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1-Allyl-3-Ethylimidazolium Bromide

    • Product Name 1-Allyl-3-Ethylimidazolium Bromide
    • Alias [AEIm]Br
    • Einecs 834-422-9
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    141762

    Product Name 1-Allyl-3-Ethylimidazolium Bromide
    Cas Number 849421-38-1
    Molecular Formula C8H13BrN2
    Molecular Weight 217.11 g/mol
    Appearance White to off-white solid
    Melting Point 70-75°C
    Solubility In Water Soluble
    Purity Typically >98%
    Storage Temperature Store at room temperature
    Synonyms [AEMIM]Br
    Smiles C=C[C+](N1C=CN=C1CC)Br-
    Application Ionic liquid, solvent, catalyst

    As an accredited 1-Allyl-3-Ethylimidazolium Bromide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Brown glass bottle with secure cap, labeled “1-Allyl-3-Ethylimidazolium Bromide, 25g,” hazard pictograms, batch number, and storage instructions.
    Shipping **Shipping for 1-Allyl-3-Ethylimidazolium Bromide:** This chemical is shipped in tightly sealed containers to prevent moisture absorption and contamination. It is transported in compliance with regulations for non-hazardous, non-flammable substances. Standard packaging ensures safe handling, and clear labeling accompanies each shipment. Store at room temperature, away from direct sunlight and incompatible materials during transit.
    Storage **1-Allyl-3-Ethylimidazolium Bromide** should be stored in a tightly-sealed container, in a cool, dry, and well-ventilated area away from moisture and direct sunlight. Keep away from incompatible substances such as strong oxidizers. Store at room temperature and protect from air exposure to prevent degradation. Always follow relevant safety and handling guidelines for ionic liquids and laboratory chemicals.
    Application of 1-Allyl-3-Ethylimidazolium Bromide

    Applications of 1-Allyl-3-Ethylimidazolium Bromide in Industrial Manufacturing

    As a dedicated manufacturer, we supply 1-Allyl-3-Ethylimidazolium Bromide for specialized industrial processes. Below, we summarize real-world downstream applications recognized within the specialty chemical sector, including detailed notes on compliance requirements, technical usage, process steps, and the range of finished products supported.

    1. Cellulose Dissolution for Fiber Spinning

    1-Allyl-3-Ethylimidazolium Bromide acts as a direct cellulose solvent in fiber spinning processes. It enables homogeneous dissolution of wood pulp or cotton linters at moderate temperatures without hazardous derivatization. Industrial fiber manufacturing plants use it for dope preparation before wet or dry-jet wet spinning, producing regenerated cellulose filaments. Chemical and thermal resilience of this ionic liquid supports repeated recycling in closed-loop systems under stringent purity control, aligning with sustainable textile manufacturing.

    Industry compliance standards

    • OEKO-TEX® Standard 100 for non-hazardous textile input chemicals
    • ZDHC MRSL v3.1 guidelines on solvent selection
    • REACH Annex XVII: Restrictions on specific organics
    • ISO 9001:2015 quality management for process plants

    Typical usage ratio

    • Cellulose loading: 5–12 wt% of solution, adjusted by pulp grade and viscosity control
    • Ionic liquid recovery rate: typically >85% per cycle, adjusted based on water entrainment and batch volume

    Downstream process integration

    • Add directly to a preheated dissolution reactor with high-shear agitation
    • Facilitates dope preparation phase prior to spinneret extrusion
    • Solvent recovery by washing and vacuum distillation after filament coagulation

    Final product types

    • Lyocell-type textile fibers
    • Cellulosic membrane films for filtration
    • Rayon staple for technical textiles
    • Medical-grade cellulose yarns

    2. Electrodeposition Bath Additive in Precious Metal Plating

    Metal finishing operations employ this ionic liquid as a conductivity modifier and morphology controller in non-aqueous electrodeposition baths for gold, silver, and palladium. The unique cation-anion pairing supports uniform metal ion reduction, enhances nucleation rates, and allows for precise grain size management. Compliance is required for heavy metal release and residue monitoring since traces may remain in effluent streams or on finished goods, especially in microelectronics plating.

    Industry compliance standards

    • RoHS Directive 2011/65/EU for residual bromide limits
    • ISO 4527:2016 for electrodeposited coatings
    • IEC 61189-5-2 for printed circuit board process chemicals
    • Local EPA wastewater discharge permit conditions

    Typical usage ratio

    • Addition level: 0.1–1.5 M in bath composition, fine-tuned per metal salt type and target layer thickness
    • Lower dosages for microfeature components (≤0.7 M), higher for macro plating baths

    Downstream process integration

    • Combine with precious metal salt and supporting electrolyte in heated plating tank
    • Add after adjusting pH and prior to current loading
    • Continuous filtration and bath life extension through real-time monitoring

    Final product types

    • Gold-plated connectors for electronics
    • Silver-coated medical device contacts
    • Palladium-plated precision components for sensors
    • Wear-resistant jewelry items

    3. Ionic Liquid Catalyst for Organic Synthesis Intermediates

    Batch and continuous-flow synthesis facilities utilize 1-Allyl-3-Ethylimidazolium Bromide as a phase-transfer catalyst and non-volatile reaction medium. It is effective in alkylation, nucleophilic substitution, and transition-metal catalyzed couplings for specialty intermediates and active pharmaceutical ingredient (API) precursors. The ionic liquid improves selectivity and allows for lower temperature operation, reducing volatile organic compound emissions from the process line.

    Industry compliance standards

    • ICH Q7 GMP guidelines for API starting materials
    • USP–NF monographs for impurity limits in process solvents
    • ISO 14001 for chemical handling and waste minimization
    • REACH registered substance dossier

    Typical usage ratio

    • Solvent loading: 1–5x molar excess relative to main organic substrate
    • Catalytic use: as low as 5–8 mol% relative to substrate, with recovery over 80% per cycle

    Downstream process integration

    • Charge pre-mixed with reactants to jacketed reactors or continuous tubular reactors
    • Allow direct phase transfer of organic ions and transition-metal complexes
    • Facilitates downstream extraction and purification via two-phase separation

    Final product types

    • Pyridine-based intermediates
    • Aryl ether pharmaceutical building blocks
    • Specialty alkyl halides
    • Fine chemical reagents

    4. Lithium Battery Electrolyte Additive

    Producers of advanced lithium metal and lithium-ion batteries incorporate this ionic liquid as an additive to electrolyte formulations. It serves to increase ionic conductivity, improve low-temperature performance, and suppress lithium dendrite growth. Its thermal and electrochemical stability allows for use in high-voltage cell assemblies conforming to UN safety and performance requirements. Pretreatment processes require in-line QC to ensure absence of unwanted impurities that might contribute to gas evolution or cell degradation.

    Industry compliance standards

    • IEC 62660-2:2018 for lithium ion battery safety
    • UN 38.3 for transport of lithium cells and batteries
    • GB/T 31485-2015 battery safety in automotive use
    • ISO/TS 16949:2009 automotive quality management

    Typical usage ratio

    • Additive proportion: 2–8 wt% in liquid organic carbonate electrolyte, tailored by full cell test results and separator compatibility
    • Batch-to-batch adjustment based on impedance spectroscopy

    Downstream process integration

    • Mix with solvent blend (e.g., EC/DMC/EMC) prior to salt dissolution and cell filling
    • Dispense using precision metering into cell assembly line under dry-room conditions
    • Blend stability monitored before electrolyte injection

    Final product types

    • Rechargeable lithium metal pouch cells
    • High-capacity NMC and LFP cylindrical cells
    • Grid energy storage system modules
    • Electric vehicle battery packs

    5. Non-Aqueous Solvent for Biomass Pretreatment

    Biofuel and biochemical plants use this ionic liquid for lignocellulosic biomass pretreatment aimed at deconstructing raw plant fiber matrices prior to enzymatic hydrolysis. This step disrupts lignin–carbohydrate complexes, improving sugar release yields in downstream fermentation. Operators run treatment at moderate temperatures, reusing the solvent through filtration and evaporation stages. Feedstock and process water control govern emissions management and economic recycling targets.

    Industry compliance standards

    • US EPA 40 CFR Part 63 Subpart JJJJJJ: Industrial boilers and process heaters (biomass feed handling)
    • EN ISO 22095 for chain of custody in bio-based processing
    • ISO 50001 energy management in process industries
    • REACH compliance for non-food biomass applications

    Typical usage ratio

    • Solvent to biomass mass ratio: 5:1 to 15:1, optimized for feedstock density and lignin content
    • Recycle ratio: >80% per batch

    Downstream process integration

    • Direct loading into pretreatment reactor with shredded biomass
    • Controlled heating and agitation, followed by solid–liquid separation
    • Solvent reclaimed after washing fibrous residue

    Final product types

    • Fermentable sugar syrups for ethanol production
    • Bio-based lactic acid feedstock
    • Cellulosic platform chemicals
    • Digestible fiber fractions for animal feeds
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    Certification & Compliance
    More Introduction

    Introducing 1-Allyl-3-Ethylimidazolium Bromide: A Reliable Ionic Liquid from a Dedicated Chemical Manufacturer

    Our Commitment to Quality in Ionic Liquid Production

    Every batch of 1-Allyl-3-Ethylimidazolium Bromide that leaves our facility reflects years of careful development and practical refinement. Our focus on small details provides end users with a product that maintains consistent purity and reliable performance, which makes a real difference in both laboratory and industrial settings. The compound, known by its short designation as AEM Br, consists of a well-defined imidazolium cation with allyl and ethyl substitutions paired with bromide anion. In our daily practice, these structural nuances shape how the material behaves in different environments, including solvents, electrochemical cells, and catalyst systems.

    Investing in a fully integrated process for ionic liquid synthesis has taught us the value of real transparency. We calibrate our reactors not by what works once in a while but by what works on every cycle. Moisture control, a careful approach to raw materials, and vigorous analysis at every stage of production produce ionic liquids that challenge many of the assumptions some people bring from bulk commodity chemicals. Here, there’s no shortcut. Each kilogram tells a story of methodical synthesis, meticulous purification, and authentic feedback from partners in research and business.

    Specifications and Consistency

    AEM Br leaves our reactors as a free-flowing, crystalline powder or as a viscous, colorless liquid, depending on requested form and shipping conditions. We strip all traces of unreacted imidazole and fine-tune the drying process to push water content well below levels that can affect sensitive applications. Every batch analyzed on NMR and ion chromatography reveals detail about purity and cation/anion balance. These steps do not make for an easier day in production, but we have seen too many inconsistent ionic liquids flummox research groups or cause disruption in manufacturing lines. Reputations form around small details. We would rather get them right at the start than hear about downstream headaches later.

    Our common specification includes a cation content above 99%, with bromide balance cross-checked against what’s required for catalytic, electrochemical, and separation research. The melting point and viscosity profile typically fall within a narrow band, and those numbers matter—small drifts can alter extraction efficiency or disrupt measurements in fuel cell reference setups. Transparency pays off. Clients in the battery sector value the way our batches perform comparably across multi-site trials and scale well from initial testing to larger preparations. Academics who need repeatable solvent conditions know they are not forced to re-optimize a process because of supplier-side inconsistencies.

    Applications in Modern Chemistry

    Practical use drives our formulation choices. The pathways available to chemists and engineers multiply with ionic liquids like 1-Allyl-3-Ethylimidazolium Bromide at hand. In synthesis labs, AEM Br creates stable, non-volatile solvent environments, enabling transition-metal catalyzed reactions or facilitating the solubilization of mixed inorganic-organic reactants. Small shifts in substituent pattern on the imidazolium ring—allyl here, ethyl there—aim directly at tunable solubility and the capacity to dissolve or stabilize otherwise tricky species. The bromide component plays a role as both a non-coordinating anion and as a counterion that resists oxidation, useful in settings where redox stability counts.

    We see AEM Br in action across areas such as:

    We are not surprised to see research groups periodically updating their reaction formats and solvent setups as new ionic liquids become available. Our partners let us know about subtle changes in their protocols, often triggered by new insights into how the cation structure steers selectivity or product recovery. AEM Br remains flexible—a distinctive asset for teams who need to pivot quickly between projects or who want a predictable baseline for screening new reactions.

    Where 1-Allyl-3-Ethylimidazolium Bromide Stands Apart

    Long experience with ionic liquids has made us skeptical of exaggerated claims about “universal solvents.” Real performance comes down to careful matching between ionic liquid properties and the demands of each application. What distinguishes this compound from other imidazolium salts—the methyl, butyl, or hexyl analogues—is the presence of the allyl group at one ring position and the ethyl at the third, loosely tuning both polarity and viscosity in a way that enables customization but does not hinder batch-to-batch synthesis.

    The allyl functional group can interact with unsaturated reactants, stirring up new possibilities for selectivity in certain reactions. Meanwhile, the ethyl substitution hits a sweet spot between volatility control and maintaining a manageable melting point. Many rival products land too high, risking solidification at typical storage or reaction temperatures, or too low, raising concerns about losses during long-term use. AEM Br stays reliably fluid in most standard laboratory setups, cutting down on surprises and cleanup time.

    Customers who have tried both chloride and bromide versions quickly spot the difference in redox stability and corrosiveness. AEM Br’s bromide base tends to offer weaker coordination, a trait valued by researchers working to avoid interfering byproducts or strong ion-pairing that can stifle catalytic cycles. Electrochemical work in particular benefits, as bromide-based ionic liquids resist anodic breakdown in a way that makes more aggressive voltage sweeps possible. Sheet metal labs and pilot plants who have suffered pitting or trace corrosion with chlorides report fewer long-term issues switching to the bromide analog.

    Supporting the Research and Industrial Community

    Feedback does not come from forms and surveys; it comes from troubleshooting sessions, candid phone calls, and problem-solving in real time. Teams running pilot plants often call for assistance in scaling from the gram to the kilogram and up. In these conversations, process stability, dosage predictability, and practical safety matter far more than what’s written on a datasheet. Several partners working with membrane fabrication or phase-transfer catalysis have reported that once they switched from generic imidazolium products to our AEM Br, their product rejection rate dropped and reproducibility across shifts improved. Stories like these underline how direct involvement in every stage of synthesis and purification brings concrete advantages.

    For the research side, advanced users often probe the boundaries of solubility and phase behavior. Our technical team spends time with LC-MS, GC, and thermal gravimetric tools to develop profiles on how AEM Br interacts with substrates, decomposes on heating, and tolerates contact with acids, bases, or transition-metal salts. Some of this work shapes best practices for storage: refrigeration brings no clumping, while the bromide counterion resists hydrolysis better than many of the bulk-market ionic liquids. Several collaborators in supercritical fluid extraction and high-pressure CO₂ work have found that switching to AEM Br improved extraction selectivity, with less interference in subsequent purification steps.

    Best Practices: Storage and Handling

    AEM Br acts as an ionic liquid with high affinity for water, which explains both its convenience and its hazards. Incorrectly stored, ionic liquids risk slow hydration over time, shifting both their electrical characteristics and solvation properties. We recommend sealing containers in dry, inert conditions—at our loading dock, we routinely check that each batch gets packed with as much care as during production. Our containers hold inert gas blankets, and we train staff to monitor seals and to inspect for early signs of moisture entrance.

    Years of filling and shipping have shown us the damage poor packaging can cause. Leaky lids waste product and create real safety issues. Crystals that have caked due to water ingress rarely regain their original performance, even after scrupulous drying. Customers achieve the most reliable results by opening containers just before use, avoiding prolonged exposure to moist air, and re-sealing tightly. We send test panels and reminder guides with every delivery, walking through protocols for weighing, transferring, and, if necessary, drying with gentle vacuum or inert gas.

    Regulatory Considerations and Authenticity

    Our team has worked directly with international customers in Europe, North America, and Asia to track changes in regulatory norms around ionic liquid handling and transportation. Over the years, industry guidance has moved beyond simple hazard labeling toward stricter controls on documentation and traceability. Our compliance group collaborates with downstream users to simplify cross-border shipments and deliver records—from synthesis history to disposal recommendations—backed by full batch analysis.

    Authenticity in labeling and analysis protects our customers from unexpected surprises and ensures that the material performs as promised. Rigorous internal controls and a refusal to outsource critical synthesis steps mean our batches remain consistent. We invite customers to audit our procedures, review batch data, and, if needed, visit our site for direct sampling and additional verification.

    Standing by Users at Scale

    Scaling from R&D to pilot, and then to full production, shakes out hidden issues that do not show up in early screening phases. Bulk users appreciate our attention to process controls and our willingness to fine-tune deliveries based on project stage—no one wants excess idle stock prone to age-related shifts, nor shortfalls that interrupt continuous operations. For groups running 24-hour lines or time-critical syntheses, we adjust logistics in response to demand spikes, seasonal transport restrictions, or changing regulatory climates.

    Some of our longest-standing users brought challenging requirements—irregular batch sizes, requests for finer powders or denser packaging, urgent shipments on short notice. Our logistics experience, rooted in hands-on involvement and anticipation of real-world disruptions, allows us to meet these needs without sacrificing quality. Over years of partnership, we have adapted packaging and documentation formats to better match actual storage conditions at customer sites, sometimes working directly with on-site personnel during scale-ups or audits.

    Why Our Approach Matters

    The chemical supply world includes many intermediaries, but manufacturing in-house is the only route that preserves the close coupling between synthesis, purification, and actual user outcomes. Our relationships with universities, industrial innovation centers, battery plants, and chemical process scale-up labs have all been shaped by this sense of investment in results. We never field complaints about mystery contaminants or unexplained batch differences. Our researchers, entrusted with access to production runs, take pride in delivering to collaborators with nothing hidden and nothing left unexplained.

    Choosing ionic liquids for new processes or product launches always carries risk. Minutes lost on flawed batches translate to missed measurement windows and lost time for everyone down the line. We continue to learn, refine, and double-check because we know the cost of being wrong. The flexibility built into the AEM Br structure reflects both input from users and our own stubborn insistence on doing the hard work at the source.

    Moving Forward with 1-Allyl-3-Ethylimidazolium Bromide

    Successful projects begin with reliable materials. AEM Br, by combining meticulous synthesis, careful control over trace impurities, and respect for practical feedback, stands as a real solution for labs and production plants that have grown tired of uncertainty and compromise. Every batch responds to lessons learned from past production runs, user feedback, and the shifting demands of both small-scale innovation and industrial scale-up. That approach is not the fastest or the cheapest, but it will be recognized by anyone who has struggled through a failed experiment or unnecessary downtime stemming from poor-quality raw materials.

    Future directions for our AEM Br line include expanded collaboration with partners in environmental chemistry, catalysis, and advanced energy. Demand for reproducibility and tailored property profiles will continue to grow. Our focus will always remain on transparent communication, direct problem-solving, and a commitment to product integrity. The value of this compound comes not just from its structure or intended application but from the confidence our partners gain when they use it, drawing on years of direct experience and honest effort at the source. Every improvement and adjustment are driven by what actually works—not by marketing promises but by tested performance in real conditions.

    We invite discussions, feedback, and collaboration—because better chemistry comes from direct engagement, honest engineering, and shared investment in real-world results.