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1-Chloro-2-Fluoroethylene

    • Product Name 1-Chloro-2-Fluoroethylene
    • Alias Vinylidene chloride
    • Einecs 204-826-4
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    586625

    Cas Number 359-12-2
    Molecular Formula C2H2ClF
    Molecular Weight 80.49 g/mol
    Appearance Colorless gas
    Boiling Point 20.2 °C
    Melting Point -160 °C
    Density 1.286 g/cm³ (at 20 °C)
    Solubility In Water Slightly soluble
    Vapor Pressure 583 mmHg (at 25 °C)
    Flash Point -55 °C
    Refractive Index 1.360 (at 20 °C)
    Iupac Name 1-chloro-2-fluoroethene
    Synonyms 1-Chloro-2-fluoroethene, Vinyl chloride fluoride

    As an accredited 1-Chloro-2-Fluoroethylene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A high-pressure steel cylinder containing 25 kg of 1-Chloro-2-Fluoroethylene, clearly labeled with hazard warnings and chemical identification.
    Shipping 1-Chloro-2-Fluoroethylene is shipped as a compressed, liquefied gas in appropriate pressurized cylinders or tanks. It is classified as a hazardous material (UN 3163), requiring labeling for toxic and flammable gas. Handling and transport must comply with DOT and international regulations, ensuring proper ventilation, temperature control, and securing against leaks or damage.
    Storage 1-Chloro-2-Fluoroethylene should be stored in a tightly sealed, clearly labeled container, away from heat, sparks, and open flames due to its flammability. Store in a cool, dry, well-ventilated area, away from incompatible substances such as strong oxidizers. Protect from moisture and direct sunlight. Ensure proper grounding and bonding during transfer to prevent static discharge.
    Application of 1-Chloro-2-Fluoroethylene

    Applications of 1-Chloro-2-Fluoroethylene in Industrial Manufacturing

    As a direct manufacturer of 1-Chloro-2-Fluoroethylene, we supply this specialty monomer to established sectors with well-defined technical requirements. Below, we outline its proven downstream applications, showing how it supports value-added processing in each focused segment.

    1. PVDF Copolymer Production for Specialty Engineering Plastics

    Leading polymer producers incorporate 1-Chloro-2-Fluoroethylene as a comonomer in the synthesis of polyvinylidene fluoride (PVDF) copolymers. This inclusion tailors copolymer crystallinity and melt processability, yielding highly chemical-resistant engineering plastics for demanding end uses. Its integration during suspension or solution polymerization occurs under tightly controlled conditions to maintain traceability and batch consistency. These advanced copolymers find critical roles in industries such as electronics, automotive, and piping systems, where long-term durability against aggressive agents counts as a primary performance metric.

    Industry compliance standards

    • ASTM D3222 Standard Specification for Unmodified PVDF Molding and Extrusion Materials
    • UL 94 Flammability Standard (Vertical and Horizontal Testing)
    • REACH Regulation (EC) No 1907/2006 – Registration and Authorization for Polymer Intermediates
    • RoHS Directive 2011/65/EU – Heavy Metals and Halogenated Substance Restrictions

    Typical usage ratio

    • 2%–12% by molar fraction relative to main monomer (vinylidene fluoride); adjustment based on target mechanical properties and melt flow requirements

    Downstream process integration

    • Direct charged into polymerization reactor during copolymer formation—either batch or continuous mode, requiring precise dosing and inert atmosphere control

    Final product types

    • High-purity PVDF copolymer pellets
    • Extruded chemical-resistant piping
    • Injection-molded pump housings and seals
    • Wire and cable insulation for electronics

    2. Fluoroelastomer Synthesis for Chemical-Resistant Seals

    In fluoroelastomer manufacturing, formulators utilize 1-Chloro-2-Fluoroethylene as a specialty modifying monomer to enhance thermal stability and chemical inertness against aggressive fluids. The material enters polymerization with other vinyl or fluoro comonomers under specific pressure and temperature profiles, governed by strict raw material isolation protocols. End-use fluoroelastomers often become critical sealing, gasket, and lining materials in industrial reactors, fuel delivery systems, and pharmaceutical processing, where exceptional long-term retention of sealing force remains essential.

    Industry compliance standards

    • ASTM D1418 Nomenclature and Designation for Rubber and Elastomers
    • ISO 23936-2 Elastomers in Oil and Gas Production—Resistance to Sour Gas
    • FDA 21 CFR 177.2600 (For gaskets/linings in repeated-use food contact)
    • Automotive Materials Standard SAE J200

    Typical usage ratio

    • 3%–10% by weight in total monomer feed; final concentration varies with elastomer grade and swelling resistance requirements

    Downstream process integration

    • Fed into solution or emulsion polymerization setups alongside tetrafluoroethylene (TFE) and related monomers; typically pre-blended, then introduced as a measured stream

    Final product types

    • O-rings for chemical handling
    • Sheet gaskets for corrosive media containment
    • Valve and pump linings in process equipment
    • Flexible fuel hose sheaths

    3. Synthesis of Heat-Resistant Coating Resins for Industrial Surfaces

    Coating formulators leverage this raw material to build up fluorinated copolymer resin matrices for high-performance coatings. The monomer’s chlorine and fluorine functionalities impart superior adhesion and ultraviolet resistance in architectural, marine, and industrial environments. Strict process validation ensures the resulting resin’s conformance to weathering standards for outdoor structural applications. The material enters free-radical polymerization reactors with select acrylic or vinyl monomers to achieve resin architectures suited for solvent-based and powder coating platforms.

    Industry compliance standards

    • ISO 12944—Paints and Varnishes: Corrosion Protection of Steel Structures
    • ASTM D522—Mandrel Bend Test for Coating Flexibility
    • GB/T 23986 for Synthetic Resin Emulsion Standards (China)
    • VOC requirements per 40 CFR Part 59 (US EPA National Volatile Organic Compound Emission Standards)

    Typical usage ratio

    • 5%–15% by mass in monomer blend; fine-tuned to achieve desired film flexibility, UV stability, and resistance profiles

    Downstream process integration

    • Charged at the initial stage of copolymer resin synthesis; temperature and inhibitor levels tightly controlled to preclude undesired side reactions

    Final product types

    • Architectural coatings for metal cladding and façade elements
    • Protective coatings for chemical plants and marine equipment
    • Pipe and tank linings requiring long-term UV and chemical exposure resistance
    • Specialty powder coatings for outdoor applications

    4. Intermediate for Fine Chemical Synthesis in Agrochemical Production

    Agrochemical synthesis operations deploy 1-Chloro-2-Fluoroethylene as a key intermediate in constructing complex fluorinated molecules with targeted bioactivity. During multi-step synthesis flows, chemists use it in halogen-exchange or addition reactions under rigorously monitored conditions, ensuring trace impurity control complies with agrochemical product registration protocols. Its input strictly occurs at defined reaction steps where the presence of both chlorine and fluorine influences reactivity and subsequent functional group installation needed for the active ingredient’s ultimate performance profile.

    Industry compliance standards

    • FAO/WHO Specifications and Evaluations for Agricultural Pesticides (JMPS guidance)
    • OECD Good Laboratory Practice (GLP) for Chemical Synthesis
    • ISO 9001: Quality Management System (for fine chemical manufacturing)
    • Regulations (EU) No 283/2013 and 284/2013 for Plant Protection Product Active Substances

    Typical usage ratio

    • Stoichiometric or slight excess on the limiting reagent, adjusted based on desired reaction conversion and side-product suppression; typically 1.05–1.20 molar equivalents

    Downstream process integration

    • Charged to batch reactors in closed system arrangements, often under inert gas, as a feedstock for halogenation or nucleophilic substitution steps in synthesis schemes

    Final product types

    • Precursor intermediates for triazole- and pyridine-based agrochemicals
    • Building blocks for selective herbicides and fungicides
    • Custom fluorinated motifs tailored for patented crop protection molecules
    • Bulk active ingredient stocks for downstream formulation
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    Certification & Compliance
    More Introduction

    Understanding 1-Chloro-2-Fluoroethylene: Direct Insight from the Production Floor

    Precision Starts Here: Real-World Experience with 1-Chloro-2-Fluoroethylene

    Every chemical manufacturer faces hard choices when it comes to designing and scaling up new molecular building blocks. In our plant, 1-Chloro-2-Fluoroethylene has become a cornerstone for teams looking for both reliability and flexibility in vinyl compounds with halogen substitution. After years of running distillation towers, scrubbing emission lines, and handling rigorous quality checks, we’ve honed both the process and the understanding of why this compound matters to advanced material producers.

    What Sets Our 1-Chloro-2-Fluoroethylene Apart?

    1-Chloro-2-Fluoroethylene does not enter the market as a general-use solvent or bulk commodity. Instead, it fills a niche among specialty chemicals designed for synthesis paths where positional halogen control changes the property landscape at a molecular level. With its unique structure, this vinyl halide supports targeted synthesis in pharmaceuticals, agrochemical intermediates, and performance polymers, right down to the engineering plastics where a balancing act between flame retardance and reactivity can make or break new product lines.

    On a granular level, the model we provide features optimized isomeric purity. Over years of iterative feedback between our R&D and navigation through regulatory constraints, the production line has focused on keeping chlorofluoroethylenes as clean as possible from similar chloro-fluoro or dihalogenated impurities. Waste reduction and process safety grow easier when customers do not have to face unpredictable by-product profiles in their reactors.

    How Advanced Applications Rely on This Molecule

    A single “chloro” or “fluoro” swap in a vinyl group can shift more than just a spectra. Our direct talks with process engineers in specialty elastomers and high-value fiber plants have proved that even trace variations in elemental content find their way downstream, altering curing responses or catalyst activity. Someone running a continuous polymerization line, for instance, cannot afford swings in thermal stability or inconsistent gas-phase purity. Consistency has driven us to invest in gas purification steps that strip out traces of water and hydrocarbon side products, confirmed by on-site GC-MS and FTIR monitoring.

    Research groups working on advanced fluoropolymer backbones or new insecticide discovery routes have echoed the same refrain: synthesis does not just need access, it demands surety. The difference between a 98.5% and a 99.8% pure feedstock becomes a raw factor in yield calculations. Our typical production cycle keeps the major impurity profile under target thresholds—never by accident, but by ongoing analysis and listening to feedback from the end users who monitor their own NMRs day in and day out.

    Daily Realities: What It Means to Manufacture 1-Chloro-2-Fluoroethylene

    On the production floor, batches are shaped by the real conditions of temperature, pressure, and material compatibility. Corrosive gases, especially in halogenated vinylic chemistry, call for line operators trained to spot leaks as soon as they form. Our reactors use purpose-built alloys rather than generic stainless, and valves are chosen based on downtime statistics, not catalog claims. Failures or unexpected stoppages in dehydrohalogenation steps have taught us how little margin there is for error when balancing throughput with quality integrity.

    We maintain tight sample control routines, pulling from every lot according to a laboratory-developed protocol written in collaboration with plant operators. Only through repeated, cautious adjustments have we reached a purity standard that stays consistent from drum to drum, rather than just meeting specs on the paperwork. Technicians work with both GC and NMR in-house so problems get caught during packaging, not by the customer after shipping racks have left our site.

    Distinguishing from Other Vinyl Halides and Market Alternatives

    Chemically, 1-Chloro-2-Fluoroethylene stands apart from other halogenated ethylenes like vinyl chloride, vinyl fluoride, or dichloroethylenes. Down the synthesis chain, its reactivity gives chemists another lever to pull—a double bond activated by different halogens delivers altered selectivity in both radical and nucleophilic pathways. This means developers in the pharmaceutical or materials sectors gain flexibility in tuning downstream modifications and polymerization rates.

    We have seen customers who trialed generic chloroethylene or fluoroethylene builds for R&D, only to abandon those lines due to limiting cross-reactivity or incomplete conversion rates. In some advanced fluoropolymer syntheses, the difference between a monomer with both a chlorine and a fluorine atom versus one with only one halogen can mean dramatic differences in final mechanical or surface properties. Customers making anti-corrosive coatings or flame-resistant cables have reported faster, cleaner reactions with our 1-Chloro-2-Fluoroethylene, accompanied by easier handling of polymer blends due to more manageable volatility.

    Safety remains a living concern. Flammability and tox profile are not the same as those of more commonly used monomers, so the burden is always on us to provide enough data for handlers to make smart operational choices. Since no two facilities run identical lines, we regularly share updated analytical and impurity profiles so technical teams can feel confident about process safety and product performance, without guessing.

    Voices from the Lab: Why the Right Sourcing Matters

    Feedback from customer labs keeps us honest. An R&D leader at a resin formulation plant once shared that switching to our process batches pushed their pilot yields up by close to 4% over a quarter, not by magic, but by removing stoppages tied to out-of-spec byproducts. This is not just a win for one customer; reduced waste pays forward to environmental and downstream engineering compliance. Our daily lab walk-throughs have reinforced the message that being a direct manufacturer is not about sales volume—it is about close monitoring, putting science ahead of quarterly targets, and keeping operators involved beyond the fabrication step.

    Over time, we have built direct ties with developers working to get new drug candidates or specialty fillers through regulatory review. They appreciate not being left with vague promises. Where testing uncovers a processing issue or unexplained reactivity, our engineering support is not a hand-off to an anonymous service center. Instead, chemists and operators who understand our own line conditions pick up the challenge with them, from sample retesting to adjusting future batches, right down to sharing insights on shipment storage in changing climates.

    Some alternative suppliers bank on digital catalogs and off-the-shelf offerings. Our experience engineers a different route—one where each product lot grows out of real process knowledge. We have participated in material traceability audits where every tank, run parameter, and QC signature is open to scrutiny. As regulations continue to tighten and customers demand performance above mere compliance, only a team steeped in process control can keep pace.

    Meeting Real-World Production Challenges with Experience

    Producing 1-Chloro-2-Fluoroethylene at scale does not translate to mere volume. Every increase in output brings new risks of process bottlenecks, heat exchange limits, and containment safeguards. Early hurdles forced us to introduce double-seal containment and train our team on high-integrity cylinder filling, even as we built out more stringent leak detection routines. Handling toxic, volatile gases brings its own unique set of lessons—ones our team has lived through, especially during unplanned shutdowns from weather or feedstock supply hiccups.

    Operators at the reactor level have encouraged innovations that traditional spec documents rarely capture. For instance, fine-tuning the charge protocol for precursor chlorofluoroalkanes cut down on start-up times and reduced off-spec output that would have cost both time and materials. Engineering group feedback led to adopting thermal imaging to catch and isolate slight exothermic hotspots before they could spiral into safety events. None of these improvements came from guesswork; they grew from a feedback loop between line staff, safety teams, and development chemists refining the process week-by-week.

    Continuous Improvement Backed by Data and Operator Cooperation

    Long-term relationships with customers have taught us that rest is never an option. Once a competitor entered the market promising ultra-high-purity product derived from a batch, not continuous, route. Their approach ended with areas of inconsistent supply and missed specs. Our own batch-control protocols and online monitors picked up the slack: regular checks for organometallic traces, halide balances, and pressure drops on the pack line helped limit both off-gassing and drum residue, maximizing both product safety and field performance.

    There have been times when environmental regulators required new tests for trace emissions tied to specialty halogenated monomers. Rather than treat compliance as a chore, we dug into the data with field teams and adjusted scrubber loads and vent stack monitoring. This partnership between operations and the compliance department did more than satisfy paperwork; it revealed efficiency gaps and uncovered ways to cut back on fugitive emissions, yielding both greener production and lower operational risk. Small steps—tightening every seal, cutting turnaround time after cleaning, reviewing waste stream analytics—add up to a cleaner, leaner process over the long run.

    The Human Element: People Driving Process Excellence

    It is common to talk about product purity or reactivity in terms of numbers and lab reports. Yet, anyone who makes 1-Chloro-2-Fluoroethylene knows that the key factor is people. From shift leaders overseeing pre-heat on mixing lines to QC technicians scrutinizing intermediate results, it is the hands-on knowledge built across years that separates average outcomes from consistent, superior lots. Employees who commit to the “why” of the process can spot nuances in smell, pressure readings, or even the resonance peaks, flagging small anomalies before they translate to big issues for the customer.

    We have seen veteran team members mentor junior operators in tracking changes—not just what the numbers are, but what they mean at a process level. Troubleshooting an unplanned spike in impurity or a subtle color drift often takes real-world, on-the-floor judgment; not everything fits a checklist. In the toughest scenarios, like a valve failure mid-run or unexpected cold snaps slowing throughput, it was a team’s collective focus that pulled batches back on line. We pay close attention to staff input on safety routines, cleaning schedules, and lab upgrades, understanding that the best process innovations stem directly from those who run the line day-to-day.

    Bringing New Products to Market: Lessons Learned Through Scale-Up

    Moving from pilot to full-plant scale has never followed a straight path. Early trials of 1-Chloro-2-Fluoroethylene drew out limits of several catalysts and brought to light the learning curve that new operators face when handling halide-laden streams under heat. Upscaling required rethinking our feedstock logistics, re-balancing preheater controls, and refining how we capture and condense the volatile monomer at each step. By working side-by-side with plant engineers and process safety teams, we ironed out batch inconsistencies and cut unplanned downtime—directly improving reliability for our customers watching critical path lead times.

    The process taught us humility and resilience, reminding us that the learning never stops. As new regulations came into force, we adapted not just safety protocols, but also our documentation and shipment handling to satisfy international regulatory teams. We come to see every adjustment in method or equipment as a way of raising the bar, not just internally but for each producer downstream who relies on steady feeds to keep their own promises to end-users.

    Supporting Future Innovation in Challenging Sectors

    As product requirements evolve and green chemistry takes firmer hold in regulatory circles, the capability to adapt synthetic protocols for efficiency and lower footprint grows more important. With 1-Chloro-2-Fluoroethylene, early adoption by specialty polymer researchers allowed us to participate in field trials for flame-retardant parts in vehicles and electronic housings where every halogen balance meant potential breakthroughs in safety or performance. Collaborating directly with development laboratories, we have provided insights not just on the product, but on the entire handling and aging process—usually including experimental results on long-term storage, stability against metals, and field evaporation loss rates.

    Downstream, coatings and adhesive scientists have taken advantage of the “activated” double bond in this compound, getting improved cross-linking yields or softer cure windows across a temperature range. Drug discovery groups, especially those building libraries of fluorinated heterocycles, have shared stories of how timely supply and attention to impurities shortened campaigns and limited wasted screening effort.

    Our technical team continues to learn alongside both established players and up-and-coming innovators, constantly adapting our upstream controls to ensure what leaves our docks meets the newest scientific and practical expectations. By choosing direct manufacturing and staying hands-on with both infrastructure and people, we believe we contribute more than molecules—we help customers push forward, faster and with greater confidence in both safety and performance.

    Conclusion: Manufacturing for a Moving Target

    The story of 1-Chloro-2-Fluoroethylene is still being written both in our facility and downstream in the labs and plants of those driving the next generation of advanced materials and chemicals. We take pride in not just what the molecule is, but in the way it is made—reflecting a history of attention to engineering detail, regulatory awareness, and open, informed cooperation with those who trust our product as a building block in their own work. Every lot represents the sum of countless hands and eyes, guided by science and a shared commitment to consistency, transparency, and continuous improvement.

    For those engaged in complex synthesis and demanding applications, the story does not end at the product gate; it unfolds over time, through each step of process adaptation and problem-solving. By remaining focused on the bedrock values of technical skill, openness, and the deep confidence that comes from experience, our team is prepared to meet both the routine and the unexpected in providing 1-Chloro-2-Fluoroethylene—now and into the future.