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1-Heptyl-3-Methylimidazolium Bromide

    • Product Name 1-Heptyl-3-Methylimidazolium Bromide
    • Alias [HMIM]Br
    • Einecs 620-130-8
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    753891

    Chemical Name 1-Heptyl-3-Methylimidazolium Bromide
    Chemical Formula C11H21BrN2
    Cas Number 850821-87-9
    Molecular Weight 261.20 g/mol
    Appearance White to off-white solid
    Melting Point Approx. 60-80°C
    Solubility Soluble in water
    Boiling Point Decomposes before boiling
    Density Approx. 1.1 g/cm³
    Storage Conditions Store at room temperature, tightly closed, dry place
    Synonyms HMIM Br; 1-Heptyl-3-methylimidazolium bromide

    As an accredited 1-Heptyl-3-Methylimidazolium Bromide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing White HDPE bottle containing 100g of 1-Heptyl-3-Methylimidazolium Bromide, labeled with chemical name, purity, hazard warnings, and batch number.
    Shipping 1-Heptyl-3-Methylimidazolium Bromide is shipped in tightly sealed containers to prevent moisture absorption and contamination. It is packaged according to chemical safety regulations and labeled with appropriate hazard information. Shipping complies with local and international transport guidelines for chemicals, ensuring safe handling during transit. Store in a cool, dry place upon receipt.
    Storage 1-Heptyl-3-Methylimidazolium Bromide should be stored in a tightly sealed container in a cool, dry, and well-ventilated area, away from direct sunlight and moisture. Keep it separated from incompatible materials such as strong oxidizing agents. Ensure proper labelling and store at room temperature, following chemical hygiene practices. Use personal protective equipment when handling to avoid contact with skin or eyes.
    Application of 1-Heptyl-3-Methylimidazolium Bromide

    Applications of 1-Heptyl-3-Methylimidazolium Bromide in Industrial Manufacturing

    As a manufacturer of 1-Heptyl-3-Methylimidazolium Bromide, we supply this ionic liquid for specialized downstream industries where selective solubilization, catalysis, phase transfer, and extraction demand high purity and reproducible performance. The following sections outline verified industrial application scenarios based on established sector requirements.

    1. Catalytic Medium for Biphasic Hydroformylation in Fine Chemical Synthesis

    Fine chemical producers integrate 1-Heptyl-3-Methylimidazolium Bromide as an ionic liquid phase in biphasic hydroformylation processes to promote catalyst retention and increase aldehyde yields. The material addresses system recyclability and separation efficiency challenges, particularly in large-scale C4–C8 alkene conversions.

    Industry compliance standards

    • OECD Guidelines for the Testing of Chemicals
    • REACH registration and use limitations (EC 1907/2006)
    • ISO 9001:2015 process control for chemical manufacturing
    • Responsible Care® program adherence for safe handling of ionic liquids

    Typical usage ratio

    • Employed at 15–40% v/v of reaction medium depending on alkene chain length and catalyst concentration; adjustments made to optimize partition outflow and product recovery.

    Downstream process integration

    • Charged into the reactor during the initial phase; maintains catalyst in ionic liquid layer through entire hydroformylation cycle; separated by decantation post-reaction before distillation of organic phase.

    Final product types

    • Linear and branched aldehydes for plasticizer, surfactant, and fragrance intermediate synthesis
    • Alcohols produced via downstream hydrogenation

    2. Electrolyte Component for Dye-Sensitized Solar Cell (DSSC) Fabrication

    Photovoltaic manufacturers utilize 1-Heptyl-3-Methylimidazolium Bromide as a non-volatile ionic liquid electrolyte in the assembly of dye-sensitized solar cells, stabilizing ionic conductivity and extending cell lifetimes under operational conditions without solvent evaporation issues.

    Industry compliance standards

    • UL 1703:2017 (Flat-Plate Photovoltaic Modules and Panels)
    • IEC 61215-2 for crystalline silicon module performance testing
    • RoHS Directive 2011/65/EU—restriction of hazardous substances
    • ISO 9001:2015 quality management for PV component production

    Typical usage ratio

    • Blended at 20–60% w/w in the electrolyte formulation, with the exact loading determined in relation to the desired ionic conductivity and stability under thermal cycling.

    Downstream process integration

    • Added during solvent and additive mixing for internal electrolyte solutions injected between photoanode and counter electrode during cell assembly, prior to vacuum sealing of the module.

    Final product types

    • Dye-sensitized solar cell modules (small-scale consumer panels; pilot and commercial-scale energy devices)

    3. Phase Transfer Catalyst in Quaternization and Alkylation Reactions

    Contract manufacturing organizations and pharmaceutical intermediates plants use 1-Heptyl-3-Methylimidazolium Bromide as a phase transfer agent in the aqueous-organic alkylation of heterocyclic precursors, optimizing contact and maximizing reaction rates for quaternary ammonium compound production.

    Industry compliance standards

    • Current Good Manufacturing Practice (cGMP) guidelines for excipient/intermediate production (21 CFR Parts 210/211)
    • ICH Q7: Good Manufacturing Practice Guide for Active Pharmaceutical Ingredients
    • USP General Chapters for process residuals monitoring
    • REACH Substance Data Sharing requirements for import and end use

    Typical usage ratio

    • Applied at 1–5% w/w relative to the limiting substrate; dosage tailored to accommodate solvent composition and agitation method.

    Downstream process integration

    • Introduced at the mixing stage after substrate dissolution, ensuring efficient transport of ionic intermediates between phases during the alkylation or quaternization step, separated upon workup.

    Final product types

    • Quaternary ammonium salts for pharmaceutical intermediate use
    • Cationic surfactants for specialty cleaning product compounds

    4. Solvent for Cellulose Dissolution in Advanced Fiber Applications

    Cellulosic fiber technology firms apply 1-Heptyl-3-Methylimidazolium Bromide for the direct dissolution of wood pulp and technical cellulose as an eco-friendly alternative to traditional viscose or NMMO-based systems, facilitating controlled molecular chain dispersion prior to wet spinning.

    Industry compliance standards

    • ISO 1833-1:2020 (quantitative chemical analysis of textiles—general procedures for cellulose solvents)
    • ISO 14001:2015 environmental management systems for chemical use in fiber processing
    • ZDHC Manufacturing Restricted Substances List (MRSL, cellulose solvent category)
    • Global Organic Textile Standard (GOTS) for applicable fiber lines

    Typical usage ratio

    • Cellulose concentrations in the range 5–12% w/w in ionic liquid; ratio can be tailored based on cellulose DP (degree of polymerization) and targeted spinning viscosity.

    Downstream process integration

    • Raw or pretreated pulp introduced into a heated, pre-dried ionic liquid bath for direct dissolution; resulting solution filtered and extruded through spinnerets into aqueous coagulation bath during fiber or film formation.

    Final product types

    • Regenerated cellulosic staple fibers and continuous filament yarns
    • Cellulose-based films for specialty filter and packaging applications

    5. Extraction Solvent for Rare Earth Metal Recovery

    Specialty metallurgy operations employ 1-Heptyl-3-Methylimidazolium Bromide as part of task-specific ionic liquid mixtures for the extraction and separation of rare earth elements from acidic leachates and waste streams, achieving high selectivity between closely related lanthanides during liquid–liquid extraction circuits.

    Industry compliance standards

    • ISO 9001:2015 for quality control in hydrometallurgical operations
    • ISO 14001:2015 for environmental impact management in metal recovery processes
    • OECD Guidance on Best Available Techniques for the non-ferrous metals sector
    • EU Waste Framework Directive (2008/98/EC) where applicable

    Typical usage ratio

    • Used at 10–40% v/v of the organic extractant phase; ratio is selected based on rare earth element load and acidity of feed solution.

    Downstream process integration

    • Mixed with primary extractant in separate solvent extraction mixers; contacts aqueous leach solution in countercurrent stages before organic stripping, concentration, and precipitation downstream.

    Final product types

    • High-purity rare earth oxide concentrates (e.g., neodymium, europium, dysprosium oxides)
    • Intermediate chloride solutions for further processing into rare earth alloys or magnets
    Free Quote

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    Certification & Compliance
    More Introduction

    1-Heptyl-3-Methylimidazolium Bromide: Reliable Performance from the Source

    Our Experience Shaping Ionic Liquid Solutions

    Manufacturing ionic liquids like 1-Heptyl-3-Methylimidazolium Bromide takes technical control and purpose-driven production. For years, we’ve worked directly with research chemists and industrial users, bringing a deep understanding of what matters in both the lab and larger scale settings. Reliable delivery, supported by stable supply chains and rigorous internal protocols, means we support development teams and factory operators without interruption. Consistent purity and batch-to-batch performance always stand as our main priorities since even small drift in quality can lead to project setbacks or lost efficiency. These are not distant issues for us—our products go through real-world evaluation, so we see firsthand the impact on productivity, downstream separation, and recyclability.

    About 1-Heptyl-3-Methylimidazolium Bromide: Characteristics Forged by Need

    This ionic liquid, often abbreviated as [HMIM]Br, builds on the imidazolium backbone but extends the alkyl side chain, introducing the heptyl group at the N1 position. That difference brings a shift in its physical properties, especially in melting point, hydrophobicity, and miscibility compared to shorter-chain analogs. Lab syntheses and scale-outs rely on its stable molten state and increased compatibility with organic systems. Our standard model uses ultra-pure starting reagents to keep halide contamination low, which helps reduce circuit corrosion or unexpected byproducts where sensitive reactions are underway.

    In production, this salt appears as a white to off-white powder, free from caking agents or diluents. Particle control lowers dusting and transference losses. Each batch receives tailored finishing to give a product that pours easily and resists compaction in long-term storage. We conduct full-spectrum NMR and water content analysis on representative lots, cutting the risk of accidental water addition—a known disruptor in certain organometallic procedures. Rigorous cation/anion ratio checks cut the chance of reaction stoichiometry drift.

    Usage in Research and Industry: Built for the Demands of Modern Chemistry

    Users depend on 1-Heptyl-3-Methylimidazolium Bromide for its balance of solubility characteristics and thermal stability. The heptyl chain gives this ionic liquid less affinity for water compared to standard 1-butyl or 1-ethyl derivatives, shifting extraction profiles and supporting use in systems with organic or slightly hydrophobic substrates. This makes it crucial in catalyst immobilization, biphasic catalysis, advanced nanomaterials synthesis, and electrochemical applications where a careful match between solubility and selectivity enables breakthrough results.

    Our customers regularly report higher yields and cleaner product isolation using this ionic liquid when synthesizing metal-organic frameworks or during cross-coupling reactions. Solubility levels in typical aromatics, ethers, and acetonitrile run consistent across batches, which eases batch transition planning. Viscosity remains manageable across a broad temperature range, so technicians can pump and blend without excessive heating or shear.

    In battery research, particularly in the refinement of next-generation electrolyte systems, this ionic liquid brings both high thermal resilience and a wide electrochemical window. Early data from collaborative pilot lines point to longer cycle life in lithium-ion and sodium-ion systems where [HMIM]Br helps suppress dendrite formation and electrolyte decomposition. This kind of performance does not happen by accident but stems from careful, hands-on quality discipline, clear traceability, and regular tweaking based on real-world feedback.

    Comparing with Other Ionic Liquids: Subtle Difference, Major Results

    Those new to ionic liquids might first encounter shorter-chain imidazolium salts like 1-butyl-3-methylimidazolium bromide ([BMIM]Br) or 1-ethyl-3-methylimidazolium bromide ([EMIM]Br). In practical use, the chain length matters. The extra carbons in the heptyl group impact nearly every aspect of performance. With longer chains, thermal stability slightly increases, while water uptake drops, resetting where and how this liquid fits in an application. [HMIM]Br introduces greater hydrophobicity, which shifts phase behavior, particularly in multi-solvent extractions or in highly competitive extraction environments.

    In catalysis, this means users often obtain sharper selectivity, reduced water sensitivity, and altered catalyst solubility. Product residue analysis finds less entrainment of water, translating to cleaner recoveries and scalable process development. If a project demands minimal cross-contamination between hydrophilic and hydrophobic streams, this product’s physical traits fit the bill.

    Price per kilogram can vary compared to shorter-chain analogs, reflecting higher input costs in synthesis and extra attention during purification. In most pilot and commercial workflows, the small increase in purchasing cost gets balanced out by less loss to waste streams, reduced need for corrective purification, or higher catalyst recovery rates. We avoid over-simplifying those differences—our clients benefit from real-case sharing and close cycle yield tracking.

    Production Practices: From Lab Bench to Ton-Scale Facilities

    From research bench blends to drum lots for pilot plants, our equipment and staff meet the needs for any volume. The reaction pathway follows a clean N-alkylation, using heptyl halide and methylimidazole under monitored, closed conditions. Purification draws on solid-liquid separation, seed crystallization, and iterative solvent wash. All solvents used in washing and finishing undergo full recovery and recycling on site, which cuts environmental load and lessens cross-sample impurities in the finished product.

    We document every step. QA staff review every spectroscopic result and record storage time, owner, and container code. If any bottle shows drift in pH, melting point, or halide ratio on retest, we pull and rescrub the affected lot. Our facility stays open to third-party inspections, and welcome auditing teams. During scale-up, process engineers adjust holding temperatures, cooling intervals, and drying times based on the data from full reactor runs, not only lab samples.

    Because this product appeals to both research chemists and process engineers, we keep a standing stock ready for delivery—no long pauses waiting on production cycles. For larger orders, we ship in lined high-density polyethylene drums to prevent contamination or moisture ingress. Custom volumes and packaging formats only move forward after consultation with end users, so compatibility headaches or unexpected transfer losses don’t appear down the line.

    Supporting Responsible Use: Health, Safety, and Environmental Perspective

    Direct handling of 1-Heptyl-3-Methylimidazolium Bromide takes experience and observation. While it offers lower volatility and flammability than traditional organic solvents, operators still must take standard chemical hygiene measures. Our on-site experience clearly shows exposure issues arise from splash events or careless decanting during high throughput. We reinforce proper PPE use and provide technical support for process safety planning.

    We take solvent and byproduct handling seriously. Every waste stream from synthesis or downstream operations routes back through filtration and solvent reclamation units. Analytical checks detect improper discharge before it happens, so we avoid halide contamination outside our fence line. Research users—both academic and commercial—have repeatedly found that our transparency in declaring trace impurities, including residual heptyl halide, reduces unnecessary retesting downstream. No batch ships without a clear impurity and moisture profile.

    On the environmental impact side, we build protocols around full compliance and reduction strategies, not just meeting minimum thresholds. This includes process solvent lifecycle analysis, full chain of custody on chemical reagents, and support for returnable containers. Most importantly, our records allow end users to look back through the entire journey of each drum or bottle, supporting any needed investigation or improvement effort.

    Ongoing Innovation: Meeting Today’s and Tomorrow’s Requirements

    Recent years have seen 1-Heptyl-3-Methylimidazolium Bromide gain traction in green chemistry, recycling, and new battery chemistries. These areas demand reliable, clean input that doesn’t introduce side products or degrade under mild thermal cycling. Our close work with university and industrial research groups has led to tailored blends and faster screening of new process routes. Chemists want results quickly—the wrong impurity or water content can bring hours, days, or weeks of lost work. That reality keeps our technical teams focused on rapid feedback, open dialogue on emerging needs, and flexible response to novel requests.

    It isn’t just about delivering a bottle or a drum. We maintain ongoing communication with users through technical forums, site visits, and knowledge sharing. That means problems get solved in real time, and efficiency gains from innovative applications flow back to both sides. Process improvement feedback from actual users, not just internal labs, guides monthly reviews and new investments in our facilities.

    Looking Forward

    Interest in sustainable and specialty solvent systems increases year by year. More firms discover that short-term price focus doesn’t match the overall benefit of predictably-performing materials. Our feedback network learns from every production batch and user report—creating a cycle where every improvement reduces downtime, shrinkage, and batch failures. As more fields, from microelectronics to advanced manufacturing and recycling, search for alternatives to volatile or toxic solvents, 1-Heptyl-3-Methylimidazolium Bromide stands ready for adaptation—supported by a team that understands the chemistry and the human impact of every kilo delivered.

    Through years of hands-on work and open feedback channels, we’ve found that shared knowledge and product transparency deliver the strongest results both for our partners and our own operations. In the world of ionic liquids, details determine outcomes. From careful synthesis to end-user application, we make certain that every container reflects the effort and skill built into every stage of development.