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1-Hydroxynaphthalene-8-Sulfonic Acid

    • Product Name 1-Hydroxynaphthalene-8-Sulfonic Acid
    • Alias 8-Hydroxy-1-naphthalenesulfonic acid
    • Einecs 202-188-7
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    576311

    Chemical Name 1-Hydroxynaphthalene-8-Sulfonic Acid
    Synonyms 1-Naphthol-8-sulfonic acid, Schaeffer's acid
    Molecular Formula C10H8O4S
    Molecular Weight 224.23 g/mol
    Cas Number 82-74-8
    Appearance Light yellow to beige powder
    Melting Point 185-190°C (decomposes)
    Solubility Soluble in water
    Pka 2.1 (sulfonic acid group)
    Storage Conditions Store in a cool, dry place, tightly closed
    Pubchem Cid 7316

    As an accredited 1-Hydroxynaphthalene-8-Sulfonic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, tightly sealed, labeled with "1-Hydroxynaphthalene-8-Sulfonic Acid, 100g", hazard symbols, and handling instructions.
    Shipping 1-Hydroxynaphthalene-8-Sulfonic Acid is shipped in tightly sealed containers, protected from moisture and direct sunlight. The packaging complies with chemical safety regulations, including appropriate labeling and hazard documentation. During transit, it is handled as a non-flammable, corrosive solid, ensuring safe delivery while minimizing environmental and health risks.
    Storage 1-Hydroxynaphthalene-8-sulfonic acid should be stored in a tightly sealed container in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers and bases. Protect from light and moisture. Properly label the container, and avoid direct contact. Follow local regulations for storage and handling to ensure safety and chemical stability.
    Application of 1-Hydroxynaphthalene-8-Sulfonic Acid

    Applications of 1-Hydroxynaphthalene-8-Sulfonic Acid in Industrial Manufacturing

    1-Hydroxynaphthalene-8-sulfonic acid serves as a key naphthalene-based intermediate in several chemical manufacturing segments. As an experienced direct manufacturer, we support strict specification control for consistent integration into advanced industrial synthesis, enabling high-purity downstream reactions across regulated end-use sectors.

    1. Azo Dye Intermediates for Synthetic Textile Colorants

    Our primary downstream partners in the textile dye sector use this sulfonic acid as a coupling component for diazo-based dye synthesis, particularly when formulating specialized direct and acid dyes for cellulosic fabrics. The material’s sulfonic function ensures clarity in shade and wash-fastness, with purity and trace metal content critical per global dyestuff production protocols. Quality control at this step directly impacts the color reproducibility in bulk textile dyeing operations and helps achieve customer shade cards.

    Industry compliance standards

    • EN 71-3 (Heavy metal migration for textile dyes, EU market)
    • OEKO-TEX Standard 100–Dye input criteria
    • ZDHC MRSL–Restricted Substance requirements for apparel supply chains
    • China GB/T 17592–Textile colorfastness and aromatic amine limits

    Typical usage ratio

    • 5%–18% by weight in the diazo coupling stage, dependent on target dye type
    • Adjusted to balance mol ratios with amine-based components or when producing composite dyes

    Downstream process integration

    • Coupling phase in batch or semi-batch synthesis after diazotization of aromatic amines
    • Followed by neutralization, filtration, and salting out to isolate the dye cake
    • Pre-dilution in process tanks to ensure full dissolution and reactivity
    • Reaction temperature maintained between 5–15°C for optimal yield

    Final product types

    • Direct Yellow series dyes
    • Acid Black 1 (Naphthol Black)
    • Water-soluble textile dyestuff powders and granules
    • Dye pastes for use in cotton, viscose, and blended fabric printing

    2. Synthesis of Pharmaceutical Color Additives

    Downstream API and excipient producers use this compound in regulated pharmaceutical colorant manufacturing, particularly for coloring oral solid dosage forms. Its sulfonic acid group provides high aqueous solubility and low migration risk, supporting strict pharmacopoeial standards. Only batches with controlled impurity profiles and endotoxin levels qualify for further processing in medicinal colorant lines.

    Industry compliance standards

    • USP/NF (U.S. Pharmacopeia/National Formulary) for color additives
    • 21 CFR Part 74 (US FDA—Listing of Color Additives Exempt from Certification)
    • European Pharmacopoeia (Ph. Eur.) Monograph 2035
    • GMP for Active Pharmaceutical Ingredients (ICH Q7)

    Typical usage ratio

    • 1%–5% as a precursor in multi-step colorant synthesis
    • Adjusted to achieve specified chromatic strength and tablet or capsule sizer requirements

    Downstream process integration

    • Direct input into first chlorination or nitration step in colorant synthesis
    • Followed by purification through recrystallization and rigorous filtration to pharma grade
    • Colorant blended with tablet coating agents or capsule shells
    • Batch certificate review for every colorant lot delivered downstream

    Final product types

    • Pharmaceutical lake colorants
    • Colored film coating agents for tablets
    • Gelatine capsule coloring solutions
    • Oral syrup and drop color additives

    3. Production of Reactive Dyes for Cellulosic Fiber Printing

    This intermediate enables the synthesis of bifunctional reactive dyes for cellulose substrates, supporting both batchwise dyeing and continuous printing. The sulfonate group enhances water compatibility and bond formation between the dye and cotton fibers during steaming or curing steps. Dye houses specify tight QC on residual sodium and iron ions, as these impact wet fastness and environmental discharge compliance.

    Industry compliance standards

    • REACH Annex XVII (EU)–Restrictions for process chemicals
    • ISO 14001/ISO 9001 for textile wet finishing operations
    • ZDHC Wastewater Guidelines–Colorant and surfactant limitations
    • ETAD (Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers) code

    Typical usage ratio

    • 3%–12% as a linking group in multi-step reactive dye formation
    • Optimized based on target reactivity and exhaustion rate in jet or pad-steam systems

    Downstream process integration

    • Chemical coupling post-formation of reactive groups (e.g., monochloro-s-triazine)
    • Dye mixture blending and standardization for consistent batch tonality
    • Spray drying to create dust-free granules for automated dye dosing
    • End-product tested for migration, exhaust efficiency, and waste minimization

    Final product types

    • Reactive Blue and Reactive Black series dyes
    • Print-ready colorant formulations for industrial textile printing
    • Mild-alkali dischargeable dyes for design fabrics
    • Low-salt high-fixation dye powders

    4. Synthesis of Naphthalene-Based Surfactants and Wetting Agents

    Chemical plants utilize this sulfonic acid in the production of naphthalene sulfonate condensates, functioning as dispersing agents in concrete admixtures, dyestuff slurries, and pigment processing. Its anionic character and water solubility contribute to stable aqueous formulations, critical where uniform dispersion and quick wet-out are essential in downstream formulation lines. Reactivity in the condensation phase determines the dispersant’s final molecular weight distribution.

    Industry compliance standards

    • EN 934-2:2019 (Admixtures for concrete, mortar, and grout—EU requirements)
    • ASTM C494/C494M (Standard Specification for Chemical Admixtures for Concrete, US)
    • SGS-Tested for low free formaldehyde content (pigment/wetting agents)
    • Eco-PASSPORT by OEKO-TEX for textile chemical auxiliaries

    Typical usage ratio

    • 10%–28% of active ingredient by weight during surfactant condensation reaction
    • Optimized for target molecular size and water reduction properties in construction applications

    Downstream process integration

    • Charge with formaldehyde and alkali in polycondensation reactors
    • Monitor pH, batch temperature, and viscosity for reaction completion
    • Final product neutralized, filtered, then spray dried or supplied in liquid state per user specs
    • Quality check for dispersibility and free sulfonic acid content

    Final product types

    • Sodium naphthalene sulfonate formaldehyde (SNF) dispersants
    • Industrial wetting agents for pigment grinding and textile prep
    • High-range water reducer admixtures for concrete mixing
    • Auxiliary agents for coating and ink manufacture

    5. Intermediates for Color Pigment Manufacturing

    Producers of organic pigments employ this compound to synthesize naphthol-based lakes and toners for inks and plastic coloration. Stepwise introduction during the pigment formation ensures proper crystalline structure and hue development. Strict limits on trace organics and heavy metals in the feedstock are necessary to meet pigment grade specifications for plastic, printing, and coatings applications.

    Industry compliance standards

    • EN 71-7 (Safety of toys—Paints and varnishes)
    • ISO 2834-1:2020 (Printing ink test methods)
    • FDA 21 CFR 178.3297 (Colorants for polymers in contact with food)
    • RoHS Directive (Heavy metal content, EU electronics)

    Typical usage ratio

    • 6%–15% by weight in pigment condensation or azo-coupling reactions
    • Adjusted according to target color depth, particle size, and matrix compatibility

    Downstream process integration

    • Initial introduction in pigment azo-coupling with aryl diazonium compounds
    • Milling and finishing steps determine final particle size and dispersibility
    • Batches filtered for grit and fine contamination
    • Surface finishing for high-gloss or matte pigment applications

    Final product types

    • Naphthol-based pigment lakes for offset and gravure inks
    • Plastic colorants for polyolefin and PVC masterbatches
    • High-strength pigment concentrates
    • Waterborne and solvent-based industrial coatings
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    Certification & Compliance
    More Introduction

    Introducing 1-Hydroxynaphthalene-8-Sulfonic Acid: Insights from Our Factory Floor

    Decades of Manufacturing Experience Behind a Reliable Dye Intermediate

    Behind every finished dye that makes it into textile plants and pigment houses, a whole chain of synthesis steps plays out, often starting with core intermediates that don’t see daylight in consumer circles. We’ve produced 1-Hydroxynaphthalene-8-Sulfonic Acid in-house for years and seen firsthand how manufacturing this compound rewards patience, attention, and gritty chemical know-how.

    Our process runs on a clear upstream: we begin with high-purity naphthalene, employing sulfonation and hydroxylation in well-controlled batches. The resulting solid—usually offered in light brown to off-white powder or granule—carries a distinctive chemical signature. With a molecular formula of C10H8O4S and molecular weight of 224.24 g/mol, this compound stands out from other naphthalenesulfonic acids for its highly selective reactivity at the 1- and 8-positions. Freight volumes fill drums every week in our shipping bay, mostly destined for industrial clients working in dye synthesis, fluorescent pigment bases, and auxiliary agents for paper and textiles.

    What Sets 1-Hydroxynaphthalene-8-Sulfonic Acid Apart?

    On the surface, it might share some handling requirements with related sulfonic acids derived from naphthalene, yet for those working a batch in the reactor hall, subtle differences make all the difference. Where other naphthalenesulfonic acids sometimes underperform in terms of shade development or coupling yield, the 1- and 8-substitution delivers a more reliable pathway to vivid, stable intermediates. We’ve tracked dye-makers scaling batch yields using this specific isomer, citing fewer byproducts and easier downstream purification in their reports. The positional arrangement matters: compared to 1-naphthalenesulfonic acid or other mono-sulfonated naphthalene isomers, this variant supports reactions where a hydroxyl group next to the sulfonic acid speeds coupling, especially in azo dye systems.

    Factories producing advanced dyes or fluorescent brighteners lean on this intermediate, arranging their supply contracts around our shipment schedules. Timing proves critical because a delay at the intermediate stage pushes back finishing runs at their own sites. We never lose sight of our responsibility, knowing that uninterrupted, high-conformity shipments keep our clients' lines humming and allow them to maintain quality in everything from textile fibers to specialty coatings.

    Control at Every Stage: Purity and Consistency in the Production Chain

    Consistency can’t be faked, not in the world of dyes and pigments where tiny shifts show up fast on the QC table. For 1-Hydroxynaphthalene-8-Sulfonic Acid, the difference between a solid intermediate and a batch gone off-spectrum usually ties back to purity. We keep our specs as tight as the chemistry allows, routinely exceeding 98% by HPLC across main output runs. Lower residual sulfate, minimized ash, targeted iron content—these don’t come from luck but from extensive line monitoring, skilled analysts, and a willingness to dump borderline batches.

    Years of running reactors at scale have taught our operators which cues matter early in a cycle. From the warmth and clarity of the solution to pH swings at the end of sulfonation, no automated sensor truly replaces experienced eyes and hands. Repeating these steps daily sharpens instinct; subtle smell, texture, color hint at batch fidelity before tests even confirm it. That hard-earned expertise feeds directly into the intermediate, carrying forward subtle advantages into every downstream application.

    Assembling Quality Dye Intermediates: The Science Behind Stability

    One client—who operates a continuous flow dye shop—once dropped us a note, pointing out that even minor variations in the intermediate would show up after coupling steps as lower color strength. High-quality 1-Hydroxynaphthalene-8-Sulfonic Acid avoids this, reacting with diazonium salts smoothly, so customers spend less time chasing unspent reactant and adjusting filter beds during workup. The labor savings alone pile up, but the real win rides on reproducible color and improved yield, which their sales teams can prove in the buyer’s lab.

    Other makers of sulfonic acids sometimes overlook trace impurities that can alter their function in dye synthesis. We spot those through regular spectral analysis, head off batch splits, and keep the downstream flow aligned with the original intent of the molecule. Our plant’s filtration system, coupled with a multi-stage crystallization approach, locks in the right moisture level and limits carry-through of minor, but troublesome, contaminants.

    Understanding Usage: Knowledge from Down the Line

    Most of our 1-Hydroxynaphthalene-8-Sulfonic Acid ends up piped or trucked to dye shops where it takes on a starring role in producing azo dyes and complex organics. This intermediate bears the toughest scrutiny during coupling steps, where its two functional groups—hydroxyl and sulfonic acid—react in synch. Chemists in finishing plants know the raw material must be both highly reactive and easy to dissolve, or the process stumbles.

    We’ve watched clients cut their filtration cycles, for example, by using our more consistently granulated material. They report less dust, fewer clumps, and more straightforward solution prep. For batch-to-batch reproducibility, others have cited lower levels of extraneous color-forming impurities—these issues always trace back to solid process control at the intermediate stage.

    Specifications That Reflect Real-World Application

    Field experience matters when setting specs. In response to demands from printing ink and pigment makers, we now tune the granule size of our product based directly on feedback from their mixing and filtration shops. Over years of direct dialogue with users, we’ve tweaked process conditions—temperature profiles, crystallization rates, final rinsing steps—to smooth out the quirks of a product that, really, doesn’t leave much room for error at scale.

    Clients in high-speed operations favor narrow particle size distribution, but their needs differ from textile auxiliaries, who ask for easier wetting and faster solubility windows. We offer both styles, shifting between dryer configurations or adjusting mother liquor content to serve the application at hand. It pays to have an agile plant with on-site QC, reducing dependence on slow external labs.

    Respecting the Chemistry: Differences from Related Intermediates

    Walk into a dye house and lay out three different naphthalenesulfonic acid intermediates—you’ll get three contrasting stories. For straight naphthalenesulfonic acids, the focus stays on sulfonation position, lability, and water compatibility. 1-Hydroxynaphthalene-8-Sulfonic Acid presents a fundamentally different profile due to its dual functional groups. By comparison, 2-naphthalenesulfonic acid lacks the activating hydroxyl, making it slower in some couplings and prone to leaving unreacted starting material. An isomer like 1-naphthol-4-sulfonic acid brings a separate reactivity set, but feedback from the field links our 1/8 arrangement to higher tinctorial strength and streamlined purification—critical for mass-scale operations.

    Over time, some dye chemists have tested blends, hoping to economize by mixing similar intermediates. They usually come back to the pure product for precision work, especially in high-value pigments or complex azo dyes where uncontrolled side reactions drive up costs and downtime.

    Addressing Problems: Handling, Storage, and Sustainability

    Practical challenges start with delivery and storage. 1-Hydroxynaphthalene-8-Sulfonic Acid remains sensitive to moisture, and we’ve seen quality drop when drums stay too long in humid warehouses. We now oversee tank unloads at customer sites for bulk buyers, share best practice storage information directly with plant teams, and validate warehouse conditions on larger contracts.

    Dust control also gets a keen focus, both at our facility and on the customer’s site. Since the powder resists excessive compaction, we design packaging to limit settling and help downstream operators charge reactors quickly, reducing exposure and risk. Collaborating with clients on best-practice handling paid off, especially after one textile finisher’s QC chief flagged airborne powder as a potential contaminant upstream of their reverse osmosis treatment. Over several site visits and a run of pilot batches, we retooled our milling section, reducing fine particulates and contributing to more stable process water in their loops.

    On environmental compliance, we recognize pressure from regulators to limit discharge and capture all effluent streams. Our own wastewater treatment integrates a stepwise neutralization and collection system; audit logs become part of our regular customer information packages. We know from talking to our clients that this type of audit-readiness often gives them an edge with their own local authorities, helping clear certifications and avoid temporary shutdowns.

    Solutions through Collaboration: Listening Drives Innovation

    One area ripe for improvement keeps coming up: integration of in-line sensors that monitor sulfonation purity in real time. Our engineers test advanced photometric and conductivity technologies in house, with a view to giving operators more immediate control over cycle endpoints. While this demands capital and retraining, years of call-and-response with customers shows that process transparency builds trust and raises the bar on product performance.

    Tougher supply chains throw up frequent requests for quicker turnaround, leaner documentation, and even custom packaging to avoid rehandling at the user’s end. Our purchasing team negotiates raw inputs nearer the source, while our plant staff streamline shift handoffs to push more finished product per month without sacrificing specs.

    The Human Element: Skilled Labor Shapes Product Assurance

    Machines run side by side with people in chemical plants, but never at the cost of judgment or skill. Many of our senior process hands started on granulation lines a decade or two ago, and their accumulated knowledge smooths out rough cycles and gets new hires up to speed on best practices. Weekly team reviews of out-of-spec batches feed directly back into SOPs, closing the learning loop between active production and laboratory verification.

    A regular refrain from clients focuses on traceability—where did this drum come from, how do you confirm what’s inside actually matches the spec sheet? We rely on strict batch logs, double-lock access to storage, and regular reconciliation between daily production records and long-term QC archives. Enforced accountability means we can answer questions promptly and keep confidence high across our user base.

    Looking Forward: Sustaining Value in Dye Intermediates

    Market demand fluctuates, but the requirement for a steady, trustworthy supply of 1-Hydroxynaphthalene-8-Sulfonic Acid does not. As green chemistry principles enter broader adoption, we see increasing calls for intermediates made with less waste, drier isolation steps, and optimized energy usage. Our plant keeps tuning heat recovery, solvent recycling, and emission control—small moves over many years add up to reduced environmental impact and lower operating risk.

    Clients with their own CSR mandates tell us they value not just the molecular performance, but how and where it’s made. We provide regular traceability documents, supply origin assertions, and process flow transparency so procurement teams can build better relationships with their own end customers—the chain of trust runs in both directions.

    Final Thoughts from the Factory: Value Built on Trust and Expertise

    No dye intermediate stands alone—it sits embedded in a complex cascade of synthetic steps, and its true worth appears over millions of tons of finished product. 1-Hydroxynaphthalene-8-Sulfonic Acid exemplifies this, and every drum our team loads out the door reflects decades of deep involvement, direct feedback, and continuous improvement.

    As actual manufacturers, we deal every day with the reality of chemical production: the need for rigor, the impacts of minor deviations, and the constant evolution of process and product. The lessons learned from making 1-Hydroxynaphthalene-8-Sulfonic Acid shape our approach to the entire suite of dye intermediates we produce, reinforcing our commitment to reliability, partnership, and progress at every link in the chain.