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1-Chlorododecane

    • Product Name 1-Chlorododecane
    • Alias dodecyl chloride
    • Einecs 212-221-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    427981

    Cas Number 112-52-7
    Molecular Formula C12H25Cl
    Molecular Weight 204.78 g/mol
    Iupac Name 1-Chlorododecane
    Appearance Colorless liquid
    Boiling Point 249-251 °C
    Melting Point -39 °C
    Density 0.86 g/cm³ at 20 °C
    Refractive Index 1.441 at 20 °C
    Flash Point 110 °C
    Solubility In Water Insoluble
    Vapor Pressure 0.01 mmHg at 20 °C

    As an accredited 1-Chlorododecane factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1-Chlorododecane is packaged in a 500 mL amber glass bottle, featuring a secure screw cap and hazard labeling.
    Shipping 1-Chlorododecane should be shipped in tightly sealed containers, protected from heat, sparks, and open flame. It must be handled as a hazardous material, in compliance with local, national, and international regulations. The chemical should be labeled properly and accompanied by its Safety Data Sheet (SDS) during transport.
    Storage 1-Chlorododecane should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from sources of ignition, heat, and incompatible materials such as strong oxidizers. Keep the container upright and properly labeled. Protect from physical damage and direct sunlight. Ensure suitable spill containment and have proper fire-fighting measures and safety equipment nearby.
    Application of 1-Chlorododecane

    Applications of 1-Chlorododecane in Industrial Manufacturing

    1-Chlorododecane, as a high-purity linear alkyl chloride, supports several downstream industrial sectors with distinct performance requirements. Our controlled synthesis, strict analytical QC, and packaging protocols equip customers for compliance and reliable integration. The following industrial applications highlight real downstream conversion and usage scenarios, including end-customer process requirements, technical use proportions, and relevant compliance regimes.

    1. Surfactant Intermediate for Industrial Detergents

    1-Chlorododecane functions as a key alkylating agent in the synthesis of quaternary ammonium salts and other cationic surfactants. These surfactants gain widespread use in textile auxiliaries, institutional cleaning formulations, and emulsifier blends. Manufacturers select alkyl chain length based on target performance in foaming, antimicrobial activity, and wetting power. Downstream users require consistently low residual halide content and tight molecular weight specification to ensure batch reproducibility and regulatory conformity. Incorporation typically occurs during the amination or quaternisation reaction stage, with direct addition under inert atmosphere to control side-products and maximize conversion.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006 for chemical registration and SVHC restrictions
    • ISO 9001 quality management throughout detergent supply chains
    • OECD and EU Biocide Product Regulation (BPR) compliance for antimicrobial surfactants
    • RoHS Directive 2011/65/EU for electronics sector cleaners (limit halogen impurities)

    Typical usage ratio

    • 15–30 mol% relative to amine reactant in quaternisation routes
    • Adjustment based on alkylation efficiency and target cationic surfactant purity

    Downstream process integration

    • Introduced at batch reactor alkylation stage, typically between 80–120 °C under controlled agitation
    • Purified intermediate transferred to surfactant finishing or blending lines
    • Residual chloride monitored to ensure compliance with downstream cleaning or industrial use regulations

    Final product types

    • Textile wetting and softening agents
    • Laundry detergent actives
    • Industrial and institutional hard surface cleaners
    • Electrostatic spray cleaner concentrates

    2. Organic Synthesis Intermediate for Lubricant Additive Manufacturing

    The high chain purity and controlled reactivity of 1-Chlorododecane make it ideal for custom lubricant additive formulation. It acts as an alkylating and chain-extension reagent in synthesising high-molecular-weight esters, sulfonates, and alkylated phenolic antioxidants used by lubricant OEMs. Producers subject feedstocks to batch or semi-continuous alkylation with co-catalysts to install the C12 group, enhancing thermal stability and oil solubility. Product QC screens for content and color to satisfy downstream base stock blending. Accurate proportioning at this stage ensures product meets bearing, gear oil, and hydraulic application performance standards, including volatility and residue specifications. End users validate full conversion to minimize halide remain and environmental risk.

    Industry compliance standards

    • ASTM D4951 for additive content and type in lubricating oils
    • API SN/CF and ACEA specifications for finished engine lubricants
    • ISO 14001 for manufacturing environmental management
    • SAE J183 for laboratory testing of lubricants

    Typical usage ratio

    • 5–25% of total additive package formulation, depending on target viscosity and oil solubility
    • Ratio adjusted based on compatibility with base oils and additive synergists

    Downstream process integration

    • Alkyl halide introduced at initial additive synthesis or chain extension stage under basic or acidic catalysis
    • Intermediates processed further by esterification, sulfonation, or oxidation as per downstream customer spec
    • QC screens each batch for halide content to ensure compatibility with metal surfaces and seals

    Final product types

    • Automotive and industrial gear oils
    • Hydraulic system additive packages
    • Compressor oil specialty blends
    • High-load bearing lubricants

    3. Intermediate in Pharmaceutical and Agrochemical Synthesis

    This raw material serves as an alkylating intermediate in the synthesis of pharmaceutical actives and crop protection agents, notably for compounds requiring hydrophobic chain installation or specialty ionisation properties. Pharmaceutical and agrochemical manufacturers favour it for its high linear purity and predictable reactivity in constructing long-chain esters and quaternaries. Typically, it enters the synthesis as an electrophile for N-alkylation or O-alkylation steps in heterocyclic or aromatic compound development. Process scale and conversion efficiency are closely monitored to meet established pharmacopoeia and residue limits. Downstream customers carry out comprehensive GMP audits and require full traceability of each batch used in regulated site synthesis pipelines.

    Industry compliance standards

    • Current Good Manufacturing Practice (cGMP) – ICH Q7 guidelines
    • US and European Pharmacopoeia (USP/Ph. Eur.) for finished product quality
    • FAO and WHO pesticide specification guidelines for crop protection actives
    • FDA 21 CFR Part 211 for process controls in drug manufacturing

    Typical usage ratio

    • Stoichiometric or slight excess (1.0–1.2 equivalents) in pharmaceutical synthesis to drive completion and ensure full conversion
    • Ratio in agrochemical synthesis depends on required alkyl chain incorporation and active molecule design

    Downstream process integration

    • Added at alkylation stage in multi-step organic synthesis of actives or intermediates
    • Residual impurities and unreacted chlorinated hydrocarbons carefully purged by downstream purification
    • Batch and in-line monitoring ensure compliance with pharmacopoeial and agrochemical purity limits

    Final product types

    • Long-chain pharmaceutical salt intermediates
    • Synthesis intermediates for antihistamines and anesthetics
    • Precursor building blocks for fungicides and insecticides
    • Hydrophobic cationic ingredients for seed treatment products

    4. Raw Material for Alkyl-Alkoxy Silicon Coupling Agents

    1-Chlorododecane features in the alkyl chain introduction step for organosilicon production, supporting the manufacture of specialty alkylalkoxysilanes. These coupling agents play a crucial role in surface treatment for glass fiber, mineral fillers, and rubber, enhancing hydrophobicity, processability, and interfacial compatibility. The chlorinated C12 is selectively coupled with silicon cores through Grignard-type or direct substitution methods. As manufacturers, we maintain low water content and high batch homogeneity to preserve silicon yield and downstream bonding performance. Downstream integration calls for complete conversion to minimize residual organochlorine, which can disrupt silicone crosslinking or degrade ultimate surface properties.

    Industry compliance standards

    • ISO 10350 for data reporting of plastics and composites
    • ASTM D2578 for measuring surface energy in plastics, films, and textiles
    • EU CLP (EC No 1272/2008) classification and labeling requirements for chemicals used in surface treatments
    • REACH Annex XVII for uses in manufacturing of treated goods

    Typical usage ratio

    • 1.0–1.3 equivalents per silicon compound in alkylation reactions
    • Usage rate determined by targeted hydrophobicity and reactivity for specific substrate types

    Downstream process integration

    • Reacted in primary alkylation or silylation reactors under moisture-free environment, often at elevated temperature
    • Intermediate transferred to blending or emulsification lines for direct surface modification products
    • Process includes molecular sieves or vacuum stripping for removal of residual halides

    Final product types

    • Glass fiber sizing agents
    • Mineral-filled plastic masterbatch dispersants
    • Rubber adhesion promoters
    • Water-repellent coatings for construction materials

    5. Synthesis of Phase Transfer Catalysts and Functional Ionic Liquids

    Due to its straight-chain structure and halide functionality, this raw material serves as a precursor in manufacturing quaternary ammonium or phosphonium salts. Such compounds operate as phase transfer catalysts or as ionic liquid components, facilitating two-phase organic reactions in industrial-scale synthesis for fine chemicals, polymers, or specialty extractives. Our manufacturing maintains low byproduct profiles and high linearity to ensure downstream catalysts maintain consistent partition behavior and facilitate reproducible chemical yields. During the production of catalysts, it reacts with trialkylamines or triarylphosphines under anhydrous and controlled temperature conditions. Downstream customers impose strict halide balance, trace contaminant, and color control for reliability in high-throughput batch and flow reactors.

    Industry compliance standards

    • OECD TG 473 for testing of phase transfer catalysts as chemical intermediates
    • Industrial Hygiene standards for handling quaternary ammonium compounds
    • GHS/EU CLP labelling for downstream storage/distribution
    • ISO 9001:2015 with chemical traceability requirements

    Typical usage ratio

    • 1.0 equivalent relative to tertiary amine or phosphine, with small margin for process conversion losses
    • Final catalyst blend concentration adjusted by downstream users according to process intensity and recyclability needs

    Downstream process integration

    • Charged to alkylation step in cation synthesis, with temperature and inert atmosphere control
    • Post-reaction purification through distillation or solvent extraction before catalyst deployment
    • Process monitored for byproduct and color index to ensure consistent reaction kinetics in customer processes

    Final product types

    • Cationic phase transfer catalysts for polymerization and halogen exchange
    • Hydrophobic ionic liquids for extraction and separation processes
    • Stationary phases for chromatography columns
    • Specialty reaction media for organometallic chemistry
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    Certification & Compliance
    More Introduction

    1-Chlorododecane: Insight from the Production Floor

    As manufacturers, we have spent years fine-tuning the process for producing 1-Chlorododecane, also termed lauryl chloride. We know this compound from its distinctive, slightly fatty odor and its clear, pale liquid form. Every batch that leaves our gate represents careful attention, starting from the selection of raw dodecane through to the stepwise, controlled chlorination reaction. We pay attention to the chain integrity, because a side reaction at any stage changes properties and can lead to off-spec byproducts.

    We often get asked what sets 1-Chlorododecane apart from other similar alkyl chlorides. The answer lies in its chain length and single chlorine substitution, which give it a distinct balance between reactivity and hydrophobicity. In practice, this means the chemical acts as a flexible intermediate or phase-transfer agent for producing antimicrobials, surfactants, lubricants, and certain specialty polymers. Mid-length alkyl chlorides, like chlorooctane or chlorononane, bring different chain mobility and sometimes more volatility, and longer-chain homologs such as 1-chlorohexadecane demand stricter handling but provide higher melting points and heavier molecular weights. With lauryl chloride, we strike a kind of sweet spot where the chain length aligns with industrial compatibilities—especially as an alkylating agent for surfactant synthesis.

    Each molecule of 1-Chlorododecane we create comes with a promise: purity above 98 percent, typically confirmed by GC-MS and titration. This result does not just happen. Years ago, we noticed that over-chlorinated byproducts would persist in the product when running older reaction systems, leaving a distinct, disagreeable odor and causing instability in downstream emulsifier applications. Today, real-time monitoring with gas analysis lets us dial in on reaction endpoints to avoid these impurities. One key step involves tight temperature control as exotherms can spike and shift the reaction toward multiple chlorination, causing a ripple effect on product quality further down the value chain.

    In the plant, we see the demand for 1-Chlorododecane shifting in response to downstream market innovation. Our customers continue to incorporate this material into quaternary ammonium compounds for biocidal formulations and corrosion inhibitors for refineries. We keep a close eye on the shifting global regulatory environment as well, since there is growing scrutiny on the volatility of organochlorides and on long-term residue in industrial effluents. Most synthetic routes employing lauryl chloride are based on nucleophilic substitution or coupling chemistry. The reactivity comes from the terminal chlorine, which makes it both a useful raw material and also, if mishandled, a candidate for unwanted side reactions—this risk always gets more pronounced at higher temperatures, and we plan our processes and train our staff to keep tight control over these variables.

    Differences become obvious if you have ever worked with shorter or branched-chain alkyl chlorides. Those substances will often provide higher vapor pressures, which means more loss to atmosphere and greater requirements for capture equipment in the reactor hall. 1-Chlorododecane’s lower vapor pressure makes it less likely to be an emission risk, but still fluid enough to pump and meter through standard lines without heating. We have refined our packaging protocols accordingly: epoxy-lined drums, stored indoors and out of direct sunlight, keep the material stable. We do this not because it ‘might improve’ shelf life, but because we have seen first-hand how storage errors chew through profits and cause headaches for end users if decomposition occurs.

    Our history with this product teaches us that consistent quality wins repeat business. Impurities create uncertainty, especially in applications like textile treatment agents and personal care additives, where a difference of half a percent can trigger changes in color, odor, or viscosity. The entire chlorination line in our plant is designed to enforce linearity of substitution. Dual temperature sensors on the reaction kettle, backed by spray-condensers, catch escapees before they have a chance to form dodecyl poly-chlorides. This translates into a drop in customer complaints and fewer rejected shipments compared to years when the process ran as more of an art than a science.

    We do not lose sight of the fact that 1-Chlorododecane ends up in finished consumer products. Textile finishers rely on our product to deliver smooth, antistatic properties to synthetic fibers. Surfactant producers seek our lauryl chloride as a feedstock for alkyltrimethylammonium salts, crucial in the making of softeners and antistatic agents. Manufacturers of specialty lubricants come to us because the chain length of our chlorinated dodecane matches their molecular design for low-friction films. In all these cases, what really matters is predictability and cleanliness of the feedstock.

    Some ask about the model and specification. Our main volume product carries a CAS number 112-52-7, with a molecular weight just over 205 g/mol. Quality control focuses on color (APHA 30 max), assay by GC above 98 percent, and a water content routinely below 0.05 percent. Every drum we ship gets traced by production lot and is held to the same standards, whether destined for a high-volume chemical synthesis plant or a specialty formulator.

    Despite its versatility, 1-Chlorododecane is not a drop-in substitute for every alkyl chloride. Its long chain gives it resistance to enzymatic breakdown, so we actively advise downstream users to ensure proper disposal routes—our technical team regularly updates customers on new options for incineration and recovery. We realize the global conversation on persistent organic compounds and sustainability has real impact: supply chains expect traceability, and our production records remain transparent for audits. We do not take shortcuts with stabilizers or diluents, since these would only shift the regulatory and performance burdens to the next node in the value chain.

    Customers who have switched from other suppliers often mention differences in handling or batch consistency. We attribute these to our attention to raw material purity—starting each batch from high-grade dodecane—and to process upgrades made possible through years of small but persistent capital investment. Our operation teams monitor reaction exotherms and chlorine flow ratios using automated feedback loops. In the early days, we ran these reactions with manual watching and incremental additions, which ate up labor hours and ran the risk of overshooting the chlorination window. Automation has not only reduced risk but has cut down production time by nearly a quarter in the last five years.

    Having direct control as the manufacturer—not just as a formulator or distributor—gives us insight into the specific downstream pain points. A typical question we face relates to odor and corrosivity. 1-Chlorododecane has a faintly pungent smell but, compared to shorter alkyl chlorides, releases far less hydrochloric acid vapor during storage and use. This trait reduces both handling risk and corrosion to packaging or plant equipment. We observed in our older steel drums more rapid pitting and rusting, prompting a shift to lined containers after only a few years. Now, customers store our product with confidence, reporting longer drum shelf life and fewer maintenance hours on their lines.

    Logistics play a bigger role than many realize. Our entire logistics team is trained to ensure the product survives the journey from our plant to customer site. We fill each drum under nitrogen to prevent moisture ingress, check closure torque, and mark every drum with production date. Tracking systems have reduced lost shipment incidents to near zero. Responding to customer feedback, we have also reduced the package headspace to minimize vapor evolution during transit. Direct feedback led us to introduce tamper-evidence packaging, improving confidence at delivery point and reducing loss claims.

    In terms of application, 1-Chlorododecane proves its value in alkylation processes, especially where a single, uniform chain is required for consistent product quality. Surfactant manufacturers appreciate that our material delivers a predictable, clean result, which aligns with regulatory standards for downstream consumer products. We have worked with clients in the corrosion inhibitor space who reported less fouling of heat exchangers after sourcing from us—a direct result of improved chlorination control and low impurity levels in our product. Others in the electronics sector rely on our chlorinated dodecane for specialty dielectric fluids, banking on its stability even under moderate thermal load.

    There is sometimes discussion in trade circles about the interchangeability of C12 chlorides. In practice, variation in isomeric content, color, and trace dodecane or didodecyl residues changes downstream performance. We follow the latest technical papers and invest in pilot studies to stay on top of process optimizations. Customers are often surprised that our in-spec batches display tighter boiling range and color than so-called ‘equivalent’ materials sourced elsewhere. This is no accident—it comes from ongoing attention at the manufacturing level. We keep our plant staff versed in small, incremental improvements. Whether it is improving condenser efficiency or updating chlorination flow meters, we see the results in real-time batch quality.

    Compatibility and storage remain major themes from user feedback. 1-Chlorododecane tolerates exposure to most nonpolar organic media, but reacts readily with strong nucleophiles or Lewis acids. For this reason, we maintain full disclosure with customers on expected stabilities and incompatibilities. From our long run of experience, we have seen batch contamination occur in the field when transfer lines are set up incorrectly—leading to contamination with water or polar solvents. These incidents, although rare, teach us about potential weaknesses in application and let us update our technical documentation and customer education.

    With environmental standards evolving rapidly, we make compliance an integrated part of our workflow. Every kilogram of chlorododecane shipped is traced from dodecane input to finished, sealed drum, with full documentation ready for customer and regulator inspection. We actively register our material with existing international chemical inventories and keep test summaries on-hand for clients needing information for regulatory filings. Our on-site waste recovery facilities reclaim wash solvents and unreacted dodecane, minimizing our environmental loading. We share these improvements with customers as part of annual sustainability briefings, seeing it not just as a marketing exercise but as a requirement for continued industry trust.

    Concerns sometimes surface about human exposure, especially when the material arrives in high-throughput chemical installations. As the manufacturer, we monitor OELs and train our plant workers in proper PPE usage, and we share best practices with customer plant managers. We do this out of recognition that well-handled material at the producer stage reduces risk for every stakeholder in the chain. Years of incident-free handling help bolster our reputation with workplace safety authorities.

    In formulation work, 1-Chlorododecane holds its place among alkyl chlorides thanks to both its high boiling point and manageable viscosity at room temp. Production partners in wet textile finishing, for instance, find our batches yield a soft, even hand in fibers while producing fewer color and odor issues than alternatives. This consistency comes from the base dodecane selection, which we double-filter before chlorination, and the real-time composition monitoring adopted in the last decade. Similar benefits show up in the antistatic and lubricating agents sector, where the clean substitution pattern translates to lasting surface properties.

    A common misconception from outside the manufacturing sector assumes all dodecyl chlorides perform alike. Our lab experience and production audits say otherwise. The production path, and purity achieved at each step, leaves a strong fingerprint in the final product. Downstream performance in emulsification, antistatic behavior, or lubricity all tie back to trace sulfate, overchlorination products, or color bodies. Each shipment we release comes with a full certificate of analysis because we have learned over time that cutting corners to boost output invites customer complaints and line shutdowns later.

    Shipping material across climate zones and long travel times highlights the benefit of minimizing impurity levels. High-purity 1-Chlorododecane shows less tendency to darken in storage or develop off-odors that could raise downstream QA flags. Our technical team regularly inspects retained samples and works closely with key customers on batch performance reviews. In fact, most improvements in our current process came straight from field audits and customer input—either during scale-up or following use in delicate applications, such as personal care or pharmaceutical intermediates, where volatility and color must stay tightly controlled.

    We take pride in the resilience and adaptability of our production program. Seasonal fluctuations, raw material shifts, and changing regulations challenge us to stay ahead on every production run. Our in-house R&D continues to test new methods for minimizing byproducts and for increasing chlorine use efficiency. Only by grounding ourselves in both chemistry and application feedback can we keep meeting market and regulatory expectations.

    Guided by our hands-on manufacturing perspective, 1-Chlorododecane remains a mainstay for those who need predictable performance and robust supply chains. We owe this stability to our plant operators, engineers, and technical advisors who carry knowledge forward in every batch. Our approach sets a standard for what manufacturing excellence should look like in a category often dominated by price-first thinking.