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1,4-Cyclohexanebis(Methylamine)

    • Product Name 1,4-Cyclohexanebis(Methylamine)
    • Alias CHMA
    • Einecs 219-941-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry sales7@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    607714

    Cas Number 822-08-6
    Molecular Formula C8H18N2
    Molar Mass 142.25 g/mol
    Appearance Colorless to pale yellow liquid or solid
    Melting Point 32-37 °C
    Boiling Point 255-260 °C
    Density 0.96 g/cm³ (at 25 °C)
    Solubility In Water Miscible
    Flash Point 137 °C
    Refractive Index 1.493 (at 20 °C)
    Synonyms 1,4-Bis(methylamino)cyclohexane; HMDA-4CH
    Purity Typically ≥98%
    Odor Amine-like
    Vapor Pressure 0.02 mmHg (at 20 °C)

    As an accredited 1,4-Cyclohexanebis(Methylamine) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing The chemical is packaged in a 1 kg amber glass bottle with a secure screw cap and a clearly labeled hazard warning.
    Shipping 1,4-Cyclohexanebis(methylamine) should be shipped in tightly sealed containers, kept cool and dry, and protected from moisture and incompatible substances. It is classified as a hazardous chemical, so follow all local, national, and international regulations for transport, including proper labeling and packaging, and use appropriate personal protective equipment during handling.
    Storage 1,4-Cyclohexanebis(methylamine) should be stored in a tightly closed container in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizers and acids. Protect it from moisture, direct sunlight, and sources of ignition. Ensure that appropriate spill containment measures are in place, and store the chemical in a designated, labeled area following all relevant safety regulations.
    Application of 1,4-Cyclohexanebis(Methylamine)

    Applications of 1,4-Cyclohexanebis(Methylamine) in Industrial Manufacturing

    1,4-Cyclohexanebis(methylamine) (CHBMA) enables high-performance specialty applications in several advanced industrial sectors. As an experienced chemical raw material manufacturer, we supply this material directly to customers in industries that demand stringent formulation control, certified quality, and traceable production processes. Below, we present key downstream application scenarios, each detailing compliance obligations, formulation practices, process integration, and resulting end products.

    1. Epoxy Curing Agents for Advanced Coatings and Composites

    Formulators in protective coatings and composite manufacturing regularly use CHBMA to produce cycloaliphatic amine-based epoxy curing systems. Its low color, high reactivity at ambient temperature, and superior chemical resistance make it suitable for applications such as marine coatings, wind turbine blades, and electronic encapsulants. Resin manufacturers value CHBMA for its ability to enhance UV stability and mechanical longevity in finished systems.

    Industry compliance standards

    • REACH Regulation (EC) No 1907/2006 for chemical safety and pre-registration
    • ISO 9001 Quality Management for coatings raw materials traceability
    • ASTM D3023 (Standard Practice for Preparation of Epoxy Resin Solutions for Testing)
    • RoHS Directive 2011/65/EU for electrical/electronic applications

    Typical usage ratio

    • 11-18% by weight of total epoxy component; exact levels depend on the targeted glass transition temperature and network crosslink density in the formulation

    Downstream process integration

    • Add CHBMA to the epoxy prepolymer during the blending phase, typically under controlled agitation and temperature (25–60°C), often combined with diluents or other amines for viscosity adjustment before application to substrate or mold

    Final product types

    • Solvent-free anticorrosion protective coatings
    • High-performance fiber-reinforced composite laminates for aerospace, energy, and marine sectors
    • Electrical/electronic component potting compounds and adhesives

    2. Polyamide and Polyurea Resin Synthesis

    Specialty resin manufacturers incorporate CHBMA as a cycloaliphatic diamine in syntheses of polyamides and polyureas, leveraging its ring structure to impart chemical and thermal stability to engineered polymers. These resins supply coatings, adhesives, and engineered plastics producers that require controlled molecular architecture for specific performance benchmarks such as flexibility, gloss retention, and solvent resistance.

    Industry compliance standards

    • EN ISO 11357 (Thermal Analysis of Polymers)
    • UL 94 Flammability Standard for finished resins used in electrical components
    • EU Regulation (EU) No 10/2011 on materials intended to contact food (for eligible grades)
    • CQC Mark Certification for plastics and resin intermediates in the China market

    Typical usage ratio

    • Stoichiometrically balanced with anhydride or isocyanate (0.95–1.05:1 molar ratio); can be modified ±5% to achieve target molecular weights or end-group levels for tailored material performance

    Downstream process integration

    • Feed CHBMA to the prepolymer reactor under inert atmosphere, react with anhydride or diisocyanate in bulk or solution phase, followed by post-polymerization devolatilization and pelletization for downstream compounding or extrusion

    Final product types

    • High-durability polyamide resin pellets for molded automotive components
    • Two-component polyurea flooring systems for industrial and commercial facilities
    • Water-resistant hot-melt adhesives for electronic assembly

    3. Chain Extender in Thermoplastic Polyurethane (TPU) Manufacturing

    Producers of specialty elastomers utilize CHBMA as a chain extender in thermoplastic polyurethane (TPU) formulations. The cycloaliphatic backbone introduces elasticity, abrasion resistance, and long-term hydrolysis stability. Industrial clients in footwear, cable jacketing, and medical device assemblies depend on tight specification control for consistent mechanical and environmental resistance properties in finished products.

    Industry compliance standards

    • ISO 10993 for biocompatibility in medical polyurethanes
    • EN 50363-10-2 for thermoplastic sheathing compounds in power cable applications
    • FDA 21 CFR 177.1680 for indirect food contact (TPU grades)
    • ISO 9001 and ISO 14001 for responsible manufacturing and quality assurance

    Typical usage ratio

    • 7–15% molar ratio relative to total diisocyanate feed; adjustments are based on Shore hardness requirements and processing method (injection, extrusion, or calendaring)

    Downstream process integration

    • Incorporate CHBMA into the polyaddition step, post-polyol and prepolymer formation, under precise temperature (~75–120°C) and agitation, directly influencing segment lengths and resultant elastomer properties

    Final product types

    • High-abrasion TPU shoe soles for sports and safety footwear
    • Flexible protective jacketing for low-voltage cables
    • Medical-grade tubing and device housings

    4. Curing Component for Hot Melt Adhesives (HMA) and Structural Bonding Systems

    Manufacturers of hot melt adhesive sticks and structural adhesives use CHBMA as a specialized diamine curative, capitalizing on its rapid reactivity and compatibility with epoxy and isocyanate systems. The result is improved adhesion strength, rapid cure speed, and resistance to chemical and environmental stress in demanding industrial and consumer assembly lines.

    Industry compliance standards

    • ISO 4587 (Shear Strength of Adhesive Joints)
    • Automotive OEM standards for interior component adhesives (e.g., GM GMW 16862)
    • FDA 21 CFR 175.105 for adhesives in food packaging (where applicable)
    • GB/T 2793-2019 for adhesive bonding strength in the Chinese market

    Typical usage ratio

    • 5–12% by weight, based on the total formulation for 2K structural adhesives; level tailored according to open time and ultimate bonding performance parameters

    Downstream process integration

    • Blend CHBMA into the adhesive base during batch compounding, after initial resin melt or prior to filler addition, ensuring homogeneous distribution before extrusion or cartridge fill

    Final product types

    • Hot melt adhesive sticks for general assembly and packaging
    • Two-component structural adhesives for automotive and electronics assemblies
    • Reactive prepolymers for panel lamination and construction bonding

    5. Intermediate in Synthesis of Specialty Polyimides

    CHBMA is frequently selected as a diamine component in the precision synthesis of polyimides, where the cyclohexyl structure contributes to thermal stability and dielectric properties essential for advanced electronics and high-temperature engineering films. Polyimide producers require controlled monomer purity and reactivity to meet stringent electrical performance benchmarks for insulating films and flexible circuits.

    Industry compliance standards

    • IPC-4101B (Specifications for base materials for printed boards)
    • UL 746B for Polymeric Materials – Long-Term Property Evaluations
    • IEC 61249-2-21 for base materials used in electronic interconnections
    • GB/T 30814-2014 Polyimide films in the Chinese standard system

    Typical usage ratio

    • 1:1 molar ratio with dianhydride equivalents for polycondensation; may be adjusted ±3% to achieve targeted film mechanical and dielectric performance in end use

    Downstream process integration

    • Introduce CHBMA during the initial polyamic acid synthesis in aprotic solvent, followed by controlled imidization through thermal or chemical processing for subsequent extrusion, casting, or coating into films and laminates

    Final product types

    • Flexible polyimide films for electronics and aerospace insulation
    • Circuit substrate base materials
    • High-temperature-resistant tapes and laminates
    Free Quote

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    Certification & Compliance
    More Introduction

    Introducing 1,4-Cyclohexanebis(Methylamine): The Backbone of Advanced Polymer Production

    Grounding Our Perspective in Direct Manufacturing Experience

    Over the past decade, our production teams have seen major changes sweep through the specialty chemical industry. Plant managers and technical staff grapple with balancing stable output, tight quality controls, and ever-evolving end-use demands. Among the aromatic amines we produce, 1,4-cyclohexanebis(methylamine), or CHMBA, stands out as a consistent favorite in several downstream applications. From our reactors to your production lines, this molecule exemplifies reliability, predictable performance, and adaptability, especially in high-performance polymer manufacturing.

    Understanding 1,4-Cyclohexanebis(Methylamine)

    CHMBA is a diamine compound with a cyclohexane ring bridging two methylamine groups at the 1 and 4 positions. Production of CHMBA starts with cyclohexanone and draws on hydrogenation technologies honed by decades of process improvements. Operators in our facilities know the importance of precise reaction control; slight deviations in temperature or feedstock purity ripple downstream, affecting crystallinity, solubility, and reactivity in customer applications. Our teams work with modern filtration and distillation equipment to reach the high purity levels trusted by major polyamide and epoxy producers.

    Model and Specifications: Built On Years of User Feedback

    We manufacture CHMBA to meet the technical requirements our clients share. Our standard delivery form comes as white to off-white flakes or granules, ensuring ease of handling and a long shelf life under the right storage conditions. Typical batches maintain purity above 99%, with water content and inorganic impurities tightly limited thanks to stepwise drying and advanced purification. Over the years, R&D teams at both our site and our clients’ have guided us toward supporting custom blends, larger batch sizes, and more precise quality guarantees, not because it makes for a tidy product listing, but because it translates to smoother reactions and improved productivity on factory floors.

    Distinctive Features from the Line Worker’s Perspective

    One detail our staff notices when packing CHMBA is its particulate stability and low dusting. This trait matters far more than most spec sheets acknowledge. Less airborne dispersion reduces respiratory risk for downstream users and minimizes product loss during transfers. Even indoor air handlers and local exhaust systems at partner plants thank us for this unintended benefit. Careful crystalline control during solidification means users encounter fewer problems in automated dosing or feed mechanisms.

    Real-World Usage: Polyamide and Epoxy Synthesis

    Technical service engineers from polyamide plants regularly call to relay feedback on product performance. Their chemists confirm that CHMBA brings cycloaliphatic structure into the backbone of nylons and related polymers, resulting in chain segments with higher flexibility and better resistance to UV degradation versus aromatic diamines. From our perspective, this directly translates into outdoor automotive parts or electronic housings that stay ductile and fade-resistant, even after years in the field.

    Epoxy formulators also rely on the secondary amine groups of CHMBA for curing. These secondary amines create networks that offer both mechanical resilience and chemical resistance. Production staff running continuous mixing lines notice that CHMBA solutions mix easily with various epoxy resins, enabling controllable gel times and curing profiles. This flexibility helps manufacturers produce coatings and adhesives for ships, wind turbine blades, and pipeline protection, cutting down returns and warranty calls due to brittle fracture or solvent attack.

    Technical support teams in adhesive factories routinely mention improved crosslink density in their formulations. This benefit does not always show up on an MSDS, but it drives real returns when a product—whether a floor coating or a structural adhesive—faces the combined assault of heat, moisture, and heavy load.

    Supply Reliability: Lessons Learned the Hard Way

    Back in 2017, one of our upstream raw materials experienced a sudden shortage. Our technical teams scrambled for alternative sourcing and tighter process control to maintain batch consistency. Several partner factories, relying on “just-in-time” inventories, called to say even slight delays led to lost output worth thousands of hours. That period cemented our commitment to redundancy in our supply chains, greater investment in local raw material storage, and tighter customer communication. No third-party reseller would ever experience or understand those supply chain headaches or the sense of urgency at stake. Direct manufacturing involvement forces us to care about quality across every drum, every delivery, and every shipment delay.

    Comparing CHMBA to Other Diamines: Why the Difference Matters

    Many engineers considering a new polyamide or resin system stack their options: 1,3-diaminopropane, meta-xylylenediamine, and hexamethylene diamine, among others. Each brings trade-offs shaped by real-world use rather than textbook chemistry.

    Hexamethylene diamine, for example, delivers high rigidity because it lacks a central cycloaliphatic ring and offers linear flexibility. That quality works in basic nylon 6,6, yet products made with it often embrittle under repeated outdoor use or UV loading. Our polymer clients find CHMBA yields chains with a subtle flexibility and improved shock absorption, making it invaluable in high-stress, impact-resistance applications—including parts for electric vehicles and solar panel mounting hardware. The saturated cyclohexane ring confers resistance to oxidizing agents, extending service life for pipes and appliance components in aggressive environments.

    Meta-xylylenediamine, with aromatic rings, raises heat resistance but increases sensitivity to yellowing from light or oxidizing conditions. We’ve watched customers swap to CHMBA after complaints about loss of mechanical strength in vacuum or heat-cured composites destined for aircraft interiors. These changes don’t need banner headlines, but plant maintenance staff and material engineers notice improvements as maintenance intervals lengthen and customer complaints drop.

    From the early days of pilot batch production, our chemists have kept field test notes from end users. Clients making cast polyamide sheets, for example, often struggle with shrinkage and surface finish. Adding CHMBA yields smoother slab surfaces and finer edge definition. Workers downstream spend less time sanding or reworking, enabling higher throughput and less dust waste in shop environments.

    Health, Safety, and Environmental Aspects Rooted in Field Practice

    Beyond purity, skilled operators know safe handling varies with amine structure. CHMBA, as a cycloaliphatic diamine, carries a moderate odor but far less vapor pressure than smaller amines. On production lines, this trait allows safer direct use, reducing the likelihood of accidental vapor release even when handling large volumes. Gloves, goggles, and extraction hoods remain essentials, but the fact that CHMBA tends not to volatilize at room temperature makes routine operations safer for workers in confined spaces. Staff at installation and maintenance sites have shared similar feedback, often grateful for materials that don’t require emergency breathing apparatus unless exposed to major spills.

    Environmental release profiles matter as regulations tighten around the world. We stock our own wastewater treatment and containment systems to ensure accidental releases meet or exceed strict guidelines. This experience shapes our product recommendations for facilities in regions with acute environmental scrutiny. Instead of just selling a chemical, we offer practical advice gained from in-house incidents—like the time a compromised valve sprayed a batch onto a shop floor, and operators quickly neutralized it using methods refined through drills, not just regulatory checklists.

    Maintaining Consistency: Lessons from Continuous Improvement

    The chemical manufacturing floor rarely runs on autopilot. Staff who work daily with CHMBA see fluctuations in color, odor, and particle size over time. Sometimes, variations trace back to upstream supplier issues or unexpected humidity spikes in storage. Years ago, a client flagged a recurring off-odor issue in finished nylon extrusion. Working back through batch records, we isolated a minor impurity spike and overhauled a drying step. Since then, our in-house lab has doubled its sample auditing frequency, and new inline spectroscopic sensors now flag even minor deviations before final packaging.

    Our continuous improvement cycles haven’t just improved batch predictability—they’ve put more confidence in the hands of line workers, process engineers, and buyers who rely on consistent quality for their own production schedules. Customer input, not just laboratory analytics, guides our updates. Over time, this feedback loop has quietly fueled innovations in filtration, drying, and blending processes, translating into material that performs predictably across a range of downstream chemistries.

    End-User Applications Beyond the Textbook

    Many engineers discover unexpected uses for CHMBA once they gain hands-on familiarity. Makers of corrosion-resistant coatings for marine infrastructure started with basic epoxy-hardener blends, only to find that CHMBA improved abrasion resistance and overcoat adhesion. Sporting goods companies bring their own demands: they require composite materials that bend without cracking at low temperatures. Adjusting the amine content or mixing with different curing agents lets them fine-tune flexural modulus and elongation in fishing rods and bicycle frames.

    Adhesive formulators, chasing higher peel strength and faster cure profiles for industrial tapes, find that CHMBA balances pot life with final bond strength. In practice, this means forklift drivers move finished rolls to the warehouse sooner, and plant QC staff spend less time managing off-spec returned batches. In pipeline rehabilitation, specialty contractors blend CHMBA into hybrid epoxy-pipe coatings; on-site, their crews see coatings cure more evenly and resist impact damage from backfill much better.

    We’ve even seen a handful of automotive R&D departments test CHMBA-containing polymers for underbody panels and noise-reducing engine covers. Technicians report greater dimensional stability after thermal cycling—vital for modern multi-material vehicles constantly exposed to heat and vibration.

    Listening to the Real-World User: Ongoing Partnerships

    Our role as a direct manufacturer gives us a front-row seat to emerging trends and growing pains in the polymer and resin space. We routinely visit customer plants and job sites, gathering stories and suggestions from maintenance technicians, production line supervisors, and field installers. In many cases, minor changes—like adjusting grain size or optimizing packaging for automated dosing—reduce downtime or manual handling injuries.

    Working relationships with key customers allow us to stay ahead of regulatory changes. When European clients raised new concerns over amine emissions in their worksites, we coordinated pilot studies to monitor workplace exposure. The resulting data not only helped improve our internal air monitoring protocols, but also provided customers with defensible statistics for their own compliance filings. We see ourselves as problem solvers grounded in the demands of the shop floor, not just remote suppliers of a commodity molecule.

    Challenges and Solutions: Surviving in a Dynamic Industry

    Cost stability always tops client concerns. Global cyclohexane and ammonia supply fluctuations add unpredictability to raw material prices. Rather than chase short-term price winners, we strengthen our position through close supplier vetting and strategic stockpiling. Our procurement teams maintain local inventories and stagger contracts to buffer sudden spikes—a strategy born from bitter lessons in lean inventory management gone wrong. In the end, this approach supports smoother, more predictable pricing for our partners, allowing them to plan production schedules with less guesswork.

    Environmental and safety regulations grow stricter every year. Evolving workplace exposure standards and discharge limits require us to upgrade process containment equipment and review all operator training annually. These costs may not show up clearly on a line-item invoice, but they support not just regulatory compliance, but the long-term health of those who work with, and near, CHMBA. Direct manufacturer experience keeps these realities in focus—something distant traders or brokers never truly grasp.

    On a technical level, innovation proceeds at a steady pace. Our teams watch R&D trends in high-performance plastics, resins, and coatings closely. For example, recent advances in additive manufacturing and 3D printing require new amine-curing profiles and molecular weight tuning. We are examining custom isomer mixtures and advanced purification steps in response. Partnerships with universities and applied research consortia introduce fresh laboratory solutions, feeding directly back into pilot production and, eventually, into the product delivered to your loading dock.

    Conclusion: Our Commitment Beyond the Drum

    Our daily work producing 1,4-cyclohexanebis(methylamine) is more than chemistry and logistics. Lessons from the field—shared by machine operators, plant managers, and R&D chemists—continually sharpen what we deliver. We never take for granted the trust placed in every container shipped, nor do we lose sight of the impact our product has down the chain. Whether building the next generation of high-performance polyamides, creating more durable epoxy resins, or enabling smarter composites, our purpose is rooted in listening, adapting, and delivering quality, backed by hard-won experience from the manufacturing floor.