations and institutional chemical safety protocols.
    Application of 1-Vinyl-3-Dodecylimidazolium Bromide

    Applications of 1-Vinyl-3-Dodecylimidazolium Bromide in Industrial Manufacturing

    As the direct manufacturer of 1-Vinyl-3-Dodecylimidazolium Bromide, we supply this specialty ionic liquid to global industrial clients who require uncompromising purity and targeted performance for advanced manufacturing processes. This material functions beyond conventional surfactants, with established downstream adoption in several high-value sectors leveraging its unique ionic structure for process efficiency and advanced material fabrication. Below, we detail its proven application scenarios and respective technical requirements.

    1. Polymer Electrolyte Membrane Production for Energy Storage

    1-Vinyl-3-Dodecylimidazolium Bromide serves as a functionalized ionic liquid monomer in synthesizing high-ionic-conductivity polymer membranes, predominantly for lithium-ion battery and supercapacitor separators. The compound’s compatibility with radical polymerization allows fine-tuning of membrane microstructure, enabling stable ionic transport under high-voltage conditions. End-users in the battery sector require materials with defined purity levels to minimize defect rates during film casting and enhance life cycles.

    Industry compliance standards

    • IEC 62660-2: Secondary lithium-ion cells for the propulsion of electric road vehicles
    • UN 38.3: Recommendations on the Transport of Dangerous Goods (relevant for downstream battery shipping)
    • ISO 9001:2015-certified battery QC management
    • RoHS 2011/65/EU: Restriction of Hazardous Substances

    Typical usage ratio

    • 0.5%–5% by weight in vinyl-based copolymer casting formulations; dosage adjusted according to desired membrane ion conductivity and mechanical robustness

    Downstream process integration

    • Dosed during in-situ radical polymerization of the monomer blend; either pre-mixed with vinyl acetate, acrylonitrile, or other co-monomers before film casting via doctor-blade or solution pouring

    Final product types

    • Lithium-ion battery separator films
    • Supercapacitor polymer electrolyte membranes
    • High-voltage hybrid capacitor separator sheets

    2. Antistatic Coatings for Electronic Component Packaging

    Downstream manufacturers incorporate this imidazolium-based ionic liquid into conductive polymer dispersions to create antistatic coatings for electronic device trays, reels, and flex circuits. The long dodecyl chain imparts persistent surface lubrication while the ionic moiety dissipates electrostatic charge, protecting sensitive microelectronics during transport and assembly. Process engineers employ the additive in strictly controlled ratios to ensure surface resistivity falls within acceptability ranges for semiconductor packaging guidelines.

    Industry compliance standards

    • IEC 61340-5-1: Electrostatics – Protection of electronic devices from electrostatic phenomena
    • ANSI/ESD S541: Packaging Materials for ESD Sensitive Items
    • ISO 14001: Environmental Management System (coating line emissions control)
    • UL 94: Flammability of Plastic Materials (for finished parts)

    Typical usage ratio

    • 0.2%–1.0% by weight in water- or solvent-borne acrylic/polyurethane dispersions, adjusted as required to achieve < 10⁹ Ω/sq surface resistivity

    Downstream process integration

    • Added as a liquid additive to the resin pre-mix, maintained under agitation; introduced before pigment grinding and final letdown on automated coating lines

    Final product types

    • Conductive packaging trays and bins
    • Antistatic reels and carrier tapes for ICs
    • ESD protective films for display modules

    3. Dispersing and Stabilizing Agent in Nanomaterial Synthesis

    Researchers and commercial producers utilize 1-Vinyl-3-Dodecylimidazolium Bromide as a dispersing agent for stabilizing nanoparticles in aqueous or polar organic media, especially for advanced materials such as graphene, carbon nanotubes, or metal oxides. Its amphiphilic structure anchors to particle surfaces while simultaneously imparting colloidal stability during sol-gel or hydrothermal synthesis, preventing aggregation and enabling consistent nanostructure morphology for advanced functional applications.

    Industry compliance standards

    • ISO/TS 80004-1: Nanotechnologies – Vocabulary
    • REACH (EC) No 1907/2006: Registration, Evaluation, Authorisation and Restriction of Chemicals
    • ISO/IEC 17025: Testing and calibration laboratory accreditation (for quality control analysis of dispersions)
    • OECD Guidelines for the Testing of Chemicals, Section 1: Physical-Chemical Properties (nanomaterial characterization)

    Typical usage ratio

    • 0.1%–2.5% by weight relative to the nanomaterial mass, depending on hydrophobicity of particle surfaces and required dispersion stability

    Downstream process integration

    • Incorporated during nanoparticle wet-milling or post-synthesis exfoliation; often sonicated with particle dispersions before downstream casting or spray drying

    Final product types

    • Dispersed graphene oxide inks
    • Functionalized carbon nanotube suspensions
    • Coatable metal oxide nanoparticle slurries for advanced coatings and ceramics

    4. Functional Monomer for Advanced Ion Exchange Resins

    Manufacturers of high-performance ion exchange resins use 1-Vinyl-3-Dodecylimidazolium Bromide as a specialty monomer during copolymerization to impart improved selectivity for organic and heavy metal cation removal. The imidazolium ring offers specific ionic binding sites within the resin matrix, while the dodecyl chain adjusts resin pore structure for tailored sorption kinetics. This approach allows the downstream user to meet rising standards for water purification in both municipal and microelectronics applications.

    Industry compliance standards

    • NSF/ANSI 61: Drinking Water System Components – Health Effects
    • EN 1508: Water supply – Quality criteria for water intended for the production of ion exchange resins
    • USP 43/NF 38: Water for Pharmaceutical Purposes (for ultrapure water applications)
    • ISO 9001:2015: Quality management for water treatment chemical manufacturers

    Typical usage ratio

    • 1%–3.5% by weight of total monomer feed; proportional adjustment based on the target resin’s required ion selectivity and exchange capacity

    Downstream process integration

    • Introduced into aqueous or solvent-based suspension polymerization reactors, blended with crosslinkers before bead formation and post-polymerization functionalization

    Final product types

    • Selective organic scavenger resins
    • Heavy metal removal cartridges for ultrapure water systems
    • Custom-developed mixed bed ion exchanger beads for electronics and pharmaceutical water circuits

    5. Additive in Enhanced Oil Recovery Surfactant Blends

    Downstream oilfield chemical blenders incorporate this ionic liquid into advanced surfactant packages to boost interfacial activity and improve wettability modulation during enhanced oil recovery (EOR) operations. Its stability under high salinity and temperature makes it suitable for injection formulations that maximize crude displacement efficiency, reducing residual oil in mature reservoirs and supporting sustained recovery rates.

    Industry compliance standards

    • API RP 63: Recommended Practices for Evaluation of Polymers Used in EOR
    • ISO 10414-1: Petroleum and natural gas industries – Field testing of drilling fluids
    • OECD 301B: Ready Biodegradability (required for environmental discharge reviews)
    • ISO 14001: Environmental Management

    Typical usage ratio

    • 0.05%–0.5% by weight of total surfactant formulation; adjusted after phase behavior and core flooding lab screening for specific field brine and temperature conditions

    Downstream process integration

    • Dosed into aqueous surfactant blends on automated batch mixing systems; typically added post-hydration of base surfactants to minimize viscosity build-up

    Final product types

    • Low-interfacial-tension surfactant flooding formulations for field injection
    • CO₂-assisted EOR chemical blends
    • Hybrid polymer-surfactant EOR chemical packages
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    Certification & Compliance
    More Introduction

    Introducing 1-Vinyl-3-Dodecylimidazolium Bromide: A Practical Perspective

    On the Factory Floor: Making a Better Ionic Liquid

    For over a decade, our work at the plant has revolved around pushing materials science where it can really make a difference — in labs, in production lines, and in every process that demands reliable performance. 1-Vinyl-3-Dodecylimidazolium Bromide stands out in our product catalog, not just as another ionic liquid but as a compound built with both researchers and industrial users in mind. The chemistry isn’t just about enabling innovation; it’s about meeting the day-to-day needs of people who work with demanding processes or unique application requirements.

    Building on Imidazolium’s Reputation

    Imidazolium-based compounds have reshaped how industries approach solvents, antistatics, and synthesis. The popularity over the years isn’t accidental. These salts offer thermal stability, tunable solubility, and chemical versatility. Adding a vinyl group at the 1-position opens up polymerization options right at the molecular level. Topping it off with a dodecyl (C12) side chain brings meaningful changes to its handling, compatibility, and downstream uses, qualities appreciated by technical buyers evaluating the cost and benefit of every kilogram purchased.

    Understanding the Specifications That Matter

    Our process yields 1-Vinyl-3-Dodecylimidazolium Bromide as a pale waxy solid that melts to a viscous liquid, evidence of the long alkyl chain and the tailored molecular weight. Users see an average molecular weight of just under 450 g/mol. Purity exceeds 98% as measured by NMR and ion chromatography — a lab number that translates into fewer headaches during large or small batch syntheses. Color can range from off-white to pale yellow, mainly because of the dodecyl chain and the bromide, not because of manufacturing shortcuts.

    Avoiding moisture is common sense when handling, not because the compound disintegrates, but because any ionic material is hygroscopic to some extent. Labs sometimes store the material sealed under nitrogen for the purest results, but packaging at our facility holds up well in most industrial storage rooms. Shelf stability runs to years. Complexity stays low for cleaning up after spills; the material doesn’t evaporate or off-gas like volatile solvents.

    Why Vinyl and What Dodecyl Brings to the Table

    Any chemist who’s tinkered with ionic liquids knows how important small structural changes are. The vinyl group attached at the 1-position doesn’t sit idly. It’s reactive and enables direct participation in polymerization. We’ve seen customers crosslink this imidazolium in building ion exchange polymers, antistatic films, and specialty membranes. Instead of using additives, the vinyl itself becomes part of the polymer backbone, reducing leachable content and boosting durability.

    The dodecyl chain, twelve carbons long, shifts the product into a class of amphiphilic ionic liquids. This changes how it dissolves, how it assembles at interfaces, and how it interacts with substrates in real applications. Solutions in water or organic solvents turn milky, showing micellar or even vesicle-like aggregation. In coatings, this helps lay down smoother films or uniform surface modifications. In electrochemical settings, the longer tail can lead to stabilized electrical double layers or more robust electrode coatings.

    Points of Difference: More Than a Simple Salt

    It’s true that plenty of imidazolium salts come off our production lines each month — methyl, ethyl, hexyl, octyl — each with a personality shaped by the alkyl chain. Dodecyl is on the longer end, so it modifies solubility and softens the material compared to short-chain analogs. That means users see less crystallinity, more tendency to form gels or thick pastes, making it better for blending with viscous monomers or for spreading thin on substrates. If you’re mixing it with acrylate monomers, the compatibility with oily phases jumps up, saving time on solvent selection or process adaptation.

    The bromide counterion plays a role, too. Compared to chloride or more exotic anions like PF6 or BF4, bromide offers solid cost control and low toxicity risk, which matter when scaling from a few grams to several hundred kilos. There’s less corrosivity than with chloride, and bromide doesn’t cloud regulatory waters the way fluorinated anions sometimes do.

    In the Lab: Giving Researchers More Room to Experiment

    Curiosity in research settings drives industrial innovation. PhD candidates and senior researchers alike favor this molecule when working on ionic conductive polymers, surface functionalization, or catalysis supports. The vinyl group participates in both free-radical and photo-initiated polymerizations. People have reported success combing it with acrylate, methacrylate, and styrene monomers, usually without needing special compatibilizers. Crosslinked gels absorb electrolytes and serve as soft solid-state ionic conductors.

    In surface science, our customers use it for crafting self-assembled monolayers, anti-fouling coatings, and anti-static surfaces. The amphiphilic nature helps it attach at interfaces between water and oil, arranging the dodecyl chain into protective barriers that resist wetting and reduce static buildup. Applications stretch from sensor manufacturing to flexible electronics, especially where direct electrical contact through harsh industrial environments occurs.

    Production Reality: Manufacturing That Matches Expectations

    We built our reactors and purification columns to deliver batch consistency over scale. Each run passes through in-line monitoring for ionic purity and residual vinyl content, which makes sure no crosslinking happens ahead of schedule. Yield losses get tracked down and eliminated wherever possible, keeping prices competitive even as feedstock volatility challenges the sector.

    Getting clean material out the door isn’t about ticking regulatory boxes. It’s a philosophy shaped by listening to the issues reported by plant engineers or research associates using competitive materials. Consistency batch-to-batch lowers wasted time during qualification and method development. We take every complaint — whether about minor color shifts or observed phase separation at elevated temperatures — seriously, and update controls or drying methods to resolve any fit-for-use issues quickly.

    In Industry: Lessons from Customer Feedback

    One of our coating manufacturer clients started out testing 1-Vinyl-3-Dodecylimidazolium Bromide as a surface-modifying agent. They reported significantly reduced static build-up and improved adhesion to plastic films, compared to using short-chain imidazolium analogs. Film-forming behavior changed, with melt-cast coatings showing smoother surfaces and less crystallization at the surface. These small changes dropped the occurrence of microcracks from five percent per lot down to less than one percent, according to their internal quality records.

    Another user in battery research reported strong ionic mobility within the polymer matrices derived from this compound. The longer dodecyl chain enabled gel formation at surprisingly low loadings, often in the 1–3 percent range, allowing them to construct stable, flexible electrolytes that withstood repeated mechanical cycling. Reports from their field trials indicated that these gels retained their flexibility and did not dry out or lose conductivity for over nine months, even in climates with sustained low relative humidity.

    In textiles, the story has been different. A development team experimented with our salt in anti-static yarn treatment. The product integrated well with their existing emulsion processing, and after several pilot runs, the static charge retention through multiple washing cycles beat their benchmarks for both synthetic and blended fibers. The customer estimated a thirty percent boost in end-use performance, which helps their competitive standing in technical apparel.

    Why Choice of Counterion Doesn’t Just Affect Cost

    Within imidazolium chemistry, the counterion influences more than just price or solubility. Switching out bromide for alternatives can reorganize the entire working protocol. Our teams have seen users struggle with competitive materials that contain chloride; corrosion on sensitive metal surfaces undermines product lifetime and complicates cleaning. Bromide, as supplied in our manufacturing processes, stays stable and minimizes these unintended effects, helping process engineers keep their downtimes in check.

    In specialty electrochemical devices, bromide can moderate the conductivity profile of polymers derived from this imidazolium. Instead of spiking initial current and then decaying, systems show leveled output and reduced noise. Analysis from several partners in diagnostics and biosensor fields point to bromide’s ability to balance performance and process simplicity, supporting their tight development timelines and keeping regulator questions manageable.

    Scaling Up: Reliable Sourcing and Ongoing Collaboration

    Every year, teams from startups to major manufacturers come through our production suites to qualify 1-Vinyl-3-Dodecylimidazolium Bromide for new uses — conductive composites, antifouling coatings, responsive materials. We don’t sell a generic product; we support people working through practical issues, whether in batch scaling, regulatory implementation, or finding suitable solvents for unfamiliar blends.

    Technical support remains a daily job. Our plant chemists answer questions about shelf life and best storage conditions, sometimes walking customers through the details. If a batch accidentally absorbs water, they know to dry it under vacuum at moderate temperature for several hours. Preventing cross-contamination with other salts or organic amines demands real training on mixing lines. These lessons have saved countless hours during both product launches and troubleshooting.

    Meeting Stringent Industry Standards

    Our business does not operate in a vacuum. Expectations from clients in electronics, energy, and materials research have driven our processes to shift continually. Every supply lot meets analysis by HPLC, NMR, and mass spectroscopy. Samples from each drum undergo inspection for not just chemical identity but phase consistency and residue content. We never ship on spec alone. Technicians monitor viscosity and physical appearance, because end users in coatings care about how the product handles, not simply if it meets a paper specification.

    Collaborating with regulatory compliance teams, we ensure our product supports the strictest workplace safety and environmental standards. Waste streams are minimized. Byproducts from production and purification are captured and recycled whenever possible. Strict adherence to occupational exposure protocols protects not just our staff but every downstream user touching the material during final conversion steps.

    Innovation and Adaptation: Seeing Beyond Standard Uses

    People often think of ionic liquids as just novel solvents for research. Over the last few years, our experience has gone much farther. Polymerizable imidazolium salts like this one keep finding new territory: photoresists for microelectronics, functional layers for flexible displays, membranes for energy storage and water purification, lubricants in precision devices. The polymerizable vinyl group opens options in additive manufacturing and rapid prototyping, a shift that traditional, more rigid ionic liquids never managed to address.

    As 3D printing and digital fabrication have gained ground, formulators discovered that this material can serve as a co-monomer, altering flexibility, conductivity, and response under dynamic load. The balance between the vinyl group’s reactivity and the dodecyl chain’s flexibility brings unique properties — not just within polymers but across blends with inorganic fillers, organic waxes, or even proteinaceous materials. Blends made with this salt have shown promise in antimicrobial coatings as well, with the quaternary imidazolium core interacting destructively with certain bacteria and fungi.

    Users in the agriculture sector are running tests on seed coatings and film mulches, where anti-fouling and anti-static performance drops spoilage and speeds up post-harvest processing. The range of uses keeps expanding, mostly thanks to the flexibility built into the molecule’s design along with our willingness to iterate process conditions.

    Comparing with Common Choices: Shortcomings and Advantages

    Compared to short-chain imidazolium salts, the dodecyl group in this material offers softer film formation, longer chain entanglement in polymers, and less tendency to sublimate under harsh conditions. Short-chain analogs have their place in rapid solution-phase processes, but anyone seeking flexibility, amphiphilicity, or specialized interfacial behavior will see clear advantages in our long-chain version.

    With respect to anion variation, compounds incorporating PF6 or BF4 anions face restrictions in disposal, risk of fluorine release under certain breakdown scenarios, and rising concern among regulatory bodies. Choosing bromide sidesteps much of the red tape and simplifies waste management, all while keeping acquisition cost in check for volume buyers.

    Some customers come to us after disappointing trials with unfunctionalized, N-alkyl imidazolium salts for antistatic performance. Lacking the vinyl functionality, their materials often leach out or migrate, leading to fading results over time. By offering a structure that integrates directly into networks by means of polymerization, 1-Vinyl-3-Dodecylimidazolium Bromide stays put, delivers longer life, and shows fewer compatibility surprises.

    Collaboration and Continuous Improvement

    Manufacturing this compound isn’t just about reacting raw materials and packing off-the-shelf orders. Every day, feedback from users drives incremental tweaks — adjustments to drying steps, filtration improvements, shifts in allowed water content. Regular dialogue between our chemists and clients opens the door to nonstandard purities or alternate packaging tailored to sectors such as medical, semiconductor, or aerospace. Large volume contracts sometimes require deviation from our normal practice, and we aren’t afraid to document, test, and implement new protocols as new applications emerge.

    Underpinning all of this: transparent communication about what the product does and what it doesn’t do. We train our technical reps to tell the truth, not to push the product past its natural fit. Users value straight talk about shelf stability, potential odor development at elevated temperatures, or incompatibility with certain reactive monomers. That approach—realistic, responsive, and tailored to what our customers actually see in their labs and factories—deserves the trust and loyalty that we continually earn and maintain.

    Looking Ahead: The Value in Steady Innovation

    Our plant has seen ionic liquids move from niche products to workhorse chemicals supporting major shifts in electronics, advanced materials, and energy. 1-Vinyl-3-Dodecylimidazolium Bromide exemplifies this journey, standing as a material shaped by hands-on feedback and unshakable attention to process reliability and product adaptability. Every batch reflects our goal of offering not just a stock chemical, but a platform for experimentation, production reliability, and genuine improvement—project after project, year after year.