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1-Allyl-3-Hexylimidazolium Chloride

    • Product Name 1-Allyl-3-Hexylimidazolium Chloride
    • Alias [APrMIm][Cl]
    • Einecs 700-110-1
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    838583

    Chemical Name 1-Allyl-3-Hexylimidazolium Chloride
    Molecular Formula C12H21ClN2
    Molecular Weight 228.76 g/mol
    Appearance Viscous liquid or crystalline solid
    Color Colorless to pale yellow
    Odor Mild
    Solubility In Water Highly soluble
    Melting Point Approx. 40-60°C
    Boiling Point Decomposes before boiling
    Density Approx. 1.0-1.1 g/cm³
    Storage Temperature Room temperature (15-25°C)
    Ph Neutral to slightly acidic in solution
    Stability Stable under recommended conditions

    As an accredited 1-Allyl-3-Hexylimidazolium Chloride factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1-Allyl-3-Hexylimidazolium Chloride, 25g: Supplied in a sealed amber glass bottle with tamper-evident cap, labeled with chemical details and safety warnings.
    Shipping 1-Allyl-3-Hexylimidazolium Chloride is shipped in tightly sealed containers, protected from moisture and extreme temperatures. It is classified as a hazardous material, requiring proper labeling and documentation according to relevant regulations. Personal protective equipment should be used during handling, and shipment is typically by ground or air under controlled, secure conditions.
    Storage Store 1-Allyl-3-hexylimidazolium chloride in a tightly sealed container, away from moisture and incompatible substances such as strong oxidizers. Keep it in a cool, dry, and well-ventilated area, ideally at room temperature. Avoid exposure to heat, direct sunlight, and open flames. Ensure proper labeling and access only to trained personnel. Handle with appropriate protective equipment.
    Application of 1-Allyl-3-Hexylimidazolium Chloride

    Applications of 1-Allyl-3-Hexylimidazolium Chloride in Industrial Manufacturing

    As a producer specializing in high-purity ionic liquids, we supply 1-Allyl-3-Hexylimidazolium Chloride to advanced industrial customers seeking reliable performance and regulatory compliance. The following sections outline primary downstream uses, integrated into customer production lines under specific industry requirements.

    1. Electrochemical Capacitor Electrolytes

    1-Allyl-3-Hexylimidazolium Chloride serves as a key ionic liquid additive in high-performance electrolytes for supercapacitor and electrochemical double-layer capacitor (EDLC) production. Its chemical stability at elevated voltages increases energy density and operating life of device cells. Our customers blend the ionic liquid during electrolyte formulation to meet targeted conductivity and suppression of volatilization under load cycling.

    Industry compliance standards

    • IEC 62391-1:2020 for fixed electric double-layer capacitors for use in electric and electronic equipment
    • RoHS Directive (EU) 2011/65/EU restrictions for hazardous substances
    • REACH Regulation (EC) No. 1907/2006 for registration and safe handling
    • UL 810A for electrolytic capacitor safety

    Typical usage ratio

    • Ranges from 2% to 15% w/w in base electrolyte solutions, adjusted to achieve specific ionic conductivity and electrochemical window based on device cell design and voltage specifications

    Downstream process integration

    • Blended with organic electrolytes during slurry preparation before vacuum drying and electrolyte impregnation of electrode assemblies for cell stacking and sealing

    Final product types

    • Electrochemical double-layer capacitors (EDLCs)
    • Hybrid supercapacitors
    • High-voltage energy storage modules
    • Automotive regenerative braking capacitor packs

    2. Cellulose Dissolution for Specialty Fiber Spinning

    Downstream producers in the man-made cellulosic fiber sector adopt this ionic liquid as a cellulose solvent in viscose-free fiber spinning processes. It enables dissolution and regeneration of dissolving pulp to form high-tenacity, low-impurity fibers. Process engineers control dosing and temperature to achieve repeatable solubilization while meeting emission regulations on process residues.

    Industry compliance standards

    • OEKO-TEX Standard 100 for textile chemical safety
    • ZDHC MRSL v3.1 (Zero Discharge of Hazardous Chemicals Manufacturing Restricted Substances List)
    • ISO 9001:2015 for quality management in fiber production
    • European BAT (Best Available Techniques) for textile processing

    Typical usage ratio

    • Ranges from 5% to 20% w/w based on cellulose concentration, viscosity control and degree of polymerization of starting pulp

    Downstream process integration

    • Charged into cellulose/xylene dissolution reactors, combined with activating water, followed by filtration and wet spinning extrusion into a coagulation bath for fiber regeneration

    Final product types

    • Lyocell fibers
    • High-purity cellulosic staple textiles
    • Medical wound dressing fibers
    • Technical textile filaments

    3. Catalytic Medium for Organic Synthesis

    Chemical manufacturers use 1-Allyl-3-Hexylimidazolium Chloride as an ionic liquid medium for selective alkylation, acylation, and cross-coupling reactions, benefiting from strong solubilizing power and recyclability. The material supports late-stage process intensification and enables improved yield and phase separation in complex molecule synthesis. Production plants monitor ionic liquid residuals in accordance with pharmaceutical or industrial quality requirements.

    Industry compliance standards

    • ICH Q7 Good Manufacturing Practice for Active Pharmaceutical Ingredients
    • 21 CFR Part 211 cGMP for drug product synthesis
    • ISO 14001:2015 for environmental management in specialty chemical production
    • REACH Annex XVII restricted substance screening in the EU

    Typical usage ratio

    • Acts as the principal solvent phase or co-solvent, with loading typically from 10% to 60% v/v relative to substrate concentration; optimized to reaction kinetics and downstream recovery requirements

    Downstream process integration

    • Introduced in batch or continuous flow reactors at the solvent charging stage, maintained throughout reaction, then separated for recovery prior to product workup and crystallization

    Final product types

    • Pharmaceutical intermediates
    • Fine chemical building blocks
    • Agrochemical actives
    • Functionalized specialty monomers

    4. Antistatic Agent in Engineering Plastics Compounding

    Major engineering plastics compounders select this ionic liquid as a functional antistatic additive for PC, ABS, and polyamide masterbatch compounding. It provides rapid charge dissipation and persistent static suppression in molded parts used for electronics and automotive assemblies. The additive disperses rapidly during extrusion, with dosage adjusted according to resin polarity and targeted static decay times as measured by surface resistivity testing.

    Industry compliance standards

    • UL 94 for flammability of plastic materials
    • ISO 11443 for polymer melt flow behavior
    • EN 61340-5-1 electrostatic discharge (ESD) protection for electronics manufacturing
    • FDA 21 CFR 177.1580 (for limited food contact applications, where permitted)

    Typical usage ratio

    • Typical addition in the range of 0.2% to 1.5% by weight, based on targeted surface resistivity and optical clarity requirements; elevated for highly insulative base resins

    Downstream process integration

    • Metered into twin-screw extruders or melt mixers, blended during compounding prior to masterbatch pelletizing, followed by downstream injection molding or extrusion into finished shapes

    Final product types

    • ESD-safe housings for electronics
    • Automotive interior panels
    • Data storage component carriers
    • Electronic device connectors

    5. Ion-Exchange Media in Rare Earth Element Extraction

    Metallurgical operations involved in rare earth element (REE) separation employ 1-Allyl-3-Hexylimidazolium Chloride as an ionic liquid phase for selective solvent extraction of lanthanides and actinides. Its tunable cation/anion chemistry improves separation factors and enables metal recovery with minimized environmental impact. Technical teams calibrate ionic liquid composition and contact times for optimized stage efficiency and regenerative operation of extraction trains.

    Industry compliance standards

    • ISO 9001:2015 for mining and metals processing operations
    • ISO 14001:2015 for environmental controls in chemical extraction
    • Chinese standard GB/T 32388-2015 for rare earth separation and extraction
    • Occupational health regulations for exposure to rare earth and extraction solvents

    Typical usage ratio

    • Applied as extraction phase at 20% to 80% v/v relative to aqueous feed, dependent on metal loading, desired partition coefficient and downstream purification targets

    Downstream process integration

    • Loaded into mixer-settler or pulsed column extractors, contacted with pregnant leach solutions, followed by metal stripping and washing for ionic liquid regeneration and closed-loop recycling within the circuit

    Final product types

    • High-purity rare earth oxides
    • Rare earth metal compounds
    • Magnet-grade lanthanide intermediates
    • Optical and phosphor-grade rare earth materials
    Free Quote

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    Certification & Compliance
    More Introduction

    Introducing 1-Allyl-3-Hexylimidazolium Chloride: Insights from Our Production Floor

    The Practical Difference Imidazolium Salts Bring to Real-World Chemistry

    Every day, our workers and engineers see firsthand how 1-Allyl-3-Hexylimidazolium Chloride unlocks new potential for research and manufacturing. In our facility, the story of this ionic liquid starts long before packaging. We stress consistently high purity and integrity during every batch, because lab chemists and process engineers count on results they can trust. Over the past several years, we’ve watched as demand for ionic liquids matured from specialized academic interest into broader industrial adoption. Many customers share with us that unique cation modifications like the allyl and hexyl chains on this imidazolium backbone often make the difference in separating stubborn organic compounds, tailoring catalytic reactions, and even stabilizing tricky intermediates.

    Focusing on our model with a specification of at least 99% purity, we don’t cut corners. Our technicians use precise column chromatography and repeated crystallization to remove side products and residual precursors. This attention to cleanliness pays off for customers. Trace contaminants or water in ionic liquids can ruin moisture-sensitive reactions, cause unpredictable freezing points, or shift solubility. The difference between a 98% and a 99.5% material often comes down to reliability. By handling the demanding purification and production steps in-house, we see fewer complaints and more repeat orders. Frequent collaboration with customers gives us insight into how small changes in quality translate directly to improved results in the field.

    Understanding the Structure: Why Allyl and Hexyl Chains Are More Than Labels

    The special character of 1-Allyl-3-Hexylimidazolium Chloride comes from its molecular structure. In our production runs, chemists scrutinize not only yield and purity but also consistency in the substitution pattern. Replacing simple methyl or butyl groups on the imidazolium cation with allyl and hexyl arms doesn’t just diversify the catalog. These two substituents each pull their own weight. The hexyl chain greatly reduces melting point compared to short-alkyl imidazoliums, so the product remains a clear, easy-to-handle liquid even at lower temperatures. That matters for bulk storage and automated feeding systems. The allyl group, with its terminal double bond, offers more than just stability; it opens opportunities for chemical reactivity not seen in saturated alkyl analogs.

    We’ve watched as chemists use this property to anchor catalysts, perform click-style reactions, and build in new functionality post-synthesis. Some even share protocols for direct copolymerization or functionalization of the allyl handle, sidestepping extra steps. Modifying the cation in this way puts more control in the hands of the end user, and we see that show up in feedback: less waste, more selective extractions, and extended catalyst lifetime compared to classic versions with two alkyl chains.

    Real-World Performance: What Sets Our Chloride Apart

    Often the conversation around ionic liquids becomes too academic, focused on ionic conductivity or theoretical properties in models. Our own experience backs up what experienced chemists know—you judge an ionic liquid by what it does in a beaker or on the process floor. Our chloride-based product handles well during transfer: it flows smoothly, stays stable if tightly capped, and rarely shows batch-to-batch color variation. Staff monitoring quality control keep a close eye on water uptake, because chloride salts draw in atmospheric moisture faster than other anions. Each batch passes Karl Fischer titration and full NMR analysis, and customers note the impact. Dry product eliminates common headaches in air- and water-sensitive reaction steps.

    Switching to longer or bulkier cations like in 1-Octyl-3-methylimidazolium or shifting to alternative anions like PF6- or BF4- clearly changes handling and physical properties. Some customers require less hygroscopic materials for open-air plant conditions. Others run reactions where hexylimidazolium chloride stays liquid at workable temperatures, unlike short-chain analogs that crystallize over weekends and jam lines. Each property—from melting point to viscosity to compatibility with metal complexes—traces back to the balance of structure and anion selection. We committed to making these differences practical instead of theoretical. Laboratory experiments run side-by-side with our competitor’s butyl analogs routinely show that our hexyl-chain product dissolves a wider range of organics and delivers more consistent phase separation after aqueous workup.

    Applications That Drive Real Change

    The true merit of a chemical shows up downstream in the safety, consistency, and cost of the operations that rely on it. 1-Allyl-3-Hexylimidazolium Chloride consistently demonstrates value in processes where separation and stability are non-negotiable. Our direct conversations with users in academic research, pharmaceuticals, and specialty polymers highlight diverse use cases: as a solvent for cellulose, an alternative to traditional volatile organic solvents, and a medium for transition metal-catalyzed couplings. Companies investing in green chemistry point out how the low vapor pressure and recyclable nature of our ionic liquid reduce emissions and simplify solvent recovery. We test our own claims by running pilot-scale trials alongside partners, closely measuring yields, product recovery, and purity.

    In real-world operations, replacing a classic imidazolium ionic liquid with this model often increases yields and eliminates the need for additional stabilizers. In the case of precious metal catalysis—such as palladium-catalyzed carbon–carbon bond formation—our chloride product allows for catalyst recycling even when reaction temperatures run higher than normal. We spend time refining the purification stage so trace transition metals like iron, copper, or nickel from stirrers and reactors don’t build up in the final liquid. Our experience matches customer reports: by starting with purer ionic liquid, users minimize batch failures and cut down on tricky analytical troubleshooting.

    From Our Factory: The Truth About Production Scalability

    Scaling up is a pain point shared by almost every project lead we meet. Research-scale syntheses prove a concept, but scaling often exposes hidden incompatibilities—solubility, phase behavior, or even simple pumping issues. Over the past six years, we’ve transitioned from glassware to jacketed reactors and continuous-flow pumps, learning firsthand how 1-Allyl-3-Hexylimidazolium Chloride responds to higher-throughput conditions. We choose raw materials for batch-to-batch reproducibility, not just paper purity ratings. N-alkylimidazoles and allyl chloride are checked for trace halides and amines, clearing a path for pure reaction intermediates and consistent yields, even if costs run slightly higher up front.

    Our reaction pathway avoids corrosive promoters or exotic reagents. This shortens cleaning times and extends equipment lifetime, benefits any operator can appreciate. Once the reaction finishes, careful fractionation and crystallization step in. Experienced staff recognize that the residue left during rotary evaporation can look like several other imidazolium products. Only our in-house analytical work—proton NMR on every lot, thin-layer chromatography against certified standards—confirms the right structure and completely purged byproducts. Staff have learned to prioritize clear communication with users when scale-up introduces changes. Sometimes a simple adjustment to the drying schedule—one we’ve already worked through in-house—saves days for a customer facing unexpected viscosity variation at plant scale.

    Reducing Environmental Impact: Lessons from the Field

    A key advantage we see in ionic liquids lies in their ultra-low volatility. On our site, emissions into the working environment drop off dramatically compared to bulk handling of chloroform, acetonitrile, or dichloromethane. Most of our customers operate in highly regulated sectors, where exhaust treatment and solvent recovery add time and cost to every campaign. Our own experience backs up the claim that using 1-Allyl-3-Hexylimidazolium Chloride as both solvent and reagent streamlines hazardous waste management and reduces costs tied to environmental controls.

    Staff safety matters too. Workers who’ve handled legacy solvents appreciate the lack of sharp, persistent odor during transfer. Downstream, the recyclable nature of the ionic liquid means that instead of sending spent solvent out for disposal, customers can recover and reuse the bulk. We support these recovery processes by offering technical advice based on our own plant optimizations—sometimes small tweaks in vacuum drying or filtration improve subsequent batches and reinforce the economic case for switching applications to ionic liquids over classic volatile organics.

    Comparing to Other Ionic Liquids: Real Observations

    We produce a full line of imidazolium-based ionic liquids, including methyl, butyl, and octyl cations, and anions ranging from BF4- to acetate and tosylate. Throughout countless trials, the allyl-hexyl chloride variant stands apart for its unique blend of physical and chemical properties. Take melting point: whereas short-chain analogs like 1-butyl-3-methylimidazolium chloride can solidify under cool ambient conditions, the hexyl tail ensures our product stays pourable year-round, even in unheated storage facilities. Customers managing physical transfer lines in colder climates often switch after they encounter flow stoppages or foaming from less robust products.

    Solubility profiles also offer insights. Our in-house side-by-side solubility tests show that the longer hexyl chain augments organic compatibility, broadening the material’s usefulness for reactions involving extended alkyl chains or larger molecules. That’s not to say there’s a one-size-fits-all. We listen to users’ stories: some specialty extractions still favor shorter alkyl chains for ultra-fine selectivity, but in the cases where product recovery, low-temperature processability, or co-solubility with both water and organic phases is key, the allyl-hexyl chloride system takes the advantage. Stability under electrochemical and photochemical conditions comes up often, particularly for academic research into energy storage, where our careful purification eliminates spurious redox peaks and false positives from trace metals.

    Supporting New Applications and Ongoing Research

    One benefit of being a manufacturer rather than a reseller is that we spot emerging research trends early. Researchers investigating green processes for cellulose derivatization or homogeneous catalysis often reach out for technical support on scale, solubility, or purity questions. We stay engaged, supplying small-lot customizations or adjusting batch sizes as R&D efforts evolve. Because we produce under controlled conditions, we document every relevant process change, meaning that end users running sensitive analytical screens or preparing samples for regulatory submission receive full batch traceability.

    We're proud that our product forms the backbone for some of the latest advances in advanced materials and pharmaceuticals. When a university consortium demonstrated improved enzyme stability using 1-allyl-3-hexylimidazolium chloride as the supporting matrix, we replicated their conditions internally to cross-check the findings. Internal labs were able to translate their reported benefits to larger volumes, which gave us confidence to recommend the product for subsequent industrial trials. This feedback loop between our facility and the broader scientific community helps us refine our own QA/QC and keeps the ionic liquid at the forefront of current research.

    Consistency Drives Industry Confidence

    One of the most critical feedback streams we receive from long-term industrial partners is the importance of steady supply and quality. Anyone involved in process chemistry knows the impact of sudden changes in raw materials: equipment downtime, out-of-spec production, and regulatory headaches. Because we own and operate our reactors, purification systems, and packaging lines, our teams respond quickly to shifts in demand. Past situations where third-party supplied ionic liquids left users scrambling due to inconsistencies, we were able to ramp up production and deliver verified, consistent material.

    Over several years of continuous supply, more industrial users now opt for our product, not because of abstract characteristics, but because their lines run smoother, waste drops, and re-work incidents fall off. The ability to work directly with our technical teams ensures adaptations for emerging needs—whether that’s tweaking water content, customizing batch size, or troubleshooting new application scenarios. All customer conversations make their way back to our R&D and production teams, informing daily process improvements.

    Partnering for the Future: Our Long-Term Commitment

    The story of 1-Allyl-3-Hexylimidazolium Chloride at our facility is still being written. With every batch, we gain deeper understanding of just how much subtle changes in molecular structure or trace impurities impact user outcomes. Heavy investment in our analytical and purification infrastructure roots back to the belief that the best performance always traces to manufacturing integrity. By staying directly connected to both research pioneers and industrial end users, we make changes that lift the whole community—improving purity, efficiency, and environmental performance in lockstep.

    Anyone considering a switch to imidazolium ionic liquids, or planning to scale new technologies, benefits from our years of direct production experience. As a manufacturer who sees the direct relationship between raw material and end product, we don’t treat this as just another commodity. Real collaboration and transparency underpin our approach—so whether you’re troubleshooting a stubborn extraction, fine-tuning a new catalyst system, or pushing green chemistry boundaries, we’re ready to share insights built from practical know-how and day-to-day problem solving on the production floor.