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1,4-Bis(Phenylethynyl)Benzene

    • Product Name 1,4-Bis(Phenylethynyl)Benzene
    • Alias BPEB
    • Einecs 607-445-6
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    477621

    Cas Number 1108-89-4
    Molecular Formula C22H14
    Molar Mass 278.35 g/mol
    Appearance Light yellow powder
    Melting Point 228-232 °C
    Solubility In Water Insoluble
    Boiling Point Decomposes before boiling
    Density 1.17 g/cm³
    Purity Typically >98%
    Synonyms 1,4-Bis(phenylethynyl)benzene; BPEB
    Structure Linear, aromatic with ethynyl bridges
    Refractive Index 1.662 (predicted)
    Storage Conditions Store at room temperature, dry, and protected from light

    As an accredited 1,4-Bis(Phenylethynyl)Benzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing A 5-gram amber glass bottle labeled "1,4-Bis(Phenylethynyl)Benzene," sealed tightly, with hazard and handling instructions displayed.
    Shipping 1,4-Bis(Phenylethynyl)Benzene is shipped in tightly sealed containers, away from moisture, heat, and incompatible materials. It should be packaged according to standard chemical shipping regulations, typically in amber bottles or high-density polyethylene containers, with labeling that complies with safety and hazard communication standards. Handle with care to prevent spills or exposure.
    Storage 1,4-Bis(Phenylethynyl)benzene should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from direct sunlight and sources of ignition. Avoid exposure to moisture and strong oxidizing agents. Store at room temperature and handle with care to prevent dust generation. Proper labeling and chemical compatibility should be ensured to avoid accidental reactions.
    Application of 1,4-Bis(Phenylethynyl)Benzene

    Applications of 1,4-Bis(Phenylethynyl)Benzene in Industrial Manufacturing

    As the producer of high-quality 1,4-Bis(Phenylethynyl)Benzene (BPEB), we supply this advanced aromatic compound to leading industries demanding reliable performance in specialty polymer synthesis, electronics, composite engineering, and aerospace sectors. Our facility ensures specification consistency, supported by rigorous quality protocols, for critical industrial applications. Below, we detail its established use in key downstream fields.

    1. High-Performance Polyimide Films for Flexible Electronics

    BPEB functions as a high-temperature crosslinking agent in the manufacture of polyimide films specifically engineered for flexible electronic circuits and displays. Its rigid structure increases glass transition temperature and mechanical durability, facilitating thin-film designs for microelectronic integration. Our customers utilize BPEB to enhance dielectric performance and withstand thermal cycling in advanced display substrates and flexible printed circuitry, requiring reliable, reproducible process control.

    Industry compliance standards

    • IEC 61249-2-21 (Materials for printed boards—Polyimide films)
    • RoHS Directive 2011/65/EU for hazardous substances
    • IPC-4101B (Requirements for Base Materials for Rigid and Multilayer Printed Boards)
    • ISO 9001:2015 certified quality systems

    Typical usage ratio

    • 1—7% by weight of total monomeric load, adjusted based on desired film flexibility and thickness; higher ranges favor increased dimensional stability for high-temperature applications.

    Downstream process integration

    • Introduced at the co-polymerization stage with dianhydrides and diamines during imidization, followed by solution casting and thermal annealing to achieve homogeneous cross-linked films.

    Final product types

    • Flexible printed circuits (FPC)
    • OLED display substrates
    • Flexible sensors
    • Thermal interface films for consumer electronics

    2. Aerospace-Grade Thermoset Resin Matrices

    The aerospace sector integrates BPEB into thermoset matrices to enhance high-temperature mechanical properties and oxidative stability for composite structures. Precise incorporation during matrix resin formulation results in components that maintain rigidity and dimensional accuracy under thermal stress, serving structural applications in both civil and defense aircraft. BPEB’s defined reactivity enables tight control of crosslink density, crucial for aerospace certification and long-term reliability.

    Industry compliance standards

    • SAE AMS 3716/1 (High-Temperature Resin Systems)
    • AS9100D (Quality Management for Aerospace Manufacturing)
    • EN 9100:2018 (European Aerospace Quality Standard)
    • REACH Regulation (EC) No 1907/2006

    Typical usage ratio

    • 3—10% by weight within polyetherimide or polyimide formulations, controlled to balance crosslinking density with impact resistance depending on targeted service temperature and mechanical profile.

    Downstream process integration

    • Metered into the main resin blend prior to solvent removal, followed by impregnation into carbon or glass fiber prepregs, then subjected to staged curing cycles and post-cure for matrix consolidation.

    Final product types

    • Aircraft secondary structure parts (e.g., panels, ribs, access doors)
    • Satellite reflector backplanes
    • Spacecraft insulation sheets
    • Jet engine secondary casings

    3. Advanced LED Encapsulation Materials

    LED manufacturing relies on BPEB as a component in high-transparency, thermally stable encapsulants, ensuring long operational life under high-brightness conditions. Its inclusion in polyimide-based encapsulant systems mitigates discoloration and physical degradation under repeated thermal cycling, especially critical for automotive, industrial, and signage LEDs exposed to harsh conditions. Producers specify BPEB for formulations supporting both optical clarity and stable refractive index.

    Industry compliance standards

    • UL 94 V-0 (Flame Retardant Requirements for Encapsulation)
    • JEDEC JESD22-A104 (Thermal Shock Testing for LED Electronics)
    • IEC 62471 (Photobiological Safety of Lamps and Lamp Systems)
    • ISO 14001:2015 (Environmental management during production)

    Typical usage ratio

    • 0.5—5% by weight in encapsulant resin formulations; adjusted according to power rating (Wattage) and thickness of optical films.

    Downstream process integration

    • Dispersed within the polyimide precursor before solution casting or injection molding, followed by controlled curing to ensure bubble-free encapsulation over sensitive LED dies.

    Final product types

    • High-lumen SMD LED modules
    • Automotive headlamp encapsulants
    • Outdoor signage LED lenses
    • Industrial and street lighting fixtures

    4. Specialty Carbon Fiber Composite Prepregs

    Carbon fiber reinforced plastics producers use BPEB as a key additive for tailoring matrix microstructure, raising heat distortion temperature and reducing microcracking in lightweight composite panels. BPEB’s controlled reactivity with matrix oligomers enables precise tuning of the interface between resin and fiber, which is vital for sports equipment, automotive composites, and high-performance parts demanding minimal thermal expansion and surface integrity through frequent load cycles.

    Industry compliance standards

    • ISO 1268-6:2002 (Fibre-reinforced plastics—Composite lamination procedures)
    • ASTM D2344/D2344M (Short-beam strength of composite materials)
    • UNI EN 2563:1997 (Carbon fibre reinforced plastics—flexural tests)
    • OEM-specific performance/QC protocols

    Typical usage ratio

    • 2—6% by weight of polymer resin; formulation tuned for desired layup thickness and post-cure modulus, with upper limit used for racing and aerospace panel applications.

    Downstream process integration

    • Added to pre-polymer solution prior to impregnation of carbon fiber mats or unidirectional tapes, followed by vacuum-assisted layup and autoclave curing to achieve consistency in cross-sectional strength.

    Final product types

    • Racing bicycle frames
    • Automotive underbody composites
    • Lightweight industrial machine housings
    • Performance sporting goods (e.g., golf clubs, tennis rackets)

    5. High-Tg Powder Coating Systems

    Manufacturers of powder coatings for electrical insulation and industrial machinery formulate BPEB into high-Tg thermosetting systems to boost thermal deformation resistance and electrical insulation properties. Its aromatic structure facilitates formation of rigid polymer networks, supporting operation in environments exposed to sustained mechanical and thermal loads. Industrial painters favor BPEB-containing systems for busbars, transformer components, and switchgear where color stability, dielectric breakdown strength, and longevity are primary demands.

    Industry compliance standards

    • IEC 60455-2 (Resinous insulation powders for electrical purposes)
    • UL 1446 (Systems of Insulating Materials)
    • ASTM D3359 (Adhesion of Coatings)
    • ISO 12944-6 (Protective Paint Systems)

    Typical usage ratio

    • 1—4% by weight relative to total binder mass; adjusted to achieve specified dielectric and thermal performance, considering film thickness and required curing protocol.

    Downstream process integration

    • Blended into epoxy or polyester powder base during pre-mixing, followed by extrusion and micronization; applied via electrostatic spray and crosslinked during high-temperature baking.

    Final product types

    • Electrical busbar coatings
    • Cast resin transformer components
    • Industrial motor stator insulation
    • Corrosion-resistant industrial housings

    6. Microelectronic MEMS Device Packaging

    MEMS (Micro-Electro-Mechanical Systems) packaging engineers employ BPEB in photo-definable polyimide-based encapsulants to protect silicon structures during backend wafer processing. It provides high-resolution patternability, dimensional stability at wafer-level process temperatures, and protection against moisture ingress. Precision dosing optimizes film uniformity and process yield, critical for sensitive actuators and sensors utilized in automotive, mobile, and medical microdevices.

    Industry compliance standards

    • JEITA ED-7305 (Materials for MEMS packaging)
    • IPC/JEDEC J-STD-020 (Moisture/Reflow Sensitivity Classification)
    • ISO 14644-1 (Cleanroom processing requirements)
    • IEC 60747-14-1 (Semiconductor devices—MEMS requirements)

    Typical usage ratio

    • 0.8—3% by weight, fine-tuned according to target film thickness (5—30 μm) and UV patterning resolution; higher proportions for critical MEMS sensor arrays.

    Downstream process integration

    • Introduced into the spin-coating formulation ahead of UV exposure and development steps, followed by final curing at elevated wafer temperatures to lock in mechanical and resistive properties.

    Final product types

    • Automotive airbag MEMS sensors
    • Inkjet printer actuator arrays
    • Smartphone gyroscopic chips
    • Medical microfluidic sensors
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    Certification & Compliance
    More Introduction

    1,4-Bis(Phenylethynyl)Benzene: Insights from a Chemical Manufacturer

    Every year, chemical developers and researchers seek out molecules that deliver not only reliability but also performance gains in their projects. Among these, 1,4-Bis(Phenylethynyl)Benzene stands out as a key building block with deep roots in the electronics, advanced materials, and polymer modification fields. Our focus on this compound comes from years of experience handling organic fine chemicals on a ton-scale for demanding technical specifications—not because it sounds impressive on paper, but because over time we've seen what this molecule actually does in the real world.

    What Makes 1,4-Bis(Phenylethynyl)Benzene Special?

    1,4-Bis(Phenylethynyl)Benzene—or BPEB for short—offers a rigid, linear backbone that functions as much more than the sum of its parts. The molecule’s two terminal phenylethynyl groups, anchored on a para-disubstituted benzene core, contribute to thermal and oxidative stability that goes beyond typical aromatic compounds. Over multiple production batches, using tightly controlled Sonogashira coupling techniques, we’ve aimed for a purity that reduces side-reactions in downstream syntheses to virtually zero. That’s important for research chemists and process engineers looking to eliminate headaches in pilot runs or scale-ups.

    Our own analytical team keeps the purity close to 99.5%, as verified by HPLC and NMR, because years of supplying to OLED and polyimide precursor manufacturers have taught us how minor impurities cascade into downstream defects. Water content stays below 0.1%—moisture triggers unwanted by-products especially in high-performance applications. Granule size consistently meets customer needs for dust-free transfers, supporting safer and cleaner plant operations.

    Why Industry Relies on This Compound

    Thermally stable yet reactive under the right conditions, BPEB lays the groundwork for specialty polymers which need to survive harsh processing conditions. We’ve watched it grow from a rare specialty item to a material now requested by advanced labs and industrial lines alike. In polyimide films requiring exceptional heat resistance and mechanical durability, BPEB can reinforce the network backbone more robustly than monomeric analogs. The terminal acetylenic groups encourage cross-linking during curing, increasing the glass transition temperature and end-use stability.

    Display panels and organic light-emitting diodes (OLEDs) represent another significant application. End users have moved toward BPEB derivatives for improved charge transport and reduced color distortion. Based on end-user feedback, adopting our high-purity BPEB in these films reduced product failures and maintenance cycles in final electronic devices. The rigid conjugation of the molecule helps achieve narrow band gaps and tailored emission properties, something that just isn’t possible with simpler benzyne or biphenyl alternatives.

    Performance Under Pressure—A Manufacturer’s Perspective

    Manufacturing materials for electronics brings a whole set of challenges that commodity-grade chemicals never encounter. Here, trace metals, residual solvents, and isomeric contaminants can all sabotage performance. By owning the process from raw material procurement through final packaging, we retain direct control over the result. There’s no substitute for that level of oversight if the aim is fewer failed lots or re-works at the client site. Automation aside, seasoned technicians catch minor process anomalies that could spiral into costly recall events down the supply chain.

    Years of continuous improvement allow us to spot deviations that might escape a basic certificate of analysis. We routinely analyze for heavy metal content, as catalytic residues in electronic applications can short-circuit device reliability. We also invest in customized filtration and purification trains, reducing batch-to-batch variation—a problem we often hear about when customers source from less-experienced traders or non-integrated plants.

    Comparing BPEB to Similar Molecules

    Laboratory scientists sometimes weigh BPEB against molecules like 1,4-diethynylbenzene or simple biphenyl derivatives. The difference in both reactivity and final product performance becomes clear through real-world use. The extended conjugation length in BPEB gives rise to better electronic properties and processability in thermoplastic blends. Unlike more volatile or flexible linear aromatics, BPEB imparts rigidity and stability without sacrificing solubility in processing solvents.

    In cross-linking efficiency tests conducted in our in-house application lab, BPEB-based formulations always show higher modulus and thermal decomposition thresholds than their diethynyl counterparts. The presence of the phenyl groups at each terminal discourages oxidative breakdown and broadens compatibility with a wider array of co-monomers. Feedback from coating formulators pointed to better film formation and fewer pinhole defects under accelerated aging tests, an important consideration for encapsulant films and flexible circuit boards.

    Addressing Manufacturing and Supply Challenges

    Certain specialty chemicals, BPEB among them, tend to face volatility in global supply chains. With growing demand from electronics and aerospace, we’re often asked about scalability and lead-time management. Early partnerships with raw material suppliers let us buffer inventories during market swings, and our vertical process lets us fast-track qualification batches for tight timelines. We believe that price stability and consistent lot quality drive long-term relationships, not just a one-time deal based on minimum specification compliance.

    We’ve witnessed large electronics manufacturers hit production snags when secondary suppliers blended or diluted BPEB with lower-grade intermediates. Full material traceability, from lab sample through multi-ton production, forms the backbone of our management system—contract auditors from major technology groups may walk our lines at any time. Regular third-party analytical checks keep customer trust high and maintain our reputation.

    Applications in Advanced R&D and Industry

    PhD chemists and senior formulation engineers have pushed BPEB’s uses beyond what textbooks describe. In our own on-site pilot plant, process teams developed precursor resins for space-grade adhesives that withstand both deep-cold storage and months of continuous operation at elevated temperatures. Research collaborations uncovered that certain photonic devices, particularly blue and green OLEDs, reach higher quantum efficiency when BPEB is used to tailor the emitter layer matrix. Several academic groups visited our facility to discuss new oligomerization methods using BPEB’s reactive acetylenic arms as functionalization anchors.

    We supplied pilot lots to industrial labs experimenting with next-generation solar cell architectures, where improved stacking and molecular orientation at electrode interfaces enhanced both device stability and power conversion efficiency. In semiconducting nanomaterial matrices, BPEB’s aromatic-rich backbone helped achieve organized, monodisperse arrays—critical for predictable device output.

    Polymer development groups value BPEB’s chemical resistance. During scale-up trials for protective coatings on electronics, its structure avoided premature cross-linking, extending pot life while delivering required hardness after full cure. The outcome? Fewer product failures in the field and less downtime for major manufacturing lines. That feedback loop from end users, combined with what we learn in our own quality and pilot lines, shapes each subsequent production run.

    Factoring in Regulatory and Environmental Accountability

    With each new compound that pushes performance limits, compliance and worker safety climb the priority list. In the case of BPEB, we comply with local and international regulatory frameworks both for environmental responsibility and occupational health. By operating a closed-loop system for waste minimization and solvent recycling, we keep emissions well below limits. In plant audits, independent inspectors review both the handling and storage conditions for materials with phenylethynyl moieties to verify safety protocols don't just exist on paper.

    Our experience suggests that environmental stewardship, waste tracking, and community transparency directly influence approval timelines for new applications. Downstream clients, particularly in Europe and North America, share our concerns about legacy pollutants. We maintain an open channel not just at the technical level, but for customers’ compliance and sustainability officers liaising on new certifications or expanded project scopes.

    Strategies to Support Customers

    Supplying specialty molecules like 1,4-Bis(Phenylethynyl)Benzene goes far beyond just meeting technical grades. Customers want active partnership, whether they face formulation troubleshooting or research pivoting into unfamiliar territory. For instance, our technical service chemists have worked directly with R&D teams on site, implementing purification steps or process tweaks to unlock higher conversion yields and lower off-spec waste rates. Not every project goes to plan, and a manufacturer’s true value comes through when things go sideways—advice and sample prep during unanticipated issues, rather than just shipping boxes off a shelf.

    We also run joint workshops with clients to optimize mixing sequences and thermal processing windows. Some OEM customers have feedback loops with our in-house application lab, co-developing test methods more closely aligned to their own product realities rather than textbook conditions. Years of collaborative troubleshooting uncovered that minor changes in particle size distribution, caused by different grinding methods, can alter dispersion properties in filled polymer systems—something missed by relying strictly on chemical purity data.

    Why Our Direct Manufacturing Makes the Difference

    Vertical integration is not just a buzzword to us. Running the whole cycle—right from incoming raw material to the final sealed drum—removes so many uncertainties faced by downstream users. Distributors and traders often can't respond quickly when something shifts in customer requirements or global sourcing. In our facility, we have decades of hands-on knowledge. Temperature drift or solvent pH drift, for example, show up in spectral changes our staff recognize from past experience. We’ve replaced or retooled entire reactor trains after finding even slight off-colors linked to trace side products. That comes only from being involved on the ground, not just buying inputs and forwarding them on.

    Through on-site testing and feedback from the field, we can adapt product forms—from extra-dry specimens for moisture-sensitive syntheses to pre-weighed, vacuum-packed bags for automated bulk lines. Flexibility in packing and shipments cuts down on handling time and improves yield in customer operations. If we hear from a customer that a particular blend had more static or caking, our team gets into the plant, figures out what happened, and makes real adjustments by the next batch. That's the advantage of true manufacturing over spot procurement.

    Outlook for 1,4-Bis(Phenylethynyl)Benzene in Evolving Technologies

    Market trends show that the demand for higher-performance organic building blocks will only accelerate, especially as miniaturization, flexible displays, and green energy move mainstream. BPEB’s performance edge—anchored in both molecular design and manufacturing consistency—positions it for continued relevance. Direct customer feedback pushes us to deliver an even tighter analytical profile and practical on-site assistance. Whether developing next-generation composites, more efficient conductive polymers, or new display materials, users want to know their supplier understands both the chemistry and the application, not just how to make a sale.

    Ultimately, our story with 1,4-Bis(Phenylethynyl)Benzene reflects how chemical manufacturing can bridge chemistry theory and real-world impact. The molecule succeeds in high-value sectors because behind every specification and certificate stands a production team committed to constant improvement. Customers return when every drum and every batch over time matches the last, and when support continues long after purchase orders are fulfilled. Our years in this field prove that real-world problem solving, combined with low-defect products, deliver more than just data sheets—they build industry trust, innovation, and growth.