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1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    • Product Name 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
    • Alias [EMMIM][TFSI]
    • Einecs 700-526-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    743155

    Chemical Name 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide
    Abbreviation EMMIM TFSI
    Molecular Formula C11H15F6N3O4S2
    Molar Mass 447.38 g/mol
    Appearance colorless to pale yellow liquid
    Melting Point -8 °C
    Boiling Point Decomposes before boiling
    Density 1.43 g/cm3 (at 25 °C)
    Solubility miscible with water and most organic solvents
    Cas Number 508155-80-4
    Purity ≥99%
    Category ionic liquid
    Conductivity 4.2 mS/cm (at 25 °C)
    Viscosity 42 cP (at 25 °C)
    Thermal Stability up to ~350 °C

    As an accredited 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Amber glass bottle, 100 grams, with tamper-evident screw cap and clear hazard labeling; chemical name, batch number, and safety information displayed.
    Shipping **Shipping Description:** 1-Ethyl-2,3-dimethylimidazolium bis((trifluoromethyl)sulfonyl)imide ships in airtight, chemical-resistant containers. Package complies with regulations for non-flammable ionic liquids. Protect from excessive heat, moisture, and physical damage. Transport in accordance with DOT, IATA, and IMDG guidelines. Safety documentation and labeling provided. Store upright and handle with appropriate personal protective equipment (PPE).
    Storage Store 1-Ethyl-2,3-dimethylimidazolium bis((trifluoromethyl)sulfonyl)imide in a tightly sealed container, in a cool, dry, and well-ventilated area, away from moisture, heat, and incompatible substances such as strong oxidizers. Avoid exposure to direct sunlight. Ensure that appropriate safety measures, such as secondary containment and labeling, are in place to prevent leaks and accidental exposure.
    Application of 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    Applications of 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide in Industrial Manufacturing

    As the direct producer, we supply 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide to global industrial clients who require high-performance ionic liquids for critical chemical processes. The following application scenarios represent real downstream use-cases in various high-tech sectors, each with specific processing protocols and compliance needs.

    1. Electrolyte Component for Advanced Lithium Battery Production

    Manufacturers in the energy storage sector incorporate this ionic liquid as a non-flammable, high electrochemical stability electrolyte in lithium ion and solid-state battery cells. The product serves in next-generation battery designs to increase ionic conductivity, thermal safety, and cycle life, supporting the manufacturing of cells for electric vehicles and stationary power storage. Producers can tune ratios for compatibility with lithium salts and cathode/anode chemistries during assembly, leveraging its low viscosity and wide electrochemical window for precise cell engineering.

    Industry compliance standards

    • UL 2580: Batteries for Use in Electric Vehicles
    • IEC 62660-2: Secondary lithium-ion cells for automotive applications
    • ISO 9001: Quality management for battery manufacturing
    • REACH Regulation (EU) 1907/2006 for safe chemical management

    Typical usage ratio

    • 5-30% by volume in mixed electrolyte formulations
    • Adjusted based on anode/cathode pair, target conductivity, and flammability limits
    • May include up to 20% as co-solvent with conventional carbonates
    • Final loading determined through pilot cell assembly and QC validation

    Downstream process integration

    • Added during the electrolyte solution preparation, after purification
    • Blended before or during cell soaking step in pouch, cylindrical, or prismatic battery lines
    • Monitored via GC and Karl Fischer titration for moisture and purity prior to sealing
    • Integrated with automated cell filling equipment in dry room environments

    Final product types

    • EV traction batteries (NMC, LFP, NCA chemistries)
    • Home and grid energy storage battery modules
    • High-rate pouch and cylindrical lithium rechargeable batteries
    • Solid-state lithium batteries for electronics

    2. Reaction Medium for Pharmaceutical Synthesis

    This ionic liquid plays a key role as an alternative reaction solvent in API and fine chemical synthesis, notably in challenging alkylation, acylation, and cross-coupling steps where conventional solvents pose selectivity or waste management issues. It enables manufacturers to boost yield, manage exothermic reactions, and simplify downstream purification in scalable batch or flow reactor formats used for registered pharmaceutical intermediates.

    Industry compliance standards

    • ICH Q7: Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • 21 CFR Part 211: cGMP for finished pharmaceuticals
    • Ph. Eur. 5.4: Residual solvents in pharmaceuticals
    • Local EPA and EU ECHA solvent waste guidelines

    Typical usage ratio

    • 10-60% by volume as direct solvent or co-solvent in reaction mixtures
    • Ratio determined by substrate solubility, temperature profile, and product isolation requirements
    • Lower ratios for high-purity multi-step syntheses; higher when used to replace traditional aprotic solvents
    • Recovered and recycled after extraction where permitted by validation protocols

    Downstream process integration

    • Charged to jacketed glass-lined or stainless flow reactors prior to substrate addition
    • Interface with automated weighing, dosing, and solvent recovery systems
    • Purity monitored by HPLC and Karl Fischer titration to minimize residual solvent risks
    • Facilitates post-reaction separation by phase disengagement or extractive workup

    Final product types

    • Registered pharmaceutical intermediates (RPI)
    • High-value bulk APIs with complex heterocyclic structures
    • Specialty fine chemicals for contract manufacturing organizations (CMOs)
    • Industrial-scale synthesis of key catalyst ligands

    3. Electroplating and Surface Finishing Additive

    In the electronics and precision metal industries, downstream users employ this ionic liquid as a conductive electrolyte and surface tension modifier in electroplating on copper, gold, nickel, and specialty alloy substrates. It improves metal deposit morphology, controls crystal grain size, and reduces hydrogen embrittlement, all while complying with tight purity controls for semiconductor or printed circuit board (PCB) metallization.

    Industry compliance standards

    • IPC-6012: Qualification and Performance Specification for Rigid Printed Boards
    • IEC 61249: Base materials for printed boards (lead/halogen-free)
    • ISO 14001: Environmental Management for Metal Surface Finishing
    • RoHS 2011/65/EU: Restriction of Hazardous Substances in Electrical and Electronic Equipment

    Typical usage ratio

    • 2-20% by weight in aqueous or organic bath solutions
    • Adjusted based on target deposit thickness and desired grain size
    • Lower loading for semiconductor and thin-film metallization
    • Up to 15% with copper or nickel sulfate for multilayer circuit applications

    Downstream process integration

    • Dosed during make-up of electroplating bath under nitrogen protection
    • Recirculated through in-line filtration and vibration-resistant pumps
    • Bath monitored by ICP-OES for trace impurities
    • Residue removal steps introduced during post-plating rinsing and drying

    Final product types

    • Microelectronic device substrates (IC leadframes, MEMS wafer contacts)
    • High-density PCB metallization
    • Precision optical device coatings
    • Anti-corrosion plated automotive and aerospace connectors

    4. Solvent and Conductivity Modifier for Industrial Gas Separation Membranes

    Downstream membrane manufacturers use this ionic liquid in the casting and post-treatment of polymeric and inorganic gas separation membranes. Its physicochemical stability and ion conductivity enhance permeability and selectivity for industrial CO₂ capture, hydrogen purification, and natural gas sweetening. The material supports scale-up in both flat sheet and hollow-fiber extrusion lines, where solvent replacement and membrane durability must meet operational and regulatory objectives.

    Industry compliance standards

    • ISO 9001:2015 for quality management in membrane manufacturing
    • EN 14181: Quality assurance for continuous emission monitoring
    • ASTM F316-03: Pore size characterization for filtering membranes
    • OSHA 29 CFR 1910.119: Process Safety Management for handling of hazardous gases

    Typical usage ratio

    • 5-35% by weight in membrane dope solutions
    • Ratio varies with polymer matrix (e.g., polyimide, PEEK, PTMSP)
    • May serve as plasticizer or pore-forming agent in asymmetric membranes
    • Optimized through pilot extrusion trials and SEM imaging for surface texturing

    Downstream process integration

    • Mixed into dope tank before degassing in extrusion or casting step
    • Removed or exchanged in post-treatment depending on target permeability
    • QC by FTIR and TGA to confirm residual content in finished membrane
    • Product tracked via batch-record integration during continuous lamination

    Final product types

    • CO₂ removal membranes for power plant and biogas upgrades
    • Hydrogen and methane purification modules
    • Oxygen- or nitrogen-enriching industrial separation membranes
    • Membrane modules for petrochemical process gas recovery

    5. Heat Transfer Medium in High-Temperature Chemical Processing

    Producers of specialty polymers and fine organic chemicals select this ionic liquid as a heat transfer and reaction medium for steps requiring stability above 200°C. Its negligible vapor pressure and low flammability enable continuous operation in closed-loop systems. Process engineers employ this material during manufacturing of polyimides, aromatic ethers, and specialty electronics-grade resins requiring precise temperature control and inert reaction environment.

    Industry compliance standards

    • ISO 14644: Cleanroom and controlled environments (for electronics chemicals)
    • OSHA 1910.119: Process safety for thermal fluid systems
    • REACH compliance for high-temperature industrial fluids
    • ISO 15378: GMP for packaging materials in pharmaceutical applications

    Typical usage ratio

    • 20-100% by volume depending on heat load and scale
    • Neat use in jacketed reactor loops for continuous manufacturing
    • Diluted to 50% in energy transfer systems when blended with inert co-fluids
    • Volume verified and topped up based on scheduled preventive maintenance

    Downstream process integration

    • Charged at system start-up and recirculated through shell-and-tube exchangers
    • Monitored for degradation via GC-MS after each production lot
    • Sampled before and during each campaign for thermal stability
    • Drained and regenerated in high-purity distillation columns as needed

    Final product types

    • High-grade polyimide films
    • Electronics insulating varnishes
    • Specialty engineering plastics (PEEK, polyethersulfone)
    • Heat-resistant optical fiber coatings
    Free Quote

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    Certification & Compliance
    More Introduction

    1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide: Practical Performance in Modern Chemical Applications

    Direct Experience in Manufacturing

    Managing an ionic liquids production line demands more than technical know-how. On the floor, you notice small differences in air quality, you learn to watch for variations in viscosity during mixing, and you memorize the faint odor that signals a clean reaction. This is where we work with 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide—in the thick of real-world chemistry, not theory.

    Years ago, this compound stood out in the lab for its stability. Many may see product codes or chemical names, but what matters to us every day is the hands-on reliability it brings to synthesis and applications. Physical characteristics can shift even with minor changes in input quality, and a manufacturer notices these subtle cues before instruments do. Our people spot issues long before datasets reflect them, and we've kept scrap rates low by valuing this type of human observation.

    Precision at Each Stage

    The batch process for 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide draws on years of optimization. Over time, we've found that temperature control yields bigger savings than automation. Too much heat during the quaternization step frustrates purity targets, and colder feeds lead to cloudiness that filtration can't fix. In our factory, operators know to catch early color changes—a batch with a faint hint of yellow spells contamination, often traced back to mishandled trifluoromethylsulfonyl starting material.

    Specifications change with demand. Jobs can require tight water content, so we build drying capacity that prevents performance loss in electrochemical setups. Lab teams test actual batches for conductivity instead of trusting calculated “typical” values, which cuts out guesswork. Electrolyte production for advanced batteries uses our ionic liquid directly on the line, and we keep differences in viscosity from one batch to the next below 3%. End users notice faster charge rates and lower failure in their tests when that happens.

    Production runs for pharmaceutical applications use a different quality threshold. Some users want levels of metal contamination that only scrupulous handling of glassware can provide, so we clean and flush our equipment between jobs. Changes in the methylation pattern on the imidazolium ring produce noticeable shifts in melting points, and this model—1-Ethyl-2,3-Dimethylimidazolium—hits a window that works across several complex organic reactions without added solvents. The flexibility has come from direct requests from our partners, not from a single use-case imagined in an office.

    Distinct Performance in Application

    One of the most important lessons in bulk manufacturing is to avoid making generalizations about “ionic liquids.” This compound’s bis((trifluoromethyl)sulfonyl)imide anion sets it apart for both solubility and chemical resistance. Our counterparts in the catalyst world use this for metal complex preparation because it manages oxidative stress better than cheaper alternatives. Water and air stability can’t always be measured by shelf life—the real test comes after weeks in organic synthesis, where others break down or lose their effectiveness. Once, a customer reported persistent yield drops; our audit found moisture ingress in a competing imidazolium salt, not ours. Their fix came with a switch to our product’s hydrophobic nature.

    In industrial electrochemistry lines, minor tweaks in cation structure have led to noticeable gains in efficiency. The 1-ethyl and 2,3-dimethyl pattern provides fluidity and conductivity over a temperature range that includes sub-zero conditions. Direct feedback from international clients has confirmed that switching from common 1-butyl-3-methyl analogues resulted in fewer unwanted byproducts and less gassing in lithium cell testing. Colleagues in academic research landed on similar conclusions after seeing electrochemical windows extend by several-tenths of a volt compared to competing materials. These users demand consistency, and our records show that new customers rarely switch back once they’ve tested our model in routine setups.

    Uncoated steel and sensitive polymers struggle with strongly acidic or basic salts, but this ionic liquid leaves far less residue and does not etch equipment surfaces at the same rate. Our facility has kept reactors running for years with minimal cleaning downtime, partially attributable to the chemical profile of our ethyl-dimethyl-imidazolium compound. Every maintenance shutdown provides more evidence in favor of our formulation versus less stable, less inert options.

    Addressing Differentiation and Value

    The value in this product does not come from scale alone. Market pressure to cut costs often brings low-quality imports, which sacrifice reliability for headline specifications. Over time, we noticed patterns in customer complaints: inconsistent viscosity, trace residues that set off unwanted reactivity, and visible cloudiness or particulates. These problems rarely emerge when the full production history is traceable, and when the people running the line have chemistry backgrounds as well as mechanical skills. We do not outsource these steps; inexperience leads to errors that can ruin whole production cycles.

    In many fields—battery production, pharmaceutical intermediates, catalysis—differences between seemingly similar imidazolium salts matter. Colleagues in quality control have traced minor issues back to different alkylation patterns. Only the 1-ethyl-2,3-dimethyl combination avoids phase separation in specific solvents or prevents caking at subzero temperatures without additives. The inclusion of bis((trifluoromethyl)sulfonyl)imide anion, which we synthesize in-house, reduces the risk of ionic exchange and contamination, giving downstream users an extra margin of safety in sensitive applications. These performance differences do not appear in generic summaries or spec sheets, but grow obvious during use—yield improvements and reduced equipment fouling tell the story better than sales language.

    Competitors may offer a range of “comparable” imidazolium variants. We’ve benchmarked ours time and again. For handling, workers prefer our batches because chemical fingerprints (odor, color, and physical feel) stay within a predictable range—and consistency beats novelty every time in production management. Sampling and shipment are quick because on-site teams respond directly to requests. Any sign of off-quality leads to immediate re-testing and adjustment, not paperwork or delay.

    Safety and Environmental Reality

    Anybody can claim green chemistry credentials. Day after day, our operators handle both benefits and challenges first-hand. Many customers cite ionic liquids as green solvents, but in reality, handling and disposal protocols demand strict adherence to safety routines. Our site updates employee training each quarter, and monitors air quality continuously in production spaces. There has never been a perfect chemical, but this compound allows us to reuse equipment longer due to very low corrosivity, and has not shown the environmental persistence or aquatic toxicity found in some early-generation ionic liquids. Actual spill records and emissions samples confirm the product remains contained when good practice is followed, and regular audits by local regulators validate our approach.

    On waste minimization, internal recycling systems capture virtually all side streams, either reprocessing leftovers for future batches or scrubbing residues out before discharge. Constant review and honest reporting have driven several changes in our process—wastewater from imide synthesis lines used to spike periodically in fluorine content, but after a process overhaul three years ago, those incidents dropped below quantifiable levels. Our operational records tell the story of both pressure and progress. Year-to-year, compliance costs rise, but so does process transparency and trust from downstream users. We know real progress in green chemistry takes sustained investment as much as smart design; that understanding steers our policy and shapes the daily work here.

    Listening to End Users and Supporting Discovery

    Most improvements in our product’s performance came from end users, not R&D alone. Over the last decade, customers have approached us with requests to tune water content, offer specific packaging, or make adjustments for cleanroom compatibility. Our technical staff respond directly, and factory-floor feedback loops to management weekly. That prevents the typical “black box” manufacturing problems that arise at large chemical sites. By fostering direct dialogue, the team solved a common issue—short shelf life in high-humidity climates—by refining drying and packaging in response to feedback from Asia-Pacific clients.

    Collaborators in energy storage research have worked closely with us to evaluate impacts on charge cycle longevity and system compatibility. At their request, we began tracking shelf life under load and sample aging more closely than before. That discipline has reduced warranty claims and product returns for both us and our partners. Several university groups sent technical reports on performance degradation with similar ionic liquids in heavy salt-loading regimes. After hearing their findings, we modified synthetic sequences to eliminate side-chain impurities. The outcome showed up in panel tests months before we would have caught it in standard QC runs.

    This shared process of iteration benefits every user. When researchers need to balance viscosity, ionic conductivity, and solvent miscibility, our technical documentation and batch archives help them avoid known pitfalls. Experience with scale brings confidence: customers receive direct access to best practice insights, and we learn just as much from their troubleshooting as from in-house trials. That give-and-take keeps our product evolving alongside real-world advances.

    Challenges That Shape Our Work

    Running a chemical manufacturing operation provides ample proof that progress succeeds practical improvement, not overnight breakthrough. Transport safety presents a constant concern, particularly as regulations on fluorinated compounds tighten worldwide. In the last year, two major logistics partners rewrote compatibility lists, forcing us to rethink our shipment procedures. We responded with upgraded leakproof packaging verified by independent testers. In the short run, that required heavier capsules and raised costs. But shipping records now show fewer delays and no product losses over the last three quarters.

    Supply security has always challenged our field, especially for critical building blocks like trifluoromethanesulfonyl imide. Sourcing these core materials at scale during global chemical shortages took personal negotiation and months of contingency planning. Our leadership values transparent supplier relationships and builds redundancy into the supply chain, drawing on years of experience. Instead of buying only on price, we prioritize consistency. This approach kept our clients in operation during recent global interruptions, even as competitors were forced to ration or delay shipments. These lessons spur ongoing reviews and forward contracts—no shortcut replaces the diligence learned while riding through difficult times.

    Another pressing challenge sits inside the plant, not just outside. Laboratory-scale success rarely translates directly to the plant floor. Scale-up often exposes new forms of fouling, unanticipated heat evolution, or process bottlenecks. The most recent round of in-house investment improved filtration and drying throughput, reducing batch turnaround by two days. We document every setback and improvement in detailed logs. New hires spend the first months learning from old mishaps as much as standard operating procedures.

    Constant Development and Trust

    Trust builds in hundreds of small choices: double-checking sample vials before delivery, keeping critical equipment maintained, maintaining open records of both successes and issues. Over several decades, we’ve shared technical guidance with partners in battery manufacturing, chemical synthesis, and extraction. Many have visited our site to see the work—no script covers those visits, only transparency and dialogue. That engagement forges reliability and shapes product details in real time.

    The compound’s balanced design—ethyl and methyl groups lending fluidity, a robust imide anion for chemical and thermal stability—delivers day after day in unpredictable, high-stress applications. Users in process scale-up don’t ask for “potential.” Instead, they tell us about the problems this compound actually solves: fewer system failures, longer run times, easier recovery after process upsets. These are the measures of value that matter outside theory.

    We continue to refine and adapt production as stricter standards shape international markets. Each new requirement—stricter moisture limits, new contaminant watchlists, more granular batch traceability—pushes our team to invent, not just maintain. We approach change as a partner to customers rather than an obstacle.

    Real-World Outcomes and Future of 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide

    Our history with 1-Ethyl-2,3-Dimethylimidazolium Bis((Trifluoromethyl)Sulfonyl)Imide traces real performance, from factory to field. Colleagues in battery research keep asking how to push energy density; catalyst manufacturers need longer equipment life. Data from use cases give us honest feedback. Manufacturing experience shapes the edges of every batch, and site visits from technical partners drive applied improvement—not marketing slogans.

    We watch the market and lead informed by the merits of practical results. Regulatory environments and global supply pressure challenge production, but they also sharpen standards and inspire invention. Ongoing technical dialogue among our experts, customers, and independent researchers drives the steady evolution of the product—leaner, safer, and more effective each year. Our ongoing investment in people and systems, not shortcuts or risky outsourcing, assures that our material stands up to critical scrutiny year after year, across industries and continents.

    We welcome direct input from partners, because every observation or unusual result often leads to long-term process gains or new applications. In this field, trust and shared results count most; products live or die according to their delivered performance. Our story isn't written in generic features or catalog descriptions, but in the work and discovery of people on both sides of the supply chain who know what's needed, what works, and what should improve next.