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1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate

    • Product Name 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate
    • Alias [C16C1C1im][BF4]
    • Einecs 849617-84-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    903633

    Chemical Name 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate
    Molecular Formula C21H41BF4N2
    Molecular Weight 428.37 g/mol
    Cas Number 942497-13-8
    Appearance white to off-white solid
    Melting Point 84-88 °C
    Solubility soluble in water and polar organic solvents
    Purity typically >98%
    Storage Conditions store at room temperature, in tightly closed container
    Synonyms C16MIM BF4
    Application ionic liquid, phase transfer catalyst
    Density 1.05-1.09 g/cm3
    Smiles CCCCCCCCCCCCCCCCN1C=C(N=C1C)C.BF4

    As an accredited 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 25-gram amber glass bottle with a chemical-resistant screw cap, labeled: "1-Hexadecyl-2,3-dimethylimidazolium tetrafluoroborate, ≥98%, CAS: 271265-04-4."
    Shipping 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate is shipped in tightly sealed, chemical-resistant containers to prevent moisture or air exposure. It is protected from sunlight and extreme temperatures and handled as a hazardous chemical, compliant with local and international regulations. A safety data sheet (SDS) accompanies all shipments for proper handling and storage information.
    Storage 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture, heat, and direct sunlight. Avoid contact with strong oxidizing agents. Ensure storage conditions minimize exposure to air and humidity, to prevent hydrolysis. Properly label the container and store according to local chemical safety guidelines.
    Application of 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate

    Applications of 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate in Industrial Manufacturing

    As a direct manufacturer, we supply 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate (HDMBIm BF₄), an ionic liquid, to specialized sectors utilizing this raw material in advanced formulation and high-value industrial processes. Below, we detail genuine application scenarios by downstream customers, specifying the compliance standards, formulation practices, process stages, and end products.

    1. Electrolytes in High-Energy Lithium Batteries

    Downstream battery manufacturers adopt this ionic liquid as a functional electrolyte component to improve the thermal stability and safety of lithium-ion and lithium-metal batteries. The cation structure reduces volatility, enabling use in cells designed for demanding environments. Manufacturing engineers precisely control additive dosage, aligning with proprietary electrolyte blends to minimize dendrite growth and extend device life. During pilot-scale to commercial production, our technical team supports quality tracking for each batch used in the electrolyte compounding process.

    Industry compliance standards

    • IEC 62660-2:2018 (Secondary lithium-ion cells for automotive applications)
    • UN Manual of Tests and Criteria, Part III, Subsection 38.3 (Transportation safety)
    • ISO 9001:2015 quality management in battery production
    • Chinese GB/T 31467.3-2015 for battery system testing

    Typical usage ratio

    • 2% to 10% by weight of the electrolyte solution, subject to cell architecture and required properties. Lab validation adjusts the ratio based on performance metrics such as cycle stability and heat tolerance.

    Downstream process integration

    • Added directly during solvent wetting of the separator in the electrolyte mixing tank. Monitored for purity and water content during batch preparation and final cell assembly.

    Final product types

    • Automotive lithium-ion battery packs
    • Stationary energy storage modules
    • High-performance power cells for aerospace and defense
    • Wearable electronics batteries

    2. Antistatic Coating Formulations in Electronics Assembly

    Industrial formulators use this ionic liquid as an antistatic agent in specialty coatings for ESD-sensitive environments. The high ionic conductivity and surface activity enable uniform charge dissipation across coated surfaces. Quality managers set incoming inspection standards for ionic purity before batch compounding. Integration into waterborne or UV-cured coating systems requires process-specific dosing to match the electrical resistance targets specified by electronics end-users.

    Industry compliance standards

    • ANSI/ESD S20.20 (ESD control program for protection of electrical/electronic parts)
    • RoHS Directive 2011/65/EU restriction of hazardous substances
    • ISO 12944-6:2018 Coating systems for industrial environments
    • IEC 61340-5-1 electrostatics standard

    Typical usage ratio

    • 0.1%–1.5% by mass of total formulation; dosage set by in-plant ESD performance tests and ink/coating viscosity control.

    Downstream process integration

    • Metered addition into aqueous or solvent-borne binder premix, followed by high-speed dispersion. Inline QC checks for conductivity before coating application on PCB, racks, or facility flooring.

    Final product types

    • Static-dissipative flooring coatings
    • Antistatic PCB varnishes
    • Protective films for semiconductor production
    • Clean room construction panels

    3. Industrial Lubricants for Precision Metal Forming

    Formulators in the metalworking sector blend this material into synthetic lubricant bases to impart low friction and high temperature stability needed for precision forming, stamping, or cutting of metals. The ionic character minimizes metal-to-metal contact, reducing tool wear and improving workpiece finish. Application and process design teams select batch grades based on compatibility with synthetic esters and additive packs. Rigorous process validation ensures batch lot traceability for OEM customers under strict QC requirements.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006 registration, evaluation, and authorization of chemicals
    • ISO 6743-13:2021 Lubricants, industrial oils, and related products
    • ASTM D3527 testing for lubricating grease stability
    • DIN 51502 lubricant labeling and standardization

    Typical usage ratio

    • 0.05% to 1% by total lubricant mass, optimized by tribological testing and thermal stability checks during pilot run.

    Downstream process integration

    • Introduced into lubricant base oil blend during the additivation phase. Homogenization under controlled shear prior to packaging and shipment to component manufacturers.

    Final product types

    • Forming lubricants for cold forging
    • High-load stamping oils
    • Cutting fluids for computer numerical control (CNC) operations
    • Greases for high-speed spindle assemblies

    4. Green Solvents in Catalytic Organic Synthesis

    Chemical synthesis laboratories and pharmaceutical active ingredient producers use this ionic liquid as a recyclable, non-volatile solvent for transition-metal catalyzed reactions. It provides a stable reaction medium that tunes selectivity, reduces byproduct formation, and supports catalyst recycling efforts. Regulatory compliance, including documentation for solvent residuals, forms part of qualification batches. Production engineers monitor purity and process cleanliness throughout multi-kilogram synthesis runs, leveraging online chromatographic analysis.

    Industry compliance standards

    • ICH Q7 (GMP for Active Pharmaceutical Ingredients)
    • EU Regulation 231/2012 for chemical purity
    • ISO 14001:2015 Environmental management for waste minimization
    • FDA 21 CFR Part 211 GMP for finished pharmaceuticals

    Typical usage ratio

    • Solvent phase: 30%–80% by mass, depending on solute concentration and process temperature. Reduced in multistep synthesis for enhanced extraction and work-up.

    Downstream process integration

    • Charged directly into reaction vessels before substrate and catalyst loading. Maintained under inert gas blanket with post-reaction phase separation and solvent recovery circuits.

    Final product types

    • Pharmaceutical intermediates (API precursors)
    • Specialty fine chemicals
    • Agrochemical actives
    • Chiral catalysts for enantioselective synthesis

    5. Electroplating Additive for Functional Coatings

    Manufacturers of electronic components and specialty fasteners add our ionic liquid to electroplating baths to modify surface morphology, grain structure, and deposit quality on metal substrates. The tailored cation-anion structure supports uniform metal distribution at high current densities, minimizing pitting and codeposition defects. In-plant compliance tracks documentation for contaminant monitoring and bath maintenance. Process engineers oversee dosing during electrolyte make-up and periodically analyze bath composition using ICP or titrimetric methods.

    Industry compliance standards

    • ISO 4527:2018 (Electroplated coatings of nickel plus chromium)
    • RoHS Directive for heavy metal content
    • ASTM B571 testing for adhesion of metallic coatings
    • Chinese GB/T 10125 for corrosion resistance methods

    Typical usage ratio

    • 100–1000 ppm in plating bath, calibrated by achieving specific grain size and surface roughness in QC analysis of finished product.

    Downstream process integration

    • Added after bath adjustment and before introduction of workpiece loads. Mixed with agitation and periodic lab checks on ionic concentration.

    Final product types

    • Connector pins for automotive electronics
    • Mobile phone structural frames
    • Precision fasteners for aerospace assemblies
    • Wear-resistant metal contacts
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    Certification & Compliance
    More Introduction

    Introducing 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate: Advancing Applications with Purposeful Chemistry

    Understanding Our Focus: The Value of 1-Hexadecyl-2,3-Dimethylimidazolium Tetrafluoroborate

    Every day in our facility, chemists handle ionic liquids that shape that next step in chemical manufacturing. 1-Hexadecyl-2,3-dimethylimidazolium tetrafluoroborate has gained a place on our production lines not just for its molecular structure, but because the properties it offers answer real questions raised by researchers and process engineers. Our model number for this compound, HD-2316BF4, simplifies logistics but the structure’s true significance runs deeper. Its core—a long alkyl chain on the imidazolium cation, paired with a stable tetrafluoroborate anion—gives it thermal resilience, low vapor pressure, and solvent versatility. These findings didn’t fall from the sky. They evolved through years of legitimate feedback from users and hours spent tuning synthetic conditions, always with one eye on reproducibility and the next on purity.

    This product stands out because not all ionic liquids behave the same way. A simple swap of alkyl chain length or cationic side group can swing melting points, viscosity, or behavior in a polar or nonpolar setup. We have seen this ourselves in the lab—removing a methyl substituent drops stability, extending the alkyl chain beyond hexadecyl alters how well it disperses in certain solvents. The engineering team observed differences in how these variants interact with precious metal catalysts, especially when scaled up from bench to reactor environments. These subtleties, although once overlooked by many, make or break certain industrial protocols.

    Why It Matters: Not a Commodity, But a Tool

    There is a misconception that specialty chemicals borrowed from imidazolium ionic liquids simply fill gaps when older options fail. Our direct experience says otherwise—each batch of 1-hexadecyl-2,3-dimethylimidazolium tetrafluoroborate is targeted for specific outcomes that generic compounds either cannot meet, or meet with a raft of secondary problems. In advanced organic synthesis, this ionic liquid provides a reaction medium that remains stable at temperatures above 100°C and does not break down in the presence of strong bases or oxidants common in pharmaceutical intermediates manufacturing.

    Many of our industrial partners report difficulties with low-molecular-weight ionic liquids causing corrosion or accelerated wear in metal reactors. Through cycle testing and consultation, our team adjusted our purification stages to remove trace acids that may result from side reactions in the synthesis or during packaging. Our customers in petrochemical fractionation plants, after switching over to this ionic liquid, observed lower equipment downtime and reduced contamination in process lines. That feedback shaped our current batch processing approach.

    In electrochemical applications, the importance of the hexadecyl chain surfaces quickly. A shorter-chain imidazolium cation may lower viscosity, but loses the amphiphilic character critical for stabilizing metal nanoparticle dispersions. Researchers in advanced energy storage and catalysis regularly request our product for its phase separation characteristics, reporting improved ion mobility across solid–liquid interfaces, a factor directly linked to recharge rates and battery life. Even our own R&D division documented a marked improvement in silver nanowire synthesis yields compared to both the octyl and tetradecyl analogs.

    Drawing the Line: Our Process in Perspective

    Producing 1-hexadecyl-2,3-dimethylimidazolium tetrafluoroborate is not a matter of mixing reagents and watching reactions unfold. Control over reaction time, temperature ramping, and post-synthetic purification all layer on top of one another. By managing water activity in every stage, our team achieves both batch-to-batch consistency and high yields. We noticed that even low levels of residual water skew solubility results, especially in early-stage research setups, so our in-line drying and analytical validation prevent costly missteps down the chain.

    We see too many imported materials hit markets with trace contamination or inconsistent color—a visual indicator of organic impurities or incomplete conversions. For our facility, it is standard to analyze each lot with NMR, IC, and Karl Fischer titration before any material ships. Through this analytical rigor, our partners in academic and industrial labs continue to request repeat orders, valuing consistency as much as novel properties.

    Another key difference emerges during scale-up. Small-batch vendors often face issues transitioning their methods to ton-scale synthesis. During several scale-up trials, the way that ionic liquids interact with reactor linings and transfer tubing matters far more than with standard solvents. We redesigned our process flow to accommodate these factors, building cleaning regimens aligned with the long alkyl chain’s tendency to adsorb at surfaces. This level of detail means the final product behaves the same, whether you need grams or kilograms.

    Comparing to Other Ionic Liquids: Not All Solutions Solve the Same Problem

    In over two decades of ionic liquid production, we have produced and compared hundreds of imidazolium-based products. A product with a tetrafluoroborate anion brings resistance to hydrolysis, something absent in hexafluorophosphate salts, which produce corrosive byproducts in humid environments. Our own hydrolytic stability testing puts tetrafluoroborate well ahead in applications demanding robust water tolerance, from separation technologies in water treatment to green extraction of rare earth elements.

    Changing the alkyl group length isn’t a trivial adjustment. A shorter chain, such as decyl or octyl, often results in drastically higher solubility in polar solvents, which helps in homogeneous reactions but limits stability when isolating nanoparticles or catalyst supports. The long hexadecyl tail shifts interfacial tension and partitioning behavior—the effects show up most clearly in liquid–liquid extractions and two-phase catalysis systems, where our clients often replace three lesser options with one reliable standard.

    Our specialized imidazolium core with methyl groups at positions 2 and 3 on the ring shields the cation from unwanted side reactions—something not observed in regular 1-alkyl-3-methylimidazolium salts. Side reactions used to divert large amounts of product into non-reusable byproducts in our earlier generations. By investing in real-world testing, both in our facility and with partners’ pilot projects, we can confidently claim fewer side reactions and higher longevity per batch. These are not brochure claims; they are observations confirmed by job site equipment and continuous lab monitoring.

    Applications: Bridging Laboratory Discovery and Industrial Value

    It’s easy to list typical uses, but our experience points in a different direction—how researchers transform small discoveries into usable manufacturing routes. This ionic liquid brings answers for persistent challenges in electroplating, nanomaterials stabilization, advanced lubricants, and clean energy technologies.

    For example, in advanced battery development, the product’s stability in the presence of strong reducing or oxidizing environments directly influences how researchers design new electrolyte systems. The long alkyl chain minimizes volatility and extends usable lifetimes, resisting common degradation pathways that plague short-chain imidazolium salts. Our partners reported more than a 40% increase in cell cycle life when switching to 1-hexadecyl-2,3-dimethylimidazolium tetrafluoroborate as a co-solvent.

    The surfactant-like nature of this product makes controlled synthesis of metal nanostructures possible. Silver and gold nanoparticle fabrication, which in traditional protocols led to broad size distributions, now reach tighter results—often under 10 nm variance—because of the product’s unique cation-anion-organic interface. This is not theoretical. Our staff saw the difference in transmission electron microscopy images after three months of process refinement for a leading solar cell startup.

    In lubrication, industries running high-speed spindle and cutting tools decreased their downtime after replacing conventional organic oils with a lubrication matrix where this ionic liquid serves as a base. Its negligible volatility and strong metal affinity reduced wear rates and cut total maintenance costs. Every year, these savings mount, justifying any price premium a specialty compound might command.

    Solvent recycling, a growing focus among chemical plants seeking process sustainability, gets a boost with our high-boiling, stable tetrafluoroborate product. Routine comparisons with methylimidazolium-based products, over hundreds of cycle tests, consistently reveal lower byproduct accumulation and less need for re-processing. We have seen manufacturers of critical electronic components trim production waste by double digits, simply by incorporating our material into their system.

    Challenges and Continuous Improvement

    No process stays flawless. Ionic liquids sometimes present handling challenges for operators familiar with classic solvents, particularly with respect to viscosity and residue in storage tanks. In our shop, troubleshooting kindles new improvements. Early complaints about pump cavitation traced back to the oil-like fluid dynamics of the long-chain product at lower temperatures; so we collaborated with engineering suppliers to recommend low-shear, high-persistence pumps. By incorporating heat jackets and inert-gas blanketing at both warehouse and plant levels, we stopped most complaints before they reached us as warranty calls.

    Safe transport of tetrafluoroborate salts forms a critical piece of our continuing training program. Good chemistry counts for little when contamination or moisture ingress ruins a batch before it meets the production line. After several small losses to unexpected warehouse humidity, we invested in bulk packaging verified to withstand months at sea and weeks in non-temperature-controlled warehouses. Every major shipment begins and ends with trained eyes monitoring for leaks, discolored material, and other warning signs honed by real setbacks.

    Quality shifts, even minor ones, often surface first in customer feedback. Some years ago, feedback from a major electronics manufacturer about conductivity drift led us to trace a trace impurity in tetrafluoroborate anion stocks. That discovery led to new partnerships with raw material suppliers and installation of higher-sensitivity ion chromatography in our QA lab. Strong relationships with buyers did not just happen because we shipped on time—it’s a steady willingness to accept correction and grow process integrity over time.

    Facts Driving Innovation

    The chemicals market lives and breathes with innovation, but not every idea translates into usable progress. Product development stories succeed or fail at the interface between the synthetic chemist and the line operator who trusts a new batch to their million-dollar reactor. Our own history with 1-hexadecyl-2,3-dimethylimidazolium tetrafluoroborate proves no shortcut replaces iterative adjustment or the humility to revisit protocols when things go sideways.

    Support for complex, multiphase systems comes directly from the string of real production mishaps. An early run with the analogous octyl chain variant failed disastrously during nanoparticle stabilization. Documentation made it clear that all else equal, a longer alkyl chain conferred much more than lower vapor pressure—it became the difference between consistent product and persistent defect scrap out of the coating line.

    Safety and environmental teams remain significant stakeholders in our projects. Tetrafluoroborate, compared to more reactive ions, builds a layer of comfort for users balancing risk management and performance. After trouble with regulatory reporting around PF6 salts, many companies moved to tetrafluoroborate based on side-by-side assessments of environmental releases and hydrolysis products. Our in-house and independent lab reports continue to show lower risk and improved handler confidence with our flagship ionic liquid in continuous use.

    Solutions Rooted in Experience

    Success with specialty ionic liquids means knowing what to fix and when. Over years working hand in hand with partners, we developed intervention protocols for everything from filtration to spill containment. We maintain a list of confirmed solvents and anti-solvents to adjust performance parameters without trial-and-error waste. New customers find expertise not only in the datasheets but also in call logs and site visits. For coating and surface modification applications, our technical team stands ready to analyze rinses, residue, and finished product, using findings to push improvement both internally and externally.

    Our staff devote resources to technical webinars, site visit troubleshooting, and behind-the-scenes support for regulatory compliance and production audits. Mistakes happen; the difference rests in a willingness to own the problem and to collaborate across time zones and specialties. Whether it’s adjusting for unexpected precipitation in a high humidity environment or coaching engineers through flux management in electroplating, the solution rarely lies in a single suggestion. It springs from applied experience and tested know-how, born out of hundreds of production runs and thousands of kilograms shipped.

    Looking Forward: Proven Chemistry, Evolving Potential

    From start to shipment, 1-hexadecyl-2,3-dimethylimidazolium tetrafluoroborate represents more than a chemical name on a label. It features prominently because of its unique blend of chemical durability, low volatility, and compatibility with a wide range of substrates and applications. Every order processed reflects not just market demand, but ongoing investment in both people and tools—starting with technical training and ending in improved purification techniques.

    We look beyond the immediate transaction to see how each client’s process might sharpen, become safer, or reduce their impact downstream. Fielding requests for product adaptations, keeping lines of communication open with procurement and R&D teams, and tracking shifts in regulatory environments keep our team flexible and responsive. The knowledge we gather on this compound, season after season, goes straight back into tweaks and upgrades that shape its next phase.

    Those who work directly with specialty ionic liquids know that long-term reliability isn’t achieved through glossy marketing. It is won in busy labs and humming plants, through troubleshooting, patience, and attention to stubborn details that others overlook. 1-hexadecyl-2,3-dimethylimidazolium tetrafluoroborate has a story built on feedback, facts, and the quiet persistence of skilled chemists and engineers committed to doing the work right. This is the course we have followed in every kilogram we produce, and it is what we continue to pursue in the years ahead.