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1,4-Bis(Trichloromethyl)Benzene

    • Product Name 1,4-Bis(Trichloromethyl)Benzene
    • Alias Heksakloroparaksilen
    • Einecs 212-779-0
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    592812

    Chemical Name 1,4-Bis(Trichloromethyl)Benzene
    Molecular Formula C8H4Cl6
    Molecular Weight 348.83 g/mol
    Cas Number 29082-74-4
    Appearance White crystalline solid
    Melting Point 249-253 °C
    Boiling Point Decomposes before boiling
    Density 1.79 g/cm³
    Solubility In Water Insoluble
    Structure Benzene ring with two trichloromethyl groups at 1,4-positions
    Synonyms p-Bis(trichloromethyl)benzene
    Smiles C1=CC(=CC=C1C(Cl)(Cl)Cl)C(Cl)(Cl)Cl
    Purity Typically >97% (commercial)
    Storage Conditions Store in a cool, dry place, tightly closed

    As an accredited 1,4-Bis(Trichloromethyl)Benzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,4-Bis(Trichloromethyl)Benzene is packaged in a tightly sealed 100-gram amber glass bottle with a chemical-resistant screw cap.
    Shipping 1,4-Bis(Trichloromethyl)Benzene should be shipped in tightly sealed, chemical-resistant containers, protected from moisture and direct sunlight. It must comply with relevant hazardous materials regulations, including appropriate labeling and documentation. During transit, ensure the package is securely packed to prevent leaks or spills. Handle with care to avoid physical damage and environmental contamination.
    Storage 1,4-Bis(Trichloromethyl)Benzene should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area, away from sources of ignition, heat, and direct sunlight. Keep it separate from incompatible substances such as strong oxidizing agents. Ensure containers are clearly labeled and protected from physical damage. Follow all relevant regulations for safe chemical storage.
    Application of 1,4-Bis(Trichloromethyl)Benzene

    Applications of 1,4-Bis(Trichloromethyl)Benzene in Industrial Manufacturing

    As a manufacturer specializing in 1,4-Bis(Trichloromethyl)Benzene, we serve global industrial producers using this raw material across multiple advanced sectors. Each application below provides specific detail on integration, usage, and compliance within major industrial fields to ensure clarity for technical procurement and production teams.

    1. High-Performance Polyester Synthesis

    Downstream manufacturers use 1,4-Bis(Trichloromethyl)Benzene as a specialty intermediate in the production of high-melting polyesters. It introduces trichloromethyl functionality, enabling increased flame retardance and chemical resistance in the final polymer. Integration occurs during the polycondensation stage, where stoichiometric ratios are carefully managed based on target molecular weight and functional group density. This application requires strict control of reaction conditions and by-product removal for product consistency, especially in electronic films and specialty fibers.

    Industry compliance standards

    • ISO 9001:2015 Quality Management for Chemical Manufacturing
    • REACH Regulation (EC No 1907/2006) for registration, evaluation, and safe handling
    • IEC 60695-11-10 flame retardance testing for polymer products
    • UL 94 certification for materials used in electrical insulation

    Typical usage ratio

    • 2–10 mol% relative to total diacid components; precisely adjusted for required flame retardance without impacting process stability

    Downstream process integration

    • Added into polyesterification reactors with diacids and diols during the melt phase
    • Managed dosing to minimize hydrolysis and guarantee uniform dispersion in the polymer matrix
    • Reaction by-products (e.g., HCl) removed via vacuum or inert purge streams
    • Ensured compatibility with subsequent pelletizing or fiber spinning equipment

    Final product types

    • Flame-retardant polyester fibers for protective clothing
    • Electronic insulating films
    • Industrial conveyor belts
    • Specialty engineering plastics

    2. Advanced Agrochemical Intermediate

    Agrochemical companies use this material as a chlorinated aromatic building block in the synthesis of selective herbicides and pesticide actives. Its electron-withdrawing groups facilitate controlled coupling and halogenation reactions. Production lines integrate it in the multi-step creation of triazine and phenylurea derivatives, with tight environmental and purity oversight as specified by agrochemical registration protocols.

    Industry compliance standards

    • ISO 14001:2015 Environmental Management for chemical synthesis
    • Registration under EPA (U.S. FIFRA), GB/T 17768-2017 for China Agrochemical Registration
    • OECD Good Laboratory Practice (GLP) for active ingredient development
    • Directive 91/414/EEC on Plant Protection Product registration in the EU

    Typical usage ratio

    • 0.1–1.0 molar equivalents as coupling or core-forming intermediate in multi-stage syntheses; varies by specific herbicide or pesticide pathway

    Downstream process integration

    • Charged during the key aromatic substitution or halogen exchange stage
    • Reaction times and temperatures tightly controlled to reduce impurity formation
    • By-products neutralized or recovered per local effluent regulation
    • Purification via crystallization or solvent extraction standardized for downstream QC release

    Final product types

    • Precursor to triazine herbicides (e.g., simazine analogs)
    • Phenylurea-type pesticides
    • Special-function agrochemical additives
    • Intermediates for crop-specific active ingredients

    3. Synthesis of Specialty Dyes and Pigments

    Manufacturers of high-performance pigments use 1,4-Bis(Trichloromethyl)Benzene as a halogenated starting material. It participates in the construction of polycyclic aromatic dyes with high photostability and solvent resistance. In dye synthesis, it enters the core cyclization or Friedel-Crafts-type attachment, requiring parameter optimization for color fastness and hue depth. This raw material provides enhanced performance characteristics important for specialty coatings and fiber coloration.

    Industry compliance standards

    • GMP for colorants (21 CFR Part 211 for use in specialty coatings)
    • REACH Annex XVII for chemical substances in dyes
    • ISO 787-24 for pigment characterization
    • ETAD Eco-Toxicological Safety Guidelines

    Typical usage ratio

    • 3–12 wt% based on total aromatic feed in pigment, modulated depending on target shade, solubility, and fastness levels

    Downstream process integration

    • Added during initial condensation stages in pigment or dye reactors
    • Catalyst and solvent selection tuned to ensure complete conversion and minimize residual trichloromethyl by-products
    • Process monitored by HPLC for purity and final spectral properties
    • Granulation or milling steps follow to achieve desired particle size distribution

    Final product types

    • Polycyclic aromatic pigments for automotive coatings
    • High-fastness textile dyes
    • Color masterbatches for engineering plastics
    • Printing ink pigments with enhanced weather resistance

    4. Electronics-Grade Circuit Board Laminate Production

    Producers of high-specification circuit board laminates rely on this chlorinated aromatic for crosslinker synthesis in polymeric resins. During epoxy or polyimide matrix manufacturing, introducing its trichloromethyl groups boosts overall dielectric performance and material stability at elevated temperatures. Integration must respect electronics industry purity requirements and non-conductivity. Quality assurance includes routine analysis for residual halogens and extractables.

    Industry compliance standards

    • IPC-4101D for base materials in PCB laminates
    • UL 94 V-0 for flame rating in electronic applications
    • RoHS Directive 2011/65/EU for restricted substances
    • IEC 61249-2-7 for halogenated laminate base sheets

    Typical usage ratio

    • 0.5–5 phr (parts per hundred resin) as a reactive modifier in the polymer blend; fine-tuned for dielectric strength versus mechanical flexibility

    Downstream process integration

    • Dispersed with epoxy or polyimide precursors before lamination
    • Resin crosslinking initiated under heat and pressure with vacuum-assisted degassing to minimize pinholes
    • Quality monitoring for delamination risk and in situ FR (flame retardance) testing
    • Final composite sheet tested for dimensional stability and surface finish before PCB fabrication

    Final product types

    • FR-4 grade circuit board laminates
    • High-frequency microwave PCBs
    • Automotive sensor module substrates
    • LED and power electronics insulation boards
    Free Quote

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    Certification & Compliance
    More Introduction

    Introducing 1,4-Bis(Trichloromethyl)Benzene: Insight from a Chemical Manufacturer

    Our Work with 1,4-Bis(Trichloromethyl)Benzene

    As a direct manufacturer of organic specialty chemicals, we dedicate significant resources to the synthesis and refinement of 1,4-Bis(Trichloromethyl)Benzene. Many years of experience in this industry have taught us a great deal about the ins and outs of aromatic halides. This compound, which some also know as p-Bis(trichloromethyl)benzene or para-Trichloromethylbenzene, features two trichloromethyl groups symmetrically bonded to a benzene ring. Its robust molecular structure offers more durability in certain reactions compared to standard mono-chlorinated benzenes. The chemical formula C10H6Cl6 sets it apart from other chlorinated aromatics thanks to its higher chlorine load and more distinctive isomer arrangement.

    Purity Profiles and Manufacturing Realities

    Our factory prioritizes both purity and consistency. Each batch is produced under strict controls. Routine QC testing focuses on chloride content, melting point, and visual clarity. Typically, our product reaches a purity level greater than 99%, which speaks to process effectiveness and careful selection of raw materials. Over the years, we've identified that impurity traces—often left behind as residual toluene or partially chlorinated analogs—can change the outcome of end-user chemistry. By optimizing temperature, solvent quality and chlorine flow rates, we consistently narrow the impurity window.

    Physical form matters. Our product leaves the reactor as snow-white crystalline solids, not oily masses or sticky residues. This comes down to dialed-in crystallization timing and controlled cooling. The fine crystals flow easily and resist caking in storage if kept dry. This matters for both accurate weighing and precise batch dosing, especially in sensitive downstream applications.

    The Operational Side: Packaging and Logistics

    Proper handling and logistics cannot be an afterthought. We have seen firsthand how humidity and even slight packaging flaws can degrade sensitive chlorinated compounds over time. To combat this, the product gets packed in airtight, high-density polyethylene lined drums or double-layered bags. Standard package sizes typically go up to 25kg, manageable for plant staff but robust enough to limit exposure and preserve product integrity across continents. For facilities needing even stricter moisture control, we deploy customized vacuum-sealed options.

    Field Applications: Utility and Value Proposition

    1,4-Bis(Trichloromethyl)Benzene does not enjoy household name status, but in the corridors of chemical manufacturing it plays a quiet but pivotal role. One primary use centers on the synthesis of high-performance agricultural chemicals, where the trichloromethyl groups help construct novel herbicides and fungicides. The compound’s symmetrical orientation on the benzene core gives it versatility as a functional group carrier. This feature is crucial for designing stable, targeted intermediates that don’t react prematurely.

    Beyond agrochemicals, polymer manufacturers rely on this molecule for specialty plastics modification. Our discussions with R&D labs confirm a growing need for chlorine-dense aromatic building blocks to increase material chemical resistance, particularly in cable insulation and electronic substrates. Researchers pursuing flame retardant materials keep returning to this molecule, due to its dense halogen content and thermal stability.

    For the dye and pigment sector, 1,4-Bis(Trichloromethyl)Benzene brings unique properties. Its two activated chloromethyl positions enable the formation of vivid, long-lasting colorants that resist fading under UV or chemical attack. This advantage comes at a molecular level, where symmetry and substitution patterns influence pigment shade and performance.

    The pharmaceutical market presents another set of challenges and opportunities. Thanks to its ring structure and multiple reactive sites, medicinal chemists use our product as a versatile scaffold in multi-step synthesis of active pharmaceutical ingredients. Although production volumes for these applications remain smaller, the demands for traceability, batch records, and low-byproduct levels often surpass those of bulk sectors. We field regular requests for ultra-pure, customized lots to meet these requirements.

    Regulatory Considerations and Customer Trust

    Regulatory scrutiny has only grown more intense in recent years. Many global authorities monitor chlorinated aromatics for environmental persistence and potential toxicity. Our compliance staff closely tracks evolving safety standards and registers every shipment with required paperwork. Adoption of industry best practices allows our staff to quickly supply safety data sheets, analytical reports, and full traceability from raw material intake through to finished drum. These measures reduce risk for both us and our customers.

    End-users increasingly expect more than just a certificate of analysis. As concerns grow over trace impurities—like dioxins or PCBs—strict process documentation earns trust. During on-site inspections or supplier audits, we welcome customer teams to observe quality checks in real time. Transparency and experience matter. Many customers return for repeat orders based on the confidence they place in our procedures, not just on pricing alone.

    Technical Advantages: Differentiating from Common Analogues

    Many buyers ask us how 1,4-Bis(Trichloromethyl)Benzene stacks up against other chlorinated benzenes, such as mono- or di-chlorotoluene. The differences start with molecular weight and continue through reactivity and physical handling. A higher chlorine count means more robust electron-withdrawing effects, which can drive reactions to completion more efficiently in certain syntheses. The para substitution, with chloromethyl groups sitting opposite each other, gives increased chemical symmetry. This helps enable precise substitution reactions—useful for multi-step synthetic work--and balances sterics such that both sites perform similarly in catalyzed processes.

    For those working in high-performance chemical synthesis, small differences in impurity profiles can either improve or sabotage a reaction route. Products with lower purity or inconsistent quality often hollow out yields or stall at problematic side reactions. We have spent years refining production techniques, which means our 1,4-Bis(Trichloromethyl)Benzene consistently provides higher conversion rates in downstream reactions compared to off-grade material from less experienced factories.

    Continuous Improvement in Production and Safety

    Operating an efficient, safe manufacturing operation means taking lessons from each batch and applying them on the floor. Workers benefit from a well-documented, established process, but they also draw on their own instincts. A central lesson has been to never cut corners on solvent recovery and gas scrubbing. The chlorination process releases significant hydrochloric acid and trace volatile byproducts. Investing in proper fume-extraction and waste handling equipment keeps both the plant environment and the surrounding community safer.

    Worker training focuses on vigilant temperature management, particularly during the exothermic stages that drive up reactor pressure. In this line of work, even a five-degree swing in jacket temperature can affect yield or throw off crystallization outcomes. Our production team meets regularly to review process control charts; cycles of small adjustments and large overhauls mean each year sees better throughput with fewer reworks. These improvements mean that new and returning clients see consistent color, composition, and reactivity whether they're placing a small or a large order.

    On the packaging end, our maintenance personnel scrutinize every closure and liner seal before shipping. Large shipments receive palletization and climate-mapping services for long-distance delivery, especially in hot or humid climates. Shipment damage or spoilage is rare, but in the event clients encounter a concern, our technical support team responds directly, addressing storage, transfer, or process optimization steps as needed.

    Collaborative Development with Downstream Partners

    Over many years, we’ve learned that listening to feedback from both large and small buyers matters more than any flowchart or theoretical guide. Some customers run direct syntheses using our 1,4-Bis(Trichloromethyl)Benzene as a starting point for advanced intermediates. Others come to our lab with requests to tweak micron size or moisture specs to better fit finely-tuned catalytic reactors. By tweaking process steps in response to these needs, both our clients and our own team have discovered new syntheses and cut down on costly waste.

    Collaboration doesn’t stop at the technical level. Changes in market demand, regulatory focus, and shipping requirements affect our planning week to week. Overseas regulations can classify the same compound differently in adjacent regions. Our export desk tracks these shifts closely, updating labeling and dossier packages as conditions require. This vigilance means less downtime at customs and a smoother flow for client inventory cycles.

    Lab managers from various sectors ask about alternate specifications. Our technical team is available to evaluate alternative salt, solvent, or stabilizer requirements on a case-by-case basis. We won’t endorse a modification without careful pilot-scale trials and field feedback, but we remain open to custom requests where it adds value to the customer process.

    Environmental Impact and Responsible Manufacturing

    Modern chemical operations are measured just as much by environmental impact as by cost or throughput. Large-scale chlorination, if handled thoughtlessly, leaves a heavy footprint—residual hydrochloric acid, waste thermal energy, and organochlorine byproducts. To stay ahead, we’ve invested in thermal oxidizers and closed-loop solvent recovery. Local emissions audits help us fine-tune gas scrubbing effectiveness and improve long-term plant operations.

    Part of our responsibility means continuous monitoring for leaks or accidental releases. Routine third-party environmental audits have helped us align our process with evolving global norms, not just local minimums. This approach forms a feedback loop: waste streams are better documented, and best-in-class managers share lessons learned to the broader staff group.

    Future Prospects and Growth Areas

    As the specialty chemicals market expands, so does demand for more sophisticated starting materials. Our ongoing investment in 1,4-Bis(Trichloromethyl)Benzene production is informed not simply by current use patterns but by close discussions with emerging sectors. The biotechnology field has identified potential downstream uses in high-value catalyst supports and advanced analytics. These future projects call for an even tighter control on micron impurities, nitrogen handling, and trace chlorinated breakdown products.

    In the world of electronics, device miniaturization and more demanding material performance standards drive the search for aromatic precursors that handle higher voltages, heat, and environmental stress. Our experience with the dual trichloromethyl configuration makes us valuable collaborators for clients working at the cutting edge of material science. We anticipate continued growth as new regulatory changes, especially those incentivizing alternatives to legacy halogenated intermediates, shift purchasing away from less stable mono-chlorinated precursors.

    Why Experience Matters in Choosing a Manufacturer

    Selecting a compound as specific as 1,4-Bis(Trichloromethyl)Benzene is about more than just price-per-kilo. It takes understanding—the difference between a supply glitch and a successful multi-step synthesis often hinges on details invisible from outside the plant gates. Batch-to-batch reproducibility cannot be taken for granted. Feedback from clients troubleshooting process hiccups has shaped our insistence on batch walks, frequent in-line monitoring, and hands-on supervision.

    Our team includes staff who have worked their way up from bagging lines to reactor control rooms. That day-to-day experience becomes critical when troubleshooting reactor fouling, handling oddball impurity readings, or responding to last-minute shipment changes. We believe in investing in both people and process—coming up with creative, workable answers, whether that means reworking a batch, tweaking a crystallization curve, or providing last-mile technical advice at a client’s site. That is what sets dedicated manufacturers apart from traders or brokers: real accountability from production through to delivery and technical support.

    Conclusion

    In a market filled with options for aromatic chlorinated intermediates, successful manufacturing comes down to diligence, proven capability, and the drive to improve. Our approach to 1,4-Bis(Trichloromethyl)Benzene production reflects a broader company commitment: value long-term relationships, sweat the technical details, and embrace changes in market demand with open feedback channels. Those values built our business for decades and earned trust from some of the most demanding industries worldwide. As application fields grow and technical challenges mount, we stand ready to adapt and support our clients across new opportunities and requirements. For anyone seeking high-quality, consistent 1,4-Bis(Trichloromethyl)Benzene, this additive-driven approach helps ensure your processes perform at their best.