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1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    • Product Name 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
    • Alias [HEMIM][TFSI]
    • Einecs 817-300-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    282217

    Molecular Formula C10H17F6N3O5S2
    Molecular Weight 485.38 g/mol
    Appearance Colorless to pale yellow liquid
    Melting Point -
    Boiling Point -
    Density 1.37 g/cm3 (approximate)
    Solubility In Water Miscible
    Ionic Liquid Type Imidazolium-based
    Cation 1-Hydroxyethyl-2,3-dimethylimidazolium
    Anion Bis((trifluoromethyl)sulfonyl)imide (NTf2)
    Viscosity High (relative to water, varies with temperature)
    Thermal Stability Up to ~300 °C
    Purity >98% (typical for commercial product)
    Refractive Index 1.41-1.44 (approximate at 20°C)

    As an accredited 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle containing 25 grams of 1-Hydroxyethyl-2,3-dimethylimidazolium bis(trifluoromethyl)sulfonyl)imide, tightly sealed with safety cap and label.
    Shipping Shipping for **1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide** requires secure, sealed packaging to prevent moisture and air exposure. Transport as a chemical substance according to applicable regulations, such as IATA or DOT guidelines. Ensure labeling with appropriate hazard and handling information. Store and ship at ambient temperature unless specified by the manufacturer.
    Storage **1-Hydroxyethyl-2,3-dimethylimidazolium bis((trifluoromethyl)sulfonyl)imide** should be stored in a tightly sealed container, in a cool, dry, well-ventilated area away from moisture, direct sunlight, and sources of ignition. Keep separate from strong oxidizing agents and acids. Properly label containers and ensure secondary containment to prevent spills. Use appropriate corrosion-resistant materials for storage containment.
    Application of 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    Applications of 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide in Industrial Manufacturing

    Our company supplies 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide to precise downstream sectors where advanced ionic liquids are essential for demanding process environments. Below are the most established industrial use cases, supported by regulatory standards, formulation guidelines, process integration points, and typical end products.

    1. Electrolytes for High-Performance Lithium Batteries

    Battery manufacturers utilize this ionic liquid as a non-flammable, chemically stable electrolyte component to enhance conductivity and cycle life in lithium-ion and next-generation lithium-metal batteries. Its unique structure enables stable operation in high-voltage cells, supporting safety and energy density targets necessary for automotive and grid-scale energy storage.

    Industry compliance standards

    • UN 38.3 transport safety requirements
    • IEC 62660-2 for secondary lithium cells
    • UL 2580 battery safety standard
    • ISO 9001:2015 for materials management

    Typical usage ratio

    • 5%–25% by weight in mixed-solvent electrolyte systems; selected based on target voltage window and temperature stability required by the application

    Downstream process integration

    • Added during the electrolyte formulation and mixing step before cell assembly; compatible with automated dosing systems under dry-room conditions

    Final product types

    • Electric vehicle lithium-ion battery cells
    • High-cycle-life lithium-metal coin and pouch cells
    • Large-format stationary grid storage batteries

    2. Electroplating and Metal Surface Treatment

    Specialty metal finishing facilities incorporate this ionic liquid as a room-temperature ionic medium that enhances ion transport and deposition control during electrodeposition of high-value or difficult metals such as gold, platinum, and palladium for electronics and aerospace parts. The use of this chemical supports cleaner deposition morphologies and reduces environmental impact compared to legacy solvent systems.

    Industry compliance standards

    • ISO 4527 for electrodeposited coatings
    • REACH Annex XIV/Annex XVII for chemical management and restriction
    • RoHS Directive 2011/65/EU for electronics coatings
    • EN ISO 9001:2015 for quality management

    Typical usage ratio

    • 10%–35% by volume in aqueous-organic electrolytic bath; adjusted for target deposition rate and layer uniformity

    Downstream process integration

    • Mixed into electrodeposition bath prior to metal salt loading; operates at moderate temperatures in closed-loop plating lines with automated monitoring

    Final product types

    • Gold- and platinum-plated electronics connectors
    • Palladium-plated aerospace fasteners
    • Decorative and functional watch and jewelry components

    3. Separation Media in Chemical Catalysis Processes

    Chemical production facilities adopt this ionic liquid as a highly selective extraction and solvent medium in transition metal catalyzed or organometallic reactions. Its low vapor pressure and controlled polarity improve reaction selectivity, reduce byproduct formation, and facilitate catalyst recycling—especially relevant in pharmaceutical intermediates and fine chemical synthesis.

    Industry compliance standards

    • GMP Part II (ICH Q7) for active pharmaceutical ingredient (API) manufacturing
    • ISO 14001:2015 for environmental management
    • EPA 40 CFR Part 261 for hazardous waste minimization
    • EU Regulation (EC) No 1907/2006 (REACH)

    Typical usage ratio

    • 15%–50% by volume relative to total reaction solvent; varies according to substrate solubility and desired phase separation efficiency

    Downstream process integration

    • Introduced into batch or flow reactors during solvent charging between catalyst and substrate addition, with phase disengagement after reaction completion

    Final product types

    • Specialty intermediates for pharmaceutical synthesis
    • Chiral fine chemicals and agrochemical actives
    • High-purity ligand complexes for catalyst recycling

    4. Heat Transfer Fluids in Electronics Thermal Management

    Advanced electronics cooling applications, particularly in semiconductor fabs and data centers, rely on this ionic liquid to serve as an efficient, non-corrosive heat transfer medium. Its thermal stability and electrical non-conductivity make it valuable for direct-contact liquid cooling of sensitive components, improving energy efficiency and device lifespan without risk of short-circuiting.

    Industry compliance standards

    • IEC 62368-1 for safety of electronic equipment
    • JEDEC JESD22-A104 for thermal cycling of electronic assemblies
    • ISO 14644-1 for cleanroom compatibility
    • RoHS Directive for restricted substances

    Typical usage ratio

    • Pure or 50%–100% concentration as supplied; direct-fill levels depend on loop size and system hold-up volume calculated from equipment layout

    Downstream process integration

    • Charged directly into sealed thermal management circulation loops post-system assembly, with regular inline filtration and replacement protocol

    Final product types

    • Immersion-cooled high-performance computing servers
    • Direct-liquid-cooled semiconductor wafer processing tools
    • Precision laboratory temperature control baths

    5. Solvent for Advanced Polymer Electrolyte Membranes

    Specialty polymer membrane manufacturers employ this ionic liquid as a casting solvent and conductivity modifier for synthesizing high-performance membranes in fuel cells and hybrid capacitor devices. Its miscibility with monomers and polymer precursors allows controlled film formation during solvent evaporation, supporting enhanced ionic mobility across the membrane matrix for reliable electrochemical performance.

    Industry compliance standards

    • ISO 14687 for hydrogen fuel cell applications
    • IEC 62282-2 for PEM fuel cell modules
    • ASTM D149 for dielectric breakdown strength
    • ISO 9001:2015 for advanced materials production

    Typical usage ratio

    • 20%–60% by weight relative to polymer solids; adjusted for membrane thickness, porosity, and targeted conductivity

    Downstream process integration

    • Blended with monomers/polymers and additives before roll-to-roll or batch membrane casting; solvent removal via controlled evaporation or phase inversion

    Final product types

    • Proton exchange membrane (PEM) fuel cell sheets
    • Separator films for hybrid supercapacitors
    • Ionic-conductive coatings for sensor substrates
    Free Quote

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    Certification & Compliance
    More Introduction

    Introducing 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide: Innovation Rooted in Chemical Experience

    The Value of Crafting Ionic Liquids at the Manufacturing Source

    Years of working on the production floor have taught us that practical chemistry unfolds differently than it does in a simulation or in a catalog listing. We see chemistry in the stories behind each drum leaving our gates, in the way raw material prices shift, and in every product tested before shipment. Many know the chemical 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide by its more technical abbreviation or as a standout ionic liquid, but on our production site, its unique structure matters beyond formulas: it’s the result of closely controlled synthesis, responsible sourcing, and continual attention to detail as it moves from reaction vessel to finished vial.

    What Sets 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide Apart

    Simple imidazolium salts once met the needs of chemical engineers who needed moderate conductivity and stability. As projects demanded higher performance, adding the hydroxyethyl group and two methyl substitutions on the imidazolium ring carved a new path. The bis(trifluoromethyl)sulfonyl)imide (TFSI) counterion responds well in high-voltage, water-sensitive, and temperature-independent environments. This combination does not just sound impressive. It actually means improved solubility in both polar and non-polar media, better resistance to hydrolysis, and measurable gains in ionic mobility.

    From a manufacturer’s view, we focus on how those extra methyl groups decrease viscosity compared to a non-substituted imidazolium. Fewer cation-anion interactions mean easier handling during operations. The hydroxyethyl branch grants a targeted hydrophilicity, sometimes essential for blending with water but not to the extent that it picks up too much atmospheric moisture during storage. The TFSI anion—well-known for introducing both lipophilicity and remarkable thermal stability—complements the cation so you see clear, repeatable performance shift over cheaper halide or tetrafluoroborate systems. These aren’t textbook differences but practical ones, showing up in less downtime, fewer complications during separation, and lower levels of corrosion in reaction vessels.

    How We Address the Challenges of Ionic Liquid Synthesis and Scale

    Producing this ionic liquid isn’t just about following standard operating procedures. Laboratory-scale batches might turn out well, but errors in temperature control or solvent purity quickly become evident at kilo and ton scales. Moisture, for example, poses a persistent enemy. Too humid an environment and the final product can start to hydrolyze. This risk led us to invest in dedicated drying lines and robotic monitoring of all water-intrusion hotspots during both synthesis and storage.

    Most ionic liquids on the market show batch-to-batch variability. We found that slight variations in the order of reactant addition and mixing regime strongly influence final product color, water content, and even odorous byproducts. By automating certain steps (without sacrificing manual checkpoints), we’ve trimmed deviations, so each lot aligns with strict physical profiles. Customers in analytical R&D, catalysis, and electrochemical sectors have remarked on the marked decrease in unexpected impurities compared to less rigorously produced alternatives.

    Meeting the Demands of New Electrochemical and Solvent Applications

    Electrochemical engineers and formulation scientists approach us not just in search of an ionic liquid, but something that won’t break down above 150°C and won’t degrade electrodes over months of cycling. The structural choices behind 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide lead to very low vapor pressure and wide electrochemical windows. This opens the door for use in batteries demanding longer shelf life. Solid-state device teams frequently specify this compound in custom electrolyte blends. The hydroxyethyl side chain aligns better within polymer matrices, so solid electrolytes and membranes adopt higher loadings without clouding, weeping, or shifting mechanical strength.

    A research lab working on CO2 reduction noticed that unlike traditional imidazolium-TFSI salts, our product improves the stability of both the cathode interface and gas-liquid boundary. The added bifunctionality in the cation seems to moderate local pH and foster subtle differences in interfacial chemistry. That's not conjecture—we have recycled pilot-cell studies and partners who trace lower failure rates and better repeatability when they switch from common ionic liquids to ours, which is the result not of engineered marketing but actual benchwork and factory experience.

    Applications Beyond the Obvious: Solvent Properties and Catalytic Support

    Working with formulation chemists, we have seen request after request for solvent systems that can dissolve both polar and hydrophobic compounds without separating or reacting with key intermediates. Most aromatic-imidazolium systems react too readily under basic conditions or foul downstream separation steps. Substituting with our hydroxyethyl, dimethyl-imidazolium design gave noticeably longer shelf life. In catalysts that demand precise activation—such as those for industrial hydrogenation—the shape and polarity of this ionic liquid helps disperse nanoscale active centers without leading to agglomeration or “caking” observed with less sophisticated salts.

    In the field, researchers measuring deep eutectic solvents often struggle with basic ionic liquid grades that pick up moisture and fail after a handful of cycles. Ours resists atmospheric uptake better, so customers report fewer batch failures, less “off” color after repeat uses, and ease of downstream purification. The chemical’s low melting point and flexibility under pressure have attracted attention in green chemistry applications, especially because it won’t introduce halide contamination. We think about purity not as a checkbox, but in terms of what it saves: remediation costs, time spent filtering, and broken glassware. Our technicians measure metal, halogen, and water levels at multiple stages and link each to the corresponding batch for direct traceability.

    What Experience Has Taught Us in Scaling, Shipping, and Usage

    Many fine chemicals show different behaviors depending on the scale and road conditions involved in getting them to users. Early on, logisticians were seeing crystallization and phase separation in cold-weather transport. A product can look perfect under the QC microscope but clog up or stratify after sitting in customs for a week. After repeated winter test shipments, and with feedback from receiving chemists, we adjusted our purification regime and tweaked storage containers: thick-walled drums and anti-static liners now mitigate most issues connected with cold shock and reduce risk of electrostatic discharge.

    Some labs send highly specific requirements: sub-ppm halides, extremely low volatile content, or assurances of non-detectable transition metals. Our batch records trace the lot history down to the kilo, and our hands-on staff review any spectrographic anomaly before shipment. Chemicals used in batteries, large pilot lines, or advanced separations deserve more than just a standard specification sheet. They need direct accountability from the people making the product. Risk of cross-contamination—from other halogenated or oxidizing agents, for example—means that we run our facility on a “campaign” basis, with deep cleaning and validated shutdowns after each run. The difference may not show on the spec sheet, but users comment on the absence of background signal or ghost peaks, and that reflects the value of direct production control.

    Differences From Standard Imidazolium Ionic Liquids

    Comparison against common imidazolium ionic liquids makes sense for anyone considering a transition. Basic imidazolium-TFSI liquids offer reliable conductivity and thermal resistance, but show greater viscosity and less versatility when blending with greener, mixed-solvent systems. Many lack the hydroxyethyl group, so their solubility in partially aqueous or polar organic mixes falls short. The presence of two methyl groups changes both the electron density and steric hindrance around the imidazole ring, resulting in lower freezing points and greater resilience when used with sensitive organometallic complexes.

    Some chemists opt for tetrafluoroborate or hexafluorophosphate salts because of cost, yet these create issues downstream: hydrolysis, unknown decomposition products, and volatile byproduct formation under elevated temperatures. Any upfront savings often vanish after replacing corroded equipment or addressing unplanned downtime. The TFSI anion, on the other hand, means our product won’t generate HF on decomposition or feed environmental persistence in the way traditional fluorinated ionic liquids do. Our experience processing these salts shows that they drop waste management costs over time.

    Labs focusing on “green” synthetic routes benefit from using an ionic liquid that can endure harsh redox cycles and frequent recycling. Some analogues degrade or color-shift after repeated exposure to reactive gases, while users running multi-cycle batch syntheses with our product see minimal degradation and shorter purification times. That difference comes not from luck but accumulated lessons from each batch we’ve run, each analysis done, and every return shipment analyzed for root cause.

    Supporting Advanced Material Science Projects

    Researchers developing energy storage systems want both electrical performance and chemical stability. The structural tweaks embodied in our compound fit those twin demands: high ionic conductivity, chemical inertness, and minimal side reactions at both low and high voltages. Flexible electronics, printable circuits, and responsive polymer coatings often call for solvents that won’t evaporate or react unexpectedly. The hydroxyethyl side chain offers compatibility with hydrogels and polar elastomers that standard imidazolium salts can’t match.

    Material developers, particularly those working in lithium or sodium batteries, seek solutions for stable electrolytes that minimize dendrite growth and resist degradation by moisture traces. Here, the robust TFSI-based ionic liquid structure maintains fluidity at room temperature, forms consistent solid-electrolyte interphases, and supports reliable ion transport at higher fields. Over years of delivering samples, troubleshooting customer pilot runs, and following up on every odd result, we have built a process for maintaining both production and technical support at a level custom fit for these industries.

    Commitment to Quality Rooted in Hands-On Practice

    Trust between a manufacturer and customer doesn’t arise through certification alone. It’s built on owning every part of the process, from incoming material checks to regular staff training on contamination risks. Our technical teams manage purification, monitor drying ovens, and even document ambient warehouse humidity to anticipate problems before they arise. If a solvent spill happens, the incident is logged, traced, and that batch quarantined for analysis. This culture ensures that what arrives at the customer site brings the qualities engineers and researchers expect—not just compliance to a document, but a predictable foundation to their work.

    As a manufacturer, we’re not in the habit of promising the impossible; rather, we share what we have consistently delivered and what we have learned through solving unexpected challenges. Users of 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide benefit from our practice of updating process conditions as new data emerges, so the product grows alongside each new application field. Technical support reaches directly to our production scientists—not offshore call centers or generic sales staff—allowing honest feedback and creative troubleshooting. This relationship makes a difference when strict timelines or unexpected project shifts change the requirements overnight.

    Building on Feedback and Continuous Process Improvement

    Many long-term customers have taught us as much as we have supplied product. Investigating a batch returned for discoloration led us to reformulate the final wash step, which improved product clarity not just for that user, but for all future shipments. Only by listening and working on-site do manufacturers learn that practical obstacles—such as bottle types, decanting practices, or compatibility with customer labware—can impact results as much as purity or chemical structure itself.

    Every new scale-up or reformulation draws from a record of what has worked and what has fallen short. We keep a detailed log of every field complaint, customer suggestion, and process tweak. Reviewing these in regular meetings helps us avoid repeated mistakes and refine both the compound itself and the support we offer. These aren’t vague values; this is the rhythm of daily operation in a real production facility, one batch after another.

    Direct Accountability and Real-World Solutions

    Maintaining direct oversight of production lines and batch records makes it possible for us to guarantee traceability, purity, and consistency. Our staff answers directly to the real-world users—researchers, process engineers, pilot plant operators—who need responsive, knowledgeable answers, not generalities. The pursuit of high-performance ionic liquids does not leave room for shortcuts or speculative improvement; every modification is tested, logged, and reflected in later shipments, supported by regular in-house and third-party analysis.

    We address each new shipping, storage, or handling challenge not as an abstraction but as an operational detail with cost or safety consequences. Improvements in product stabilization or purity save time, reduce rework, and preserve the reputation not just of the product, but of every customer application built on it. As chemical manufacturing continues to sharpen expectations for high-functionality and low impurity, the need for active, hands-on improvement from the manufacturer side only grows more critical.

    Final Thoughts on Using 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    No single ionic liquid meets every conceivable requirement. The specialized structure and thoughtful process development behind 1-Hydroxyethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide give it an edge across demanding use cases—energy storage, specialty solvents, electrochemistry, and advanced catalysis. These distinctions take form in reduced equipment wear, longer operating lifespans, higher cycle stability, and measurable productivity gains in the laboratory and factory setting alike.

    Our daily operations and ongoing collaborations with technical teams have shaped both the chemistry and the service supporting this product. Each challenge, request, and new result feeds back into the next production batch, growing the body of evidence and expertise for others to build upon. This approach ensures users receive not only a chemical, but the backing necessary for tangible research and manufacturing success.