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1-Ethyl-3-Methylimidazolium Chloride-Aluminum

    • Product Name 1-Ethyl-3-Methylimidazolium Chloride-Aluminum
    • Alias EMIMCl–AlCl3
    • Einecs 639-514-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    115081

    Chemical Name 1-Ethyl-3-Methylimidazolium Chloride-Aluminum
    Abbreviation [EMIM]Cl-AlCl3
    Appearance Colorless to pale yellow liquid
    Molecular Formula C6H11N2Cl-AlCl3 (varies with composition)
    Molar Mass Depends on AlCl3 proportion; base [EMIM]Cl is 146.62 g/mol
    Melting Point Ambient to below 0°C (depends on AlCl3 ratio)
    Density Approximately 1.1–1.3 g/cm³
    Conductivity High ionic conductivity, ~10⁻³ – 10⁻² S/cm
    Viscosity Moderate to high, typically 50–200 cP at room temperature
    Solubility Miscible with polar solvents, hygroscopic
    Color Colorless to yellowish
    Main Uses Electrolytes in batteries, electrodeposition, catalysis

    As an accredited 1-Ethyl-3-Methylimidazolium Chloride-Aluminum factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1 kg of 1-Ethyl-3-Methylimidazolium Chloride-Aluminum is packaged in a tightly sealed, amber glass bottle with hazard labeling.
    Shipping 1-Ethyl-3-Methylimidazolium Chloride-Aluminum is typically shipped in tightly sealed, chemical-resistant containers to prevent moisture and air exposure. The packaging must be clearly labeled with hazard and handling information. It should be transported in compliance with relevant regulations, ensuring protection from physical damage and temperature extremes during transit.
    Storage 1-Ethyl-3-Methylimidazolium Chloride-Aluminum should be stored in a cool, dry, and well-ventilated area, away from moisture, heat, and incompatible substances such as strong oxidizers. Keep the container tightly closed and protected from air exposure. Use suitable, labeled chemical-resistant containers. Store in accordance with local regulations and Material Safety Data Sheet (MSDS) recommendations. Handle with appropriate personal protective equipment.
    Application of 1-Ethyl-3-Methylimidazolium Chloride-Aluminum

    Applications of 1-Ethyl-3-Methylimidazolium Chloride-Aluminum in Industrial Manufacturing

    1-Ethyl-3-Methylimidazolium Chloride-Aluminum (EMImCl-AlCl3) has become integral in several advanced chemical manufacturing sectors due to its unique ionic liquid properties, high thermal stability, and exceptional electrochemical performance. Our manufacturing expertise and strict process controls ensure that every batch meets the stringent requirements of downstream users who incorporate this material into differentiated production environments.

    1. Aluminum Electroplating for Corrosion-Resistant Metal Components

    Manufacturers use EMImCl-AlCl3 as an ionic liquid electrolyte in non-aqueous aluminum electrodeposition processes. This approach produces highly uniform, adherent aluminum coatings on complex geometries and ferrous substrates, specifically demanded by the aerospace, automotive, and electronics sectors for superior corrosion protection. The product’s performance allows precise management of layer thickness, improved surface morphology, and minimal hydrogen embrittlement compared to aqueous electrolytes.

    Industry compliance standards

    • SAE AMS 2469 (Electroplated Aluminum for Corrosion Protection)
    • ASTM B253 (Standard Guide for Preparation of Aluminum Alloys for Electroplating)
    • ISO 4527 (Metallic Coatings—Electroplated Coatings of Aluminum)

    Typical usage ratio

    • EMImCl-AlCl3 is formulated at a molar ratio of 1:1.5 to 1:2.2 aluminum chloride to EMImCl, with adjustments based on bath temperature (80–120°C) and deposition current density (2–10 mA/cm2).

    Downstream process integration

    • Users introduce the ionic liquid electrolyte into dedicated electrodeposition baths after pre-cleaning and degreasing components. Bath composition and agitation ensure consistent ion transport during the plating cycle.

    Final product types

    • High-reliability connectors for aerospace wiring harnesses
    • Automotive fuel system components
    • Electronic device casings requiring EMI shielding
    • Precision fasteners used in corrosive marine environments

    2. Catalytic Alkylation in Pharmaceutical Fine Chemicals

    Process engineers utilize EMImCl-AlCl3 as a chlorometallate ionic liquid catalyst in Friedel-Crafts alkylation for the synthesis of complex aromatic pharmaceutical intermediates. The catalyst offers strong Lewis acidity under mild conditions, allowing site-selective functionalization and decreasing the formation of undesired by-products compared to traditional liquid AlCl3 systems. Its recyclability and ease of separation contribute to process intensification and alignment with green chemistry protocols.

    Industry compliance standards

    • ICH Q7 (Good Manufacturing Practice for Active Pharmaceutical Ingredients)
    • 21 CFR Part 211 (US cGMP for Finished Pharmaceuticals)
    • EU GMP Volume 4, Part II (Guidelines for APIs in Europe)
    • REACH Regulation (EC) No 1907/2006

    Typical usage ratio

    • Usage ranges from 5–15 mol% catalyst loading relative to limiting substrate, with adjustment for aromatic ring reactivity and desired conversion/purity profiles.

    Downstream process integration

    • Users introduce the ionic liquid catalyst at the start of the alkylation reaction within jacketed glass reactors or stainless systems, providing continuous stirring and in-line separation after reaction completion.

    Final product types

    • Intermediates for antihistamine actives (e.g., alkylated benzene derivatives)
    • Precursors for antipsychotic APIs
    • Pharmaceutical-grade aromatic ketones
    • Fine chemical building blocks for contract manufacturing

    3. Advanced Lithium-Ion Battery Electrolyte Systems

    Cell manufacturers blend EMImCl-AlCl3 as a non-flammable ionic liquid co-solvent and aluminum source in advanced lithium-ion battery electrolyte formulations. This material improves ionic conductivity, suppresses dendrite formation, and broadens thermal operating windows. Producers especially favor the formulation in next-generation high-capacity anode chemistries, such as lithium metal and silicon-dominant cells, where stable solid-electrolyte interfaces are critical.

    Industry compliance standards

    • IEC 62660-2 (Safety performance testing for lithium-ion cells)
    • UN 38.3 (Transport of Dangerous Goods for Batteries)
    • GB/T 31485-2015 (China Safety Requirements for Power Batteries)
    • ISO 9001:2015 (Quality Management Systems for Battery Manufacturing)

    Typical usage ratio

    • Blended at 10–30% by mass in the total electrolyte mixture, with precise levels determined by cell capacity targets, separator compatibility, and required cycle life benchmarks.

    Downstream process integration

    • Incorporated during the electrolyte mixing stage under dry-room or controlled-atmosphere conditions to avoid hydrolysis. The resulting electrolyte solution is injected into assembled cells before electrolyte soaking and cell formation.

    Final product types

    • High-energy density pouch cells
    • Automotive high-power battery modules
    • Stationary grid storage battery packs
    • Battery systems for portable medical devices

    4. Chloride-Based Zeolite Synthesis for Petrochemicals

    EMImCl-AlCl3 functions as a chloride ion template and mineralizing agent during hydrothermal synthesis of specific zeolite frameworks required for FCC catalysts in the petrochemical industry. This ionic liquid route enables crystallization control and template removal at lower temperatures, resulting in zeolites with tailored pore structures and improved catalytic efficiency for feedstock cracking and isomerization processes.

    Industry compliance standards

    • API RP 751 (Safe Operation of Hydrofluoric Acid Alkylation Units)
    • ISO 9001:2015 (Catalyst Quality Systems)
    • EU Directive 2010/75/EU (Industrial Emissions for Catalyst Production)
    • REACH compliance for imported feedstocks

    Typical usage ratio

    • Introduced at 3–10% by mass relative to aluminosilicate source, with precise dosing determined by targeted pore size, framework topology, and hydrothermal processing parameters.

    Downstream process integration

    • Added during the zeolite hydrothermal synthesis stage in stirred reactors, maintained under controlled pH, pressure, and temperature to direct crystal growth before template removal.

    Final product types

    • Fluid catalytic cracking (FCC) catalysts for refineries
    • Hydrocracking catalysts with customized acidity
    • Zeolitic adsorbents for gas purification
    • Shape-selective catalyst pellets for alkylation

    5. Electrosynthesis of High-Purity Aluminum Metal

    Producers employ EMImCl-AlCl3 as a low-melting-point liquid electrolyte for the room-temperature electrodeposition of high-purity aluminum metal. This process offers a pathway to produce ultra-pure aluminum foils and wires used in electronics, optical reflectors, and aerospace microfabrication, reducing the environmental impact compared to traditional Hall-Héroult electrolysis methods requiring high temperatures and cryolite.

    Industry compliance standards

    • ASTM B921/B921M (Standard Specification for Metal Foil and Thin Sheet)
    • IEC 61340-5-1 (Electrostatic Protection for Aluminum Components)
    • ISO 14001:2015 (Environmental Management in Metal Production)

    Typical usage ratio

    • Molar composition maintained at 1:1.7–2.0 AlCl3 to EMImCl, with adjustment for target deposition thickness (5–100 µm) and current efficiency.

    Downstream process integration

    • Electrolyte is loaded into sealed electrodeposition cells, followed by controlled current application and in situ monitoring of deposited layer purity by inductively coupled plasma analysis.

    Final product types

    • Semiconductor-grade aluminum foil
    • Ultra-fine aluminum wires for microelectronic interconnects
    • Reflector films for optical assemblies
    • Specialty layers in aerospace sensor devices
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    Certification & Compliance
    More Introduction

    Introducing 1-Ethyl-3-Methylimidazolium Chloride-Aluminum: A Closer Look from the Manufacturer’s Perspective

    Understanding What Sets 1-Ethyl-3-Methylimidazolium Chloride-Aluminum Apart

    Today’s chemical industry navigates increasing demands for reliable, high-performance materials. At our facility, we put decades of experience into crafting 1-Ethyl-3-Methylimidazolium Chloride-Aluminum. It stands out in the family of ionic liquids for its stability, conductivity, and room-temperature ionic nature. Each batch is produced with the same precision, whether destined for a pilot research project or scaled industrial runs. Compared with diluted commercial blends or basic room temperature ionic liquids, this compound holds its unique place thanks to a tightly controlled manufacturing process and honed synthesis methods that reflect years of accumulated know-how across hundreds of processes and applications.

    Our Focus on Model and Specifications

    This product, sometimes identified by the code EMIC-AlCl3, follows a specific molar ratio between the organic cation and anhydrous aluminum chloride. Chemical producers sometimes treat this as a simple mixture, but the real magic comes from maintaining exacting ratios, which impact everything from viscosity to electrochemical stability. We keep water content extremely low, as trace water disrupts intended reaction profiles and can create corrosivity risks in finished systems. Our in-house instrumentation tracks every step, ensuring chloride, cation, and Lewis acid levels meet the agreed spec.

    Material purity forms the backbone of our manufacturing model. Trace metals, residual solvents, and organic byproducts influence downstream performance in batteries, electroplating, or related catalytic systems. We routinely analyze for sub-ppm impurities with ICP-MS and NMR, since overlooked contaminants wreak havoc in high-precision applications. Our facilities are equipped to handle the chemical’s air-sensitive nature, right through to air-tight packaging and climate-controlled storage. Over the years, our team invested in containment solutions that streamline filling and minimize worker exposure—practices not always present in smaller-scale or lab-only producers.

    Application: Going Beyond the Surface

    Customers approach us when they need a high-performing, metal-containing ionic liquid for more than just solvent properties. 1-Ethyl-3-Methylimidazolium Chloride-Aluminum functions as both an electrolyte and a Lewis acid catalyst. In aluminum battery research, for example, performance swings significantly based on compound integrity. One client recently improved cell cycling and energy density by fine-tuning the molar composition within our recommended process window, eliminating spurious side reactions and cathode passivation. Our technical support team often walks partners through parameter tweaks—from current density to bath composition—which helps close the gap between academic results and scaled pilot lines.

    When researchers in electroplating or surface finishing needed finer deposit control, our refined EMIC-AlCl3 blends reduced nodular growth and produced brighter, more uniform coatings. Laboratory tests across several years made clear that higher chloride ratios boost deposition rates but may compromise corrosion resistance without correct post-treatments. By drawing on real-world use feedback, our plant can adjust blending protocols or recommend pretreatments that fit those needs. Synergy between our technical bench and customer input lets us see challenges before they translate into lost time on the shop floor.

    Comparing with Other Ionic Liquids: Decoding the Differences

    Every ionic liquid in our product catalog carries different strengths, but EMIC-AlCl3 anchors unique capacities. Traditional imidazolium-based ionic liquids—for example, BMIM-PF6 or EMIM-BF4—lack the Lewis acidity and aluminum complexation properties that drive electrochemical utility. On the other extreme, some aluminum chloride–based systems miss the air-stability and convenience of handling delivered by our formulation. Many resellers overlook the fact that shelf-stability depends on packaging quality and precise molar ratios. We overcome this through tailored synthesis, inert-gas handling, and packaging protocols developed after observing years of field returns and customer obstacles.

    Colleagues across electrochemistry often mention batch-to-batch variability in market samples from other sources—issues such as yellowing, phase separation, or volatility. Our team’s direct control over feedstocks and real-time process monitoring eliminates these interruptions. For customers who scale up from grams to hundreds of kilograms, shipping large volumes brings its own risks of stratification and degradation. We invest in quality testing not just at the production step, but as material leaves our facility, limiting surprises upon arrival. Reports of instability in competitor products typically point to compromised molarity or residual contaminants—a problem much less likely with our direct-from-manufacturer system.

    Handling, Storage, and Real-World Learnings

    Any air- or moisture-sensitive ionic liquid expects a measured approach to storage and use. From our earliest days producing EMIC-AlCl3, we learned the value of providing customers with direct storage advice—airtight vessels, low humidity environments, and oxygen exclusion become standard. Watching customers worldwide adapt their own storage regimes, we know that carrier gases like dry nitrogen help, but user vigilance goes further. We ship with clear labeling, batch-specific analysis, and comprehensive paperwork, much of which evolved after feedback from industrial customers running 24/7 operations under tight performance tolerances.

    Our operators have seen firsthand how improper handling saps long-term utility from a well-prepared batch. By encouraging users to decant under inert conditions, avoid unnecessary transfers, and monitor viscosity changes, we extend the working life of each container. Problems like unwanted polymerization or darkening only developed in facilities lacking appropriate protocols and staff training, leading us to offer additional on-site guidance for critical users. For handling rare spills or containment events—whether in warehousing or research—our own plant safety drills have shaped how we guide customers through mitigation and clean-up, leaning on real incident reports and not just textbook theory.

    Production Challenges and Solutions Born from Experience

    Scaling the manufacture of EMIC-AlCl3 brought its share of surprises. Early efforts faced issues with heat management during aluminum chloride addition—exothermic reactions caused local hot spots, sometimes leading to byproduct formation. Over multiple cycles, our process engineers re-designed reactor configuration and agitation patterns, enabling uniform mixing without localized overheating. Realizing the sensitivity of the AlCl3 moiety to trace impurities, we switched to double-distilled precursors and introduced in-line monitoring for each critical quality attribute. These changes transformed what was once a finicky lab product into a reliable industrial raw material.

    Many in the industry still produce at small lab scales, limiting their capacity to guarantee consistency at higher throughputs. By investing in semi-automated reactors and purpose-built cleanrooms, we've been able to drive efficiency without sacrificing product quality. Production runs are halted immediately if deviation is seen in inline analytics, and every flask or drum receives a lot code for complete backward traceability. This ongoing vigilance helps us address downstream customer questions about batch variability or anomalous behaviors in use.

    There’s also the matter of environmental responsibility. Ionic liquids enjoy a reputation for “green chemistry,” but end-of-life disposal and waste minimization remain top priorities for manufacturers. Through careful selection of recyclable packaging and continuous investment in closed-loop waste handling, we reduce impacts from both spent product and wash streams. In speaking with regulatory authorities, we made a point of transparently reporting solvent use and process emissions. As new compliance rules arise, we adjust workflow rather than waiting for penalties or environmental reviews.

    Supporting Innovation: Why Direct Manufacture Matters

    In working directly with product developers and process engineers, we’ve learned that communication clears up more issues than blind adherence to datasheet specs. Our technical staff spends time understanding the details of each partner’s process: agitation profiles in large plating baths, target ash levels for catalyst regeneration, conductivity requirements in experimental batteries. Sometimes customers walk through the plant floor and see the difference between a manufacturer’s approach and material simply relabeled from elsewhere. We value their questions, since those insights drive continuous process improvement in formulation and finishing.

    Without direct control over synthesis, it’s almost impossible to accommodate experimental requests—minor adjustments in cation ratio, modification of chloride content, or substitution of non-standard precursors for regulatory reasons. Because EMIC-AlCl3 is so chemically sensitive, even small adjustments in the synthesis route or raw material choice can yield large performance swings in complex applications. Direct communication lets us tailor product slightly outside standard ranges, giving R&D and pilot lines a leg up in solving unique engineering challenges.

    Researchers sometimes share data on unexpected outcomes—chromatic shifts, precipitate formation, or short circuiting in energy storage cells. Through systematic process review and small-batch reproductions, we’ve tracked causes to trace contaminants, improper thermal management, or storage abnormalities. Because our production team and technical support are under one roof, corrective actions move quickly from feedback to implementation.

    Meeting Demands of Advanced Manufacturing and Research

    Today’s demand for EMIC-AlCl3 touches markets from next-generation batteries and supercapacitors to corrosion-resistant aluminum coatings. Our client base drives home that specifications on paper rarely account for site-specific needs: one partner requires high purity for semiconductor electroplating, while another prioritizes relaxed cost targets for scale-up feasibility. Having manufactured and refined this product through multiple generations of equipment and chemical regulations, we keep records on how specific tolerances influence end results—from yield rate to waste formation and environmental hazard scores.

    One emerging area involves hybrid aluminum battery cells, where engineers combine EMIC-AlCl3 with organic co-solvents for performance tweaking. Materials processed in uncontrolled or impure states usually shut down pilot lines through premature passivation or reduced current density. By collaborating directly with technical buyers, we supply demonstration quantities that match commercial scale—no unexpected phase splits or color instability—supporting trouble-free tech transfer from lab to plant. In feedback meetings, users have pointed out that manufacturer-direct product smooths development cycles, compared to buying from brokers with mismatched documentation or dubious cold-chain reliability.

    Safety, Compliance, and Forward-Looking Practices

    Experience manufacturing EMIC-AlCl3 taught us that safe production and handling require commitment rather than checkbox compliance. Our safety team receives regular hazardous handling training; incident drills are based on documented plant events, not simply generic guidelines. Regular air monitoring, specialty PPE, and fast-acting containment units support a culture where every worker feels responsible for both their own safety and the integrity of the batch. Unexpected events—spills, container failures, or power outages—have all shaped our protocols. We encourage customers to apply similar rigor, supported by our hazard assessments and hands-on demonstrations.

    Environmental stewardship forms another major focus. We developed solvent capture and neutralization systems after reviewing industry best practices and seeing waste reduction in action at leading facilities overseas. Regular audits and process optimizations feed into our continuous improvement plans, and lessons from real-world production incidents or near-misses inform future upgrades. Large-scale buyers increasingly demand transparency about material origin, compliance with evolving legislation, and end-to-end emissions accounting. Having already implemented many of these features, our plant navigates audits and supply chain reviews with minimal disruption.

    Looking to the Future: Continuous Improvement Through Collaboration

    Every year brings new technical requests and regulatory hurdles. As the direct manufacturer of 1-Ethyl-3-Methylimidazolium Chloride-Aluminum, we track these trends and invest in both improved people and process. Customers’ needs for lower impurity levels, more stable packaging, and greater environmental responsibility push us to conduct long-term storage tests, invest in advanced analytics, and consult with authorities about evolving restrictions on raw materials and product documentation. Several years ago, a shift in global supply for precursor chemicals prompted us to qualify secondary sources—and our investment in multi-stage QA/validation meant no dips in delivered product.

    Innovative customers regularly challenge our assumptions and expose blind spots, whether in electrolyte benchmarking studies or through failure analysis in corrosion labs. In response, our R&D group does more than replicate standard tests—they expand into emerging user concerns like recycling of spent ionic liquid, closed-circuit circularity strategies, and more universal compatibility with dry-room production lines. We’ve run pilot trials in partnership with forward-looking tech firms, sometimes adjusting production or post-treatment protocols for entirely new target markets. These partnerships ultimately strengthen product quality and customer trust.

    Real Expertise, Direct Accountability

    We know the limitations of EMIC-AlCl3 as well as its possibilities. Technical support, continuous investment in manufacturing improvements, and monitoring global regulatory changes ensure our product keeps pace with evolving needs in electrochemistry, catalysis, and related industries. The value we add as a direct manufacturer doesn’t just come from stable supply—it comes from open dialogue, attention to user feedback, and ongoing progress in safety and environmental responsibility. Our product is shaped as much by end-user requirements as by raw material chemistry, and we respond in real time to ensure the next batch always performs as expected.