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1-Allylnaphthalene

    • Product Name 1-Allylnaphthalene
    • Alias 1-Allyl-naphthalene
    • Einecs 211-034-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
    VTB
    Specifications

    HS Code

    370290

    Name 1-Allylnaphthalene
    Cas Number 132-86-5
    Molecular Formula C13H12
    Molar Mass 168.23 g/mol
    Appearance Colorless to pale yellow liquid
    Boiling Point 292-294 °C
    Melting Point -38 °C
    Density 1.04 g/cm³
    Refractive Index 1.607
    Flash Point 124 °C
    Synonyms 1-Naphthalenylpropene, 1-allyl-naphthalene
    Solubility In Water Insoluble
    Pubchem Cid 11754

    As an accredited 1-Allylnaphthalene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1-Allylnaphthalene is supplied in a 100 mL amber glass bottle with a secure cap, labeled with safety and chemical information.
    Shipping 1-Allylnaphthalene should be shipped in tightly sealed containers, protected from light and moisture, and stored in a cool, well-ventilated area away from sources of ignition. Ensure compliance with local regulations for transporting chemicals. Proper labeling and handling precautions are required to prevent leaks, spills, or exposure during transit.
    Storage 1-Allylnaphthalene should be stored in a cool, dry, and well-ventilated area, away from sources of ignition or heat. Keep the container tightly closed and protect it from light and moisture. Store separately from oxidizing agents and acids. Ensure that appropriate spill containment and fire-fighting equipment are available nearby in case of accidental release or fire.
    Application of 1-Allylnaphthalene

    Applications of 1-Allylnaphthalene in Industrial Manufacturing

    1-Allylnaphthalene serves as a key intermediate in several downstream chemical manufacturing sectors, offering specific functional value in synthetic processes for specialty chemicals, performance materials, and fine chemical end-uses. Our experience as a primary chemical producer ensures process knowledge from scale-up to quality assurance, supporting efficient application in select industries where advanced organic synthesis and high purity are essential.

    1. Advanced Dye Intermediates Production

    Manufacturers rely on 1-allylnaphthalene as an important building block during the multi-step synthesis of complex naphthalene-based dyes, particularly for applications requiring enhanced light fastness and color stability. The material typically enters condensation or alkylation reactions, where process control over side products and purity ensures downstream pigment performance. Performance requirements in industrial and technical textile dyeing demand high-purity streams and stringent impurity profiles. Downstream operators must implement defined purification and QC stages due to the influence of side-chain functionalization on final dye shade strength and durability.

    Industry compliance standards

    • REACH Annex XVII – Restrictions on hazardous naphthalene compounds
    • OEKO-TEX Standard 100 for textile chemical safety
    • EN 71-3 (Safety of Toys - migration of certain elements for pigments used in children's textiles and toys)
    • ISO 9001:2015 (Quality Management Systems)

    Typical usage ratio

    • Allylnaphthalene input is 12%–18% by mol in the naphthalene/pigment precursor stage, with adjustments based on color intensity specifications and required dye purity; higher loadings may be adopted for deeper shade formulas.

    Downstream process integration

    • Charged into the alkylation reactor with naphthalene core substrates in presence of strong base catalyst.
    • Intermediate fraction purified before subsequent nitration or azo-coupling reactions.
    • QC sampling after each reaction stage to monitor for unwanted side-chain byproducts or incomplete conversion.
    • Final intermediates isolated before being finished into powder or paste dyes for textile mills.

    Final product types

    • Reactive dyes for cellulose fibers
    • Disperse dyes for polyester and acetate textiles
    • High-performance pigments for automotive coatings
    • Colorants for technical plastics, engineering resins, and printing inks

    2. Synthesis of Naphthyl-based Agrochemical Actives

    Our customers employ 1-allylnaphthalene in creating novel naphthalene frameworks used in crop protection agents and plant growth management. As a precursor, it undergoes functionalization via Friedel–Crafts-type alkylation and epoxidation steps to generate intermediates critical for structure-activity relationships in specialty agrochemicals. Strict process control governs the introduction and subsequent modification of the allyl group, as consistency at this stage impacts biological behavior and regulatory compliance in the final active.

    Industry compliance standards

    • EU Regulation (EC) No 1107/2009 (placing of plant protection products on the market)
    • US EPA 40 CFR Part 180 (tolerances and exemptions for pesticide chemicals in food)
    • ISO 17025 (Testing and calibration laboratories for final product quality validation)
    • Good Laboratory Practice (GLP, OECD)

    Typical usage ratio

    • 5%–15% by weight of active ingredient precursor mass; varies according to the agrochemical’s molecular design constraints, functional group introduction route, and targeted activity spectrum.

    Downstream process integration

    • Added to the initial synthesis vessel during allylation and naphthalene ring modification.
    • Intermediate crystallized and further derivatized in secondary synthesis line.
    • Process monitored for yield and purity, especially for trace allyl side products affecting environmental fate.
    • QC and compliance checks before formulation into technical concentrates.

    Final product types

    • Pre-emergent herbicide actives featuring naphthyl backbones
    • Plant growth regulators for horticulture and field crops
    • Seed treatment agents based on naphthalene-derived scaffolds
    • Selective insecticides and fungicides for specialty crops

    3. Polymer Modifier Synthesis for Performance Plastics

    Compounders and resin manufacturers use 1-allylnaphthalene as a reactive monomer precursor, especially for designing high glass transition temperature (Tg) thermoplastic and thermoset polymers. Its naphthalene structure imparts rigidity and chemical stability, while the allyl group offers functional reactivity during polymer chain extension or cross-linking. Typical applications include modifying engineering plastics to improve dimensional stability, chemical resistance, or fire retardancy profiles, demanding precise stoichiometry and strict controls on monomer batch homogeneity to avoid polymerization defects.

    Industry compliance standards

    • UL 94 (Tests for flammability of plastic materials)
    • RoHS Directive (2011/65/EU, Restriction of Hazardous Substances)
    • EN ISO 11357 (Thermal analysis, DSC method – for polymer development)
    • ISO 14001 (Environmental Management Systems for manufacturing site control)

    Typical usage ratio

    • 0.2%–5.0% by weight of total monomer feed; dosage varies according to target resin properties, with increased proportions in high-Tg formulations for structural applications.

    Downstream process integration

    • Pre-mixed with primary monomers such as styrene, acrylonitrile, or epoxy precursors prior to chain initiation.
    • Allyl site participates in free-radical or ionic polymerization to introduce pendant aromatic units.
    • Finished polymer batches subjected to QC analysis for molecular weight distribution and cross-link density.
    • Modified pellets or resins granulated and tested for fire performance and mechanical strength before being shipped to molders or extruders.

    Final product types

    • Engineering thermoplastics for automotive and electrical components
    • Flame-retardant polymer compounds for electronic housings
    • Heat-resistant composite prepregs for aerospace interiors
    • Chemically stable specialty films for industrial packaging

    4. Intermediates Manufacture for Fine Organic Synthesis

    Chemical manufacturers specializing in fine chemicals integrate 1-allylnaphthalene as a scaffold for multi-step custom molecule assembly. Its unique aliphatic-aryl structure allows for targeted substitution, cross-coupling, or cyclization, enabling access to specialized aromatics used in advanced catalysts, pharmaceutical research, and optical materials. Proper stage sequencing, strict solvent selection, and monitoring minimize side-chain migration or polyalkylation, crucial for downstream purity and performance in high-value custom organics where documentation and traceability are mandatory.

    Industry compliance standards

    • IPEC-PQG GMP Guide for Pharmaceutical Excipients (as required for research intermediates)
    • ISO 9001:2015 – batch traceability and change management
    • 21 CFR Part 211 (for GMP traceability where utilized in pharma R&D)
    • Responsible Care / ChemStewards Management Practices

    Typical usage ratio

    • 0.5–6.0 molar equivalents in target synthetic schemes; selection depends on target product skeleton and functional group transformations, adjusted based on conversion efficiency.

    Downstream process integration

    • Charged at the initial ring functionalization or as a nucleophile in Suzuki/Mizoroki coupling steps.
    • Reacts with halide or organometallic intermediates in presence of tailored catalysts.
    • Pilot plant processes frequently recycle mother liquor and monitor impurity profile by GC/MS or HPLC.
    • Intermediates shipped as solids or solutions under temperature-controlled protocols for subsequent conversion by customers’ synthesis teams.

    Final product types

    • Pharmaceutical research intermediates for early-stage drug synthesis
    • Ligands or pre-catalysts for homogeneous or heterogeneous catalysis
    • Optical brightener intermediates for LCD and lighting panels
    • Custom-tailored aroma chemicals and flavor precursors for specialty applications
    Free Quote

    Competitive 1-Allylnaphthalene prices that fit your budget—flexible terms and customized quotes for every order.

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    Certification & Compliance
    More Introduction

    Introducing 1-Allylnaphthalene: A Modern Approach from the Manufacturer’s Perspective

    Real-World Insight into 1-Allylnaphthalene Production

    Working in chemical manufacturing, demands of consistency, purity, and safety never really let up. Over the past decade, 1-Allylnaphthalene has become a steady fixture in our product line. Every production batch reflects the daily effort of the people running our reactors, keeping impurities in check and ensuring traceability from raw material booking to final material handover. This material, with its straightforward naphthalene core and a single allyl group, seems simple on a sheet of paper. But reality introduces plenty of variables—reaction selectivity, careful distillation, specific storage settings—these details drive the meaningful performance customers find valuable.

    About the Product: Chemical Character and Manufacturing Practice

    Our 1-Allylnaphthalene starts its journey with naphthalene sourced directly through established upstream partners, not cargo that’s changed hands several times. We rely on tested alkylating agents, and everyone on our process team knows that the key to hitting the 99+% GC purity comes from disciplined reaction temperature and atmosphere control. The allyl group sits at the first position on the ring, which gives it a distinct reactivity, setting it apart from isomeric products where the allyl group sits elsewhere.

    The physical appearance often offers immediate feedback—colorless to pale-yellow liquid, low-melting, faint odor that sometimes escapes during tank transfers. Our typical packaging involves sealed stainless drums or lined glass containers for smaller quantities since leaks mean both loss and unnecessary exposure. We do not relax our standards: water remains under the analytical specification, and aromatics with similar boiling points receive close scrutiny through GC-MS confirmation. We train our technicians to spot off-spec product by both instrumentation and practical checks, since small amounts of over-alkylation or isomer formation will show up later in synthesis chains.

    Where 1-Allylnaphthalene Fits: Applications Built on Practical Chemistry

    The real importance of 1-Allylnaphthalene can’t be appreciated from a technical index alone. Most users come from the world of specialty polymers or advanced intermediate synthesis, and many have spent years searching for materials that balance reactivity with manageable volatility. We have followed our product into large-scale pharmaceutical plants, pilot lines making performance resins, and research benches working on organometallic catalysis.

    Our customers often look to 1-Allylnaphthalene as a key starting point in building more complex naphthalenic structures. The allyl group allows for straightforward Diels-Alder cyclization or further functionalization—direct routes that save steps, cost, and lab waste. In practical terms, this translates to fewer purification cycles, more predictable batch-to-batch yields, and easier compliance audits for downstream users. It’s become a quiet workhorse in the labs of those developing next-generation ligands, certain types of lightfast dyes, and even some unique rubber-reinforcing additives.

    Many users bring us real challenges: scale-up support, alternative packaging to minimize waste, or technical advice on storage to prevent unwanted polymerization. Our product managers work shoulder-to-shoulder with our QC team, reviewing customer feedback and running trial adjustments if project needs shift. In one example, we partnered with an industrial coating producer to modify our handling process since their storage tanks sometimes led to slow discoloration over weeks. By introducing trace stabilizers and tightening moisture specs, they cut material loss by a third—and saw more consistent curing in their finished product.

    Product Model and Specifications: Focus on Practical Features

    Although we avoid “one size fits all” approaches, our most requested grade clocks in at GC purity above 99%, water content no higher than 0.1%, and color no deeper than APHA 20. Each lot receives an individual certificate confirming these traits, and our technical sales team double-checks results before signing off. Some customers with low impurity tolerance (especially in medical synthesis) opt for further treated material—smaller batches, extra distillation cycles, sometimes even molecular sieve drying. That flexibility in the plant means customers do not need to clean up after us on their production floor.

    Working in a manufacturing setting, small process shifts can matter more than raw specs. A colder distillation column drives higher recovery, but just a few degrees too low can let high-boiling naphthol drag in; raising pressure too fast pushes light-ends over and erases the purity advantage. Dozens of operational controls go into each drum of 1-Allylnaphthalene, and these choices appear on the resulting COA—not just numbers entered into a spreadsheet, but lived experience from those running the plant.

    Differentiation: What Sets Our 1-Allylnaphthalene Apart in the Field

    It’s easy to treat chemicals like commoditized widgets, but experience shows that narrow-purity and consistent handling win repeat business. We often hear from clients burned by variable quality from previous suppliers. Some batches show subtle shifts in reactivity—not immediately obvious until key reactions behave unpredictably. With 1-Allylnaphthalene, the difference starts with single-point sourcing and stable transportation: our drums move quickly from synthesis shop to packaging to outbound dock without prolonged storage under poor conditions.

    We invest in process redundancy, and our in-house GC/MS analytics run at multiple points along the filling path. If any lot strays near specification limits, contents return to reprocessing or are set aside for non-critical grade use. Our plant workers too notice the difference—a drum that loads clean, a tank that holds stable color for a full production run, downstream reactions that “click” without adjustment. This reliability is a result of manufacturing experience, not just chemical theory.

    Most other products on the market—especially material from brokers trading surplus—arrive several months post-production and sometimes lack proper analytical history. By staying close to our own process and keeping logistics streamlined, we monitor integrity all the way through delivery. We let customers observe our facility audits if their own compliance standards call for it. Direct feedback from one polymer synthesis client led us to tighten our filtration procedures two years ago, cutting down on carryover and other trace contaminants.

    Many competing naphthalenes offer similar technical outlines on data sheets but introduce headaches downstream—reactivity drifts, more colored fractions, or stability issues during transfer. End users working in performance-sensitive industries (think pharmaceuticals, specialty coatings, or electronics) have no time or budget for lengthy trouble-shooting. Our consistent product minimizes that risk, so that formulation and scale-up progress smoothly.

    Direct Manufacturing Experience: Challenges We Solve with Practice and Persistence

    Running a chemical plant isn’t just about automation and SOPs. In the case of 1-Allylnaphthalene, much of the operational wisdom comes from adjusting in response to production anomalies. Hot spots in the alkylation reactor can introduce unexpected side products, so we stage-in feeds and monitor temperature gradients manually—an approach that’s reduced problem batches by half compared to early years. We maintain a running troubleshooting guide based on plant logs, not just whiteboard theory. Near-reactor sampling remains a critical tool; waiting for post-batch lab analytics loses hours if off-spec material appears.

    We treat downtime as learning moments. About four years ago, a utility failure forced us to recover an “overcooked” batch. Instead of sending the whole thing to waste, plant leadership coordinated a controlled re-distillation, tracked contaminant markers, and ended up salvaging 70% of the product without compromising purity. That real-world experience translates directly into robust process steps—and, crucially, into support for clients needing rush orders or quick scale-ups.

    Training new operators calls for both technical depth and procedural clarity. Old hands pass on lessons about valve settings, sight-glass readings, and recognizing the appearance of fouling or color drift in transparent lines. These observations help the line keep material in specification, prevent incidents, and preserve the equipment across long campaigns. Many high-turnover sites miss these subtleties, leading to unnecessary equipment changeouts or rejected loads.

    Our close-knit process team prefers to catch deviations early, emphasizing good operator rounds before automation flags a variable out of control. Years of handling 1-Allylnaphthalene have proved that human skill, backed up by data, matters when producing high-value intermediates. Customer site visits reinforce this—seeing technical staff answer practical questions and demonstrate plant practices instills confidence, particularly for clients working under tight regulatory regimes.

    Applications: Depth in Downstream Use Cases

    Out in the real market, chemists and engineers push 1-Allylnaphthalene into some demanding syntheses. The product’s allyl group offers a practical attachment point for chain extension, functional group modification, and cross-coupling transformations. Diels-Alder cyclization remains a favorite route, thanks to efficient ring closure and minimal byproduct generation. In polymer research, the material serves as a monomer or co-monomer in performance plastics, contributing rigidity and optical clarity to end-use profiles.

    Some labs pursue novel catalyst development, using 1-Allylnaphthalene as a ligand parent for metal complexation. Across the dye and pigment sector, its presence supports stability and colorfastness in demanding applications—from inks to specialty coatings and UV-resistant plastics. A Japanese customer in the specialty surfactants segment leverages the unique binding profile of the allyl group, opening up performance not seen in older naphthalene derivatives.

    Similar compounds—like 2-allylnaphthalene or simple naphthalene alkylates—show different reactivity and require different purification steps. These variations aren’t mere chemical trivia. We’ve worked alongside formal process chemists to troubleshoot unwanted side-reactions: double-alkylation from positional isomers, waste generation from sub-optimally placed double bonds, endpoint drift due to impurity accumulation. Our material’s positional precision (allyl at carbon #1) prevents such headaches, streamlining both scale-up and validation in demanding regulated fields.

    Batch documentation, full traceability, and close communication remain table stakes as regulatory scrutiny continues to grow. Supply chain interruptions are real—pandemics, severe weather, or political events have all forced customers to re-examine priorities. Our commitment to holding key stock and supporting custom batch timing ensures fewer project bottlenecks and better adoption into customer R&D and production. Time after time, researchers confirm that a dependable supply chain ranks alongside purity as a top purchasing driver.

    Addressing Real-World Issues: Safety and Environmental Considerations

    Safety leadership underpins every run. With 1-Allylnaphthalene, we monitor ventilation, operator PPE, and emergency response drills. Our environmental controls capture vented organic vapors and collect spent streams for responsible disposal. Compliance is not a box checked for us—auditors visit, inspect, and consult on process improvements. This relationship with regulatory and watchdog groups reduces surprises, keeps us current with evolving regional standards, and reassures end users of safe, responsible sourcing.

    A critical difference between a manufacturer and a simple reseller comes from this safety engagement. If a customer asks about batch traceability, we answer from firsthand records. If storage concerns arise—say, about temperature sensitivity or the prevention of light-induced degradation—we deliver procedures based on our own failures and course corrections, not textbook hypotheticals. When supply shocks ripple through the industry, we bring honest answers about timelines, production ramp-ups, or alternative sourcing from our own facilities.

    Sustainable operations drive our long-term reputation. Waste minimization programs reclaim off-gas, and routine process audits catch inefficiencies before they worsen. Our engineering team directs upgrades so that energy use per ton of product keeps dropping. By keeping a consistent dialogue with local communities and responsible agencies, our facility integrates into the neighborhood rather than isolating itself behind walls.

    Reviewing Customer Success: Building Long-Term Trust

    Several long-term clients testify to the gains they’ve made after switching to our production—mainly shorter qualification runs, lower off-grade rates, and more reliable behavior in complex synthetic steps. Real feedback from manufacturers in the pharmaceutical sector led us to reinforce our cleaning regime, minimizing risk of contamination and supporting fast-track regulatory audits. These real world advantages matter more for product adoption than abstract specification listings or marketing claims.

    Through open channel communication, customers alert us to rare performance issues or special handling needs. We have modified packaging configurations and updated cold-chain protocols based on these lessons. For global shipments, we maintain data loggers in containers to keep both clients and our own QA group informed. In the rare event of a quality deviation, our direct reporting structure means feedback routes straight to operations—closing the loop quickly without getting bogged down in intermediaries or disconnected sales desks.

    Future development hinges on a two-way knowledge flow. By partnering with top users for bench-to-plant piloting, we stay ahead of evolving performance needs and regulatory shifts. New application pathways sometimes push processing techniques into new territory, and we’re always willing to run pilot trials or adjust formulations as processes change. This direct line to customers keeps us grounded and ensures our 1-Allylnaphthalene stays relevant as applications develop.

    Continuous Improvement: A Manufacturer’s Outlook

    The field keeps moving—new demands arrive, regulation tightens, and competitors attempt to match quality. As longtime producers of 1-Allylnaphthalene, we know there’s no finish line to hitting the mark. Investments in analytical capability, staff knowledge, and process upgrades are ongoing. Product reliability lets customers focus on discovery and manufacturing, not on chasing down sources of variability or quality compromises.

    By focusing on traceable production, true operational discipline, and close customer integration, we keep 1-Allylnaphthalene fit for increasingly demanding uses. End users have real-world stakes—whether for precise pharmaceutical synthesis, high-value materials, or emerging electronics applications, downtime or off-grade lots have real costs. Our years in the business, daily attention to process, and genuine respect for the chemists and engineers who rely on our materials shape every decision around quality and delivery.

    For clients choosing between paper promises and process-tested supply, that difference becomes clear after a few shipments—minimal surprises, responsive support, and true accountability in every batch that leaves the gate.