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1-Phenylimidazoline-2-Thione

    • Product Name 1-Phenylimidazoline-2-Thione
    • Alias 2-Imidazoline-2-thiol, 1-phenyl-
    • Einecs 258-940-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    490865

    Chemical Name 1-Phenylimidazoline-2-Thione
    Molecular Formula C9H8N2S
    Molecular Weight 176.24 g/mol
    Cas Number 14233-37-5
    Appearance White to off-white powder
    Melting Point 149-151 °C
    Solubility Slightly soluble in water; soluble in organic solvents
    Smiles c1ccc(cc1)N2C=NC(=S)C2
    Synonyms 2-Thio-1-phenylimidazoline; Phenylimidazoline-2-thione
    Storage Conditions Store in a cool, dry place; keep container tightly closed
    Purity Typically >98%
    Hazard Statements May cause irritation to eyes, skin, and respiratory tract

    As an accredited 1-Phenylimidazoline-2-Thione factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 100g amber glass bottle with a tight-sealed cap, labeled “1-Phenylimidazoline-2-Thione,” hazard symbols, and handling instructions.
    Shipping 1-Phenylimidazoline-2-thione is shipped in tightly sealed containers, protected from moisture, heat, and direct sunlight. Packages comply with chemical safety regulations, including labeling and documentation. Transport typically occurs via ground or air, ensuring secure handling and minimal exposure to external elements. Appropriate hazard and handling information accompanies each shipment for safe delivery.
    Storage 1-Phenylimidazoline-2-thione should be stored in a tightly sealed container, protected from moisture and light, in a cool, dry, well-ventilated area. Avoid exposure to strong oxidizing agents and acids. Store at room temperature or as recommended by the manufacturer. Ensure proper labeling and access is restricted to trained personnel to prevent accidental contact or ingestion.
    Application of 1-Phenylimidazoline-2-Thione

    Applications of 1-Phenylimidazoline-2-Thione in Industrial Manufacturing

    As the original manufacturer of 1-Phenylimidazoline-2-Thione, we enable chemical processors and material suppliers to meet stringent industry requirements through reliable supply for demanding downstream applications. Our product directly supports established industrial value chains in sectors where performance, regulatory compliance, and detailed process control are essential. The following sections outline recognized uses, integration methods, and quality references, ensuring industrial customers can assess suitability and compliance for their production lines.

    1. Vulcanization Accelerator in Rubber Processing

    Rubber compounders utilize 1-Phenylimidazoline-2-Thione as a delayed-action accelerator, particularly in the production of high-performance technical rubber goods for automotive, industrial, and specialty applications. The compound enters the closed mixing phase, interacting with sulfur donors to control crosslinking rates, and is favored for critical components requiring improved reversion resistance and aging stability. This application supports rubber manufacturers tasked with delivering consistent quality and ensuring conformity to regional regulations and customer specifications in mass production.

    Industry compliance standards

    • ASTM D3182, ASTM D2000 (Rubber compounding and characterization)
    • EU REACH Regulation (EC) No 1907/2006
    • ISO 9001 certified manufacturing and documented batch traceability
    • US FDA 21 CFR 177.2600 (Rubber articles intended for repeated use, relevant for food-grade products)

    Typical usage ratio

    • 0.3%–1.2% by weight of total rubber formulation; dosage optimized based on polymer type, processing equipment, and target cure kinetics

    Downstream process integration

    • Added at the pre-mixing or final mixing stage with compounding ingredients; interacts during the heating stage to modulate vulcanization speed and crosslink structure

    Final product types

    • Radial and bias-ply tire sidewalls and treads
    • Oil-resistant industrial belts
    • Seals and gaskets for automotive and machinery applications
    • Rubber hoses complying with automotive and hydraulic specifications

    2. Corrosion Inhibitor Additive for Industrial Metalworking Fluids

    Metalworking fluid manufacturers incorporate 1-Phenylimidazoline-2-Thione in aqueous and semi-synthetic cutting fluids as a non-nitrosamine-generating corrosion protection agent. Its use aids in meeting user demand for extended equipment life while maintaining compliance with occupational safety and environmental exposure limits, especially in high-volume machining centers and automated production operations bound to OHS management frameworks.

    Industry compliance standards

    • DIN 51360-2: Testing corrosion protection in metalworking fluids
    • OEM-specific coolant and additive requirements (e.g., VW TL 52654, GM 9985486)
    • OSHA 29 CFR 1910.1200 (Hazard Communication Standard)
    • EU CLP Regulation (EC) No 1272/2008 on classification and labeling

    Typical usage ratio

    • 0.05%–0.3% by weight in concentrated fluid; final dilution adjusted according to sump size, water quality, and metal type being processed

    Downstream process integration

    • Blended into concentrate before final filtration and packaging; remains stable during storage, and disperses thoroughly upon dilution for end-user application in recirculated fluid systems

    Final product types

    • Water-miscible cutting fluids for CNC machining centers
    • Anti-corrosion additives for forming and stamping fluids
    • Final rinse additives in parts cleaning formulations
    • Temporary rust-preventive fluids for stored metal parts

    3. Polymerization Modifier in Specialty Resins Synthesis

    Manufacturers of specialty epoxy and polyurethane resins deploy 1-Phenylimidazoline-2-Thione as a chain transfer regulator and catalyst during controlled addition polymerization. Its use ensures precise molecular weight targeting and reduces gel content, which is critical for applications requiring high-performance coatings and adhesives with predictable thermal and chemical resistance. The integration occurs within a closed, monitored reaction environment to maintain process consistency and product certification according to application end-use.

    Industry compliance standards

    • ISO 9001:2015 QMS in specialty chemicals manufacturing
    • EN 13986 (Panel products: Emissions, safety in construction use)
    • US EPA TSCA Inventory listing for processing aids and intermediates
    • Company-specific QA protocols for batch-to-batch polymer property validation

    Typical usage ratio

    • 0.02%–0.2% by weight based on total monomer; concentration optimized through lab-scale trials to balance reaction time and target viscosity

    Downstream process integration

    • Charged to the reaction vessel early or mid-cycle; dosing accuracy is monitored via automated feed systems under inert atmosphere control

    Final product types

    • High-gloss, chemically resistant floor coatings
    • Structural adhesives used in automotive and aerospace
    • Electrical encapsulant resins
    • Composite panel binders for electronics and high-load applications

    4. Accelerator for Photographic and Imaging Chemicals

    Producers of photographic developers and imaging chemicals apply 1-Phenylimidazoline-2-Thione as a developer booster in black-and-white film processing formulations. This function influences image contrast and grain, supporting commercial film laboratories as well as fine art printing workflows demanding consistent batch output with compliance to relevant photographic standards and environmental handling requirements for darkroom chemicals.

    Industry compliance standards

    • ANSI/PIMA IT9.5: Archival storage requirements for processed photographic films
    • ISO 18902: Imaging materials - Album, framing and storage
    • OSHA 29 CFR 1910.1200 (Chemical hazard communication during chemical handling)
    • Local environmental authority regulations for chemical effluent and handling

    Typical usage ratio

    • 0.005%–0.05% by weight in developer concentrate; adjustment based on desired image tone, developer type, and film emulsion response during trial runs

    Downstream process integration

    • Dispersed in concentrate mixtures under controlled pH and temperature; stability and homogeneity checked before bottling for distribution to end users or commercial labs

    Final product types

    • Black-and-white film developer concentrates
    • Specialty photo print developer solutions
    • Contrast boosters used in reprographic imaging chemicals
    • Darkroom kit developer for professional and hobbyist use
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    Certification & Compliance
    More Introduction

    1-Phenylimidazoline-2-Thione: Our In-Depth Experience and Commitment to Quality

    Reliable Chemistry with 1-Phenylimidazoline-2-Thione

    Every batch of 1-Phenylimidazoline-2-Thione that leaves our plant represents years of chemistry experience, an insistence on purity, and direct operational know-how. As a manufacturer, we see every lot as more than a line item. The compound—a robust organosulfur heterocycle—has a subtle complexity in both synthesis and downstream application.

    With every reaction, we've learned where impurities tend to creep in and understand the delicate temperature window that prevents degradation or unwanted byproducts. This compound’s stability relies on material selection, precise batch control, and real-time analytics. We never trust just a spot check. Our quality team works close to production, often seeing a challenge days before it could hit the drum.

    Specifications That Make a Difference

    Over the years, we have developed our own model: tight focus on crystalline form, moisture content, and purity. Our process yields white to light yellow crystalline powder, avoiding clumps or over-drying. Lab technicians validate the melting point and scan for residual solvents. We have learned that downstream users, whether working in rubber accelerators or fine chemicals, notice even small deviations. Residual traces of starting materials compromise product performance—sometimes in ways that only show at scale or under demanding conditions.

    Analyses for each lot include HPLC purity checks (over 99%), water content measured by Karl Fischer titration typically below 0.2%, and heavy metal testing below recognized thresholds. We document each run, archiving trends to spot shifts in raw material sources or subtle impacts from equipment maintenance. No lot leaves the warehouse unless we see batch-to-batch consistency.

    From Synthesis to Packaging: Lessons Learned

    Sourcing high-quality aniline and imidazoline intermediates makes a difference in final yield and waste handling. Early in our manufacturing journey, some vendors supplied off-spec material that seemed minor on paper but led to higher formation of colored byproducts that complicated purification later. We reworked supplier relationships and tightened incoming inspections. Over time, that upstream attention translated into less rework and more predictable output, benefiting not just us but everyone downstream.

    Controlling sulfur-related emissions—the "rotten egg" smell familiar to anyone in organosulfur synthesis—drives much of our in-house protocols. Scrubbing systems, closed transfers, and constant atmospheric sampling keep operations safe and keep local regulators satisfied year after year. Old equipment struggled with leaks; retrofits have paid for themselves in both safety and reduced loss of valuable product. We accept the need for periodic shutdowns to maintain these standards, regardless of pressure to push capacity.

    Final packing in moisture-resistant liners minimizes hydrolysis risk. We shifted to double-walled drums after a few export shipments arrived with clumped or partially hydrolyzed goods; hot, humid ports proved riskier than lab conditions could predict. Now, long-haul customers in Southeast Asia and South America regularly share positive feedback on receipt quality—not because we asked, but because they used to have problems before our packaging changes.

    How Our Customers Use 1-Phenylimidazoline-2-Thione: Direct Insights

    The compound serves mostly in making rubber accelerators such as MBT and related thiazoles. Chemical plants feeding these tire additives demand fast-dissolving, high-purity input to keep reaction times short and end-product specs tight. Customers in the east of China and parts of India, where automotive and tire manufacturing has grown, have taught us a lot about real-world requirements. They keep us honest: if our product leaves crystals that don’t dissolve within minutes, productivity drops and their operators complain.

    Some use the material as a key intermediate for antioxidants or metal chelators. Small molecule pharmaceutical firms sometimes call us with questions about side product formation for custom syntheses. We discuss, chemist to chemist, how our lot composition might differ from a competitor and the small ripple effects in their next step. These conversations have made us improve our technical documentation—structural data, impurity profiles, solubility details—so problems can be prevented before purchase, not revealed at the kettle.

    Environmental regulators also look closely at our materials. Many jurisdictions update discharge limits and workplace exposure levels faster than summary literature can track. We watch not only our own stack emissions, but the waste data of customers using our compound in closed- or semi-closed reactors. Where they spot increased off-gassing, we look back at impurity logs and batch changes, cross-referencing every raw material receipt. Knowledge shared both ways keeps everyone ready for new audits.

    How It Stands Apart From Other Related Compounds

    Anyone thinking one sulfur-laden imidazoline looks like another hasn’t seen the headaches different substitution patterns bring. 1-Phenylimidazoline-2-Thione offers a unique blend of volatility, binding, and compatibility that direct analogues just can’t mimic. Some try to substitute the thione with an oxo group or add alkyl chains, only to find end-point yields drop or unexpected precipitates form. Our R&D team has run control reactions side by side. Results show that phenyl substitution at the 1-position keeps the ring tension and solubility needed for applications in rubber chemistry—while still delivering on safety and handling.

    Buyers sometimes ask if regular imidazoline-2-thione or even phenylimidazoles can work instead. We’ve charted the unwanted reactivity, unexpected odor, and even safety profile problems that come with such swaps. Granule size, flow behavior out of hoppers, color stability: these all shift in ways that affect plant operations, not just laboratory notation. Anyone watching a 500-kilogram reactor seize up knows that a spec sheet can’t predict every variable. We have adjusted our output particle size distribution after seeing frequent clogging at a client’s plant, learning where bulk density and powder handling truly intersect.

    Direct competitors selling lower-grade material sometimes point to “sufficient” performance. Our position has always rested on repeatability. Nothing angers a line operator like sudden batch failure because a trace impurity changed reactivity. We’ve lost jobs on price and later got calls for emergency deliveries when other lots failed at scale. That’s our reality check: users remember who kept them running and who left them with downtime. Relationships run deep in this business.

    Addressing Concerns From Key Industries

    We see the shifting landscape of downstream regulations. The tire industry faces new pressure over zinc and sulfur compound leaching. Synthetic rubber blending, too, gets regular scrutiny from both municipal and global agencies. Any step in our process that might raise persistent organic pollutant risk gets reviewed several times each year. We built internal labs just to meet the demand for newer, more sensitive trace detection—even analytes that don’t yet map to local regulations.

    Occupational exposure remains a frontline concern. We upgrade employee PPE regularly and rotate shifts so no one hits exposure thresholds. Visitors touring the plant notice that air handling systems back up each bench line. Our decision to automate certain reagent additions, at some expense, has minimized hand transfer and sharply reduced onsite accidents. These are choices we believe set real manufacturers apart from traders more interested in quick markups.

    Real accidents—loss of containment, bad valve seals, sudden fume releases—never make headlines unless a disaster occurs. Still, keeping systems overbuilt for safety, not just compliance, is how we run. Our neighbors in the industrial park trust us more now that smell complaints have disappeared. A safe workplace and a safe product line up; one doesn’t work without the other.

    Building Relationships: Dialogue and Continuous Improvement

    Direct calls and plant visits tell us more than any glossy industry report can. Users never hide their frustration with supply chain snags or underperforming lots. We schedule feedback sessions, not just sales meetings. Sometimes, end users invite us to audit their own batch processes so we can see our compound at work—in reactors, in real air, handled by real people. Our process engineers have changed drying protocols to tighten powder size, after seeing how their equipment clogged when particle sizes drifted into the wrong range.

    Shipping and transport get equal attention. Early on, long transit times and humidity gave us serious headaches. Batches that handled well in our warehouse sometimes lumped during ocean transport. Adjusting desiccant pack size seems trivial, but feedback from warehouse managers taught us to make the switch. Now, even port storage under tropical sun rarely affects goods. We apply that lesson to each outgoing order, not just for big customers.

    Competitive pricing pressures keep us lean, but never at the cost of shorting key process steps. Simple changes—doubling filter checks, extra moisture scans in monsoon season—often pay for themselves in fewer complaints. We cost out energy and raw material to stay viable, but focus on waste minimization for everyone involved. Lean doesn’t mean cheap; it means careful, data-driven choices.

    Navigating Global Challenges

    Every country sets its own bar for what counts as “safe,” “low residue,” or “environmentally responsible.” As a global supplier, we interpret European REACH, US EPA, and Asian standards as baselines. Each year, our compliance teams invest in tracking new guidelines and testing protocols. Years ago, we discovered that a new Japanese regulation treated a minor impurity in thione synthesis as a restricted environmental toxin. We pivoted: new purification column, extra analytics, a few headaches, but we kept every customer without a gap. Missing such a step could have ended our shipments to a vital regional market.

    Shifting sourcing and logistics pose their own risks. Pandemic years, and more recent shipping disruptions, forced us to stockpile certain intermediates. We learned not to chase one low-cost supplier, even if initial yields look tempting. Dual sourcing feels expensive up front, but a few close calls with delayed raw materials proved the cost of lost business can be far higher. We don’t gamble when a customer’s production line depends on every drum showing up, to spec, every time.

    Keeping product quality high in a changing landscape means more than hitting last year’s metrics. Our team tracks every run, logs every batch number, and investigates even minor complaints. Supply chain transparency isn’t a slogan; it’s rows of data in our system, letters in a logbook. Real accountability comes from openness: showing lot traceability, revealing impurity trends, and inviting customer audits. We spot-check not just what leaves our gate, but what returns in customer feedback or market news.

    Next Steps in Product Evolution

    Research and innovation don’t end with a validated process. We maintain R&D capacity for both process optimization and downstream support. Collaborative work with major tire manufacturers led us to trial new drying techniques that slash energy use and reduce solvent needs. Smaller users—specialty chemical labs, academic institutes—push for higher levels of structural characterization and narrow impurity windows for new applications. Such requests push us to hone every analytical method.

    Future demand for greener chemistry shapes our road map. Pressure mounts for solvent recycling, lower energy footprints, and alternatives to hazardous reagents where substitution is possible. We have already trialed solvent recovery on pilot scale and see promise in greener oxidation methods. Changing a single step on the line means months of validation and market feedback, but over time, such steady investments lead to less environmental risk, fewer recalls, and more trust across the value chain.

    We also invest in technical education. Regular workshops for both internal staff and client engineers keep safety and handling best practices current. We provide on-site seminars when process changes create new challenges. Problems rarely stop at the factory gate; our reputation rides on helping troubleshoot, not merely fulfilling sales orders.

    Why We Stay Hands-On in Manufacturing

    We believe chemical manufacturing prizes experience, attention to detail, and real communication. 1-Phenylimidazoline-2-Thione, like most specialty substances, rewards transparency and close technical ties with customers. Our team doesn’t hand off responsibility to distant partners. Each complaint triggers an internal root cause investigation. Every new application drives us to rethink process steps or introduce new checks and balances.

    Large customers can afford to pressure for price, but we hold the line on specifications. Reputation in this space turns on reliability, not flash. Some of our oldest clients have visited the plant, checked the data, and seen the people behind every drum shipped. Continuing these relationships keeps even the most routine order grounded in mutual benefit rather than transaction.

    End-users are demanding; new entrants offer cheap alternatives with less documentation and less transparency. Still, our focus remains on consistency and technical dialogue. Selling anything less means more trouble down the road—for us and for those relying on our chemistry for their own manufacturing needs.

    Our Philosophy on Raw Material and Supply Chain Integrity

    Long-term contracts and deep supplier audits mean less drama during market spikes. We seek partners that commit to more than price; we share risk, trace every load, and maintain backup supply whenever feasible. Tracking back every “off” batch, we have learned just how minor impurities or poorly stored barrels can change product quality months later. Preventing problems at the source keeps our operations and those of our end users steady, even in unpredictable markets.

    Raw material disruptions impact everyone. We learned early that betting on volume discounts while sacrificing reliability rarely pays off. Dividing orders across multiple suppliers and maintaining transparent, prompt communication has saved us from costly shutdowns. This supply management approach costs more in short-term paperwork, but provides security in the long haul for both us and our clients.

    The Future of 1-Phenylimidazoline-2-Thione Manufacturing

    We live in an age of tighter scrutiny and steeper expectations, both in product performance and environmental impact. As a direct manufacturer, we see our product’s journey from raw material to application line as one unbroken process. Technical development, client feedback, regulatory changes, and process refinement loop together year after year.

    With each batch of 1-Phenylimidazoline-2-Thione, we apply lessons learned—unexpected failures, triumphs in process optimization, and feedback direct from customer plants and labs. Every improvement, whether a part-per-million impurity reduction or a modest change to packaging, stacks up across thousands of kilograms. At scale, these incremental changes have allowed our compound to remain a standard for demanding applications in the rubber industry and beyond.

    Our vision goes beyond mere compliance. By seeking out new technologies, investing in people, and demanding accountability at every stage, we aim to keep raising the benchmark for specialty chemical manufacture. With open communication, continual R&D, and unshakeable dedication to product integrity, we stake our name on every shipment of 1-Phenylimidazoline-2-Thione we produce.