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1,4-Bis(Aminomethyl)Benzene

    • Product Name 1,4-Bis(Aminomethyl)Benzene
    • Alias p-Xylylenediamine
    • Einecs 202-456-5
    • Mininmum Order 1 g
    • Factory Site Tengfei Creation Center,55 Jiangjun Avenue, Jiangning District,Nanjing
    • Price Inquiry admin@sinochem-nanjing.com
    • Manufacturer Sinochem Nanjing Corporation
    • CONTACT NOW
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    Specifications

    HS Code

    418327

    Chemical Name 1,4-Bis(Aminomethyl)Benzene
    Synonyms Terephthalamine, p-Xylylenediamine
    Molecular Formula C8H12N2
    Molar Mass 136.19 g/mol
    Cas Number 823-40-5
    Appearance White to off-white crystalline solid
    Melting Point 153-155 °C
    Boiling Point 350 °C (decomposes)
    Solubility In Water Moderately soluble
    Density 1.13 g/cm³
    Structure Type Aromatic diamine
    Ph Of 1 Solution 10-11
    Flash Point ≥ 200 °C
    Refractive Index 1.613 (calculated)
    Ec Number 212-497-3

    As an accredited 1,4-Bis(Aminomethyl)Benzene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 1,4-Bis(Aminomethyl)Benzene, 100g: Supplied in a sealed, amber glass bottle with tamper-evident cap, clearly labeled for laboratory use.
    Shipping 1,4-Bis(Aminomethyl)Benzene should be shipped in tightly-sealed containers, clearly labeled, and protected from moisture and incompatible substances. It is typically transported as a solid at ambient temperature. Ensure compliance with local, national, and international regulations for hazardous materials, and include appropriate safety documentation and hazard warning labels during shipping.
    Storage 1,4-Bis(Aminomethyl)Benzene should be stored in a tightly closed container, in a cool, dry, and well-ventilated area, away from incompatible substances such as strong oxidizing agents and acids. Keep away from sources of ignition and direct sunlight. Use corrosion-resistant shelving, and ensure proper labeling. Personal protective equipment should be used during handling to avoid skin and eye contact.
    Application of 1,4-Bis(Aminomethyl)Benzene

    Applications of 1,4-Bis(Aminomethyl)Benzene in Industrial Manufacturing

    As a direct manufacturer, we supply 1,4-Bis(Aminomethyl)Benzene (also known as p-Xylylenediamine or PXDA) for specialized use in several high-value industrial sectors. The following application scenarios detail direct downstream manufacturing uses for this raw material, focusing on compliance, formulation, process integration, and end product types.

    1. Epoxy Resin Curing Agent Formulation

    Epoxy system formulators use this diamine as a hardener due to its efficient crosslinking and rapid reaction kinetics. Direct batching into the epoxy mix enables tunable cure speed, improved chemical resistance, and maintenance of high glass transition temperature. This allows tailored mechanical and corrosion performance in heavy-duty coatings demanded by civil infrastructure, automotive, and aerospace sectors.

    Industry compliance standards

    • REACH Annex XVII for chemicals in coatings
    • US EPA TSCA regulations
    • GB/T 20110-2006 (China national epoxy standards)
    • ISO 9001:2015 plant QA/QC requirements

    Typical usage ratio

    • Typically 5-15 phr (parts per hundred resin), adjustable based on required hardness
    • Higher ratio (up to 20 phr) for extreme chemical resistance formulations
    • Exact levels set by epoxide equivalent weight calculation and application specs
    • Blends with cycloaliphatic amines or polyetheramines possible for modified reactivity

    Downstream process integration

    • Direct addition during epoxy premix or immediately before application
    • Vacuum degassing after amine addition to reduce air entrapment
    • Mixing with fillers, pigments, and other additives for functional coatings
    • Thermal or ambient temperature curing for part fabrication or surface protection

    Final product types

    • Protective industrial floor coatings
    • Heavy-duty primer and topcoat systems
    • Adhesives for structural components
    • Industrial corrosion barrier linings

    2. Polyamide Resin Production for Hot Melt Adhesives

    Manufacturers of polyamide resins employ this aromatic diamine in condensation polymerization with dicarboxylic acids. Its rigid structure delivers high adhesive strength, good thermal and solvent resistance, and improved performance at elevated temperatures. It is crucial in specialty hot melt formulations favored in packaging, automotive, and electronic assembly sectors where resistance to deformation under load matters.

    Industry compliance standards

    • 21 CFR 175.105 (FDA Indirect Food Additives: Adhesives and Components)
    • EN 923:2015 (European adhesives terminology and requirements)
    • ISO 9001:2015 operational QA
    • RoHS Directive for electronics applications

    Typical usage ratio

    • 20-35 mol% in diamine component mixture, balanced with aliphatic diamines for desired hardness and flexibility
    • Ratios adjusted for bond strength and softening point targets
    • Batch-level blending consistency documented per lot
    • Final resin composition verified by amine value testing on each production lot

    Downstream process integration

    • Aromatic diamine charged to polycondensation reactor with dicarboxylic acid monomers
    • Continuous or batch melt polymerization at controlled temperatures (180–240°C)
    • In-process viscosity, acid value, and amine value monitoring
    • Cooling, pelletizing, and QC sampling for adhesive manufacturers

    Final product types

    • Hot melt adhesives for bookbinding and packaging
    • Automotive trim assembly adhesives
    • Electronic device encapsulation compounds
    • Laminating adhesives for wood and textile substrates

    3. Polyurea and Polyurethane Elastomer Manufacturing

    1,4-Bis(Aminomethyl)Benzene finds use as an aromatic chain extender in polyurea and polyurethane elastomer systems. By introducing this diamine into the isocyanate reaction step, operators achieve enhanced tensile modulus, abrasion resistance, and improved thermal properties. Custom mechanical profiles suit the demanding requirements of wheel coatings, rollers, and dynamic seals produced for mining, oil & gas, and construction equipment.

    Industry compliance standards

    • ISO 9001:2015 certified batch control and traceability
    • OECD Guidelines for testing of chemicals (toxicity, migration)
    • ASTM D412 (Tensile properties of elastomers)
    • Directive 2011/65/EU (RoHS, for electronic-related elastomers)

    Typical usage ratio

    • 10–25% aromatic diamine in polyurea chain extender mix, adjusted for hardness and rebound
    • Lower ratios (10–15%) for flexible elastomers
    • Higher ratios (20–25%) for rigid, high-load applications
    • Ratio optimization by isocyanate index and final product modulus testing

    Downstream process integration

    • Inline dosing into prepolymer blend before spraying or casting
    • Mixing under inert (N2) atmosphere to reduce fouling and discoloration
    • Immediate molding, spraying, or RIM (reaction injection molding)
    • Batch logs maintained for each elastomer run including amine charge record

    Final product types

    • Heavy-duty wheel coatings
    • Wear-resistant conveyor rollers
    • Pump seals and dynamic gaskets
    • Protective bridge deck membranes

    4. Specialty Polyimide Resin Synthesis

    This aromatic diamine, when polymerized with dianhydrides, forms linear or cross-linked polyimides. End-use applications leverage its high-temperature stability and chemical resistance—essential properties for electronics, aerospace, and automotive insulation parts. Manufacturers apply strict molecular weight control and purity standards to meet advanced circuit and composite performance demands.

    Industry compliance standards

    • IPC-4101B (Printed circuit board base materials)
    • EN 45545-2:2020 (Railway fire safety for electronics materials)
    • ISO 14001:2015 (environmental management for high-performance composites)
    • REACH SVHC evaluation for use in electrical/electronic components

    Typical usage ratio

    • 1:1 molar equivalent with dianhydride components
    • Adjustments up to 10% excess for process losses or partial imidization
    • Optimization for film casting or molded component viscosity
    • Precise weighing required for reproducible dielectric and mechanical properties

    Downstream process integration

    • Monomer solution preparation at controlled pH
    • In-situ polyamidation followed by thermal or chemical imidization
    • Film casting, solvent evaporation, or direct molding
    • Stringent QC on imidization degree and monomer residue

    Final product types

    • Flexible printed circuit substrates
    • High-temperature wire enamel coatings
    • Molded electronic insulation spacers
    • Laminated structural composite films

    5. Manufacturing of Aromatic Polybenzoxazine Thermosets

    Producers synthesize thermosetting benzoxazine resins by reacting phenolic compounds with this diamine. The material enables polybenzoxazine networks with high glass transition, dimensional stability, and flame resistance valued in advanced composites for electronics, aerospace, and specialty construction materials.

    Industry compliance standards

    • UL 94 (Flammability of plastic materials)
    • JIS K 6911 (Japanese standards for thermosetting plastics)
    • ISO 11357 (Differential scanning calorimetry of polymers)
    • IEC 61249 (Epoxy and benzoxazine composite base materials)

    Typical usage ratio

    • Equimolar ratio with phenolic precursor
    • Stoichiometry control critical for molecular weight distribution
    • Adjustments up to +5% diamine for increased crosslink density
    • Careful monitoring of residual free amine in final resin

    Downstream process integration

    • Benzoxazine prepolymer preparation with in-situ amine addition
    • Blend incorporation into prepreg or bulk molding compounds
    • Thermal cure cycles under nitrogen atmosphere
    • Post-cure at elevated temperature to achieve final crosslink density

    Final product types

    • High-performance composite panel prepregs
    • Printed wiring board laminates
    • Low-smoke, halogen-free insulation panels
    • Flame-retardant building claddings
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    Certification & Compliance
    More Introduction

    Experience and Craftsmanship with 1,4-Bis(Aminomethyl)Benzene

    Decades in Synthesis: The Perspective of a Chemical Manufacturer

    Years on the production floor give a different appreciation of a molecule like 1,4-Bis(Aminomethyl)Benzene (also known among chemists as p-Xylylenediamine or PXDA). This aromatic diamine isn’t new in the specialty chemicals field, but every batch still calls for meticulous detail and a deep understanding of what customers count on. Seen up close, PXDA brings a point of reliability as a hardener, chain extender, or intermediate; our familiarity with its strengths comes directly from scaling up synthesis and fine-tuning quality from batch one to shipment.

    Molecular Identity and the Built-In Advantages

    We take pride in delivering a product marked by its structure—an aromatic backbone with amine groups bonded to the para positions. This geometry unlocks a balance of chemical reactivity and physical stability. In the plant, it’s more than a formula; it’s the blueprint guiding each adjustment. With a molecular weight roughly 162.23 g/mol and a melting point typically between 79 and 82°C, each specification shapes the way the compound interacts with epoxies and polyurethanes or contributes to advanced resins.

    Achieving consistency in crystalline form starts much earlier than anyone outside the industry might think. From feedstock sourcing through hydrogenation and purification, every step shifts the purity and performance. The aromatic ring absorbs some of the mechanical stresses in final products, while linear amine groups react smoothly in formulations, whether in adhesives or coatings. The subtlety of its reactivity often surprises first-time users—a benefit that only becomes clear with hands-on formulation trials.

    Standards that Shape the End Result

    Comparison with aliphatic diamines or more traditional aromatic hardeners highlights what makes PXDA stand out. Aliphatic options like hexamethylenediamine bring faster cure rates but tend to sacrifice thermal stability. Our experience sees PXDA leading in projects demanding resistance to heat and certain chemicals. The aromatic core slows down yellowing under UV and prevents excessive softening when composites undergo long-term use, especially in automotive and electronic applications.

    Recent years brought more attention to process control. Our teams routinely reach purities above 99%, with careful removal of by-products and color bodies. This level of detail holds importance for end users: cleaner diamine means fewer surprises in polymer properties and better batch-to-batch tracking. The industry shifts toward more demanding applications—high-temperature resins, electrically insulating epoxies, and tough coatings—have only deepened our commitment to real, verifiable purity.

    Why Purity and Traceability Matter in Advanced Manufacturing

    Industry knowledge comes from seeing how even small deviations can ripple through a production line. When resins underperform, partners often trace the problem back to minute impurities or inconsistent melting points. By controlling our entire manufacturing and QA pipeline, we spot tiny shifts in crystallinity or moisture pick-up before they cause large-scale material failures.

    We don’t just run standardized HPLC or GC scans—experienced eyes still watch for color shifts or odor changes as early quality flags. Batch logs track everything, from pressure changes in reactors to filtration times. It’s this kind of documentation that lets downstream industries—composite fabricators, electronics manufacturers, adhesive formulators—trust the resin’s final performance and repeat complex fills or cures without surprise.

    Product in Application: Satisfying Real-World Demands

    Real chemistry happens at the intersection of material science and field need. The amine groups in 1,4-Bis(Aminomethyl)Benzene form robust links with epoxy resins, toughening the network and boosting resistance to cracking. Electrical engineers value the way it restricts ionic migration, helping prevent insulation breakdown in circuit boards. Polyurethane manufacturers lean on its ability to impart rigidity and dimensional stability—especially important for components exposed to high-cycle loads or thermal swings.

    Whereas other diamines can emit strong odors or sensitize operators, our customers have noted PXDA’s relative mildness in handling. Good environmental controls and dust management during synthesis minimize particulate drift, helping teams deliver a cleaner working environment. Sometimes this goes overlooked in public datasheets, but years on a production floor reinforce how such factors sit at the core of safe, practical chemistry.

    Comparing PXDA to Other Amines—Where Differences Shape Outcomes

    In an industry with many options, choosing between diamines is more than splitting hairs. Aliphatic diamines like ethylenediamine appeal for their cost and rapid reaction rates, but in actual composites or adhesives, the trade-off often becomes clear. Customers report better aging properties in PXDA-cured epoxies. Our own testing finds higher thermal limits and lower volatility, so long-term durability wins out over speed of cure.

    Aromatic diamines come in a few common flavors. p-Phenylenediamine shares structural rigidity but lacks the methyl-amine extensions of PXDA, which offer a little more flexibility and slightly altered melting behavior. Methylene dianiline (MDA) draws attention for thermal strength, but its toxicity profile and regulatory scrutiny make PXDA a safer choice in most open plant operations. The difference often doesn’t stand out until process risk analyses and worker safety tallies start stacking up.

    Customers sensitive to impurities—such as color or secondary amine content—see faster qualification cycles with our PXDA than with imports that lack batch-level transparency. The shift toward stricter emission control and REACH compliance only underlines the importance of traceable production and minimized secondary side-products.

    Operational Commitments: Balancing Throughput and Quality

    Managing throughput on a 24/7 synthesis line for PXDA isn’t as simple as dialing up reactor speeds. Over the years, our teams learned how weather, humidity, and even seemingly minor feedstock shifts can nudge yields or crystal morphology. Line operators run manual sampling alongside continuous analytics, pairing sensors with trained judgment. Our maintenance on reactors, chromatographic purification trains, and utility systems feeds straight back into output purity and reliability.

    Small details—like how a precipitation tank is drained, or where a technician checks the seed batch—help avoid formation of dust-prone ultra-fine crystals, which can clump or degrade packing efficiency. Even logistics ties into this: experienced warehouse staff rotate and climate-control storage, minimizing clumping or loss of flow.

    Supporting Progress in Advanced Materials and Sustainability

    Markets shape products. A decade ago, much PXDA left our warehouse bound for brake pads or legacy adhesives. Now, specialty polymers and high-performance coatings command tighter tolerances. Applications like wind turbine blades, compact electrical insulators, or scratch-resistant automotive surfaces lean on reliable diamine chemistry—an area where process improvements directly map to end-product value.

    Growing environmental awareness and pressure to reduce hazardous chemicals push research toward greener chemistry. Our technical teams have piloted both process optimizations (to minimize waste and energy) and green feedstocks. Instead of chasing cost savings through cuts, we've looked at solvent recovery loops, spent catalyst re-use, and water conservation, all steps that have tightened our process and reduced overall impact. In finished goods—especially in parts destined for electronics or lightly regulated consumer spaces—these improvements reduce emissions without sacrificing technical quality.

    Research Partnerships and Industry Dialogue

    We see ourselves as more than producers. Across pilot programs with customers, academia, and equipment suppliers, we have supplied custom grades—higher purity, controlled particle size, or tailored melting range. Through these partnerships, our chemists gain feedback on how different resin combinations or fill ratios respond to minor composition tweaks, closing the gap between theory and practical formulation.

    Technical service isn’t just a helpline. Our engineers visit customer plants, walk the floor, and see how mixing, curing, and post-processing steps fit into full production runs. These observations drive our in-house research, whether in lowering dust, anti-caking, or exploring new surface passivation techniques to cut discoloration. Trust builds through these shared projects; a reliable supply chain means little if the material doesn’t perform as advertised in application trials.

    Customer Impact on Product Direction

    Feedback loops from end-users keep us honest and progressive. One electronics customer flagged ionic leaching in their application, prompting us to refine rinse stages and adjust a key filtration point, directly lowering their product rejection rates. In adhesives destined for passenger safety systems, one vehicle OEM’s demand for even higher clarity and color stability drove us to raise bar in pigment and secondary amine controls.

    Not everyone sees the behind-the-scenes work that goes into what the industry calls a “standard” product. Years spent tuning particle size, moisture limits, or batch labeling can seem minor next to big-ticket launches, yet they keep supply chains humming and avoid costly recalls or down-line rework. As regulations evolve, particularly in Europe and North America, this approach ensures our PXDA keeps passing both legacy and next-generation compliance hurdles.

    Challenges in a Changing Regulatory and Supply Landscape

    In procurement meetings, price usually ranks high, but experience teaches that security of supply and reliability often prove more valuable. Raw materials for PXDA sometimes face volatile pricing or sudden shortages. Our local sourcing channels and in-house contingency stores allow us to buffer customers against spikes or production hiccups—something that became especially critical during global logistics disruptions in recent years.

    On the regulatory side, ever-tightening chemical handling standards challenge us to improve documentation, labeling, and site safety. Our investment in data logging and digital QA systems allows point-to-point traceability for every batch, easing audits and ensuring customers can demonstrate compliance right down to the original drum’s fill time.

    Looking Ahead: Opportunities in Market and Science

    As requirements for more demanding polymers and composites grow, 1,4-Bis(Aminomethyl)Benzene’s profile continues to rise. Advanced manufacturers seek intermediates that bond physical and chemical stability with real field performance—the terrain where a finely produced PXDA shines. Its dual amine structure allows new block copolymer configurations; in composites exposed to weather or aggressive chemicals, our customers have drawn value from its resistance to hydrolysis.

    Our R&D teams dig into potential derivatizations and blend systems, collaborating with formulators building tomorrow’s electronics, transportation, and clean energy infrastructure. Even as new production technologies drive down impurities, the market’s interest in greener, safer alternatives builds demand for chemistries like PXDA, especially when delivered by manufacturers with open, defensible process records.

    Production Realities and Day-to-Day Experience

    No amount of laboratory work replaces time in a full-scale plant setting. Operators here know the rhythm of a well-run PXDA train. They react to subtle cues—steam hiss, pump vibration, vessel temperatures—keeping each parameter inside specifications. Plant managers review daily logs, watch trends, run extra spot-checks after weather events, and coordinate shifts to capture peak yields. Years of shared lessons get codified in work instructions and training sessions for the next generation, blending deep product memory with evolving technique.

    Respect for the complexity of even a “simple” aromatic diamine keeps our focus on continuous improvement. We revisit every repeat customer issue, benchmark ourselves against leading regulatory bodies, and watch emerging science for signs of what might outpace PXDA in future applications. For now, the blend of stability, reactivity, and operational reliability gives 1,4-Bis(Aminomethyl)Benzene a long runway—a truth known best in factories where theories meet daily practice.

    Conclusion: Craft Values in Modern Chemical Manufacturing

    Every kilogram of PXDA represents patient work from a supply chain that stretches from raw feedstock through shipment to customers’ gates. Our vantage point as manufacturers grounds every decision—from purity tweaks and packaging, to logistics and support post-sale. Years spent responding to customer needs, regulatory tightening, and rapid advances in materials science teach us one lesson above all: stewardship of both product and process drives reputation and reliability. PXDA continues to enable progress in tomorrow’s applications, built on the backbone of today’s manufacturing craft.