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1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate

    • Product Name 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate
    • Alias [BMIM][OTf]
    • Einecs 682804-42-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    188887

    Product Name 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate
    Abbreviation BSMIM OTf
    Chemical Formula C9H17F3N2O5S2
    Molecular Weight 372.37 g/mol
    Appearance Colorless to pale yellow liquid
    Cas Number 1233182-82-9
    Density 1.47 g/cm3 (approximate)
    Melting Point Below room temperature
    Solubility In Water Miscible
    Ph Neutral to slightly acidic
    Boiling Point Decomposes before boiling
    Storage Conditions Store at room temperature, keep tightly closed
    Purity Typically >98%
    Application Ionic liquid, solvent, catalyst

    As an accredited 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The chemical is packaged in a 100g amber glass bottle with a secure screw cap, labeled for laboratory use and safety instructions.
    Shipping 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate is shipped in tightly sealed containers, protected from moisture and extreme temperatures. Transport complies with relevant hazardous material regulations. Packages are clearly labeled, with safety data sheets included. Ensure upright storage during transit, and avoid contact with incompatible substances. Handle with appropriate personal protective equipment upon receipt.
    Storage 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture, direct sunlight, and incompatible materials such as strong oxidizers. It should be kept at room temperature and protected from atmospheric exposure to prevent hydrolysis or contamination. Clearly label the container and follow all safety guidelines for handling ionic liquids.
    Application of 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate

    Applications of 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate in Industrial Manufacturing

    1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate delivers consistent ionic conductivity, stability under acidic and oxidizing environments, and tailored solubility profiles for advanced production environments. As a manufacturer, we support downstream partners in integrating this specialty ionic liquid into their process workflows, targeting critical paths in catalysis, electrochemistry, polymer processing, and specialty separations.

    1. Acidic Catalytic Media for Alkylation Reactions

    Chemical producers employ this ionic liquid as a key reaction solvent and proton source for high-selectivity alkylation, specifically in the production of pharmaceutical intermediates, specialty aromatics, and fine chemicals. Its strong acid character enables enhanced reactivity, supports recyclable reactor setups, and maintains minimal side-product formation. Our material matches performance standards for batch and continuous flow synthesis lines requiring low water content for high-yield outcomes.

    Industry compliance standards

    • REACH Regulation (EC 1907/2006) for chemical safety
    • ISO 9001:2015 for quality management in fine chemical production
    • 21 CFR Part 210/211 for API raw material use in regulated pharmaceutical synthesis
    • IPEC-PQG GMP Guide compliance for excipient manufacturing when required

    Typical usage ratio

    • 20–60% by weight in alkylation reaction mixtures; exact concentration set by substrate type and target turnover frequency

    Downstream process integration

    • Input as the main reaction solvent or co-solvent at reactor charge-in phase
    • Reclaimed and recycled post-reaction via water quench and liquid-liquid separation when process optimization allows

    Final product types

    • Pharmaceutical intermediates with controlled regioselectivity
    • Specialty aromatics for agrochemical applications
    • High-purity fine chemicals for electronics-grade reagents

    2. Electrolytes for High-Performance Electrochemical Capacitors

    Manufacturers of next-generation supercapacitors and hybrid energy storage cells integrate this ionic liquid as a non-volatile, non-flammable electrolyte. Its broad electrochemical window and high ionic conductivity provide significant cycle-life extension and stable charge-discharge performance across temperature and voltage ranges. It supports advanced symmetric and asymmetric cell designs for grid storage and automotive systems.

    Industry compliance standards

    • IEC 62860 for electrical safety in capacitor construction
    • RoHS Directive (2011/65/EU) for restriction of hazardous substances
    • UN Manual of Tests and Criteria, Section 38.3 for transport safety of cells containing new electrolytes
    • ISO 14001:2015 for environmental management in battery production

    Typical usage ratio

    • 90–100% ionic liquid when used as neat electrolyte; 30–70% in mixed solvent systems with acetonitrile or propylene carbonate, based on device architecture

    Downstream process integration

    • Injected into finished capacitor cell under vacuum or atmospheric fill system during dry room assembly
    • Blended with co-solvents if required, with inline monitoring for viscosity and purity

    Final product types

    • Supercapacitor modules for public transport or automotive
    • High-power hybrid storage cells for renewable integration
    • Specialty laboratory reference electrodes

    3. Polymerization Solvent for Specialty Functional Polymers

    Producers of advanced functional polymers use this ionic liquid as a polymerization medium, promoting homogeneous mixing and ionic conduction during synthesis. Especially in the in-situ polymerization of conductive or proton-exchange materials, its sulfonic acid group acts as a proton donor and chain transfer agent, enabling the precise control of polymer architecture and physicochemical properties.

    Industry compliance standards

    • ISO 13485:2016 for quality management in medical-grade polymer components
    • FDA 21 CFR 177.2600 for elastomers used in food contact, if end-use applies
    • ASTM D4065 for thermal analysis of polymer composites
    • ISO 14644-1 for cleanroom standards in precision extrusion lines

    Typical usage ratio

    • 10–40% by mass to total monomer input for in-situ polymerizations; adjusted for chain length and ionic exchange requirements

    Downstream process integration

    • Mixed with monomer feedstock prior to polymerization reactor entry
    • Post-polymerization, removed by extraction or retained in final product if functional requirements demand

    Final product types

    • Ionic conductive membranes for PEM fuel cells
    • Polymer electrolytes for solid-state batteries
    • Specialty ionomer films for electronics encapsulation

    4. Separation Agent in Non-Aqueous Metal Extraction

    Industrial hydrometallurgical processors utilize this ionic liquid as a selective extractant for rare earth metals and platinum group metals from complex leachates. It enables high phase separation efficiency and selectively coordinates metal ions under low-water conditions. Operators in electronics recycling and secondary resource valorization settings implement this method to boost yield and lower energy input in comparison to traditional extractants.

    Industry compliance standards

    • OECD Guideline 105 for water solubility assessment
    • ISO 9001:2015 for quality control in extractive metallurgy
    • Regulation (EU) 2017/821 for responsible sourcing of conflict minerals
    • Industry-specific effluent and waste management requirements (e.g., US EPA 40 CFR Parts 260-265)

    Typical usage ratio

    • 5–15% ionic liquid in organic extraction phases; actual concentration varied as a function of feed leachate composition and targeted ion selectivity

    Downstream process integration

    • Added to organic phase mixer-settler systems post-leach, prior to aqueous/organic separation step
    • Regenerated and recycled via acid stripping and back-extraction

    Final product types

    • High-purity rare earth oxide concentrates
    • PGM (Platinum Group Metal) solutions for catalyst manufacturing
    • Refined metal salts for electronics and energy applications

    5. Homogeneous Sulfonating Agent in Organic Synthesis

    Specialty chemical synthesis operations use this ionic liquid as a dual-function reagent and solvent for sulfonation steps, particularly where controlled introduction of sulfonic acid groups is required. Its excellent solubilizing power and acidity enable effective transformation of aromatic and aliphatic substrates under mild conditions, producing intermediates for surfactant and dye manufacturing with reduced byproduct load.

    Industry compliance standards

    • ISO 9001:2015 certified QC processes for sulfonated intermediates
    • Hazard Communication Standard (OSHA 29 CFR 1910.1200) for workplace safety in handling strong acids
    • Registration under REACH for supply in the European Union
    • Globally Harmonized System (GHS) of Classification and Labelling of Chemicals

    Typical usage ratio

    • 15–30% by weight of total reaction mass, sometimes directly proportional to target degree of sulfonation for given substrate

    Downstream process integration

    • Charged into sulfonation reactors along with substrate and co-solvent
    • Allows for direct phase separation and product extraction post-reaction

    Final product types

    • Alkylbenzenesulfonic acid precursors for detergent blends
    • Sulfonated dyes for textile and paper industry
    • Surfactant base stocks for specialty cleaning applications

    6. Acidic Medium for Organic Electrochemical Synthesis

    Producers of value-added organics use this ionic liquid as a stable acidic medium for controlled-potential electrochemical transformations. Its thermal and chemical stability allows for precise oxidation or reduction steps, supporting high-purity production of intermediates such as quinones and heterocyclic compounds otherwise sensitive to aqueous acid treatment. Electrochemical cell operators benefit from high ion transport and electrode stability during prolonged operation.

    Industry compliance standards

    • ISO/TS 80004-8 for electrochemical terminology and method validation
    • IEC 61010 for laboratory safety in electrochemical installations
    • REACH Regulation (EC 1907/2006) for specialty solvents and media
    • ISO 17025:2017-compliant laboratory quality control

    Typical usage ratio

    • 70–100% ionic liquid as electrolyte medium; diluted to 50% when paired with co-solvents such as acetonitrile, depending on cell design

    Downstream process integration

    • Filled into divided or undivided electrochemical cell prior to substrate dosing
    • Monitored for conductivity and pH stability throughout batch duration

    Final product types

    • Quinone derivatives for pharmaceutical intermediates
    • Oxidized aromatic compounds for fine chemicals
    • Heterocyclic building blocks for agro and specialty synthesis
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    Certification & Compliance
    More Introduction

    1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate: A Practical Approach from the Factory Floor

    Getting to Know the Product

    We work with 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate every day—often called BSMIM OTf. Watching this ionic liquid come off our production lines, we see not just a chemical compound, but a piece of what makes new technology hum behind the scenes. Developed for situations where stability and ionic conductivity matter the most, BSMIM OTf has proven itself reliable even under demanding lab and industrial projects.

    This product consists of an imidazolium ring modified with a butylsulfonic side chain on one end and a methyl group on the other, paired with a trifluoromethanesulfonate anion. The result is a salt which remains liquid at room temperature, showing little tendency to decompose even near its thermal limits. This trait alone saves headaches for teams who have watched other similar materials fail in pilot reactors.

    We don’t view BSMIM OTf only through technical data; we see it as something that solves bottlenecks in high-performance electrochemistry, selective extractions, and advanced catalysis. In our facilities, technical teams focus on every step, from precise synthesis to streamlined purification, to keep trace impurities low. This hands-on approach lets us respond rapidly, especially when tight tolerance grades are requested for projects with high compliance demands.

    How BSMIM OTf Stacks Up in Real Workflows

    Comparing one ionic liquid to another reveals details that lab books often gloss over. Our colleagues regularly remark on BSMIM OTf’s compatibility with a wider range of metal cations and transition states. That comes from the influence of the trifluoromethanesulfonate anion, which doesn’t coordinate strongly to metal centers. Chemists mixing up metal salt solutions often comment on clearer solutions and consistent behavior compared to ionic liquids based on halide or tetrafluoroborate anions.

    Colleagues working on CO2 capture and organic transformations point out that the butylsulfonic group brings extra hydrophilicity and facilitates ion movement. In multi-phase setups, where other ionic liquids form stubborn emulsions or resist phase-transfer tasks, BSMIM OTf improves distribution and speeds up reactions without extra tweaks or surfactant additives. Our team noticed that extraction rates and yields can improve even when scaling up from bench to pilot runs.

    From direct experience, users note BSMIM OTf keeps its performance after repeated cycles. Instead of degrading in presence of acid traces or oxidizing agents, it resists many such breakdown paths. This comes from the stability both the imidazolium core and the trifluoromethanesulfonate anion offer. The sulfonic side-chain remains inert even when some residual water or acidic vapors enter the system. That’s helped chemical plants and academic labs reduce waste and downtime alike.

    Specifications Rooted in Practice

    Our standard BSMIM OTf batches meet demanding water, halide, and organic impurity targets. Typical synthesis lines produce material with moisture below 500 ppm fresh out of the reactor, and technicians monitor every load for residual chloride and organic by-products. Because requests differ by project, we routinely adjust final drying and filtration to supply material for analytical, preparative, and scale-up work alike.

    Rather than simply offering lab-grade options, we maintain several qualification lots specifically for energy storage prototypes and process R&D lines. These specialties derive from input gathered directly from field engineers and formulation teams who saw their work hit snags because of drift in purity or trace contaminant content. Their feedback led us to integrate extra purification points, inert-gas handling steps, and batch-segregation protocols into every lot intended for sensitive equipment or electrosynthesis projects.

    We handle storage conditions and final packaging with hands-on care. On the shop floor, we keep BSMIM OTf away from excess heat and moisture, storing it in fluoropolymer-lined drums or amber glass depending on client needs. Shipping teams confirm container integrity at each step, a process that grew out of long experience supplying ionic liquids worldwide and learning where seal or liner failures tend to show up.

    Standing Apart from Other Ionic Liquids

    BSMIM OTf’s practical differences stand out most once users engage with solvents, catalysts, or electrolyte prototypes. Many off-the-shelf ionic liquids struggle with selective solubility and reproducibility in real chemical environments. Imidazolium halides, for example, bring trace halogen risks which catalysis teams try hard to avoid. Tetrafluoroborates, while stable enough at lower heats, break down under harsher conditions, leading to unpredictable performance and extra cleaning steps. BSMIM OTf, based on our trials and years on the factory line, bypasses these issues with better thermal stability and freedom from halide breakdown.

    Another area where this product stands out relates to residual conductivity across temperature ranges. Battery research labs and electrochemical engineers highlight how BSMIM OTf maintains ionic flow even as cells cycle through freezing or high-temperature states. Many other ionic liquids exhibit sluggish behavior or sharp conductivity loss as temperatures fall below room temperature. You can see this most clearly in next-generation battery pilots, where the demand for safe, constant performance runs up against the limits of older salt mixes.

    Our team takes pride in the record of real, in-the-field runs rather than just marketing promises. From extraction trials at pilot plants to custom synthesis runs in university labs, BSMIM OTf has earned its keep by lasting longer, causing less trouble with fouling, and supporting more ambitious project timelines. Teams send direct feedback—not just numbers, but stories of easier purification steps or longer reactor uptime compared to previous formulas.

    Common Usage Scenarios

    BSMIM OTf shows up in research and industry wherever tunable ionic environments are critical. On our own shop floor, the compound’s unique cation makes it compatible with an expanding menu of metal salts and organic reactants. That flexibility opened doors for R&D labs chasing higher selectivity in phase-transfer catalysis or greener paths to complex molecules. It’s now common to see BSMIM OTf used as a non-volatile solvent in high-value extractions. Teams also use it in sustainable processes, where reducing hazardous waste has both regulatory and economic value.

    In energy research, this ionic liquid finds a place in test cells and experimental supercapacitors where stability and wide liquid phase range matter. Users report smoother operation and fewer cell failures compared to selections based on early-generation ionic liquids. Process chemists blending electrolytes for specialty batteries appreciate that BSMIM OTf tolerates mishaps with ambient humidity better than competitors, helping to keep test cycles on track.

    We’ve seen catalytic runs for C–C and C–N coupling reactions bypass steps necessary with traditional alkylimidazolium systems, thanks to the sulfonic acid’s ability to moderate microenvironments and the low nucleophilicity of the OTf anion. Instead of clogging lines or forming persistent salt stubs, spent BSMIM OTf often remains clear and readily recyclable, cutting overhead from extra cleaning.

    Beyond chemical manufacturing, specialists in optics and electronics have developed pilot projects where BSMIM OTf’s low volatility and chemical inertness underpin thin-film deposition and specialty coating processes. Having supplied ionic liquids to those teams, we watched their shift to BSMIM OTf directly—from complex purification steps using old blends, to more streamlined operations with fewer failures. Their feedback looped back into our QC and production methods, inspiring even tighter contaminant controls.

    Tackling Industry Challenges: From Scale to Sustainability

    Supplying niche ionic liquids means navigating raw material cost swings, scale-up hurdles, and regulatory oversight. BSMIM OTf synthesis depends on specialized intermediates, so process improvements and waste reduction routines matter a lot. We lean on decades of technical experience to manage batch consistency, trace impurity reduction, and safe handling procedures. Teams meet daily to discuss small tweaks that yield tighter output variance or minimize loss and waste.

    Worker and user safety drives every update. Because OTf-based ionic liquids draw regulatory scrutiny, we keep lab records and production logs tight. Every change, whether it’s increased distillation throughput or an improved inert-atmosphere filter, gets logged for both internal traceability and external audits. This mindset means end users—professional chemists, process engineers, and R&D teams—can count on BSMIM OTf batches to arrive in-spec and behave as promised.

    Environmental responsibility sits at the center of our efforts. As ionic liquids grow more common in mainstream chemical and energy industry, the push for lower toxicity, reduced volatility, and cutback in halogen or heavy metal residues influences everything from our purchasing decisions to how we manage spent intermediates. BSMIM OTf’s chemical profile—free from persistent halides, easily separated from many waste streams—matches those aims better than many older-generation chemicals. Operations teams recycle side-products or repurpose off-spec batches for process optimization trials, squeezing efficiency from every step.

    As client needs shift, we keep lines flexible. This means readiness to produce custom grades or to tweak packaging or container types for specific regulatory or logistical challenges. That flexibility grows from direct feedback; it’s not abstract, but built from conversations with battery developers, academic chemists, and field engineers who count every hour and every gram in pilot and plant runs.

    What Sets Manufacturer-Supplied BSMIM OTf Apart

    Manufacturing BSMIM OTf in-house brings practical advantages that traders and third-party distributors struggle to replicate. Maintaining direct control over synthesis, purification, and logistics means we catch small issues before they cascade into supply disruptions. This hands-on approach acts as an early-warning system; seeing subtle color or texture shifts at the filter stage prevents downstream headaches.

    Feedback from our partners in energy storage, catalysis, and chemical extraction often lands in production meetings the same week. Those suggestions guide process tweaks, such as adjustments in reaction temperature or holding times during purification. We engage directly with teams seeking application-specific formulations, tailoring every batch closely to laboratory needs. This direct loop from application to factory floor speeds up troubleshooting, helps keep purity on target, and cuts out layers of translation loss between user and producer.

    Long-term partnerships with raw materials suppliers offer us dependable access even during market shake-ups. That consistency ensures clients see short lead times and predictable delivery windows—an advantage built over years of mutual trust, precise forecasting, and persistent communication. It’s a lesson learned each time sudden demand surges hit other specialty chemicals, cutting off smaller or less-connected suppliers.

    Our engagement doesn’t end at the loading dock. Plant engineers—some with decades of experience on the same lines—field technical questions directly. This practice grew naturally: clients prefer working with someone who knows the shop floor, not only the sales office. Troubleshooting flows easier, giving users confidence as they push BSMIM OTf into new niches or larger scale runs.

    Supporting Innovation, One Batch at a Time

    We make BSMIM OTf not only to meet today’s research and industrial needs, but also to support the next breakthroughs. Our product has already played key roles in projects seeking low-carbon paths to fine chemicals, safer electrolytes for grid storage, and cleaner separations for pharmaceutical development. That comes down to persistence in keeping quality high, listening closely to process engineers and lab chemists, and staying flexible as projects evolve.

    We took lessons from each hurdle—unexpected impurities, tricky filtration steps, fouling at the crystallization stage—and built them into new protocols. Those updates ripple out, improving not just BSMIM OTf quality, but the shape of every ionic liquid batch our shop produces. The direct conversations with users help us see around corners; it’s not theory, but the outcome of process trials and scaled-up runs that yielded more resilient, easier-to-use materials.

    We see more labs and chemical innovators shifting to BSMIM OTf, drawn by reliability and chemical transparency after disappointments with less consistent materials. The lessons they learned—shared openly with us—have helped sharpen every aspect of manufacture, from process chemistry to packaging, and from compliance tracking to safe transport. Every lot carries this combined experience, distilled into practical gains for the next project down the line.

    Our work doesn’t end when we solve today’s questions. As research, policy, and environmental goals change, so do the expectations for BSMIM OTf. We ramp efforts to minimize waste, find greener synthesis partners, and create new quality assurance steps as soon as challenges crop up in the field. It’s a process of continual improvement and open feedback—a loop supported by everyone who chose to work directly with the source.

    Delivering Value Through Trusted Manufacturing

    For those seeking more stable ionic environments, improved extraction cycles, or better-performing batteries and catalysts, BSMIM OTf brings proven, practical value. We stand behind it not as salespeople, but as the team that built each lot, checked each drum, and responded to each batch trial. Every improvement or workaround in process steps grew from a real need, not wishful thinking or theory. By working with project leaders and field staff, we translate years of hands-on practice into each kilogram shipped.

    The real measure of any specialty chemical comes not from glossy brochures or one-size-fits-all claims, but from direct results after application in challenging processes. For us, BSMIM OTf proves its worth every time a user reports higher yields, cleaner extracts, longer catalyst lifespans, or smoother system cycles. We’ve watched it unlock new opportunities across industries and research groups, and we keep building on that foundation with each successive batch.

    Supplying BSMIM OTf means staying ahead of challenges—whether that’s batch scale-up, quality consistency, logistical complexity, or changing regulatory standards. Each time the industry faces a new demand, we turn to our own process data, listen to on-the-ground reports, and build improvements directly into manufacturing routines. The product known as 1-Butylsulfonic-3-Methylimidazolium Trifluoromethanesulfonate ends up reflecting not just chemical engineering, but the ongoing dialogue between those making it and those putting it to work.