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1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    • Product Name 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
    • Alias [PMIM][TFSI]
    • Einecs 809-285-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    989690

    Chemical Name 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
    Cas Number 68443-16-1
    Molecular Formula C11H18F6N4O4S2
    Molecular Weight 470.41 g/mol
    Appearance Colorless to pale yellow liquid
    Melting Point -12 °C
    Boiling Point Decomposes before boiling
    Density 1.42 g/cm3 (at 20 °C)
    Solubility In Water Slightly soluble
    Viscosity 42 cP (at 25 °C)
    Refractive Index 1.429 (at 20 °C)
    Flash Point > 150 °C
    Purity >99%
    Storage Conditions Store in a cool, dry place, tightly closed

    As an accredited 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 100 g, sealed with PTFE-lined cap, chemical label displays hazard symbols and product details, vacuum-packed for safety.
    Shipping This chemical is typically shipped in sealed, airtight containers to prevent moisture absorption and contamination. It should be packaged according to chemical safety guidelines, labeled clearly, and transported as a non-hazardous liquid unless otherwise specified. Standard shipping involves ground or air freight, with temperature control if required by the manufacturer’s safety data sheet (SDS).
    Storage 1-Propyl-2,3-dimethylimidazolium bis((trifluoromethyl)sulfonyl)imide should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture, heat, and direct sunlight. Keep away from sources of ignition and incompatible materials such as strong oxidizers. Ensure secondary containment to prevent leaks. Store under inert gas if specified by the manufacturer.
    Application of 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    Applications of 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide in Industrial Manufacturing

    1-Propyl-2,3-dimethylimidazolium bis((trifluoromethyl)sulfonyl)imide is a high-performance ionic liquid widely applied in advanced chemical process routes. Its properties meet strict requirements in multiple specialized fields due to chemical stability, electrochemical window, and solubility characteristics. Below are detailed, real-world downstream application scenarios where this material directly enables process innovation and commercial manufacturing.

    1. Lithium Battery Electrolyte Formulation

    This ionic liquid plays a key role in lithium battery electrolyte systems for high-performance and next-generation lithium-ion batteries. Its thermal stability and low flammability improve safety in energy storage systems. As an electrolyte additive or replacement for conventional solvents, it supports stable cycling at elevated voltages and temperatures. Manufacturers blend this component into the electrolyte to enable greater ion mobility and expand battery lifespan, especially in applications demanding robust safety margins such as electric vehicles and stationary grid storage.

    Industry compliance standards

    • UN 38.3 Transport Tests for Lithium Batteries
    • GB/T 31486 Performance Requirements for Lithium-ion Traction Batteries
    • IEC 62660-2 Safety Testing of Lithium-ion Cells
    • ISO 9001:2015 for manufacturing processes

    Typical usage ratio

    • 5% to 30% of total electrolyte solvent mass; producers adjust proportion based on required ionic conductivity, target working temperature, and battery form factor.

    Downstream process integration

    • Blended into lithium salt and co-solvent mixtures after cell assembly dry room prep, followed by vacuum filling into cell housings before final sealing and formation cycles.

    Final product types

    • Prismatic lithium-ion batteries
    • Pouch cell batteries for electric vehicles
    • High-capacity stationary storage modules
    • Rechargeable lithium-polymer cells

    2. Catalytic Reaction Medium for Organic Synthesis

    Downstream chemical producers utilize this ionic liquid as a reaction medium in catalyst-assisted transformations, such as alkylation, Diels–Alder reactions, and oxidative couplings. Its unique polarity and ability to dissolve both organic and inorganic substrates allow consistent yields in fine chemical and pharmaceutical intermediate synthesis. It also aids product separation steps, reducing downstream purification complexity for commercial process chemists scaling from pilot plant to full production.

    Industry compliance standards

    • ICH Q7 GMP for Active Pharmaceutical Ingredient Manufacturing
    • European REACH for chemical safety assessment
    • CFR 21 Part 211 for API synthesis plants (if used in regulated steps)
    • ISO 14001:2015 for environmental management in chemical manufacturing

    Typical usage ratio

    • Usually 0.5 to 3 molar equivalents relative to reactants; chemists adjust based on solubility, reaction rate, and scalability studies.

    Downstream process integration

    • Charged directly as the principal solvent medium with catalyst and substrates at the start of batch reaction; retained or recycled during product isolation and repeated cycles.

    Final product types

    • Pharmaceutical intermediates
    • Fine chemicals for agrochemical synthesis
    • High-purity specialty monomers
    • Functionalized aromatics for advanced materials

    3. Antistatic Additive for Engineering Plastics

    Manufacturers of engineering plastics such as polycarbonate, acrylonitrile-butadiene-styrene (ABS), and polyamide incorporate this ionic liquid as an internal antistatic agent. Its ion mobility and compatibility with polar polymers ensures enduring antistatic performance without affecting transparency or processing behavior. Automotive, electronic, and packaging sector molders rely on its integration for static-dissipative components, reducing the accumulation of dust and minimizing risk of static discharge in sensitive applications.

    Industry compliance standards

    • UL 94 Flammability Rating for Plastics
    • RoHS Directive (EU 2015/863) on Hazardous Substances
    • EN 61340-5-1 Electrostatic Control Standard
    • ISO 9001 for polymer compounding

    Typical usage ratio

    • 0.1% to 1.5% by weight in polymer melt; content optimized for V-2 or higher flame rating and anti-static performance per application test panels.

    Downstream process integration

    • Pre-blended with base polymer resins and melt-compounded on twin-screw extruders, pelletized, and injection molded or extruded into finished items.

    Final product types

    • Automotive dashboard components
    • Electronic device housings
    • Transparent anti-static films for packaging
    • Cleanroom plastic assemblies

    4. Solvent for CO2 Capture in Gas Treatment

    This ionic liquid serves as an absorbent solvent in industrial gas treatment, specifically for selective carbon dioxide capture from flue gas streams in power plants or chemical process industries. Its high CO2 solubility and low volatility lower emission control costs compared to amine alternatives. Operators leverage its recyclability and non-aqueous nature to minimize equipment corrosion and reduce solvent makeup frequency in continuous absorption-desorption cycles.

    Industry compliance standards

    • ISO 14064-1 Greenhouse Gas Reporting
    • EPA 40 CFR Part 98 for Greenhouse Gas Mandatory Reporting
    • EN 7799:2021 Industrial Emissions (Large Combustion Plants)
    • ISO 9001 Quality Management for process plants

    Typical usage ratio

    • Utilized as the primary absorbent phase; operating concentration depends on absorber loading rate, typically 100% ionic liquid or blended with up to 20% co-solvent for viscosity adjustment.

    Downstream process integration

    • Pumped into absorber towers to contact flue gas for CO2 uptake, then transported to a desorber unit for thermal regeneration and re-circulation.

    Final product types

    • Captured CO2 for food/beverage use
    • Compressed CO2 for industrial reuse
    • CO2-lean effluent gas for emission reduction
    • Recovered ionic liquid for recycling
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    Certification & Compliance
    More Introduction

    1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide: Meeting Demands for Modern Chemistry

    A Look Into Our Manufacturing Process

    In the chemical manufacturing business, quality cannot be separated from experience. Our journey with 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide started in the lab, but every step since has come down to hands-on fine-tuning and close attention to detail. This ionic liquid, which falls under the imidazolium family, represents a breakthrough that only those working closely with such specialty salts can truly appreciate. Producing this material, we control every stage, right down to impurity levels not always found on a spec sheet. Consistent performance begins with high-purity reagents, tight control of temperature profiles, and complete exclusion of moisture, and our staff maintain these every day, limiting batch-to-batch deviations that otherwise disrupt research or manufacturing results.

    Understanding Its Structure—And Why That Matters

    A lot of laboratory-grade materials float around with a host of different cations and anions. At its core, 1-Propyl-2,3-Dimethylimidazolium cation couples with the bis(trifluoromethyl)sulfonylimide, or NTf2 anion. Skilled chemists instantly grasp the difference made by this pairing. The propyl group delivers lower viscosity than longer alkyl chains, making the liquid easier to handle, mix, and stir under a broader range of conditions. Dimethyl substitution on the imidazolium ring improves thermal stability and cuts down reactive “hot spots” that might mess with sensitive catalysis or extraction tasks. Now layer in the NTf2 anion, which is hydrophobic and chemically resistant, and you have an ionic liquid that resists hydrolysis and provides wide electrochemical windows.

    Why This Model Picks Up Where Others Leave Off

    We manufacture a full range of imidazolium ionic liquids, but after years of working with customers in advanced materials, battery research, and catalysis, the functionality of this particular model stands out. Some applications, including electrochemical devices, extraction processes, and high-end separation science, can’t tolerate stray water or inconsistent batch quality. Our production runs target the lowest possible water and halide content without compromising throughput. This isn’t something you spot with a quick test; it’s a process matured by hundreds of analytical runs, regular collaboration with end users, and a habit of tracing even small anomalies back to source materials.

    There’s more to distinction than purity alone. The NTf2-based ionic liquids have proven time and again to outperform chloride-based, tetrafluoroborate, or hexafluorophosphate analogues under harsh conditions. We monitor electrical conductivity, viscosity, and long-term thermal performance—not just as once-off specs, but across full production lots. Many times, customers in research and industry have commented on the unmistakable reproducibility of this ionic liquid compared to broader-market offerings. Each bottle comes from carefully managed synthesis, not blending or dilution from bulk imports, eliminating surprises that can sideline costly R&D projects.

    Applications and Real-World Usage

    There’s a tendency in specialty chemical marketing to gloss over actual field experience. Our approach differs. Most users of 1-Propyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide come to us not just for molecular performance on paper, but because their own work demands absolute reliability—whether that’s in lithium-ion battery electrolytes, custom solvent systems for heterogeneous catalysis, or extracting rare earth metals. Some of the earliest customer trials involved electrodeposition cells for advanced materials, where high ionic mobility and resistance to decomposition at elevated voltages proved decisive. Battery developers now utilize this ionic liquid in electrolyte blends due to its stable electrochemical window, low moisture pickup, and ability to suppress dendrite growth. Safety managers and process engineers appreciate that thermal stability and non-flammability go hand-in-hand with robust production methods, removing the risks associated with less reliably made ionic liquids.

    In laboratory-scale extractions, the hydrophobic NTf2 anion practically eliminates the water solubility that limits many other ionic liquids in multiphase separation. Chemists working in pharmaceutical development highlight how predictable partitioning between phases gives them reproducible yields and easier downstream workups. Our relationships with academics have us supporting research into novel catalysts—including metal complexes that only survive in NTf2 media—where a stray trace of halide or a rise in viscosity, even at low temperatures, can throw off months of results. The transparency and ongoing feedback loops we’ve built with end users have helped us tune not just purity, but physical handling. Some wanted lower density for pipetting; others required viscosity within a tight envelope for microfluidic applications. Whenever possible, we’ve built practical improvements directly into our process lines.

    What Sets Our Material Apart on the Factory Floor

    Mass production of advanced ionic liquids rarely gets discussed in public. That’s a shame, because practical issues emerge at scale—batch consistency, handling safety, cross-contamination, and bottle-to-bottle uniformity. Customers have told us about headaches with competitors: inconsistent flow in automated filling setups, slow pouring from high-viscosity materials, bottles fouled by residual acid, or a faint haze from incomplete drying. Our background in industrial scale-up has let us bypass these roadblocks. Our incoming controls on reagents reach back to the original manufacturer level, not just to trading documentation, because trace contaminants—copper, iron, free acid—will show themselves in certain downstream uses, hurting performance. Frequent analytical verification, along with strong investment in purification, has made the difference. Each batch meets the published spec, but actually runs tighter in practice, based on our lab’s daily experience running partition, GC, and Karl Fischer tests.

    We monitor moisture to much lower thresholds than broad-market suppliers would consider, often by request from clients working in deep-eutectic, battery, or catalyst development projects. Packing and storage also matter. For a complex ionic liquid like this, wide-mouthed containers, excessive headspace, and permeable seals become trouble sources; all our offerings ship in inert-gas purged, tightly capped vessels, with small packaging volumes available for research-scale work. Multiple customers citing previous crystallization or gelling issues after transport have observed our product arrives fluid, clear, and ready for immediate use—no re-drying or filtration required. These may sound like niche improvements, but they have saved hundreds of hours for chemists troubleshooting elective problems totally unrelated to their primary research.

    Deeper Dive Into Properties: Real-World Trade-Offs

    Chemical manufacturers traditionally present product data as a checklist. Yet, over decades of conversations, it has become clear that the real value comes from giving honest context—where each attribute shines, and where trade-offs appear. This ionic liquid brings a combination of low melting point, high chemical and thermal stability, and minimal reactivity with process metals or organic phases. Lab managers comment that the propyl substituent strikes a sweet spot, keeping viscosity manageable for stirring and pipetting at room temperature, while avoiding excessive volatility. Compared directly with ethyl or butyl analogues, this model does not thicken under cold conditions as fast, and it stores more easily in under-regulated spaces—no need for special heating or bulky ovens.

    Not all ionic liquids live up to their reputation in complex applications. Some cheaper grades from bulk outfits arrive with bright color, a clear sign of remaining side-products or unreacted starting materials. High chloride or halide content damages sensitive electrodes, reacts with rare metal catalysts, or triggers rapid breakdown during electrolysis. Bulkier anions often lead to phase separation and unpredictable solubility profiles, creating headaches in high-throughput screening or continuous-flow setups. Feedback from one industrial customer running automated synthesis lines prompted us to reduce the trace proton content, after they observed side reactions otherwise not documented in the literature. Another group reported issues with metal catalyst longevity, which we traced—using our in-house NMR—to sodium and potassium footprints picked up during competitor’s manufacture. Our team routed the problem by shifting from older glassware to newer PTFE-lined reactors, a fix that improved purity across subsequent lots.

    Environmental and Safety Considerations from Decades of Practice

    After years handling imidazolium ionic liquids, the question always comes up: what about downstream safety, cleanup, and disposal? No product stands on properties alone without practical, day-to-day handling, and long experience tells us that a safer workplace means fewer lost batches and happier chemists. Despite the extremely low volatility and high flash point of the NTf2 anion, the hydrophobic residue can persist in drains and piping when cleaned up poorly. We follow closed-system synthesis and washing methods learned through years, minimizing human contact and cross-contamination, and providing clear guidance to users about not mixing leftover product streams with acid or alkali waste. Fire risk almost never arises, in sharp contrast to many other solvents, and we’ve seen first-hand that properly manufactured NTf2 ionic liquids do not produce the noxious byproducts associated with lower-quality material breakdown. We encourage all our customers to store these materials in cool, dry spaces, away from open air, to prevent slow water absorption and any risk of acid hydrolysis, albeit unlikely at high purity levels. Our facility is set up to handle chemical spills and emergency neutralization with solid-absorbent cleanup—techniques taught by old hands, not just regulatory instructions. This kind of operational knowledge, passed on each year, shows that safe handling involves more than just reading labels; it’s about lived experience and lessons learned from real incidents on the production floor.

    Keeping Pace With Scientific Demands

    We have witnessed the evolution of ionic liquid applications, right alongside the rapid progress in energy storage, catalysis, and analytical chemistry. Not that long ago, most of the demand centered on small-batch quantities and basic physicochemical research. Now, battery material programs expect hundreds of kilos for pilot lines, while major pharma explorations request multi-liter lots cleaned to the tightest trace element tolerances. The spike in demand for NTf2-based solvents in CO2 capture, biomass valorization, and precious metal extraction forced us to reconsider every aspect of our process—procurement, batch sizing, tank cleaning, and staff cross-training. Each new request from users in high-flux sectors like electronics, electroplating, and green chemistry brings a new set of requirements or practical challenges. Rarely does an off-the-shelf solution suffice. It takes dialog, sometimes even inviting customers on-site to walk through methods together, and rapid feedback between bench and plant. We have invested in expanded analytical facilities: multi-element ICP analysis, advanced drying lines, and automation for repetitive sampling. This pays off in more reliable results, fewer outliers, and a reputation for solutions over excuses.

    How Our Work Differentiates from Traders and Resellers

    In the chemical community, word travels fast. Many users have stumbled across the limitations of third-party dealers—opaque supply chains, product relabeling, inconsistent certificates, and hidden impurities showing up only after costly failed experiments. As manufacturers in the truest sense, our process begins with raw materials and ends in a finished bottle, handled by staff engaged throughout. We track every step, hold samples from every lot, and match analytics to in-house reference standards. We don’t rely on generic, broker-supplied material; every step aims for transparency and traceability. If something ever seems off, customers can expect a real chemist to walk them through a root-cause investigation.

    Our vision has always placed long-term reliability ahead of chasing one-off orders. This approach has earned us deep partnerships, not just transactional sales. We see our users’ challenges as our own, whether that’s optimizing yields for demanding catalysts, improving separation in rare metal recovery, or troubleshooting stubborn moisture pickup in remote research locations. We regularly participate in collaborative development projects, directly adjusting parameters like pH, ionic strength, and residual base to support emerging chemistry. Whether shipping liters or hundreds of kilograms, our focus stays on functional performance and day-to-day ease of use—not abstract claims or hollow marketing.

    Collaborative Problem-Solving, Not One-Size-Fits-All

    Each request for a new lot or special packing method offers the chance to help solve a real-world challenge. Sometimes, a project in flow chemistry needs a particular viscosity to optimize residence time, or a separation works better at a specific hydrophobicity. Other times, a high-throughput battery screening wants our input on solvent aging or impurity tracking. Every case brings new insight for improvement. Laboratory managers at top institutes have reached out after receiving materials from alternative sources that failed simple purity tests, highlighting the value of our direct production oversight.

    We learn by responding to those nuanced, real conditions—whether that’s adding extra steps to eliminate a visible haze, designing small-batch, argon-sealed vials, or threading sampling ports into bulk tanks for rapid quality checks. These aren’t generic improvements—they’re direct answers to needs that only appear after repeated practical use. When mistakes or surprises have happened (and in manufacturing, absolute perfection is a myth), our open-door approach has helped fix problems fast and incorporate those lessons for future lines. Every improvement comes from a confluence of front-line feedback, hands-on analytics, and upstream process tweaks. Our strongest asset remains field experience—ours and, increasingly, that of our customers, who trust us to support and respond to their toughest technical puzzles, not just sell to spec.

    Staying Flexible as Requirements Change

    Regulations evolve, analytical methods improve, and research directions shift. We invest continually in updating our diagnostics, routinely revisiting even well-validated methodologies to catch trace impurities or physical property drifts before they affect customers. Working with battery manufacturers, environmental chemists, and advanced pharma researchers, we stay alert to novel purity challenges and unknown side-reactions. Our process design accommodates small-scale, customized refinements without pausing the main production flow. Over the years, that flexibility has saved many customers from disruptions when a critical property specification changes, or a previously acceptable impurity must be reduced even further.

    This adaptability extends to logistics. Not long ago, an academic partner needed a batch with modified labeling and staggered shipment timing for time-sensitive runs. Another customer requested a custom inert-gas packing method that involved several days of stability trials. Our technical and logistics teams adapted rapidly, proving that direct manufacturing involvement translates not only into better process control, but real agility in meeting changing market needs. For us, being a manufacturer does not stop at the production reactor; it lives in every phone call, every label revision, and every coordinated shipment.

    Lessons From Real World Application

    Much of what sets our product apart comes from listening to, and learning from, the chemists and engineers who rely on it daily. In research labs, battery pilot plants, and production environments, this ionic liquid keeps proving itself. Early on, a battery startup found their commercial-scale experiments always yielded inconsistent electrodeposits—that problem traced directly to unnoticed halide contamination in lower-grade ionic liquids. By working together, refining purification, and sending detailed impurity logs, reliable results emerged; the startup’s process switched over exclusively to our supply. In separation tasks, rare earth extraction from industrial waste literally proved unsolvable until stability and phase separation improved, an outcome reached only by tuning water and acid content during synthesis and shipment. These experiences turn abstract chemical names into solutions that save time and resources, and let users focus on growing their ventures, not resolving technical headaches.

    Looking Forward: Supporting New Frontiers

    The next wave of chemical innovation depends on reliable, specialized ionic liquids. As manufacturers, we take pride in delivering materials that meet today’s toughest standards, proven through field experience, feedback, and years of iterative improvement. Our roots in in-house synthesis, direct analytics, and hands-on troubleshooting drive us to build long-term partnerships, not one-off sales. Each customer challenge enriches our knowledge and motivates new investments in quality and capability. The value lies not just in high-purity material, but in the expertise and accountability that can only come from living the full production cycle—from raw input to final delivery, and every step in between.